|Publication number||US20060219919 A1|
|Application number||US 11/433,850|
|Publication date||Oct 5, 2006|
|Filing date||May 12, 2006|
|Priority date||Nov 11, 2003|
|Also published as||US7935937, US20090294690|
|Publication number||11433850, 433850, US 2006/0219919 A1, US 2006/219919 A1, US 20060219919 A1, US 20060219919A1, US 2006219919 A1, US 2006219919A1, US-A1-20060219919, US-A1-2006219919, US2006/0219919A1, US2006/219919A1, US20060219919 A1, US20060219919A1, US2006219919 A1, US2006219919A1|
|Inventors||Thomas Moore, Gonzalo Amador, Lyudmila Zaykova-Feldman|
|Original Assignee||Moore Thomas M, Gonzalo Amador, Lyudmila Zaykova-Feldman|
|Export Citation||BiBTeX, EndNote, RefMan|
|Referenced by (6), Classifications (16), Legal Events (2)|
|External Links: USPTO, USPTO Assignment, Espacenet|
This continuation-in-part patent application claims the priority of U.S. application Ser. No. 10/896,596, filed Jul. 22, 2004, further claiming priority from U.S. provisional patent application No. 60/519,046, filed Nov. 11, 2003. Application Ser. No. 10/896,596 is incorporated into this continuation-in-part application by reference.
This disclosure relates to the use of focused ion-beam (FIB) microscopes for the preparation of specimens for later analysis in the transmission electron microscope (TEM), and apparatus and methods to facilitate these activities.
The use of focused ion-beam (FIB) microscopes has become common for the preparation of specimens for later analysis in the transmission electron microscope (TEM). The structural artifacts, and even some structural layers, in the device region and interconnect stack of current integrated-circuit devices can be too small to be reliably detected with the secondary electron imaging in a Scanning Electron Microscope (SEM), or FIB, which offers a bulk surface imaging resolution of approximately 3 nm. In comparison, TEM inspection offers much finer image resolution (<0.1 nm), but requires electron-transparent (<100 nm thick) sections of the sample mounted on 3 mm diameter grid disks.
Techniques were later developed for cutting out and removing specimens for examination that required little or no preliminary mechanical preparation of the initial semiconductor die sample before preparation in the FIB. These lift-out techniques include an “ex-situ” method that is performed outside the FIB chamber, and “in-situ” methods performed inside the FIB.
The conventional process of in-situ lift-out can be simplified into three successive steps. The first is the excision of the sample using focused ion-beam milling and extraction of the sample from its trench. The second is the “holder-attach” step, during which the sample is translated on the probe-tip point to the TEM sample holder. Then it is attached to the TEM sample holder (typically with ion beam-induced metal deposition) and later detached from the probe-tip point. The third and final step is the thinning of the sample into an electron-transparent thin section using focused ion beam milling.
A significant portion of the total time involved in completing a TEM sample with in-situ lift-out is spent during the holder-attach step. The relative amount of time involved depends on the amount of time required to mechanically isolate the lift-out sample from the initial bulk sample (ion beam milling rate), but will vary between 30% to 60% of the total time for TEM sample preparation. In order to eliminate the holder-attach step, it would be desirable to directly join the probe tip to the material that will form the TEM sample holder, and thereafter attach the excised sample to the probe tip of the newly-formed TEM sample holder. This newly created assembly is robust and easy to pick up with the tweezers, allowing smooth transfer inside and outside the FIB without the necessity to vent the FIB vacuum chamber.
The preferred embodiment includes a novel method and apparatus for joining a nano-manipulator probe tip (150) to a solid piece of material comprising a TEM sample holder pre-form (100). In the preferred embodiment, this mechanical process is performed outside the vacuum chamber, although it could be performed inside the FIB chamber as well. In the preferred embodiment, the step of embedding a probe tip (150) into the TEM sample holder pre-form (100) is completed outside the FIB, using the mechanical press described in the U.S. patent application Ser. No. 10/896,596. In the present disclosure, however, the TEM sample holder (210) with the probe tip (150) attached is formed before the attachment of an excised sample to the probe tip point (160), rather than afterwards.
The assembly comprising the probe tip (150) attached to a TEM sample holder pre-form (100), can be picked up by the tweezers or grippers (350) and then transferred into the FIB for the in-situ lift-out procedure or for other purposes. This transfer can be accomplished by several means, including but not limited to, the transfer of the assembled TEM sample holder (210) through the sample door of a FIB equipped with a door, translation of the TEM sample holder (210) through a vacuum airlock on the nano-manipulator device, or the translation of the sample holder (210) in a cassette that passes through a vacuum airlock on the FIB chamber. All but the first means listed do not require that the FIB vacuum chamber be vented to atmosphere, which offers cycle time reduction and long-term equipment reliability advantages.
In the preferred embodiment, the probe tip (150) is attached to a TEM sample holder pre-form (100) by a combined mechanical forming and cutting operation, as described in U.S. patent application Ser. No. 10/896,596. As shown in
The probe tip (150) can be joined to the material that will form the TEM sample holder pre-form (100), so as to preserve the attachment between the probe tip (150) and this material, and prevent the probe tip (150) from separating from the TEM sample holder pre-form material (100) during transportation, storage or inspection in the TEM. The assembly should not interfere with the normal operation of the FIB, TEM, or other intended analytical instrument, and should survive well in the internal environment of the TEM, or other intended analytical instrument.
The TEM sample holder pre-form (100) material is preferably soft copper, but may also be molybdenum, aluminum, gold, silver, nickel, beryllium, or copper coated with such metals, if appropriate to the application.
The TEM sample holder pre-form (100) may also be fabricated from a material harder than copper, such as molybdenum, or it may have a surface structure that facilitates the mechanical embedding of the probe tip (150) in the TEM sample holder pre-form (100) material, illustrated in
Excess parts of the TEM sample holder pre-form material (100), if any, are severed during the combined mechanical forming and cutting operation, described in the U.S. patent application Ser. No. 10/896,596. In addition, the probe tip (150) is cut off substantially at the edge of the finished TEM sample holder (210).
Once the assembly of the TEM sample holder pre-form material (100) with the probe tip (150) attached to it has been created, it can be picked up by the grippers or tweezers (350) (shown in
After initial system setup in step 355, the probe tip (150) and the TEM sample pre-form (100) are permanently attached in step 360, using the press as described above, forming the TEM sample holder (210). The completed sample holder (210) is grasped by grippers (350) in step 365 and transferred into the FIB chamber in step 370. Inside the FIB, in step 375, the in-situ lift-out of the sample of interest (140) is performed, including the attachment of the sample (140) to the probe tip point (160). At step 380 the sample (140) may optionally be thinned before transfer outside the FIB. At step 385 the sample holder (210) bearing the attached sample (140) is removed from the FIB, optionally for final thinning at step (390). Finally, at step 395, the sample holder (210) with the attached sample (140) is transferred to a TEM or other instrument for inspection.
Since those skilled in the art can modify the specific embodiments described above, we intend that the claims be interpreted to cover such modifications and equivalents.
|Citing Patent||Filing date||Publication date||Applicant||Title|
|US7851769||Oct 17, 2008||Dec 14, 2010||The Regents Of The University Of California||Motorized manipulator for positioning a TEM specimen|
|US7884326 *||Sep 26, 2007||Feb 8, 2011||Fei Company||Manipulator for rotating and translating a sample holder|
|US7888655 *||Jul 25, 2007||Feb 15, 2011||Fei Company||Transfer mechanism for transferring a specimen|
|US7935937 *||Feb 24, 2009||May 3, 2011||Omniprobe, In.c||Method of forming TEM sample holder|
|US8288740 *||Jun 27, 2008||Oct 16, 2012||Omniprobe, Inc.||Method for preparing specimens for atom probe analysis and specimen assemblies made thereby|
|US20090320624 *||Dec 31, 2009||Omniprobe, Inc.||Method for Preparing Specimens for Atom Probe Analysis and Specimen Assemblies Made Thereby|
|International Classification||B01F, G01N23/00, H01J37/20, G21K7/00|
|Cooperative Classification||H01J2237/31749, G01N1/286, H01J37/26, H01J2237/31745, H01J37/3056, H01J37/20, H01J37/31|
|European Classification||H01J37/305B2, H01J37/26, H01J37/31, H01J37/20|
|Jul 6, 2006||AS||Assignment|
Owner name: OMNIPROBE, INC., TEXAS
Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:MOORE, THOMAS M.;AMADOR, GONZALO;ZAYKOVA-FELDMAN, LYUDMILA;REEL/FRAME:018042/0161
Effective date: 20060504
|Jul 10, 2006||AS||Assignment|
Owner name: OMNIPROBE, INC., TEXAS
Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:MOORE, THOMAS M.;AMADOR, GONZALO;ZAYKOVA-FELDMAN, LYUDMILA;REEL/FRAME:018079/0243
Effective date: 20060504