|Publication number||US20070074733 A1|
|Application number||US 11/241,978|
|Publication date||Apr 5, 2007|
|Filing date||Oct 4, 2005|
|Priority date||Oct 4, 2005|
|Also published as||CA2623219A1, CA2623219C, CN101277621A, CN101277621B, DE602006013007D1, EP1933654A2, EP1933654B1, WO2007054826A2, WO2007054826A3|
|Publication number||11241978, 241978, US 2007/0074733 A1, US 2007/074733 A1, US 20070074733 A1, US 20070074733A1, US 2007074733 A1, US 2007074733A1, US-A1-20070074733, US-A1-2007074733, US2007/0074733A1, US2007/074733A1, US20070074733 A1, US20070074733A1, US2007074733 A1, US2007074733A1|
|Inventors||Firooz Rasouli, John Hearn, Ping Li|
|Original Assignee||Philip Morris Usa Inc.|
|Export Citation||BiBTeX, EndNote, RefMan|
|Referenced by (6), Classifications (16), Legal Events (1)|
|External Links: USPTO, USPTO Assignment, Espacenet|
A wide variety of materials have been suggested in the art as filters for tobacco smoke. Such filter materials include cotton, paper, cellulose, and certain synthetic fibers. These filter materials are known to remove particulates and condensable components from tobacco smoke. They have little or no effect in removing certain gaseous components, e.g., aldehydes, from tobacco smoke. See for example commonly assigned U.S. Pat. No. 6,209,547, which is hereby incorporated herein in its entirety for all purposes.
Smoking articles, such as cigarettes and cigarette filters, and methods of manufacturing smoking articles are provided. In one exemplary embodiment, a smoking article contains hollow fibers which affect mainstream tobacco smoke drawn through the smoking article.
In another exemplary embodiment, a cigarette, comprising: a tobacco rod; a filter joined to the tobacco rod, wherein the filter comprises a bundle of hollow fibers, wherein the lumens of the hollow fibers are aligned axially in parallel to one another; and an additive material in extra-cellular spaces of the hollow fibers, wherein one end of at least one of the hollow fibers is obstructed is provided.
In another exemplary embodiment, a cigarette filter, comprising: hollow fibers; an outer layer covering an outer region of the hollow fibers; and cellulose acetate, wherein the hollow fibers and the outer layer are embedded within the cellulose acetate is provided.
In another exemplary embodiment, a method of manufacturing a cigarette filter, comprising: preparing hollow fibers with a smoke impermeable material covering one end of at least one of the hollow fibers; at least partially filling extra-cellular spaces within the hollow fibers with an additive material; and placing the hollow fibers with the smoke impermeable material and the additive material in a cigarette filter is provided.
Also provided is a method of treating mainstream smoke, comprising: drawing tobacco smoke axially through hollow fibers, wherein the mainstream tobacco smoke is drawn into an open upstream end into lumens of the hollow fibers and is drawn through permeable walls of the hollow fibers to a downstream end of a smoking article.
Also provided is a cigarette filter, comprising: a hollow fiber membrane, wherein the hollow fiber membrane comprises: hollow fibers; and a smoke impermeable material, wherein the smoke impermeable material obstructs a downstream end of a lumen of the hollow fiber.
Smoking articles are provided that include hollow fibers therein, wherein the hollow fibers are obstructed on one end to force a fluid through the walls of the hollow fibers.
As used herein, the term “feed” is used to indicate a material or fluid which is fed into the hollow fibers. Also as used herein, the term “retentate” is used to indicate the portion of the feed which does not pass through the walls of the hollow fibers and is trapped within or on an outer surface of the lumens of the hollow fibers. Additionally, the term “filtrate” is used to indicate the portion of the feed which passes through the walls of the hollow fibers.
The term “obstruct” is intended to include blocking, partial blocking, filtering, or any other means of reducing flow through an area. For example, an impermeable or semi-permeable material can be used to obstruct the downstream end of the hollow fibers by blocking filtrate or feed from passing through a downstream end of the hollow fibers, or by merely increasing the resistance to flow for filtrate or feed passing through the downstream end of the hollow fibers.
An exemplary use of a cigarette 100 with hollow fibers is illustrated in
Upon entry into the filter section 130, the smoke feed 140 is forced into lumens, or inner diameters, 15 of hollow fibers 10 within the filter section 130. In
Additionally, the first smoke impermeable material 20 can also be provided between the individual fibers 10 in the bundle, as illustrated in
Next, also as illustrated in
It is noted that as illustrated in
The filtrate permeable material 30 can be provided to hold the hollow fibers 10 in place in relation to one another, as well as in relation to the filter 130. Alternatively, a ring, an adhesive, or other physically containing material can be used, as long as it does not substantially obstruct filtrate flow through the filter 130. An exemplary embodiment of the filtrate permeable material 30 is a porous, filtrate permeable material, such as cellulose acetate.
By obstructing the downstream ends 35 of the hollow fibers 10, smoke 140 is forced through the walls of the hollow fibers 10 because of the pressure exerted by the smoker on the downstream end 120. By forcing smoke 140 through the hollow fibers 10, the walls of the hollow fibers 10 can be used to filter smoke 140 therethrough. Thus, the walls of the hollow fibers 10 behave as a membrane in that the walls of the hollow fibers 10 allow the filtrate 150 from the smoke 140 to pass, while the retentate (not shown) is trapped within the lumens 15.
It is noted that in another exemplary embodiment, illustrated in
Additionally, as also illustrated in
By providing the two smoke impermeable materials 20, 30, smoke feed 140 can be routed between an outer circumference of the bundle of fibers 10 and the inner diameter of the cigarette filter 130 at an upstream end 25, through the walls of the hollow fibers 10 and out the downstream end 35. By passing the smoke filtrate 150 through the walls of the hollow fibers 10, the hollow fibers 10 behave as a hollow fiber membrane in that the smoke is separated into retentate and filtrate 150, wherein the retentate (not shown) can be trapped on the outer surfaces of the hollow fibers 10. After passing through the walls of the hollow fibers 10, the filtrate 150 can then be passed through the downstream end 35 of the hollow fibers 10.
The hollow fibers 10 used herein are preferably embodied, as illustrated in
It is noted that the material used for the hollow fibers 10 can be chosen to have a predetermined pore size by determining the materials used for the walls. For example, if the hollow fibers 10 are made of larger pore materials, larger constituent filtrates are allowed to pass through. Thus, the material used for the hollow fibers 10 can be chosen to selectively restrain passage to only certain ranges of filtrates, if desired.
In a preferred smoking article, hollow fibers 10 are oriented in a direction in which smoke will travel through the smoking article. By providing such alignment, smoke can travel through lumens of the hollow fibers in a direction approximately parallel to the suction or vacuum force applied at the downstream end of the smoking article drawing smoke from the upstream or lit end.
Additionally, the hollow fibers 10 are approximately parallel to the one another in order to allow smoke feed 140 to evenly penetrate the hollow fibers 10, pass through the walls of the hollow fibers evenly, and for fitting bundles of hollow fibers into the axis of a cigarette. For example, as illustrated in
These hollow fibers 10 can be used within any smoking article, like a traditional or non-traditional cigarette, e.g., in a cigarette filter. Preferred embodiments provide hollow fibers for use in smoking articles, such as cigarettes and non-traditional cigarettes. Non-traditional cigarettes include, by way of example, cigarettes for electrical smoking systems as described in commonly-assigned U.S. Pat. Nos. 6,026,820; 5,988,176; 5,915,387; 5,692,526; 5,692,525; 5,666,976; and 5,499,636, the disclosures of which are hereby incorporated by reference herein in their entireties.
Hollow fibers are preferably sized to a length less than the length of a filter so that the entire length of the fiber can fit within the area of the filter as the hollow fibers are aligned in the direction of smoke flow. Also, the diameters of the lumens of the hollow fibers (in combination with the material used to make the hollow fibers and the density of any bundle of hollow fibers) control the amount of flow possible, as well as the force required to pull the tobacco smoke through the hollow fibers (hereinafter, resistance to draw (RTD)).
In addition to using hollow fibers as hollow fiber membranes to filter materials, such as smoke, therethrough, the hollow fibers can also be used to provide additives. For example, as illustrated in
The outer diameter and wall thickness of the hollow fibers are preferably sized to optimize the hollow fibers' ability to hold additive materials and to control filtrate flow through the walls and retentate trapping on the walls . It is noted that additive materials tend not to be absorbed in the lumen of the hollow fibers due to capillary forces, thus the holding of additive materials is primarily carried out by the extra-cellular spaces within the walls. As the outer diameter of the hollow fibers increases, and/or the number of hollow fibers provided increases, the amount of the porous spaces within walls of a hollow fiber (i.e., extra-cellular spaces, such as crack or crevices in walls of hollow fibers) would tend to increase. By increasing the amount of extra-cellular spaces, more additive materials can be absorbed. On the other hand, narrower lumens, and/or fewer hollow fibers can cause the hollow fibers to hold less additive materials due to their lesser total outer surface wall areas.
Preferred embodiment hollow fibers 10 are used to releasably hold additive materials within the extra-cellular spaces of the hollow fibers 10. Thus, because of the releasable hold, additive materials in the hollow fibers 10 can be sufficiently contained to substantially avoid or minimize unwanted migration of the additive materials, such as, for example, during storage of the smoking articles with the additive materials therein.
In order to provide additive materials in hollow fibers, the additive materials are provided for absorption or adsorption within the extra-cellular spaces of the hollow fibers 10. For example, additive materials can be provided by soaking the hollow fibers 10 in a bath of additive materials, wherein the additive material can be absorbed into the extra-cellular spaces.
Therefore, in an average sized cigarette (e.g., a cigarette with a length between 65-100 mm, a diameter of 6-9 mm and a filter length of 15-30 mm), the hollow fibers can have a lumen (i.e., inner) diameter of approximately 50 microns to approximately 1500 microns (e.g., 50-100, 100-150, 150-250, 350-500, 500-1000, or 1000-1500 microns), preferably approximately 90 microns to approximately 450 microns. Additionally, the hollow fibers can have a highly porous wall with a thickness of approximately 10 microns to 100 microns, preferably approximately 10 to approximately 50 microns, and an outer diameter of approximately 100 microns to approximately 2100 microns, preferably 100 to approximately 500 microns.
For example, an exemplary embodiment cigarette can be designed to include a bundle of 10 to 15 hollow fibers, wherein each hollow fiber has a lumen diameter of approximately 200 microns, a wall thickness of approximately 50 microns with an outer diameter of approximately 350 microns.
Hollow fibers can be made by spinning or other fiber making techniques. For example, methods of making hollow fibers have been described in U.S. Pat. Nos. 2,999,296 and 4,234,431, which are hereby incorporated herein in their entireties by reference.
In order to use the hollow fibers 10 in a smoking article, the hollow fibers 10 are cut or otherwise made to a specific length. The hollow fibers 10 can preferably be used in a circumferentially spaced relation in a filter section of a smoking article or can be gathered into a bundle prior to insertion into a final product. If the hollow fibers are bundled, the hollow fibers 10 can be held together using a permeable, semi-permeable or impermeable material, as mentioned above, an enclosure, such as a ring, or an adhesive, such as triacetin, epoxy, and silicone rubber.
Additionally, because of the releasable hold, the additive materials are preferably mobile enough within the extra-cellular spaces of the hollow fibers to be released therefrom upon demand. For example, the additive material can preferably be released from the hollow fibers upon application of a vacuum force or drawing action as mentioned above.
Hollow fibers 10 can also be incorporated into a cigarette filter to provide a means for controlling a resistance to draw (RTD) in a cigarette. In a preferred embodiment, a cigarette filter would include hollow fibers 10 therein. By providing hollow fibers in a cigarette, a cigarette can be provided with as little or as much resistance to draw as desired.
Additionally, hollow fibers 10 can be used to supplement or replace multi-section filter assemblies, which are often more difficult to manufacture than hollow fibers 10. Thus, hollow fibers 10 in cigarette filters could be used to simplify the manufacturing process while still providing tailored levels of RTD.
2. Potting Materials
As mentioned above, first and second filtrate obstructing or smoke impermeable materials can be used to obstruct smoke flow through a smoking article as illustrated in
As used herein, “potting material” is intended to include materials that can be used to hold hollow fibers in place, as well as materials that can direct feed, filtrate, and retentate flow in, around and through lumens of the hollow fibers. As such, the potting material can be made of any non-toxic, permeable, semi-permeable or impermeable material that can hold the hollow fibers in a fixed positional relationship with one another (i.e., in parallel to one another). Further discussion of hollow fiber membranes in potting material can be found in U.S. Pat. Nos. 3,228,887, 3,528,553 and 6,685,832, which are hereby incorporated herein in their entireties by reference.
Preferably, the potting material is a polymer or a composite, wherein the material can be selected depending upon the degree of permeability desired. For potting material used to obstruct airflow through an end of a hollow fiber, a filtrate impermeable or semi-permeable potting material may be desired. For example, epoxy is a filtrate impermeable potting material. On the other hand, for potting material used to hold the fibers in place, wherein filtrate obstruction is not desired, a permeable potting material may be desired. For example, cellulose acetate is a permeable potting material.
The potting material can be formed on any portion of the hollow fibers 10. For example, the potting material can be formed on a portion or the entirety of the length, the circumference of the fibers, and/or on ends of the hollow fibers. However, if the potting material is chosen to obstruct airflow, the potting material is preferably formed on less than the entire surface of the hollow fibers, as to allow for at least some filtrate to pass through walls 18 of the hollow fibers 10.
Additionally, less than full coverage of the walls 18 of the hollow fibers 10 can be desired to not completely enclose and possibly isolate the extra-cellular spaces and additive materials that can be contained therein. As such, coverage by the potting material on the hollow fibers 10 is preferably less than 90% of the wall surface of the hollow fibers 10, and even more preferably, less than 60% of the wall surface of the hollow fibers 10 (e.g., 100-90%, 90-80%, 80-70%, 70-60%, 60-50%, 50-40%, 40-30%, 30-20%, 20-10% or 10-0%).
The potting material can be formed on the hollow fibers in any manner that provides the airflow controlling properties desired by the embodiment. For example, methods of forming potting material on hollow fibers have been discussed in U.S. Pat. Nos. 6,702,561, 6,663,745, 6,623,637 and 5,480,553, which are incorporated herein in their entireties by reference.
As mentioned above, the potting material can be made of any material that can obstruct smoke passage. As such, the potting material can be made of an impermeable, semi-permeable or permeable material. If the potting material is a semi-permeable or permeable material, then the potting material can be used as permeable barrier and can increase the resistance to airflow therethrough.
Therefore, a smoking article can be provided with hollow fibers in a conformation such that the structure and orientation for the hollow fibers 10 allows for at least some of the extra-cellular spaces of hollow fibers 10 to be accessible to hollow fibers. Additionally, as provided herein, the smoke flow can still be at least partially directed through the lumens 15 and the walls 18 of the hollow fibers 10, wherein additive materials in the extra-cellular spaces can interact with the airflow as it passes through the walls 18 of the hollow fibers 10.
3. Outer Layer
The hollow fibers 10 can also include an outer layer covering or encapsulating the hollow fibers 10 (with additive material therein, if desired). Preferably, the outer layer is a solid wall or film, wherein the solid wall or film can be used to temporarily seal or encapsulate the hollow fibers 10 (and anything encapsulated within the hollow fibers 10) away from the surrounding environment.
Preferably, the outer layer is applied around the outer surfaces of the hollow fibers 10 such that additive materials added to the hollow fibers 10 can be sealed within the hollow fibers 10, and/or within their extra-cellular spaces. Further, the outer layer is preferably easily frangible and can be ruptured to allow additive materials to be released from the hollow fibers 10.
The outer layer can be any frangible material, such as a polymer, which is capable of both sealing the hollow fibers, as well as breaking, rupturing or perforating on demand. Preferably, the outer layer is made of sugar or pectin, which can also be provided to flavor filtrate, such as smoke filtrate, contacting the outer layer if desired. The outer layer is preferably used to immobilize additive materials within the hollow fibers 10, and thus preferably reduces dissipation of the additive material until the outer layer is broken, ruptured or perforated.
Preferably, the outer layer is a frangible thin film. By providing a frangible thin film, a difference in fluid pressure on either side of the outer layer and the hollow fiber walls (i.e., drawing on a cigarette with hollow fibers and the outer layer therein) can be sufficient to cause the outer layer to break to release the additive materials therefrom.
For example, in a cigarette, an outer layer can be designed to break when smoke is drawn through the walls of the hollow fibers, wherein the vacuum pressure of drawing the smoke can cause the outer layer to break. In other words, when a smoker can puff on a cigarette causing the outer layer to be broken by the smoke being drawn through the walls of the hollow fibers and additive materials can be released into the smoke as it passed through the walls of the hollow fibers.
The outer layer can be formed by any method capable of applying a film that is sufficiently thin to allow vacuum pressure to rupture the film. Preferably, the outer layer is applied by spraying a film forming material onto the outer surfaces of hollow fibers and allowing for the film forming material to solidify into a film to provide an outer layer.
4. Smoking Articles
In a preferred embodiment, the hollow fibers 10 are used in smoking articles, along with sorbents, such as microporous materials, to filter or remove gas phase constituents from cigarette smoke. Sorbents (i.e., microporous sorbents) such as an activated carbon and/or a zeolite sorbent can be used.
While any suitable material can be used as a sorbent, a preferred embodiment includes activated carbon. However, sorbents can hinder a cigarette designer's ability to add materials, such as volatile flavor components like menthol, as the sorbents can adsorb and/or absorb migrating volatile compounds during the time between cigarette manufacture and its being smoked.
Two problems occur when additive materials, such as volatile flavor components, are included in smoking articles with sorbents: first, the additive materials can migrate throughout the smoking article; and second, the additive materials can be adsorbed or absorbed by the sorbents. These problems have previously been addressed by using centrally located flavor elements in commonly assigned U.S. patent application Ser. No. 2003/0224918, as well as filters for a smoking article containing a flavored hollow fiber in U.S. Pat. No. 4,971,078, both of which are incorporated herein in their entirety by reference.
When additive materials are sorbed by sorbents, not only can additive materials be lost, but also the additive materials can also occupy active sites in the sorbent. If the additive materials occupy active sites in the sorbent, the ability of the sorbent to remove targeted gases or constituents from smoke can be compromised. However, hollow fibers 10 can be used to overcome this problem by containing and isolating the additive materials from the sorbent prior to smoking, and therefore avoiding interaction between the additive materials and the sorbent during storage.
In a cigarette filter, in addition to the hollow fibers 10 and the sorbent, a molecular sieve material can also be present. Preferably, the molecular sieve material can be present in monolithic or particle form sized at about 0.1 mm to 1 mm, and more preferably 0.3 mm to about 0.9 mm (e.g., 0.3 mm to 0.4 mm, 0.4 mm to 0.5 mm, 0.5 mm to 0.6 mm, 0.7 mm to 0.8 mm or 0.8 mm to 0.9 mm) to facilitate processing into cigarette filters so as to achieve a desirable filter pressure drop or RTD (resistance to draw).
Various filter constructions known in the art can be used, in which hollow fibers 10 can be incorporated. Exemplary filter structures that can be used include, but are not limited to, a mono filter, a dual filter, a triple filter, a single or multi cavity filter, a recessed filter, a free-flow filter, combinations thereof and the like. Filter elements are typically constructed from cellulose acetate tow or cellulose paper materials.
The length and pressure drop of the segments in a dual filter can be adjusted to provide optimal sorption, while maintaining acceptable draw resistance. Triple filters can include mouth and smoking material or tobacco side segments, and a middle segment comprising paper. Cavity filters include two spaced-apart filter plugs. The filters can also be ventilated and/or comprise additional sorbents (such as activated carbon), catalysts or other additives suitable for use in a cigarette filter.
Additionally, in an exemplary embodiment, a cigarette 100 with a bundle of hollow fibers 10 in the filter 130 can also include a sorbent 60. For example, as illustrated in
Preferably, the hollow fibers 10 can be located in a portion of the filter 130 downstream from the sorbent 60 with a section of filter material 70, such as cellulose acetate, between the two, as illustrated in
While a preferred filter includes a sorbent and hollow fibers 10, the hollow fibers 10 can also be used in smoking articles without a sorbent in the filter, as illustrated in
Hollow fibers can desirably be used to encapsulate additives in a smoking article, as mentioned above, wherein additives can be encapsulated within extra-cellular spaces of the hollow fibers. By such encapsulation, additives can both be protected from loss and can be mixed with entrainment air as air passes through the walls of the hollow fibers.
In order to immobilize or encapsulate additives within hollow fibers 10, hollow fibers 10 are preferably soaked in additives. Soaking allows the additives to be absorbed into extra-cellular spaces 35 of hollow fibers 10, where the additives can remain due to capillary forces, thus preventing dissipation of the additives.
The hollow fibers 10 can preferably be placed in a smoking article, more preferably a cigarette filter, where the hollow fibers 10 are aligned in a cigarette for airflow. For example, the long axes of the hollow fibers 10 can be aligned with the long axis of the cigarette for airflow purposes. Also, a downstream potting material 30 can be used to obstruct fluid flow through the downstream end of the hollow fibers 10.
Additionally, an outer layer can be formed on the hollow fibers 10 in order to prevent dissipation and to further encapsulate additive materials in extra-cellular spaces of the hollow fibers, as mentioned above.
The additives can be flavors, which can be selected from any number of known artificial and natural materials, such as, for example, peppermint, spearmint, wintergreen, menthol, cinnamon, chocolate, coffee, tobacco, vanillin, licorice, clove, anise, sandalwood, geranium, rose oil, vanilla, lemon oil, cassia, spearmint, fennel, ginger, ethylacetate, isoamylacetate, propylisobutyrate, isobutylbutyrate, ethylbutyrate, ethylvalerate, benzylformate, limonene, cymene, pinene, linalool, geraniol, citronellol, citral, peppermint oil, orange oil, coriander oil, borneol, fruit extract and the like. Illustrative of such tobacco flavorants are those described in U.S. Pat. Nos. 3,580,259; 3,625,224; 3,722,516; 3,750,674; 3,879,425; 3,881,025; 3,884,247; 3,890,981; 3,903,900; 3,914,451; 3,915,175; 3,920,027; 3,924,644; 3,966,989; 4,318,417; and the like, which are incorporated herein by reference in their entirety.
The additives can also be chemicals, wherein the chemicals can be used to attract or repel aerosols, or react with smoke constituents to remove or chemically extract smoke constituents.
For example, chemicals which can be used to attract or repel aerosols include surfactants containing distinct hydrophobic (apolar) and hydrophilic (polar) regions. For example, polar surfactants can be used to attract or repel selected tobacco smoke constituents like polar tobacco constituents due to intrinsic attractive polarity properties. For example, by attracting tobacco smoke constituents, these tobacco smoke constituents can be trapped and held within the hollow fibers chemically (in addition to mechanically being selectively separated by pore size of the walls of the hollow fibers, as mentioned above).
As mentioned above, chemicals or chemical systems can also be used to react with smoke constituents to remove smoke constituents. For example, chemical systems such as aminopropylsilyl (APS), aminoethyl aminopropylsilyl (AEAPS) and aminoethylaminoethyl aminopropylsilyl (AEAEAPS) can be used. See commonly assigned U.S. Pat. Nos. 6,595,218 and 6,209,547, both of which are hereby incorporated herein by reference in their entirety.
As mentioned above, chemicals can also be used to react with smoke constituents to extract smoke constituents. The term “chemical extractive smoking” is intended to mean providing predetermined tobacco smoke constituents to a smoker without any combustion of tobacco (i.e., smokeless smoking).
Chemical extractive smoking provides a chemical or reagent, such as water or alcohol, for interaction with tobacco in a tobacco product. By allowing the chemical or reagent to interact with tobacco, a tobacco enriched chemical or reagent can be formed, which in turn can be inhaled as a vapor or aerosol. For example, the chemical or reagent can be solvents, such as water or alcohol, such as ethyl alcohol. Preferably, the chemical extractive smoking occurs at lower than combustion temperatures; however heat can be utilized to promote vaporization (or volatilization) of the tobacco enriched chemical or reagent.
However, it is noted that heat can be used to increase the vapor and the solubility of the tobacco constituents for “smoking.” By using heat, the tobacco enriched chemical or reagent can be heat vaporized and the mobilization of the tobacco properties within the vapor can potentially be increased.
As an exemplary embodiment of a chemical extractive smoking article, a cigarette can be made with hollow fibers including immobilized chemicals therein. When “smoked,” the drawing action on one side of the hollow fibers 10 releases chemicals into the tobacco, whereupon the chemicals cause extractive release of a tobacco aerosol.
While the invention has been described in detail with reference to specific embodiments thereof, it will be apparent to those skilled in the art that various changes and modifications can be made, and equivalents employed, without departing from the scope of the appended claims.
|Citing Patent||Filing date||Publication date||Applicant||Title|
|US7946294 *||Dec 18, 2007||May 24, 2011||Philip Morris Usa Inc.||Sealed cigarette filter|
|US8113215||Jun 20, 2008||Feb 14, 2012||Philip Morris Usa Inc.||Smoking article filter having liquid additive containing tubes therein|
|US8952038||Mar 25, 2011||Feb 10, 2015||Philip Morris Usa Inc.||Inhibition of undesired sensory effects by the compound camphor|
|US9038643||Nov 7, 2011||May 26, 2015||Philip Morris Usa Inc.||Inhibition of sensory irritation during consumption of non-smokeable tobacco products|
|WO2009127894A1 *||Apr 15, 2008||Oct 22, 2009||Pt Hanjaya Mandala Sampoerna Tbk.||Filter for a smoking article|
|WO2012069791A1 *||Nov 24, 2011||May 31, 2012||Filtrona Filter Products Development Co. Pte. Ltd||Tobacco smoke filter|
|U.S. Classification||131/231, 131/232, 131/345|
|Cooperative Classification||B01D2313/14, A24D3/065, A24D3/048, B01D63/024, A24D3/14, B01D53/22, A24D3/04|
|European Classification||B01D53/22, A24D3/04, A24D3/04E, B01D63/02D, A24D3/14|
|Dec 14, 2005||AS||Assignment|
Owner name: PHILIP MORRIS USA INC., VIRGINIA
Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:RASOULL, FIROOZ;HEARN, JOHN;LI, PING;REEL/FRAME:017116/0758;SIGNING DATES FROM 20051117 TO 20051118