US20060292749A1 - Photochromic substrate container - Google Patents

Photochromic substrate container Download PDF

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Publication number
US20060292749A1
US20060292749A1 US11/484,887 US48488706A US2006292749A1 US 20060292749 A1 US20060292749 A1 US 20060292749A1 US 48488706 A US48488706 A US 48488706A US 2006292749 A1 US2006292749 A1 US 2006292749A1
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United States
Prior art keywords
container
carrier
photochromic material
transparent portion
electromagnetic radiation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
US11/484,887
Inventor
John Burns
Matthew Fuller
Jeffery King
Martin Forbes
Mark Smith
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Entegris Inc
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Entegris Inc
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Filing date
Publication date
Application filed by Entegris Inc filed Critical Entegris Inc
Priority to US11/484,887 priority Critical patent/US20060292749A1/en
Publication of US20060292749A1 publication Critical patent/US20060292749A1/en
Abandoned legal-status Critical Current

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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/67—Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere
    • H01L21/673—Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere using specially adapted carriers or holders; Fixing the workpieces on such carriers or holders
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/67—Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere
    • H01L21/67005—Apparatus not specifically provided for elsewhere
    • H01L21/67242—Apparatus for monitoring, sorting or marking
    • H01L21/67288—Monitoring of warpage, curvature, damage, defects or the like
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D79/00—Kinds or details of packages, not otherwise provided for
    • B65D79/02—Arrangements or devices for indicating incorrect storage or transport
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D85/00—Containers, packaging elements or packages, specially adapted for particular articles or materials
    • B65D85/30—Containers, packaging elements or packages, specially adapted for particular articles or materials for articles particularly sensitive to damage by shock or pressure
    • B65D85/38—Containers, packaging elements or packages, specially adapted for particular articles or materials for articles particularly sensitive to damage by shock or pressure for delicate optical, measuring, calculating or control apparatus
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F1/00—Originals for photomechanical production of textured or patterned surfaces, e.g., masks, photo-masks, reticles; Mask blanks or pellicles therefor; Containers specially adapted therefor; Preparation thereof
    • G03F1/66—Containers specially adapted for masks, mask blanks or pellicles; Preparation thereof
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/67—Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere
    • H01L21/673—Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere using specially adapted carriers or holders; Fixing the workpieces on such carriers or holders
    • H01L21/6735—Closed carriers
    • H01L21/67366—Closed carriers characterised by materials, roughness, coatings or the like
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/67—Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere
    • H01L21/68—Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere for positioning, orientation or alignment

Definitions

  • the invention relates to wafers containers for transport, shipping and storage of substrates.
  • wafers are spin coated with a photoresist.
  • the photoresist is then baked to adhere it to the wafer.
  • an image of the desired circuitry is projected onto the wafer using electromagnetic radiation.
  • electromagnetic radiation Today, this is commonly deep ultraviolet radiation from a laser.
  • the photoresist material is chemically altered by exposure to ultraviolet light to create either a negative or positive image of the circuit depending on the process used.
  • the undesired photoresist material is then etched away leaving an integrated circuit pattern on the wafer.
  • photoresists that are used in semi-conductor processes are sensitive to light in the ultraviolet wavelengths. Because of the tiny size of the critical elements of modern integrated circuits only a very small exposure to uncontrolled ultraviolet radiation can lead to spoilage of a wafer. Consequently, it is desirable, in the production process, that photoresists only be exposed to the ultraviolet wave lengths of light under carefully controlled conditions. Unintended exposure will destroy the usability of wafers exposed.
  • wafer shipping containers used in the handling, storing and shipping of wafers are made of materials, typically plastics, that block ultraviolet light to prevent it from affecting wafers coated with photoresist material. It is also desirable that wafer shipping containers be, at least partially transparent to visible light to allow workers to determine whether a shipping container is empty or full. Thus, shipping containers have been made of materials that are transparent, at least in part, to visible light but that are relatively opaque to ultraviolet light.
  • ultraviolet blocking is never absolute and it is desirable to expose wafer containers to ultraviolet radiation as little as possible.
  • wafer containers themselves could signal to workers that the wafer container was currently exposed to ultraviolet radiation. This would signal the worker to move the wafer container to an ultraviolet sheltered location.
  • the present invention solves the above problem by providing a semiconductor wafer, substrate, or reticle storage or shipping device that includes a photochromic indicator of ultraviolet exposure.
  • Photochromic materials darken when exposed to sunlight or another source of ultraviolet radiation. Photochromic material transitions between two different states. A low energy state in which the material is clear, uncolored and an activated state in which the material is colored. When electromagnetic radiation of an appropriate energy level impinges on the photochromic material.
  • the present invention includes the incorporation of a photochromic material into the plastic used to fabricate semiconductor wafer, disk, or reticle shipping or storage containers.
  • the photochromic container is used to transport and store semiconductor wafers in a similar fashion to any other semiconductor shipping container.
  • the container is left exposed to sunlight or another source of ultraviolet radiation that may, with sufficient time, have an affect on the photoresist layer which is sensitive to ultraviolet radiation, the shipping container will darken in color. This darkening in color will provide an immediate indication to the shipping workers that the containers are being exposed to ultraviolet light and should be removed from the situation as soon as possible to avoid having a negative affect on the photoresist materials.
  • the photochromic container is used to transport and store semiconductor wafers, disks, or reticles in a similar fashion to any other known substrate container.
  • the shipping container will darken in color. This darkening in color can provide an immediate indication to the shipping workers that the containers are being exposed to ultraviolet light and should be removed from the situation as soon as possible to avoid having a negative affect on the photoresist materials. Additionally, the darkening in color can provide the functional effect of reducing the UV entering the container.
  • FIG. 1 depicts an exemplary partially transparent wafer container
  • FIG. 2 depicts an exemplary substantially transparent wafer container.
  • a partially transparent wafer container 10 generally includes a case 12 and a door 14 .
  • Case 12 includes a handle 16 for use in carrying and encloses a wafer holder 18 .
  • Wafer holder 18 is adapted to support a number of wafers in axially aligned arrays.
  • case 12 includes a transparent portion 20 and opaque portion 22 .
  • transparent portion 20 is formed of a photochromic material that will change color or darkness upon expose to ultraviolet light.
  • Transparent portion 20 may also be a portion of door 14 or a smaller window into wafer container 10 .
  • substantially transparent wafer container 24 generally includes a case 26 and a door 28 .
  • Wafer container 24 encloses wafer array 30 which includes a plurality of wafers axially arrayed. Either case 26 or door 28 may support handle 32 .
  • wafer container 24 is substantially transparent throughout a large portion of its construction. At least a portion of wafer container 24 is made from a photochromic material that changes color or darkness in response to exposure to ultraviolet light.
  • partially transparent wafer container 10 or substantially transparent wafer container 24 are used to transport wafers between work sites. If either partially transparent wafer container 10 or substantially transparent wafer container 24 are exposed to ultraviolet light for a significant period of time, the photochromic portions of the containers will darken or change color to signal this to the workers handling the containers. Thus, a worker having received this readily obvious signal indicating exposure to ultraviolet light can alter the location of the containers in order to prevent signification ultraviolet exposure leading to harm of the wafers or the darkening itself may reduce the entry UV radiation and prevent or minimize damage to the substrate or reticles.
  • the invention includes photochromatic materials in reticle carriers.
  • Reticle carriers are illustrated in U.S. Pat. Nos. 6,513,654 and 6,216,873 which are incorporated by reference.
  • the invention includes disk shippers such as illustrated in U.S. Pat. Nos. 4,557,382 and 5,253,755 and incorporated herein by reference.

Abstract

A semiconductor wafer, substrate, or reticle storage or shipping device that includes a photochromic indicator of exposure to undesired electromagnetic radiation. The present invention includes the incorporation of a photochromic material into the plastic used to fabricate at least a portion of a semiconductor wafer, disk, or reticle shipping or storage containers. The container may include photochromic material in the form of a transparent window or a larger portion of the container. the photochromic material may change color or darkness in response to exposure to a selected range of wavelengths of light.

Description

    RELATED APPLICATION
  • This application is a continuation of application Ser. No. 10/971,556 filed Oct. 22, 2004, which claims the benefit of U.S. Provisional Application No. 60/514,164 filed Oct. 24, 2003.
    • FIELD OF THE INVENTION
  • The invention relates to wafers containers for transport, shipping and storage of substrates.
    • BACKGROUND OF THE INVENTION
  • During processing semi-conductor wafers are subjected to numerous process steps in various machines and at various locations. The wafers must be transported from workstation to workstation and from facility to facility to accomplish these various steps. Numerous types of shipping devices are known for handling storing and shipping semi-conductor wafers. In general, such devices hold the wafers in axially aligned arrays. Where wafers are shipped from facility to facility the wafers may be exposed to sunlight for significant periods of time. Sunlight includes substantial amounts of electromagnetic radiation in the ultraviolet wavelengths. Wafer containers may also be exposed to ultraviolet light from other sources.
  • Current, state of the art, semi-conductor lithography production processes use deep ultraviolet lasers to image circuits with critical features ranging in size as small as one hundred thirty to one hundred fifty nanometers. It is expected that in the near future critical features may shrink to a size range of about seventy nanometers.
  • In the production process wafers are spin coated with a photoresist. The photoresist is then baked to adhere it to the wafer. Next, an image of the desired circuitry is projected onto the wafer using electromagnetic radiation. Today, this is commonly deep ultraviolet radiation from a laser. The photoresist material is chemically altered by exposure to ultraviolet light to create either a negative or positive image of the circuit depending on the process used. The undesired photoresist material is then etched away leaving an integrated circuit pattern on the wafer.
  • As discussed above, photoresists that are used in semi-conductor processes are sensitive to light in the ultraviolet wavelengths. Because of the tiny size of the critical elements of modern integrated circuits only a very small exposure to uncontrolled ultraviolet radiation can lead to spoilage of a wafer. Consequently, it is desirable, in the production process, that photoresists only be exposed to the ultraviolet wave lengths of light under carefully controlled conditions. Unintended exposure will destroy the usability of wafers exposed.
  • Thus, wafer shipping containers used in the handling, storing and shipping of wafers are made of materials, typically plastics, that block ultraviolet light to prevent it from affecting wafers coated with photoresist material. It is also desirable that wafer shipping containers be, at least partially transparent to visible light to allow workers to determine whether a shipping container is empty or full. Thus, shipping containers have been made of materials that are transparent, at least in part, to visible light but that are relatively opaque to ultraviolet light.
  • Nonetheless, ultraviolet blocking is never absolute and it is desirable to expose wafer containers to ultraviolet radiation as little as possible. Thus, it would be a benefit to the semiconductor industry if wafer containers themselves could signal to workers that the wafer container was currently exposed to ultraviolet radiation. This would signal the worker to move the wafer container to an ultraviolet sheltered location.
  • Additionally, similar issues exist with regard to the storage and processing the disks for computer hard drives and the reticles for the lithography operations.
    • SUMMARY OF THE INVENTION
  • The present invention solves the above problem by providing a semiconductor wafer, substrate, or reticle storage or shipping device that includes a photochromic indicator of ultraviolet exposure.
  • Photochromic materials darken when exposed to sunlight or another source of ultraviolet radiation. Photochromic material transitions between two different states. A low energy state in which the material is clear, uncolored and an activated state in which the material is colored. When electromagnetic radiation of an appropriate energy level impinges on the photochromic material.
  • The present invention includes the incorporation of a photochromic material into the plastic used to fabricate semiconductor wafer, disk, or reticle shipping or storage containers.
  • In operation, the photochromic container is used to transport and store semiconductor wafers in a similar fashion to any other semiconductor shipping container. However, if the container is left exposed to sunlight or another source of ultraviolet radiation that may, with sufficient time, have an affect on the photoresist layer which is sensitive to ultraviolet radiation, the shipping container will darken in color. This darkening in color will provide an immediate indication to the shipping workers that the containers are being exposed to ultraviolet light and should be removed from the situation as soon as possible to avoid having a negative affect on the photoresist materials.
  • It is known in the prior art to introduce organic molecules exhibiting photochromic properties into a number of light-transmissible articles.
  • The fabrication of photochromic polymers is known in the polymer arts. Some available options for introducing dyes into a polymer article, such as a wafer carrier, are, for example: (1) Impregnation or imbibing from a fluid medium contacting the surface of the polymer, (2) Incorporation of the dye in a resin coating applied to the surface; (3) Impregnation or diffusive transfer from a solid or gel in contact with the polymer surface, (4) Dispersion of the dye in the monomer or thermoplastic from which the article is to be fabricated.
  • In operation, the photochromic container is used to transport and store semiconductor wafers, disks, or reticles in a similar fashion to any other known substrate container. However, if the container is left exposed to sunlight or another source of ultraviolet radiation that may, with sufficient time, have an affect on the photoresist layer which is sensitive to ultraviolet radiation, the shipping container will darken in color. This darkening in color can provide an immediate indication to the shipping workers that the containers are being exposed to ultraviolet light and should be removed from the situation as soon as possible to avoid having a negative affect on the photoresist materials. Additionally, the darkening in color can provide the functional effect of reducing the UV entering the container.
    • BRIEF DESCRIPTION OF THE DRAWINGS
  • FIG. 1 depicts an exemplary partially transparent wafer container; and
  • FIG. 2 depicts an exemplary substantially transparent wafer container.
    • DETAILED DESCRIPTION OF THE INVENTION
  • Referring to FIG. 1, a partially transparent wafer container 10 generally includes a case 12 and a door 14. Case 12 includes a handle 16 for use in carrying and encloses a wafer holder 18. Wafer holder 18 is adapted to support a number of wafers in axially aligned arrays.
  • In this example, case 12 includes a transparent portion 20 and opaque portion 22. Preferably, transparent portion 20 is formed of a photochromic material that will change color or darkness upon expose to ultraviolet light. Transparent portion 20 may also be a portion of door 14 or a smaller window into wafer container 10.
  • Referring now to FIG. 2, substantially transparent wafer container 24 generally includes a case 26 and a door 28. Wafer container 24 encloses wafer array 30 which includes a plurality of wafers axially arrayed. Either case 26 or door 28 may support handle 32. In this exemplary embodiment, wafer container 24 is substantially transparent throughout a large portion of its construction. At least a portion of wafer container 24 is made from a photochromic material that changes color or darkness in response to exposure to ultraviolet light.
  • In operation, partially transparent wafer container 10 or substantially transparent wafer container 24 are used to transport wafers between work sites. If either partially transparent wafer container 10 or substantially transparent wafer container 24 are exposed to ultraviolet light for a significant period of time, the photochromic portions of the containers will darken or change color to signal this to the workers handling the containers. Thus, a worker having received this readily obvious signal indicating exposure to ultraviolet light can alter the location of the containers in order to prevent signification ultraviolet exposure leading to harm of the wafers or the darkening itself may reduce the entry UV radiation and prevent or minimize damage to the substrate or reticles.
  • The invention includes photochromatic materials in reticle carriers. Reticle carriers are illustrated in U.S. Pat. Nos. 6,513,654 and 6,216,873 which are incorporated by reference. Similarly, the invention includes disk shippers such as illustrated in U.S. Pat. Nos. 4,557,382 and 5,253,755 and incorporated herein by reference.
  • The present invention may be embodied in other specific forms without departing from the central attributes thereof, therefore, the illustrated embodiments should be considered in all respects as illustrative and not restrictive, reference being made to the appended claims rather than the foregoing description to indicate the scope of the invention.

Claims (23)

1. A carrier for transporting articles including semiconductor wafers, disks, or reticles, comprising:
a container comprising an openable enclosure, the container being formed to support, enclose and protect the articles; and
an at least partially transparent portion at least partially formed of a photochromic material that changes color or darkness in response to exposure to electromagnetic radiation of a selected wavelength or range of wavelengths.
2. The carrier as claimed in claim 2, in which the container comprises a case and a door
3. The carrier as claimed in claim 2, in which the transparent portion is a part of the case.
4. The carrier as claimed in claim 2, in which the transparent portion is a part of the door.
5. The carrier as claimed in claim 1, in which the selected wavelength or range of wavelengths comprises ultraviolet light.
6. The carrier as claimed in claim 1, in which the selected wavelength or range of wavelengths comprises deep ultraviolet light.
7. The carrier as claimed in claim 2, in which substantially the entire door is formed of the photochromic material.
8. The carrier as claimed in claim 2, in which substantially the entire case is formed of the photochromic material.
9. The carrier as claimed in claim 1, in which a window in the carrier is formed of the photochromic material.
10. A method for determining if a carrier for transporting articles including semiconductor wafers, disks, or reticles is exposed to undesired electromagnetic radiation comprising the steps of:
placing the articles in a container comprising an openable enclosure, the container being formed to support, enclose and protect the articles; and an at least partially transparent portion at least partially formed of a photochromic material that changes color or darkness in response to exposure to electromagnetic radiation of a selected wavelength or range of wavelengths;
transporting the container; and
observing the photochromic material to discern any change in color or darkness.
11. The method as claimed in claim 10, further comprising the step of selecting the wavelength to include ultraviolet light.
12. The method as claimed in claim 10, further comprising the step of selecting the wavelength to include deep ultraviolet light.
13. The method as claimed in claim 10, in which the in which the container comprises a case and a door
14. The carrier as claimed in claim 13, in which the transparent portion is a part of the case.
15. The carrier as claimed in claim 13, in which the transparent portion is a part of the door.
16. A method for protecting articles including semiconductor wafers, disks, or reticles from exposure to undesired electromagnetic radiation comprising the steps of:
placing the articles in a container comprising an openable enclosure,
forming the container to support, enclose and protect the articles; and
forming the container to include an least partially transparent portion at least partially formed of a photochromic material that changes color or darkness in response to exposure to electromagnetic radiation of a selected wavelength or range of wavelengths.
17. The method as claimed in claim 16, further comprising the step of selecting the photochromic material such that it changes color or darkens to absorb or reflect the undesired electromagnetic radiation.
18. The method as claimed in claim 16, further comprising the steps of observing the photochromic to discern a change in color or darkness; and
acting to remove the container from the exposure to undesired electromagnetic radiation.
19. The method as claimed in claim 16, further comprising the step of selecting the wavelength to include ultraviolet light.
20. The method as claimed in claim 16, further comprising the step of selecting the wavelength to include deep ultraviolet light.
21. The method as claimed in claim 16, in which the in which the container comprises a case and a door.
22. The carrier as claimed in claim 21, in which the transparent portion is a part of the case.
23. The carrier as claimed in claim 21, in which the transparent portion is a part of the door.
US11/484,887 2003-10-24 2006-07-11 Photochromic substrate container Abandoned US20060292749A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
US11/484,887 US20060292749A1 (en) 2003-10-24 2006-07-11 Photochromic substrate container

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US51416403P 2003-10-24 2003-10-24
US10/971,556 US7073667B2 (en) 2003-10-24 2004-10-22 Photochromic substrate container
US11/484,887 US20060292749A1 (en) 2003-10-24 2006-07-11 Photochromic substrate container

Related Parent Applications (1)

Application Number Title Priority Date Filing Date
US10/971,556 Continuation US7073667B2 (en) 2003-10-24 2004-10-22 Photochromic substrate container

Publications (1)

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US20060292749A1 true US20060292749A1 (en) 2006-12-28

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US10/971,556 Expired - Fee Related US7073667B2 (en) 2003-10-24 2004-10-22 Photochromic substrate container
US11/484,887 Abandoned US20060292749A1 (en) 2003-10-24 2006-07-11 Photochromic substrate container

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US10/971,556 Expired - Fee Related US7073667B2 (en) 2003-10-24 2004-10-22 Photochromic substrate container

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US (2) US7073667B2 (en)
EP (1) EP1689657A4 (en)
JP (1) JP2007509013A (en)
KR (1) KR100769395B1 (en)
IL (1) IL175096A0 (en)
WO (1) WO2005040011A1 (en)

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KR100769395B1 (en) 2007-10-22
EP1689657A1 (en) 2006-08-16
EP1689657A4 (en) 2007-12-12
US20050139511A1 (en) 2005-06-30
US7073667B2 (en) 2006-07-11
WO2005040011A1 (en) 2005-05-06
JP2007509013A (en) 2007-04-12
KR20060088897A (en) 2006-08-07
WO2005040011B1 (en) 2005-06-30
IL175096A0 (en) 2006-08-20

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