US 20070042598 A1
A polymer dielectric material includes a sidewall passivating layer on the opposing sidewall surfaces of an opening in the dielectric layer for a via or trench. The sidewall passivating layer may be deposited on the sidewall surfaces, as well as the bottom surface of an opening having a first depth in the polymer dielectric layer. After the sidewall passivating layer is added, the depth of the opening may be increased to a second depth. The sidewall passivating layer provides a barrier to removal of the polymer dielectric from the sidewalls, preventing or reducing undercutting below a hard mask.
1. A device comprising:
a semiconductor substrate having a conductive layer, a barrier layer over the conductive layer, and a polymer dielectric layer over the barrier layer;
an opening in the polymer dielectric layer having a bottom surface and substantially vertical opposing sidewall surfaces; and
a passivating layer on at least the opposing sidewall surfaces of the opening.
2. The device of
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7. A method comprising:
etching a polymer dielectric material over a barrier layer on a substrate to provide an opening having a first depth, the opening having a bottom surface and sidewall surfaces;
forming a passivating layer over the bottom surface and sidewall surfaces of the opening, the passivating layer providing a barrier layer; and
etching the polymer dielectric material at the bottom of the opening to remove the passivating layer and the polymer dielectric material from the bottom surface of the opening and increase the depth of the opening to a second depth.
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This application is a divisional of U.S. patent application Ser. No. 10/379,061, filed on Mar. 4, 2003.
The present invention relates to a method for making integrated circuits, and more specifically to the formation of layers having low dielectric constants.
Integrated circuits are made by forming on a substrate, such as a silicon wafer, layers of conductive material that are separated by layers of a dielectric material. Openings called vias and trenches may be etched through the dielectric layers, then filled with a conducting material to electrically connect the separated conductive layers.
A commonly used material to form a dielectric layer is silicon dioxide. Although a thermally stable and mechanically strong material, silicon dioxide has a relatively high dielectric constant. Consequently, certain materials such as various organic polymers that have a relatively low dielectric constant may be used as a dielectric material in place of silicon dioxide. When such materials are used in place of those with a higher dielectric constant, RC delay may be reduced, which can enable a higher speed device.
Etching is a process of removing selected portions of a layer from a wafer surface through openings in a hard mask with a specified resist pattern. Dry etching typically is used to obtain sufficient control and precision for integrated circuits with features below 3 μm. Dry etch techniques include plasma etching, ion beam etching, and reactive ion etching. Plasma etching requires a chemical etchant and an energy source. For example, a plasma etcher may include a chamber, vacuum system, gas supply, and power supply. The wafers may be loaded into the chamber, the pressure inside is reduced by the vacuum system, and the chamber is filled with the reactive gas. For example, to etch silicon dioxide, the gas may be CF4 mixed with oxygen. The energy source, such as a power supply that creates a radio frequency field through electrodes in the chamber, energizes the gas mixture to a plasma state. In the energized state, the etchant attacks the dielectric material, converting it into volatile components that are removed by the vacuum system.
Polymer-based dielectrics may be etched with chemical etchants that include and/or are based on O2-based chemistry. The etchant also may include additives such as N2, H2, or CO. Ion bombardment also may be used to etch a polymer dielectric material, in conjunction with a chemical etchant. Typically, some over-etching is done of the polymeric dielectric material. Over-etching may be needed to ensure complete removal of the selected material, at least in part due to variations in material thickness and etch non-uniformity across the surface.
However, over-etching also can cause or increase a problem referred to as undercutting. Undercutting is the unwanted removal of dielectric material below the edges of a mask. In general, etching of a dielectric can result in undercutting because etching tends to be somewhat non-directional, or isotropic, especially with polymer dielectrics. Undercutting results in sidewall surfaces that are not vertical, but are bowed. If etch time is increased, the etching may remove even more of the polymeric dielectric material from underneath the mask, worsening the undercutting problem. Although attempts to reduce undercutting have been made by simply reducing the over-etch time, this is not a practical solution because some over-etch is needed to compensate for material thickness variations and etch non-uniformity.
The undercutting problem is an obstacle to the development of smaller and faster devices, because undercutting can result in variations and departures from designs that seek to minimize spacing of dielectric materials between conductive elements such as conductive elements in vias and trenches, misalignment of conductors and/or insulating elements extending through or into the etched dielectric layers, and other similar problems. What is needed is a device without the undercutting problem, that has more vertical sidewalls on the sides of an opening in a polymer dielectric layer. A method for etching a polymer dielectric with a low dielectric constant is needed that will reduce, minimize or eliminate the undercutting problem.
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Dielectric layer 103, also referred to as interlayer dielectric (ILD), comprises a polymer formed on top of barrier layer 102. Dielectric layer 103 may be formed by spin coating the polymer onto the surface of barrier layer 102, using conventionally employed equipment and process steps. Dielectric layer 103 preferably is between about 2,000 and about 20,000 angstroms thick. Dielectric layer 103 preferably has a low dielectric constant; i.e., less than about 3.5 and more preferably less than about 2.0. Because of layer 103's low dielectric constant, the capacitance between various conductive elements that are separated by layer 103 may be reduced, when compared to the capacitance resulting from use of other conventionally used dielectric materials such as silicon dioxide. Such reduced capacitance may decrease the RC delay that would otherwise exist and may also decrease undesirable cross-talk between conductive lines.
Dielectric layer 103 may comprise an organic polymer. Such organic polymers include, for example, polyimides, parylenes, polyarylethers, polynaphthalenes, and polyquinolines, or copolymers thereof. Although several examples of materials that can be used to make dielectric layer 103 have been identified here, any polymer that may insulate one conductive layer from another is within the spirit and scope of the present invention.
Above dielectric layer 103 is hard masking layer 104. The hard masking layer 104 may be formed by chemical vapor deposition, for example. The minimum thickness required for hard masking layer 104 may be dictated by the process used to perform a subsequent polishing step to remove excess metal formed on the surface of that layer. The preferred materials for making hard masking layer 104 are silicon nitride and silicon dioxide, although other materials, such as SiOF, may be used.
In one embodiment, photoresist layer 105 may be patterned on top of the hard masking layer to define a trench or via formation region for receiving a subsequently formed conductive layer. Photoresist layer 105 may be patterned using conventional photolithographic techniques, such as masking the layer of photoresist, exposing the masked layer to light, then developing the unexposed portions.
Passivating layer 106 may be formed using conventional equipment used for etching, i.e., an ion beam source and plasma gas chemistry. Preferably, the passivating layer has a depth or thickness of between about 2 nanometers and about 20 nanometers over the polymer dielectric. However, the depth of the passivating layer may be varied based on the chemistry used and time to form the passivating layer. For example, in one embodiment, after the passivating layer is initially formed, it may have a greater depth or thickness on the bottom surface than on the sidewall surfaces. In one embodiment, a passivating layer may be formed in approximately 10 seconds.
In one embodiment, the passivating layer may be a carbon and fluorine-based material such as CF2, C2F4, etc. The chemistry used to form the passivating layer may be a carbon-fluoro gas or hydrocarbon-flouro gas, such as C2F8, C2F6, CHF3, CH3F, or CH2F2, and also may include or be mixed with other gases such as argon, oxygen or nitrogen. The gas may be broken into several different ions during formation of the passivation layer. The chemistry used to form the passivating layer should be selected so it does not penetrate, attack or etch the polymer dielectric layer significiantly.
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The polymer dielectric layer on the bottom surface of the opening may be removed until a second depth is reached. For example, the second depth may be at or near the depth of barrier layer 102. In one embodiment, the remaining polymer dielectric material may be removed by etching for approximately 25 seconds. After the removal of the additional dielectric material on the bottom surface, however, some or all of the passivating layer on the sidewall surfaces may remain.
In block 202, a passivating layer is formed on the opposing sidewalls of the opening in the polymer dielectric layer. In one embodiment, the passivating layer also may be formed on the bottom surface of the opening. The passivating layer may be formed by using an ion beam source and suitable etch chemistry to create a layer of carbon and fluorine-based material to a depth or thickness of between about 2 nanometers and about 20 nanometers. In one embodiment, the passivating layer may reach a greater depth over the bottom surface than the sidewall surfaces of the opening.
The chemistry used to form the passivating layer in block 202 may include a carbon-fluoro gas, such as C2F8, C2F6, CHF3, CH3F, CH2F2, or CH3F, and also may include or be mixed with other gases such as argon, oxygen or nitrogen. The depth of the passivating layer may depend on the time, chemistry and other parameters. In one embodiment, a passivating layer may be formed in approximately 10 seconds.
In block 203, additional polymer dielectric material may be removed from the bottom of the opening to reach a second depth. The same or similar methods or techniques may be used as in block 201. For example, conventional etch techniques may be used that include ion bombardment and/or etch chemistries. If there is a passivating layer on the bottom surface, ion beam etching techniques may be used to remove the passivating layer therefrom, as well as the remaining polymer dielectric layer on the bottom surface of the opening, until reaching a second depth. In one embodiment, the second depth may be at or near the barrier layer. Techniques for removal of the polymer dielectric include employing an ion beam in a direction normal to the substrate surface. Such techniques allow removal of the passivating layer and the polymer dielectric from the bottom surface of the opening, without significantly penetrating or removing the passivating layer and/or polymer dielectric from the sidewall surfaces. In one embodiment, the remaining polymer dielectric material may be removed from the bottom surface of the opening in approximately 25 seconds.
After the polymer dielectric is removed from the bottom surface of the opening to reach a desired via or trench depth, some or all of the passivating layer may remain on the sidewall surfaces. Significantly, the passivating layer on the sidewalls protects the polymer dielectric sidewalls from isotropic etching that may result in undercutting. Optionally, some or all of the passivating material remaining on the sidewalls may be removed subsequently through a conventional wet clean process.
In one embodiment, the passivating layer may be formed between cycles of a cyclic etch process. For example, a polymer dielectric etch process of 75 seconds duration may be split into two or more intervals, and the sidewall passivating layer may be formed between two of the intervals. In one embodiment, the polymer dielectric etch process is divided into three 25 second intervals.
As a result of including a sidewall passivating layer, an opening in the polymer dielectric layer may have a significantly improved profile for a via or trench. The improved etch profile may be characterized by vertical sidewalls, with little or no undercutting of the polymer dielectric material below the edges of a hard mask. Thus, the present invention significantly reduces the undercut or etch bias of a low-k polymer dielectric.
While the present invention has been described with respect to a limited number of embodiments, those skilled in the art will appreciate numerous modifications and variations therefrom. It is intended that the appended claims cover all such modifications and variations as fall within the true spirit and scope of this present invention.