US20040017449A1 - Aqueous latent image printing method and aqueous latent image printing ink for use therewith - Google Patents
Aqueous latent image printing method and aqueous latent image printing ink for use therewith Download PDFInfo
- Publication number
- US20040017449A1 US20040017449A1 US10/202,423 US20242302A US2004017449A1 US 20040017449 A1 US20040017449 A1 US 20040017449A1 US 20242302 A US20242302 A US 20242302A US 2004017449 A1 US2004017449 A1 US 2004017449A1
- Authority
- US
- United States
- Prior art keywords
- printing composition
- latent image
- salt
- printing
- humectant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
- C09D11/38—Inkjet printing inks characterised by non-macromolecular additives other than solvents, pigments or dyes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M3/00—Printing processes to produce particular kinds of printed work, e.g. patterns
- B41M3/14—Security printing
- B41M3/142—Security printing using chemical colour-formers or chemical reactions, e.g. leuco-dye/acid, photochromes
Definitions
- the present invention relates to the field of security printing, in general, as well as to the field of ink jet printing and compositions useful therein.
- This invention particularly relates to an aqueous latent image printing method and an aqueous latent image printing ink for use therewith.
- aqueous latent image printing method information is printed on a substrate, such as paper, which is transferred in the form of a latent image or “secure image” which is invisible to the eye and any other usual image detecting device at the time of printing, and is revealed only after the substrate is subjected to a subsequent process of image activation.
- Invisible inks have existed for many years. Many such ink systems have been found, developed and used in a limited way mainly because of the limited accessibility of such invisible inks and delivery systems for the latter.
- Ink jet printing systems generally are of two types: continuous stream and drop-on-demand.
- continuous stream ink jet systems ink is emitted in a continuous stream under pressure, through at least one orifice or nozzle.
- drop-on-demand systems a droplet is expelled from an orifice directly to a position on a recording medium in accordance with digital data signals. Since drop-on-demand systems require no ink recovery, charging, or deflection, the system can be much simpler than the continuous stream type.
- drop-on-demand ink jet systems There are two types of drop-on-demand ink jet systems.
- One type of drop-on-demand system has as its major components an ink filled channel or passageway, having a nozzle on one end and a piezoelectric transducer near the other end to produce pressure pulses.
- the other type of drop-on-demand system is known as thermal ink jet, or bubble jet, and produces high velocity droplets and allows very close spacing of nozzles.
- the major components of this type of drop-on-demand system are an ink filled channel having a nozzle on the open end and a heat generating resistor near the nozzle.
- the drop-on-demand ink jet printers provide simpler, lower cost devices than their continuous stream counterparts, and yet have substantially the same high speed printing capability.
- Thermal ink jet processes are well known and are described in, for example, U.S. Pat. No. 4,601,777, U.S. Pat. No. 4,251,824, U.S. Pat. No. 4,410,899, U.S. Pat. No. 4,412,224, and U.S. Pat. No. 4,532,530.
- U.S. Pat. No. 5,395,432 teaches the use of certain ink jet compositions for use in printing latent images an a substrate.
- ink jet compositions comprising zinc chloride are taught for use in making latent images.
- a problem associated with those formulations, however, is their corrosiveness to metal parts of the printing apparatus with which the ink comes into contact.
- U.S. Pat. No. 5,935,308 purports to address this problem.
- the '308 patent teaches the use of certain ink jet compositions for use in printing latent images on a substrate.
- ink jet compositions comprising zinc bromide and preferably tetraethylammonium p-toluene sulfonate (“TEA p-TS”) are taught for use in making latent images.
- TEA p-TS tetraethylammonium p-toluene sulfonate
- the present invention provides an aqueous latent image printing method comprising applying to a substrate, such as paper, a latent image ink composition, via an ink jet printer. Subsequently, the latent image is activated to render it visible, by application of an activator.
- Embodiments of the present invention are particularly suitable for security printing on a substrate which enables the free flow of information without the concern for fraud.
- the information that is printed on a substrate is invisible to the naked eye, and cannot be revealed without the use of an activator.
- This method is particularly useful for authentication and identification of financial transactions on the internet, such as checks, to secure the privacy of the user.
- the present invention provides a printing composition
- a printing composition comprising an aqueous medium, i.e. water, a hydroquinonesulfonic acid salt, and a humectant
- Suitable humectants typically include organic materials miscible with water.
- the preferred humectant of the present invention is polyethylene glycol.
- suitable humectants that can be used include ethylene glycol, propylene glycol, diethylene glycols, glycerine, dipropylene glycols, polypropylene glycols, amides, urea, substituted ureas, ethers, carboxylic acids, esters, alcohols, organosulfides, organosulfoxides, sulfones (such as sulfolane), alcohol derivatives, carbitol, butyl carbitol, cellusolve, ether derivatives, amino alcohols, ketones, N-methylpyrrolidinone, 2-pyrrolidinone, cyclohexylpyrrolidone, hydroxyethers, amides, sulfoxides, lactones, and other water miscible materials, as well as mixtures thereof.
- the preferred latent image former is hydroquinonesulfonic acid salt.
- the amount of hydroquinonesulfonic acid salt used in the latent ink formulations can vary over a wide range, depending on the intensity of the latent image that is desired, and the solubility of the hydroquinonesulfonic acid salt in the aqueous medium. Typically, the amount of hydroquinonesulfonic acid salt present will vary from about 0.5 percent up to about 7 percent, with the preferred amount being 3 to 7 percent.
- the present printing composition can be printed on a substrate, for example, paper via a conventional printing process, preferably an ink jet printer.
- a conventional printing process preferably an ink jet printer.
- Other preferred printing processes include a commercial bubble jet printer, a flexographic or gravure press, a coater or other methods of printing with aqueous inks.
- Aqueous inkjet compositions must meet certain rigid requirements to be useful in ink jet printing operations. These relate to viscosity, resistivity, solubility, compatibility of components and wettability of the substrate. Also, the ink must be quick-drying and smear resistant, must be capable of passing through the ink jet nozzle without clogging, and must permit rapid cleanup of the machine components with minimum effort.
- the ink composition of the present invention has been constructed to work effectively on all thermal or bubble jet printing equipment.
- the ink is printed on the substrate, it is activated by an activator which is soluble in water and is applied over the invisible printed ink to result in a permanent color change which makes the information printed on the substrate visible in ambient light.
- the latent aqueous ink is a hydroquinonesulfonic acid salt of potassium or sodium which is placed in water with polyethylene glycol and mixed by standard mixing equipment to make an invisible, colorless ink.
- This ink is applied via a printing device to create an invisible, message or mark on a substrate, such as paper, cardboard, plastic, metal, etc.
- a ferric salt activator which is soluble in water can then be applied over the printed ink to effect a permanent color change due to the reaction product formed from the mixture of the ferric salt and the hydroquinonesulfonic acid (sodium or potassium) salt.
- the substrate such as paper, etc.
- the substrate can be prepared ahead of time with security features that make the ink totally invisible under different wavelengths of light and secure against attempted alterations.
- the paper can then be sent to a user, via mail or fax, without the concern of others intercepting private information. After the user receives the paper, the information can be revealed by applying the ferric salt activator.
- Further embodiments of the present invention include a method for covertly communicating information which comprises applying an aqueous solution of a hydroquinonesulfonic acid salt and polyethylene glycol to the substrate.
- the acid salt is capable of reacting with a water soluble ferric salt to produce a reaction product having a color which is visible in ambient light.
- the method of printing the aqueous ink uses any conventional method of printing aqueous ink onto a substrate, but preferably comprises the use of an ink jet printer.
- the present invention provides an aqueous composition.
- the aqueous ink can be printed on a substrate via a conventional printing process, such as by use of an inkjet printer, a commercial bubble jet printer, a flexographic or gravure press, a coater or other methods of printing water based inks.
Abstract
Description
- The present invention relates to the field of security printing, in general, as well as to the field of ink jet printing and compositions useful therein. This invention particularly relates to an aqueous latent image printing method and an aqueous latent image printing ink for use therewith.
- In an aqueous latent image printing method, information is printed on a substrate, such as paper, which is transferred in the form of a latent image or “secure image” which is invisible to the eye and any other usual image detecting device at the time of printing, and is revealed only after the substrate is subjected to a subsequent process of image activation.
- Invisible inks have existed for many years. Many such ink systems have been found, developed and used in a limited way mainly because of the limited accessibility of such invisible inks and delivery systems for the latter.
- A problem with the use of latent image printing for the purpose of product identification was that no good means existed for placing such information on a variety of substrates. Contact printing is not suitable for many such uses, as there is no good means to place the image on the desired substrate if it is irregularly shaped or is substantially inaccessible to traditional contact printing devices. Thus, latent image variable information such as production date, lot number, batch number, serial number, and the like, could not be placed on many products, except by hand, which is cumbersome, expensive, and prone to inaccuracies, defeating the purpose of using such information.
- To address such problems, ink jet technology has been employed for security printing. Ink jet printing systems generally are of two types: continuous stream and drop-on-demand. In continuous stream ink jet systems, ink is emitted in a continuous stream under pressure, through at least one orifice or nozzle. In drop-on-demand systems, a droplet is expelled from an orifice directly to a position on a recording medium in accordance with digital data signals. Since drop-on-demand systems require no ink recovery, charging, or deflection, the system can be much simpler than the continuous stream type.
- There are two types of drop-on-demand ink jet systems. One type of drop-on-demand system has as its major components an ink filled channel or passageway, having a nozzle on one end and a piezoelectric transducer near the other end to produce pressure pulses.
- The other type of drop-on-demand system is known as thermal ink jet, or bubble jet, and produces high velocity droplets and allows very close spacing of nozzles. The major components of this type of drop-on-demand system are an ink filled channel having a nozzle on the open end and a heat generating resistor near the nozzle. The drop-on-demand ink jet printers provide simpler, lower cost devices than their continuous stream counterparts, and yet have substantially the same high speed printing capability. Thermal ink jet processes are well known and are described in, for example, U.S. Pat. No. 4,601,777, U.S. Pat. No. 4,251,824, U.S. Pat. No. 4,410,899, U.S. Pat. No. 4,412,224, and U.S. Pat. No. 4,532,530.
- U.S. Pat. No. 5,395,432 teaches the use of certain ink jet compositions for use in printing latent images an a substrate. In accordance with that patent, ink jet compositions comprising zinc chloride are taught for use in making latent images. A problem associated with those formulations, however, is their corrosiveness to metal parts of the printing apparatus with which the ink comes into contact.
- U.S. Pat. No. 5,935,308 purports to address this problem. The '308 patent teaches the use of certain ink jet compositions for use in printing latent images on a substrate. In accordance with the '308 patent, ink jet compositions comprising zinc bromide and preferably tetraethylammonium p-toluene sulfonate (“TEA p-TS”) are taught for use in making latent images.
- It would be desirable to provide an ink jet composition for latent image printing that is not corrosive.
- All references cited herein are incorporated herein by reference in their entireties.
- The present invention provides an aqueous latent image printing method comprising applying to a substrate, such as paper, a latent image ink composition, via an ink jet printer. Subsequently, the latent image is activated to render it visible, by application of an activator.
- Embodiments of the present invention are particularly suitable for security printing on a substrate which enables the free flow of information without the concern for fraud. The information that is printed on a substrate is invisible to the naked eye, and cannot be revealed without the use of an activator. This method is particularly useful for authentication and identification of financial transactions on the internet, such as checks, to secure the privacy of the user.
- The present invention provides a printing composition comprising an aqueous medium, i.e. water, a hydroquinonesulfonic acid salt, and a humectant
- Suitable humectants typically include organic materials miscible with water. The preferred humectant of the present invention is polyethylene glycol. Examples of other suitable humectants that can be used include ethylene glycol, propylene glycol, diethylene glycols, glycerine, dipropylene glycols, polypropylene glycols, amides, urea, substituted ureas, ethers, carboxylic acids, esters, alcohols, organosulfides, organosulfoxides, sulfones (such as sulfolane), alcohol derivatives, carbitol, butyl carbitol, cellusolve, ether derivatives, amino alcohols, ketones, N-methylpyrrolidinone, 2-pyrrolidinone, cyclohexylpyrrolidone, hydroxyethers, amides, sulfoxides, lactones, and other water miscible materials, as well as mixtures thereof. The humectant can be present in the ink composition in any effective amount. Typically, the water to organic ratio is from about 100:0 to about 30:70, preferably from about 97:3 to about 50:50, although the ratio can be outside this range.
- The preferred latent image former is hydroquinonesulfonic acid salt. The amount of hydroquinonesulfonic acid salt used in the latent ink formulations can vary over a wide range, depending on the intensity of the latent image that is desired, and the solubility of the hydroquinonesulfonic acid salt in the aqueous medium. Typically, the amount of hydroquinonesulfonic acid salt present will vary from about 0.5 percent up to about 7 percent, with the preferred amount being 3 to 7 percent.
- The present printing composition can be printed on a substrate, for example, paper via a conventional printing process, preferably an ink jet printer. Other preferred printing processes include a commercial bubble jet printer, a flexographic or gravure press, a coater or other methods of printing with aqueous inks.
- Aqueous inkjet compositions must meet certain rigid requirements to be useful in ink jet printing operations. These relate to viscosity, resistivity, solubility, compatibility of components and wettability of the substrate. Also, the ink must be quick-drying and smear resistant, must be capable of passing through the ink jet nozzle without clogging, and must permit rapid cleanup of the machine components with minimum effort.
- The ink composition of the present invention has been constructed to work effectively on all thermal or bubble jet printing equipment.
- In preferred embodiments, once the ink is printed on the substrate, it is activated by an activator which is soluble in water and is applied over the invisible printed ink to result in a permanent color change which makes the information printed on the substrate visible in ambient light.
- In preferred embodiments, the latent aqueous ink is a hydroquinonesulfonic acid salt of potassium or sodium which is placed in water with polyethylene glycol and mixed by standard mixing equipment to make an invisible, colorless ink. This ink is applied via a printing device to create an invisible, message or mark on a substrate, such as paper, cardboard, plastic, metal, etc. A ferric salt activator which is soluble in water can then be applied over the printed ink to effect a permanent color change due to the reaction product formed from the mixture of the ferric salt and the hydroquinonesulfonic acid (sodium or potassium) salt.
- In further preferred embodiments of the present invention, the substrate, such as paper, etc., can be prepared ahead of time with security features that make the ink totally invisible under different wavelengths of light and secure against attempted alterations. The paper can then be sent to a user, via mail or fax, without the concern of others intercepting private information. After the user receives the paper, the information can be revealed by applying the ferric salt activator.
- Further embodiments of the present invention include a method for covertly communicating information which comprises applying an aqueous solution of a hydroquinonesulfonic acid salt and polyethylene glycol to the substrate. In accordance with the invention, the acid salt is capable of reacting with a water soluble ferric salt to produce a reaction product having a color which is visible in ambient light. The method of printing the aqueous ink uses any conventional method of printing aqueous ink onto a substrate, but preferably comprises the use of an ink jet printer.
- Unlike certain prior art compositions, the present invention provides an aqueous composition. The aqueous ink can be printed on a substrate via a conventional printing process, such as by use of an inkjet printer, a commercial bubble jet printer, a flexographic or gravure press, a coater or other methods of printing water based inks.
- While the invention has been described in detail and with reference to specific examples thereof, it will be apparent to one skilled in the art that various changes and modifications can be made therein without departing from the spirit and scope thereof.
Claims (13)
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US10/202,423 US6672718B1 (en) | 2002-07-23 | 2002-07-23 | Aqueous latent image printing method and aqueous latent image printing ink for use therewith |
EP03816293A EP1565706A2 (en) | 2002-07-23 | 2003-07-22 | Aqueous latent image printing method and aqueous latent image printing ink for use therewith |
AU2003304054A AU2003304054A1 (en) | 2002-07-23 | 2003-07-22 | Aqueous latent image printing method and aqueous latent image printing ink for use therewith |
PCT/US2003/022739 WO2004094157A2 (en) | 2002-07-23 | 2003-07-22 | Aqueous latent image printing method and aqueous latent image printing ink for use therewith |
CA002493170A CA2493170A1 (en) | 2002-07-23 | 2003-07-22 | Aqueous latent image printing method and aqueous latent image printing ink for use therewith |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US10/202,423 US6672718B1 (en) | 2002-07-23 | 2002-07-23 | Aqueous latent image printing method and aqueous latent image printing ink for use therewith |
Publications (2)
Publication Number | Publication Date |
---|---|
US6672718B1 US6672718B1 (en) | 2004-01-06 |
US20040017449A1 true US20040017449A1 (en) | 2004-01-29 |
Family
ID=29735403
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US10/202,423 Expired - Lifetime US6672718B1 (en) | 2002-07-23 | 2002-07-23 | Aqueous latent image printing method and aqueous latent image printing ink for use therewith |
Country Status (5)
Country | Link |
---|---|
US (1) | US6672718B1 (en) |
EP (1) | EP1565706A2 (en) |
AU (1) | AU2003304054A1 (en) |
CA (1) | CA2493170A1 (en) |
WO (1) | WO2004094157A2 (en) |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8235516B2 (en) * | 2008-12-18 | 2012-08-07 | Pitney Bowes Inc. | Print enhancement of pixels to improve readability |
WO2014130573A1 (en) | 2013-02-19 | 2014-08-28 | LaserLock Technologies Inc. | Characteristic verification system |
US9159016B2 (en) | 2013-03-14 | 2015-10-13 | LaserLock Technologies Inc. | System and method for providing tangible medium with electromagnetic security marker |
AR100871A1 (en) * | 2014-06-20 | 2016-11-09 | Nomacorc Llc | MULTICOMPONENT SYNTHETIC CLOSURE AND MANUFACTURING METHOD OF THIS |
EP3707681B1 (en) | 2017-11-07 | 2023-11-29 | VerifyMe, Inc. | Dual code authentication process |
EP3776500A1 (en) | 2018-03-26 | 2021-02-17 | VerifyMe, Inc. | Device and method for authentication |
WO2022098545A2 (en) | 2020-11-04 | 2022-05-12 | Verifyme, Inc. | Remote infrared ink reader and authenticator |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2945658A1 (en) | 1978-11-14 | 1980-05-29 | Canon Kk | LIQUID JET RECORDING METHOD |
JPS56139970A (en) | 1980-04-01 | 1981-10-31 | Canon Inc | Formation of droplet |
JPS57102366A (en) | 1980-12-18 | 1982-06-25 | Canon Inc | Ink jet head |
US4532530A (en) | 1984-03-09 | 1985-07-30 | Xerox Corporation | Bubble jet printing device |
US4601777A (en) | 1985-04-03 | 1986-07-22 | Xerox Corporation | Thermal ink jet printhead and process therefor |
CA2056283A1 (en) * | 1991-11-27 | 1992-05-26 | Jacqueline M. Saville | Latent image ink |
US5395432A (en) | 1993-10-05 | 1995-03-07 | Videojet Systems International, Inc. | Security jet ink |
JP3472027B2 (en) * | 1996-03-26 | 2003-12-02 | キヤノン株式会社 | Inkjet printing method |
DE19801759A1 (en) * | 1998-01-20 | 1999-07-22 | Bayer Ag | Aqueous pigment preparation for dyeing e.g. paper and nonwovens, aqueous varnish/paint system, aqueous printing dyes, and ink-jet printing, having low tendency to drying out |
US5935308A (en) | 1998-07-31 | 1999-08-10 | Videojet Systems International, Inc. | Latent image jet inks |
-
2002
- 2002-07-23 US US10/202,423 patent/US6672718B1/en not_active Expired - Lifetime
-
2003
- 2003-07-22 CA CA002493170A patent/CA2493170A1/en not_active Abandoned
- 2003-07-22 WO PCT/US2003/022739 patent/WO2004094157A2/en not_active Application Discontinuation
- 2003-07-22 AU AU2003304054A patent/AU2003304054A1/en not_active Abandoned
- 2003-07-22 EP EP03816293A patent/EP1565706A2/en not_active Withdrawn
Also Published As
Publication number | Publication date |
---|---|
AU2003304054A1 (en) | 2004-11-19 |
AU2003304054A8 (en) | 2004-11-19 |
WO2004094157A2 (en) | 2004-11-04 |
CA2493170A1 (en) | 2004-11-04 |
WO2004094157A3 (en) | 2005-01-27 |
US6672718B1 (en) | 2004-01-06 |
EP1565706A2 (en) | 2005-08-24 |
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