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Publication numberUS20020170460 A1
Publication typeApplication
Application numberUS 10/137,847
Publication dateNov 21, 2002
Filing dateMay 2, 2002
Priority dateOct 24, 2000
Also published asCA2426814A1, CA2426814C, DE60132673D1, DE60132673T2, DE60132673T3, EP1337684A1, EP1337684A4, EP1337684B1, EP1337684B2, US6399152, WO2002034961A1
Publication number10137847, 137847, US 2002/0170460 A1, US 2002/170460 A1, US 20020170460 A1, US 20020170460A1, US 2002170460 A1, US 2002170460A1, US-A1-20020170460, US-A1-2002170460, US2002/0170460A1, US2002/170460A1, US20020170460 A1, US20020170460A1, US2002170460 A1, US2002170460A1
InventorsGary Goodrich
Original AssigneeGoodrich Gary D.
Export CitationBiBTeX, EndNote, RefMan
External Links: USPTO, USPTO Assignment, Espacenet
Chrome coating composition
US 20020170460 A1
Abstract
A metallic coating composition and vacuum metalization process for applying the coating composition on aluminum and steel substrates, for example on vehicle wheels, hub caps, bumpers and the like. The process is environmentally compatible and produces a decorative, wear-resistant chrome finish and comprises four stages: a cleaning or preparation stage, a base coat application stage, a two-step PVD stage, and a topcoat application stage. An organic epoxy, thermosetting powder base coat is applied to smooth the surface to a glass-like finish and to ensure adhesion of the metal coatings. A two part metal coating is applied via a PVD process, consisting of a Ni/Cr base and a Cr layer. A protective acrylic, thermosetting topcoat is applied to protect the metal coating layers.
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Claims(20)
That which is claimed is:
1. A metallic coating composition for a prepared aluminum or steel substrate comprising:
a) a first stabilizing metallic layer, said first stabilizing metallic layer comprising a mixture of approximately 50-80% Nickel and 50-20% Chromium;
b) a second metallic layer applied to said first stabilizing metallic layer, said second metallic layer comprising approximately 99% Chromium; and
c) a top protective layer applied to said second metallic layer.
2. The metallic coating composition of claim 1, wherein said top protective layer is an acrylic thermosetting powder and is cured at an approximate range of 320-360° C.
3. The metallic coating composition of claim 1, further comprising a base coat beneath said first stabilizing metallic layer.
4. The metallic coating composition of claim 3, wherein said base coat is a thermosetting powder.
5. The metallic coating composition of claim 1, wherein said first stabilizing metallic layer and said second stabilizing metallic layer have a combined thickness of approximately 350-600 Å.
6. The metallic coating composition of claim 1, wherein said first metallic layer and said second metallic layer are applied via a vapor deposition process.
7. The metallic coating composition of claim 1, wherein said coating composition on the aluminum or steel substrate is for use in the automotive industry.
8. A metallic coating composition for a substrate comprising:
a) a first metallic layer, said first metallic layer comprising a mixture of approximately 50-80% Nickel and 50-20% Chromium; and
b) a second metallic layer applied to said first metallic layer, said second metallic layer comprising approximately 99% Chromium.
9. The coating composition of claim 8, further comprising a base coat beneath said first metallic layer and a top coat applied over said second metallic layer.
10. The coating composition of claim 9, wherein said base coat is a thermosetting powder and wherein said top coat is an acrylic thermosetting powder.
11. The coating composition of claim 8, wherein said first metallic layer and said second metallic layer have a combined thickness of approximately 350-600 Å.
12. The coating composition of claim 8, wherein said substrate is aluminum or steel and wherein said first metallic layer and said second metallic layer are applied via a vapor deposition process.
13. A layered coating composition for a prepared substrate comprising:
a) a first layer applied via a vacuum vapor deposition process, wherein said first layer is comprised of two metals, a first metal and a second metal, and wherein said first layer is comprised of approximately 50-80% of said first metal and approximately 50-20% of said second metal; and
b) a second layer applied over said first layer via a vacuum vapor deposition process, wherein said second layer is comprised of approximately 99% of said second metal.
14. The coating composition of claim 13, wherein said prepared substrate is made of metal.
15. The coating composition of claim 14, wherein said metal is aluminum or steel.
16. The coating composition of claim 13, wherein said first metal is Nickel.
17. The coating composition of claim 13, wherein said second metal is Chromium.
18. The coating composition of claim 13, wherein a third layer is applied over said second layer and wherein said third layer is a protective top coat layer.
19. The coating composition of claim 13, wherein a base coat is applied onto the substrate beneath said first layer is applied.
20. The coating composition of claim 13, wherein said layered coating composition on said substrate is utilized in the automotive industry.
Description
  • [0001]
    This application is a Division of Applicant's co-pending application U.S. Ser. No. 09/695,509, filed Oct. 24, 2000 and titled Vacuum Metalization Process For Chroming Substrates, which application is pending, and which is incorporated by reference herein.
  • BACKGROUND OF THE INVENTION
  • [0002]
    This invention relates generally to a coating composition and a process for providing a chrome finish onto substrates. Particularly, the invention relates to a metallic coating composition and a process for vacuum metalizing chromium onto metal substrates. Specifically, this invention relates to a two step vacuum metalization process for chroming aluminum and steel substrates for automotive parts, for example, for providing a chrome layer on automotive parts such as vehicle wheels, hub caps, bumpers, and the like.
  • [0003]
    The metalization process of the present invention has specific and sequential steps to produce chromed aluminum and steel automotive parts having superior chrome adhesion characteristics to prevent delaminations and having chemical and road hazard resistant qualities. Although the disclosure herein discusses the process of metalizing chromium in the production of vehicle wheels, other chroming processes as well as the chroming of other metal substrates are within the purview of this invention.
  • [0004]
    In the past, aluminum and steel vehicle wheels, for example, have traditionally been electroplated to produce chrome wheels. These prior art processes require the wheel rim to be polished to provide a very smooth surface for the chrome plating to be effective. Further, the wheels are pretreated in hazardous chemicals to provide a clean and homogeneous surface for adherence of the chrome plating. The wheels are then coated with up to three different metal coatings with each step requiring the wheel to be submerged in hazardous solutions. The failure rate of these prior art processes is generally high. Additionally, should the chrome plated surface be damaged, corrosion or rust will typically begin rapidly, causing the chrome plating to delaminate from the wheel surface.
  • [0005]
    Another alternative prior art process has been developed which applies the chrome coating by vacuum metalization, thereby eliminating the application of the decorative coating using hazardous solutions. This prior art process entails applying one or two primer coat compositions to provide a smooth surface and to provide a suitable adhesion for the Cr to be applied. The wheel is then placed into a vacuum metalization chamber where a decorative coating is applied. Subsequently, a coating is applied to protect the metalized layer from environmental elements. The process produces chrome-like finishes on wheels, but not equal to the quality of the plating process and as such has not been accepted by the wheel manufacturers in the United States.
  • [0006]
    The present invention has overcome the difficulties and the shortcomings of the prior art. An object of the present invention is to provide a true chrome finish on wheels and the like that will be resistant to harsh climatic conditions. A further objective is to eliminate hazardous materials used during the application process and to greatly reduce the potential for delamination should the coating be damaged, impacted or scratched, as has been a problem with the prior art. This process is also applicable to any substrate where a durable, decorative, chrome finish is desired on automotive parts, for example, on vehicle wheels, bumpers, hub caps, and the like. Particularly, the object of the invention is to provide a vacuum metalization process for chroming metal substrates, such as aluminum and steel substrates.
  • SUMMARY OF THE INVENTION
  • [0007]
    The present invention relates to a metallic coating composition and a process for chroming aluminum and steel substrates. The process of the invention utilizes a vacuum metalizing process which, preferably, comprises four stages: a cleaning or preparation stage utilizing a number of steps, a base coat application stage, a two-step Physical Vapor Deposition (PVD) stage, and a top coat application stage. Each stage utilizes specific process steps and uses particular formulations under specific process step parameters.
  • [0008]
    An aluminum or steel substrate or object, for example a vehicle wheel, to receive a decorative chrome coating is first cleaned to eliminate contamination. The base coat applied in the base coat application stage is preferably an organic, thermosetting powder or the like and provides a smooth surface for Nickel/Chromium adhesion, however, an inorganic compound may be utilized. Alternatively, the base coat may be comprised of an electroplated coating, or e-coating. The wheel and base coat are heated to permit the coating to melt and flow evenly across the surfaces of the wheel. The temperature is then increased so that the organic powder will crosslink and solidify. The wheel temperature is then reduced in preparation for the two-step PVD stage.
  • [0009]
    To begin the two-step PVD stage, the wheel is placed into a PVD chamber to receive the chrome coating layer. The PVD stage consists of two steps. Both steps take place in vacuum conditions and by a sputtering or similar process, for example. The first step comprises sputtering an approximately 80% Nickel (Ni) and 20% Chromium (Cr) base metal layer onto the base coat on the wheel. The second step comprises sputtering an approximately 99.9% pure Chromium layer onto the metal base layer. As known in the art, various PVD and CVD processes are known utilizing metallic targets in vacuum conditions. Any such known processes may be utilized to deposit the Nickel/Chromium and Chromium layers according to the teachings of the invention.
  • [0010]
    The protective top coat applied in the topcoat application stage is preferably a clear, organic, thermosetting powder, although an inorganic compound and means to produce a colored finish may also be utilized. Alternatively, the top coat may be comprised of an electroplated coating, or e-coating. The top coat is applied to the wheel to cover the Chromium layer and is subsequently heated to cause crosslinking and solidification. The wheel is then permitted to cool down.
  • [0011]
    The vacuum metalization process of the present invention permits a decorative, chrome coating to be applied to a metal object, for example an aluminum or steel wheel, in an environmentally compatible manner without the use of hazardous chemicals and which is resistant to harsh climatic conditions and delamination. These and other benefits of this invention will become clear from the following description by reference to the drawings.
  • BRIEF DESCRIPTION OF THE DRAWINGS
  • [0012]
    [0012]FIG. 1 is a flow diagram showing the steps of the process of the present invention; and
  • [0013]
    [0013]FIG. 2 is a cross-sectional view of a substrate showing the coating layers formed thereon from the process of the present invention.
  • DESCRIPTION OF THE PREFERRED EMBODIMENTS
  • [0014]
    The present invention relates to a coating composition and a process of chroming aluminum and steel substrates, and particularly to the vacuum metalization of chromium onto aluminum or steel substrates. The process of this invention provides a decorative and durable chrome finish for aluminum or steel objects, for example vehicle wheels, hub caps, bumpers, or the like which is conducted in an environmentally compatible manner.
  • [0015]
    Although it is within the purview of this invention to provide a vacuum metalization process for chroming aluminum and steel substrates to produce articles exhibiting strong adhesion qualities of the metalized chrome and useful for a variety of articles, the chroming of an aluminum or steel wheel for automotive use will be used herein to describe the process stages and steps of the invention.
  • [0016]
    Referring to FIG. 1, the four steps comprising the process of the present invention are set forth. The four general steps of the process are as follows: 1) Cleaning or Preparation Stage, 2) Base Coat Application Stage, 3) Two-Step PVD Stage and 4) Top Coat Application Stage.
  • Cleaning and Preparation Stage
  • [0017]
    The Cleaning and Preparation Stage 1 as shown in the process flow diagram of FIG. 1 is comprised of process steps. The cleaning and preparation stage steps provide a proper or prepared metal surface for the remaining stages of the process of the invention.
  • BASE COAT APPLICATION STAGE
  • [0018]
    The Base Coat Application Stage 2 is shown in FIG. 1. The base coat preferably consists of a hybrid epoxy, thermosetting powder coating or the like. However, the base coat used in this step may be comprised of an organic or inorganic chemical composition. The base coating may also be comprised of an electroplated coating or e-coating. E-coatings are generally applied in liquid form via an electroplating process whereby the substrate is either submerged in a dip tank under specified electrically charged conditions or is sprayed with the liquid e-coating material and then heated for curing purposes.
  • [0019]
    Referring to FIG. 1, the wheel is coated in the horizontal face up position to ensure even and smooth coverage. By applying the powder at the elevated temperature of approximately 150° F. to 250° F., the powder begins to melt on the wheel upon application. This process step accomplishes several advantages: it ensures that all areas are coated and that the pores of the aluminum or steel are still in an outgased stage, it enables a thinner coat to be applied, and it reduces the time to preheat the metal in the next step. The desired thickness of the base coat is approximately 1.5 to 5.0 mils. The wheel is next preheated to an approximate temperature range of 285° F. to 310° F. after which it remains in that temperature range for a period of approximately 8 to 12 minutes. During this phase step the powder continues to melt and flow evenly across all wheel surfaces. Temperature fluctuations above the desired range will cause the flow-out process to stop, while fluctuations below can cause thermal shock and effect the smoothness of the surface. Variations in time, outside the parameters will typically result in an uneven, wavy or orange peal type finishes.
  • [0020]
    The wheel is next preheated to a temperature range of approximately 445° F. to 475° F., after which it remains at that temperature for a period of approximately 13 to 20 minutes. During this step the powder crosslinks and solidifies. If the temperature or time is reduced, typically evidenced by a light, transparent brown appearance, the surface will experience some movement during the curing of the top coat stage and thereby cause cracking in the Cr coating. If the temperature or time exceeds the parameters as typically evidenced by a black, non-transparent appearance, the surface will become too brittle and may separate from the wheel during the top coat stage and/or reduce its ability to absorb impacts causing premature coating failure. A properly cured base coat has a dark, transparent brown appearance on completion of the base coat curing. The wheel is next cooled to a temperature range of approximately 100° F. to 250° F., in preparation for the metalization process. By keeping the wheel at an elevated temperature, the metalization layers adhere better to the organic base coat, for example, and it provides a brighter (lighter color) to the Cr coating.
  • Two-Step PVD Stage
  • [0021]
    The wheel is next placed into a Physical Vapor Deposition (PVD) chamber for metalization. The chamber is equipped with Ni/Cr targets and Cr targets. Sufficient targets are arranged so that one of each type target will cover 100% of the wheel as the wheel is rotated on its axes in the chamber, to ensure complete coverage. The pressure in the chamber is then reduced to a pressure of approximately 0.2 to 0.75 mTorr to evacuate any moisture, outgas chamber walls and wheel base coat, and to create a vacuum environment. Argon, of approximately 99.99% purity is then injected into the chamber to bring the pressure up to approximately 2.5 to 3.5 mTorr, in order to create a plasma environment. At this step, a base metal layer consisting of approximately 50% to 80% Ni and approximately 50% to 20% Cr is applied by sputtering for approximately 10 to 20 seconds at approximately 700 volt, 17 amps and 12 kW. These process step parameters are exemplary and vary depending upon the type of PVD machine and power supply utilized in the PVD machine. For example, changes in the power supply would change the time and voltage required. A lower content of Ni and a higher content of Cr in a target will produce a lighter color on the second (Cr) metalization layer. The base metal coating of this invention step provides a stable base for the Cr to be applied over. Samples without the Ni/Cr base developed cracks in the final step of heating the wheel to cure the top coat.
  • [0022]
    The pressure in the chamber is then reduced to a pressure of approximately 1.5 to 3.5 mTorr, in preparation for applying the Cr metal coating. Cr of approximately 99.99% purity is then applied by sputtering for approximately 5 to 10 seconds at approximately 620 volts, 19 amps and 12 kW. These process steps are exemplary depending upon PVD machine type, power supply, size of targets and chamber pressure, etc. During the Ni/Cr application the Cr target will be charged in a range of approximately 0.25 kW to 0.3 kW, and during the Cr application the Ni/Cr target is charged in a range of approximately 0.04 kW to 0.05 kW to prevent contamination from each other. The desired thickness of the combined two metal layers is about 350 Å to 600 Å. On completion of the base and top coat the chamber is vented back to atmospheric pressure using compressed air that is heated, dried and filtered. Using the processed air to vent the chamber prevents contamination of the chamber's interior. The wheel is then removed from the vacuum chamber for application of the protective, clear organic top coat, for example. The two-step PVD stage set forth herein is exemplary and the NiCr and Cr layers may be deposited onto the prepared substrate surface in any known manner including for example, by Arc, CVD or similar methods of vacuum metalization. The important aspect of this stage being the use of the sequential NiCr and Cr layers onto the prepared substrate surface.
  • [0023]
    As known in the art, various PVD and CVD processes are known utilizing metallic targets in vacuum conditions and employing magnetrons to produce magnetic fields for concentrating the deposit of the metal ions to the object. For example, a planar magnetron configuration has been found suitable in the two-step PVD process of the present invention. Thus, a planar magnetron sputtering source or one having a flat or planar shaped target has been found suitable in accordance with the process of this invention. However, other vacuum metalization processes may also be utilized in the chroming of aluminum and steel substrates process of this invention.
  • Topcoat Application Stage
  • [0024]
    The Topcoat Application Stage 4 is shown in FIG. 1. The clear organic top coat application preferably consists of an acrylic, thermosetting powder coating or the like. The purpose of the topcoat is to provide protection to the metal coatings, wear resistance and UV protection. The topcoat may have an organic or inorganic chemical composition. The top coating may also be comprised of an electroplated coating or e-coating. The e-coating provides a scratch resistant top coat for the chrome layer applied in the two-step PVD process of the invention. E-coatings are generally applied in liquid form via an electroplating process whereby the chromed substrate is either submerged in a dip tank under specified electrically charged conditions or is sprayed with the liquid e-coating material and then heated for curing purposes.
  • [0025]
    The wheel is coated in the horizontal face up position to ensure even and smooth coverage. The desired thickness of the coating is in a range of approximately 2.0 to 3.0 mils. The clear top coat is applied at a temperature range between approximately 80° F. to 200° F. Temperatures exceeding these parameters will cause the Cr layer to darken. After application of the clear top coat, the wheel is preheated to an approximate temperature range of 320° F. to 360° F., after which it will remain at that temperature for a period of approximately 15 to 20 minutes. During this method step, the powder will crosslink and solidify. The wheel then enters a cool down chamber where filtered air cools the wheels to ambient temperature.
  • [0026]
    [0026]FIG. 2 shows a cross-section of the layers formed on the chromed substrate 10 as a result of the process steps of the present invention. The wheel or substrate 11 is shown to have a base coat layer 12, a Ni/Cr metal layer 13, a Cr layer 14, and a top coat layer 15. The base coat 12 is preferably a hybrid epoxy, thermosetting powder or the like. The Ni/Cr layer 13 and the Cr layer 14 are formed in the two-step PVD process and are, together, preferably approximately 350 Å to 600 Å in thickness. The top coat is preferably an acrylic, thermosetting powder coating or the like, however, organic or inorganic top coat compositions may be utilized as previously discussed.
  • [0027]
    The discussion above regarding the base coat application stage and the top coat application stage, particularly with respect to FIG. 1, relates respectively to the application of a hybrid epoxy, thermosetting powder coating for the base coat and the application of an acrylic thermosetting powder coating for the top coat. The application of these base coat and top coat formulations require specific process parameters, i.e., temperatures, times, etc., as set forth in FIG. 1. As also discussed herein, other base coat and top coat formulations may also be used in the metalization process of the invention. The application parameters of these base coat and top coat formulations would be different from those discussed with respect to FIG. 1 and are generally set by the manufacturers of the coating formulations.
  • [0028]
    Although a clear top coat has been discussed in the process of the invention, various colored tints may also be utilized on the chromed layer produced in this invention. For example, the top coat itself may be tinted with a color, or a color may be provided to the object itself during the PVD process. For example, the introduction of a gas such as Argon, Nitrogen, or the like in the PVD process, as known in the art, will produce a specified color to the object.
  • [0029]
    A wheel coated using the process of the present invention produced the following test results:
    1) Salt Spray Test (ASTM B-117) 480+ Hours
    2) Adhesion (ASTM D-3359) 100%
    3) Pencil Hardness (ASTM D-3363) H-2H
    4) Thermal Cycle (GM 264M) Passed
  • [0030]
    In summary, the process of the present invention provides a Preparation Stage 1, a Base Coat Application Stage 2, a Two-Step PVD Stage 3, and a Top Coat Application Stage 4. The process produces or forms metallic layers or a chrome coating on a surface, preferably aluminum or steel, of an object, such as vehicle wheels, hub caps, bumpers and the like, on which it is desirable to have a decorative chrome finish. The process of this invention is conducted without the use of hazardous chemicals, making it environmentally friendly, and produces a chrome finish which is resistant to the elements and has a reduced potential for delamination.
  • [0031]
    As many changes are possible to the embodiments of the processes of this invention utilizing the teachings thereof, the descriptions above, and the accompanying drawing should be interpreted in the illustrative and not in the limited sense.
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Referenced by
Citing PatentFiling datePublication dateApplicantTitle
US7150923 *Nov 17, 2004Dec 19, 2006Goodrich Technology CorporationChrome coating composition
US7235167Feb 4, 2005Jun 26, 2007Dr. Ing. H.C.F. Porsche AktiengesellschaftMethod for the manufacture of corrosion resistant and decorative coatings and laminated systems for metal substrates
US7297397Jul 22, 2005Nov 20, 2007Npa Coatings, Inc.Method for applying a decorative metal layer
US8123967Jul 1, 2008Feb 28, 2012Vapor Technologies Inc.Method of producing an article having patterned decorative coating
US9138776Jun 7, 2006Sep 22, 2015Sidasa Engineering, S.L.Process for applying coatings with metallic chromium
US20050067273 *Nov 17, 2004Mar 31, 2005Goodrich Gary D.Chrome coating composition
US20050175785 *Feb 4, 2005Aug 11, 2005Dr. Ing. H.C. F. Porsche AktiengesellschaftMethod for the manufacture of corrosion resistant and decorative coatings and laminated systems for metal substrates
US20060019089 *Jul 22, 2005Jan 26, 2006Npa Coatings, Inc.Method for applying a decorative metal layer
US20070020396 *Jun 7, 2006Jan 25, 2007Analisi Tecnologica Innovadora Per A Processos.Process for applying coatings with metallic or ceramic finish
CN1651607BFeb 7, 2005Jan 18, 2012F.波尔希名誉工学博士公司Process for the production of corrosion resistant decorative coatings and coating systems for substrates of light-metal
DE102004006127A1 *Feb 7, 2004Aug 25, 2005Dr.Ing.H.C. F. Porsche AgVerfahren zur Herstellung von korrosionsbeständigen und dekorativen Beschichtungen und Schichtsystemen für Substrate aus Metallen
WO2004061159A2 *Jan 6, 2004Jul 22, 2004Bergmann ErichMulti-layer coating which is used to protect parts against corrosion, method of producing one such coating and part comprising same
Classifications
U.S. Classification106/1.12, 106/1.22, 106/1.27, 106/1.25
International ClassificationC23C28/00, B05D5/06, C23C14/16, C23C14/02
Cooperative ClassificationB05D5/068, C23C14/165, C23C14/025, C23C28/00
European ClassificationC23C28/02B, C23C28/02A, B05D5/06T3, C23C14/02B2, C23C14/16B, C23C28/00