US20080217165A9 - Apparatus and methods for electrochemical processing of microelectronic workpieces - Google Patents

Apparatus and methods for electrochemical processing of microelectronic workpieces Download PDF

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Publication number
US20080217165A9
US20080217165A9 US11/096,428 US9642805A US2008217165A9 US 20080217165 A9 US20080217165 A9 US 20080217165A9 US 9642805 A US9642805 A US 9642805A US 2008217165 A9 US2008217165 A9 US 2008217165A9
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Prior art keywords
fluid flow
electrode
reaction vessel
workpiece
flow
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US11/096,428
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US20050189214A1 (en
Inventor
Kyle Hanson
Thomas Ritzdorf
Gregory Wilson
Paul McHugh
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Individual
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Individual
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Priority claimed from PCT/US2000/010120 external-priority patent/WO2000061498A2/en
Priority claimed from US10/158,220 external-priority patent/US20030038035A1/en
Application filed by Individual filed Critical Individual
Priority to US11/096,428 priority Critical patent/US20080217165A9/en
Publication of US20050189214A1 publication Critical patent/US20050189214A1/en
Publication of US20080217165A9 publication Critical patent/US20080217165A9/en
Abandoned legal-status Critical Current

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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/67Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere
    • H01L21/67005Apparatus not specifically provided for elsewhere
    • H01L21/67011Apparatus for manufacture or treatment
    • H01L21/67155Apparatus for manufacturing or treating in a plurality of work-stations
    • H01L21/6719Apparatus for manufacturing or treating in a plurality of work-stations characterized by the construction of the processing chambers, e.g. modular processing chambers
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D17/00Constructional parts, or assemblies thereof, of cells for electrolytic coating
    • C25D17/001Apparatus specially adapted for electrolytic coating of wafers, e.g. semiconductors or solar cells
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D7/00Electroplating characterised by the article coated
    • C25D7/12Semiconductors
    • C25D7/123Semiconductors first coated with a seed layer or a conductive layer
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/67Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere
    • H01L21/67005Apparatus not specifically provided for elsewhere
    • H01L21/67011Apparatus for manufacture or treatment
    • H01L21/67098Apparatus for thermal treatment
    • H01L21/67103Apparatus for thermal treatment mainly by conduction
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/67Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere
    • H01L21/67005Apparatus not specifically provided for elsewhere
    • H01L21/67011Apparatus for manufacture or treatment
    • H01L21/67155Apparatus for manufacturing or treating in a plurality of work-stations
    • H01L21/67207Apparatus for manufacturing or treating in a plurality of work-stations comprising a chamber adapted to a particular process
    • H01L21/6723Apparatus for manufacturing or treating in a plurality of work-stations comprising a chamber adapted to a particular process comprising at least one plating chamber

Definitions

  • This application relates to reaction vessels and methods of making and using such vessels in electrochemical processing of microelectronic workpieces.
  • Microelectronic devices such as semiconductor devices and field emission displays, are generally fabricated on and/or in microelectronic workpieces using several different types of machines (“tools”). Many such processing machines have a single processing station that performs one or more procedures on the workpieces. Other processing machines have a plurality of processing stations that perform a series of different procedures on individual workpieces or batches of workpieces. In a typical fabrication process, one or more layers of conductive materials are formed on the workpieces during deposition stages. The workpieces are then typically subject to etching and/or polishing procedures (i.e., planarization) to remove a portion of the deposited conductive layers for forming electrically isolated contacts and/or conductive lines.
  • tools such processing machines have a single processing station that performs one or more procedures on the workpieces. Other processing machines have a plurality of processing stations that perform a series of different procedures on individual workpieces or batches of workpieces.
  • etching and/or polishing procedures i.e., planarization
  • Electroplating and electroless plating techniques can be used to deposit copper, solder, permalloy, gold, silver, platinum and other metals onto workpieces for forming blanket layers or patterned layers.
  • a typical copper plating process involves depositing a copper seed layer onto the surface of the workpiece using chemical vapor deposition (CVD), physical vapor deposition (PVD), electroless plating processes, or other suitable methods. After forming the seed layer, a blanket layer or patterned layer of copper is plated onto the workpiece by applying an appropriate electrical potential between the seed layer and an anode in the presence of an electroprocessing solution. The workpiece is then cleaned, etched and/or annealed in subsequent procedures before transferring the workpiece to another processing machine.
  • FIG. 1 illustrates an embodiment of a single-wafer processing station 1 that includes a container 2 for receiving a flow of electroplating solution from a fluid inlet 3 at a lower portion of the container 2 .
  • the processing station 1 can include an anode 4 , a plate-type diffuser 6 having a plurality of apertures 7 , and a workpiece holder 9 for carrying a workpiece 5 .
  • the workpiece holder. 9 can include a plurality of electrical contacts for providing electrical current to a seed layer on the surface of the workpiece 5 . When the seed layer is biased with a negative potential relative to the anode 4 , it acts as a cathode.
  • the electroplating fluid flows around the anode 4 , through the apertures 7 in the diffuser 6 and against the plating surface of the workpiece 5 .
  • the electroplating solution is an electrolyte that conducts electrical current between the anode 4 and the cathodic seed layer on the surface of the workpiece 5 . Therefore, ions in the electroplating solution plate the surface of the workpiece 5 .
  • the plating machines used in fabricating microelectronic devices must meet many specific performance criteria. For example, many processes must be able to form small contacts in vias that are less than 0.5 ⁇ m wide, and are desirably less than 0.1 ⁇ m wide.
  • the plated metal layers accordingly often need to fill vias or trenches that are on the order of 0.1 ⁇ m wide, and the layer of plated material should also be deposited to a desired, uniform thickness across the surface of the workpiece 5 .
  • One factor that influences the uniformity of the plated layer is the mass transfer of electroplating solution at the surface of the workpiece. This parameter is generally influenced by the velocity of the flow of the electroplating solution perpendicular to the surface of the workpiece.
  • Another factor that influences the uniformity of the plated layer is the current density of the electrical field across the surface of the wafer.
  • existing plating tools generally use the diffuser 6 to enhance the uniformity of the fluid flow perpendicular to the face of the workpiece.
  • the diffuser 6 improves the uniformity of the fluid flow, it produces a plurality of localized areas of increased flow velocity perpendicular to the surface of the workpiece 5 (indicated by arrows 8 ).
  • the localized areas generally correspond to the position of the apertures 7 in the diffuser 6 .
  • the increased velocity of the fluid flow normal to the substrate in the localized areas increases the mass transfer of the electroplating solution in these areas. This typically results in faster plating rates in the localized areas over the apertures 7 .
  • many different configurations of apertures have been used in plate-type diffusers, these diffusers may not provide adequate uniformity for the precision required in many current applications.
  • the diffusion layer in the electroplating solution adjacent to the surface of the workpiece 5 can be disrupted by gas bubbles or particles.
  • bubbles can be introduced to the plating solution by the plumbing and pumping system of the processing equipment, or they can evolve from inert anodes.
  • Consumable anodes are often used to prevent or reduce the evolvement of gas bubbles in the electroplating solution, but these anodes erode and they can form a passivated film surface that must be maintained.
  • Consumable anodes moreover, often generate particles that can be carried in the plating solution.
  • gas bubbles and/or particles can flow to the surface of the workpiece 5 , which disrupts the uniformity and affects the quality of the plated layer.
  • Still another challenge of plating uniform layers is providing a desired electrical field at the surface of the workpiece 5 .
  • the distribution of electrical current in the plating solution is a function of the uniformity of the seed layer across the contact surface, the configuration/condition of the anode, and the configuration of the chamber.
  • the current density profile on the plating surface can change.
  • the current density profile typically changes during a plating cycle because plating material covers the seed layer, or it can change over a longer period of time because the shape of consumable anodes changes as they erode and the concentration of constituents in the plating solution can change. Therefore, it can be difficult to maintain a desired current density at the surface of the workpiece 5 .
  • the present invention is directed toward reaction vessels for electrochemical processing of microelectronic workpieces, processing stations including such reaction vessels, and methods for using these devices.
  • reaction vessels in accordance with the invention solve the problem of providing a desired mass transfer at the workpiece by configuring the electrodes so that a primary flow guide and/or a field shaping unit in the reaction vessel direct a substantially uniform primary fluid flow toward the workpiece.
  • field shaping units in accordance with several embodiments of the invention create virtual electrodes such that the workpiece is shielded from the electrodes.
  • additional embodiments of the invention include interface members in the reaction vessel that inhibit particulates, bubbles and other undesirable matter in the reaction vessel from contacting the workpiece to enhance the uniformity and the quality of the finished surface on the workpieces.
  • the interface members can also allow two different types of fluids to be used in the reaction vessel, such as a catholyte and an anolyte, to reduce the need to replenish additives as often and to add more flexibility to designing electrodes and other components in the reaction vessel.
  • a reaction vessel in one embodiment, includes an outer container having an outer wall, a first outlet configured to introduce a primary fluid flow into the outer container, and at least one second outlet configured to introduce a secondary fluid flow into the outer container separate from the primary fluid flow.
  • the reaction vessel can also include a field shaping unit in the outer container and at least one electrode.
  • the field shaping unit can be a dielectric assembly coupled to the second outlet to receive the secondary flow and configured to contain the secondary flow separate from the primary flow through at least a portion of the outer container.
  • the field shaping unit also has at least one electrode compartment through which the secondary flow can pass separately from the primary flow. The electrode is positioned in the electrode compartment.
  • the field shaping unit has a compartment assembly having a plurality of electrode compartments and a virtual electrode unit.
  • the compartment assembly can include a plurality of annular walls including an inner or first annular wall centered on a common axis and an outer or second annular wall concentric with the first annular wall and spaced radially outward.
  • the annular walls of the field shaping unit can be positioned inside of outer wall of the outer container so that an annular space between the first and second walls defines a first electrode compartment and an annular space between the second wall and the outer wall defines a second electrode compartment.
  • the reaction vessel of this particular embodiment can have a first annular electrode in the first electrode compartment and/or a second annular electrode in the second electrode compartment.
  • the virtual electrode unit can include a plurality of partitions that have lateral sections attached to corresponding annular walls of the electrode compartment and lips that project from the lateral sections.
  • the first partition has an annular first lip that defines a central opening
  • the second partition has an annular second lip surrounding the first lip that defines an annular opening.
  • the reaction vessel can further include a distributor coupled to the outer container and a primary flow guide in the outer container.
  • the distributor can include the first outlet and the second outlet such that the first outlet introduces the primary fluid flow into the primary flow guide and the second outlet introduces the secondary fluid flow into the field shaping unit separately from the primary flow.
  • the primary flow guide can condition the primary flow for providing a desired fluid flow to a workpiece processing site. In one particular embodiment, the primary flow guide directs the primary flow through the central opening of the first annular lip of the first partition. The secondary flow is distributed to the electrode compartments of the field shaping unit to establish an electrical field in the reaction vessel.
  • the primary flow can pass through a first flow channel defined, at least in part, by the primary flow guide and the lip of the first partition.
  • the primary flow can be the dominant flow through the reaction vessel so that it controls the mass transfer at the workpiece.
  • the secondary flow can generally be contained within the field shaping unit so that the electrical field(s) of the electrode(s) are shaped by the virtual electrode unit and the electrode compartments.
  • the electrical effect of the first electrode can act as if it is placed in the central opening defined by the lip of the first partition
  • the electrical effect of the second electrode can act as if it is placed in the annular opening between the first and second lips.
  • the actual electrodes can be shielded from the workpiece by the field shaping unit such that the size and shape of the actual electrodes does not affect the electrical field perceived by the workpiece.
  • the field shaping unit shields the workpiece from the electrodes.
  • the electrodes can be much larger than they could without the field shaping unit because the size and configuration of the actual electrodes does not appreciably affect the electrical field perceived by the workpiece.
  • This is particularly useful when the electrodes are consumable anodes because the increased size of the anodes prolongs their life, which reduces downtime for servicing a tool. Additionally, this reduces the need to “burn-in” anodes because the field shaping element reduces the impact that films on the anodes have on the shape of the electrical field perceived by the workpiece. Both of these benefits significantly improve the operating efficiency of the reaction vessel.
  • Another feature of several embodiments of the invention is that they provide a uniform mass transfer at the surface of the workpiece.
  • the field shaping unit separates the actual electrodes from the effective area where they are perceived by the workpiece, the actual electrodes can be configured to accommodate internal structure that guides the flow along a more desirable flow path. For example, this allows the primary flow to flow along a central path.
  • a particular embodiment includes a central primary flow guide that projects the primary flow radially inward along diametrically opposed vectors that create a highly uniform primary flow velocity in a direction perpendicular to the surface of the workpiece.
  • the reaction vessel can also include an interface member carried by the field shaping unit downstream from the electrode.
  • the interface member can be in fluid communication with the secondary flow in the electrode compartment.
  • the interface member for example, can be a filter and/or an ion-membrane.
  • the interface member can inhibit particulates (e.g., particles from an anode) and bubbles in the secondary flow from reaching the surface of the workpiece to reduce non-uniformities on the processed surface. This accordingly increases the quality of the surface of the workpiece.
  • the interface member can be configured to prevent fluids from passing between the secondary flow and the primary flow while allowing preferred ions to pass between the flows. This allows the primary flow and the secondary flow to be different types of fluids, such as a catholyte and an anolyte, which reduces the need to replenish additives as often and adds more flexibility to designing electrodes and other features of the reaction vessel.
  • FIG. 1 is a schematic diagram of an electroplating chamber in accordance with the prior art.
  • FIG. 2 is an isometric view of an electroprocessing machine having electroprocessing stations for processing microelectronic workpieces in accordance with an embodiment of the invention.
  • FIG. 3 is a cross-sectional view of an electroprocessing station having a processing chamber for use in an electroprocessing machine in accordance with an embodiment of the invention. Selected components in FIG. 3 are shown schematically.
  • FIG. 4 is an isometric view showing a cross-sectional portion of a processing chamber taken along line 4 - 4 of FIG. 8A .
  • FIGS. 5A-5D are cross-sectional views of a distributor for a processing chamber in accordance with an embodiment of the invention.
  • FIG. 6 is an isometric view showing a different cross-sectional portion of the processing chamber of FIG. 4 taken along line 6 - 6 of FIG. 8B .
  • FIG. 7A is an isometric view of an interface assembly for use in a processing chamber in accordance with an embodiment of the invention.
  • FIG. 7B is a cross-sectional view of the interface assembly of FIG. 7A .
  • FIGS. 8A and 8B are top plan views of a processing chamber that provide a reference for the isometric, cross-sectional views of FIGS. 4 and 6 , respectively.
  • microelectronic workpiece is used throughout to include a workpiece formed from a substrate upon which and/or in which microelectronic circuits or components, data storage elements or layers, and/or micro-mechanical elements are fabricated. It will be appreciated that several of the details set forth below are provided to describe the following embodiments in a manner sufficient to enable a person skilled in the art to make and use the disclosed embodiments. Several of the details and advantages described below, however, may not be necessary to practice certain embodiments of the invention. Additionally, the invention can also include additional embodiments that are within the scope of the claims, but are not described in detail with respect to FIGS. 2-8B .
  • electrochemical reaction vessels are best understood in light of the environment and equipment in which they can be used to electrochemically process workpieces (e.g., electroplate and/or electropolish). As such, embodiments of integrated tools with processing stations having the electrochemical reaction vessels are initially described with reference to FIGS. 2 and 3 . The details and features of several embodiments of electrochemical reaction vessels are then described with reference to FIGS. 4-8B .
  • FIG. 2 is an isometric view of a processing machine 100 having an electrochemical processing station 120 in accordance with an embodiment of the invention. A portion of the processing machine 100 is shown in a cut-away view to illustrate selected internal components.
  • the processing machine 100 can include a cabinet 102 having an interior region 104 defining an interior enclosure that is at least partially isolated from an exterior region 105 .
  • the cabinet 102 can also include a plurality of apertures 106 (only one shown in FIG. 1 ) through which microelectronic workpieces 101 can ingress and egress between the interior region 104 and a load/unload station 110 .
  • the load/unload station 110 can have two container supports 112 that are each housed in a protective shroud 113 .
  • the container supports 112 are configured to position workpiece containers 114 relative to the apertures 106 in the cabinet 102 .
  • the workpiece containers 114 can each house a plurality of microelectronic workpieces 101 in a “mini” clean environment for carrying a plurality of workpieces through other environments that are not at clean room standards.
  • Each of the workpiece containers 114 is accessible from the interior region 104 of the cabinet 102 through the apertures 106 .
  • the processing machine 100 can also include a plurality of electrochemical processing stations 120 and a transfer device 130 in the interior region 104 of the cabinet 102 .
  • the processing machine 100 can be a plating tool that also includes clean/etch capsules 122 , electroless plating stations, annealing stations, and/or metrology stations.
  • the transfer device 130 includes a linear track 132 extending in a lengthwise direction of the interior region 104 between the processing stations.
  • the transfer device 130 can further include a robot unit 134 carried by the track 132 .
  • a first set of processing stations is arranged along a first row R 1 -R 1 and a second set of processing stations is arranged long a second row R 2 -R 2 .
  • the linear track 132 extends between the first and second rows of processing stations, and the robot unit 134 can access any of the processing stations along the track 132 .
  • FIG. 3 illustrates an embodiment of an electrochemical-processing chamber 120 having a head assembly 150 and a processing chamber 200 .
  • the head assembly 150 includes a spin motor 152 , a rotor 154 coupled to the spin motor 152 , and a contact assembly 160 carried by the rotor 154 .
  • the rotor 154 can have a backing plate 155 and a seal 156 .
  • the backing plate 155 can move transverse to a workpiece 101 (arrow T) between a first position in which the backing plate 155 contacts a backside of the workpiece 101 (shown in solid lines in FIG. 3 ) and a second position in which it is spaced apart from the backside of the workpiece 101 (shown in broken lines in FIG. 3 ).
  • the contact assembly 160 can have a support member 162 , a plurality of contacts 164 carried by the support member 162 , and a plurality of shafts 166 extending between the support member 162 and the rotor 154 .
  • the contacts 164 can be ring-type spring contacts or other types of contacts that are configured to engage a portion of the seed-layer on the workpiece 101 .
  • Commercially available head assemblies 150 and contact assemblies 160 can be used in the electroprocessing chamber 120 . Particular suitable head assemblies 150 and contact assemblies 160 are disclosed in U.S. Pat. Nos. 6,228,232 and 6,080,691; and U.S. application Ser. Nos. 09/385,784; 09/386,803; 09/386,610; 09/386,197; 09/501,002; 09/733,608; and 09/804,696, all of which are herein incorporated by reference.
  • the processing chamber 200 includes an outer housing 202 (shown schematically in FIG. 3 ) and a reaction vessel 204 (also shown schematically in FIG. 3 ) in the housing 202 .
  • the reaction vessel 204 carries at least one electrode (not shown in FIG. 3 ) and directs a flow of electroprocessing solution to the workpiece 101 .
  • the electroprocessing solution for example, can flow over a weir (arrow F) and into the external housing 202 , which captures the electroprocessing solution and sends it back to a tank.
  • Several embodiments of reaction vessels 204 are shown and described in detail with reference to FIGS. 4-8B .
  • the head assembly 150 holds the workpiece at a workpiece-processing site of the reaction vessel 204 so that at least a plating surface of the workpiece engages the electroprocessing solution.
  • An electrical field is established in the solution by applying an electrical potential between the plating surface of the workpiece via the contact assembly 160 and one or more electrodes in the reaction vessel 204 .
  • the contact assembly 160 can be biased with a negative potential with respect to the electrode(s) in the reaction vessel 204 to plate materials onto the workpiece.
  • the contact assembly 160 can be biased with a positive potential with respect to the electrode(s) in the reaction vessel 204 to (a) de-plate or electropolish plated material from the workpiece or (b) deposit other materials (e.g., electrophoric resist).
  • materials can be deposited on or removed from the workpiece with the workpiece acting as a cathode or an anode depending upon the particular type of material used in the electrochemical process.
  • FIGS. 4-8B illustrate several embodiments of reaction vessels 204 for use in the processing chamber 200 .
  • the housing 202 carries the reaction vessel 204 .
  • the housing 202 can have a drain 210 for returning the processing fluid that flows out of the reaction vessel 204 to a storage tank, and a plurality of openings for receiving inlets and electrical fittings.
  • the reaction vessel 204 can include an outer container 220 having an outer wall 222 spaced radially inwardly of the housing 202 .
  • the outer container 220 can also have a spiral spacer 224 between the outer wall 222 and the housing 202 to provide a spiral ramp (i.e., a helix) on which the processing fluid can flow downward to the bottom of the housing 202 .
  • the spiral ramp reduces the turbulence of the return fluid to inhibit entrainment of gasses in the return fluid.
  • the particular embodiment of the reaction vessel 204 shown in FIG. 4 can include a distributor 300 for receiving a primary fluid flow F p and a secondary fluid flow F 2 , a primary flow guide 400 coupled to the distributor 300 to condition the primary fluid flow F p , and a field shaping unit 500 coupled to the distributor 300 to contain the secondary flow F 2 in a manner that shapes the electrical field in the reaction vessel 204 .
  • the reaction vessel 204 can also include at least one electrode 600 in a compartment of the field shaping unit 500 and at least one filter or other type of interface member 700 carried by the field shaping unit 500 downstream from the electrode.
  • the primary flow guide 400 can condition the primary flow F p by projecting this flow radially inwardly relative to a common axis A-A, and a portion of the field shaping unit 500 directs the conditioned primary flow F p toward the workpiece.
  • the primary flow passing through the primary flow guide 400 and the center of the field shaping unit 500 controls the mass transfer of processing solution at the surface of the workpiece.
  • the field shaping unit 500 also defines the shape the electric field, and it can influence the mass transfer at the surface of the workpiece if the secondary flow passes through the field shaping unit.
  • the reaction vessel 204 can also have other configurations of components to guide the primary flow F p and the secondary flow F 2 through the processing chamber 200 .
  • the reaction vessel 204 may not have a distributor in the processing chamber, but rather separate fluid lines with individual flows can be coupled to the vessel 204 to provide a desired distribution of fluid through the primary flow guide 400 and the field shaping unit.
  • the reaction vessel 204 can have a first outlet in the outer container 220 for introducing the primary flow into the reaction vessel and a second outlet in the outer container for introducing the secondary flow into the reaction vessel 204 .
  • FIGS. 5A-5D illustrate an embodiment of the distributor 300 for directing the primary fluid flow to the primary flow guide 400 and the secondary fluid flow to the field shaping unit 500 .
  • the distributor 300 can include a body 310 having a plurality of annular steps 312 (identified individually by reference numbers 312 a - d ) and annular grooves 314 in the steps 312 .
  • the outermost step 312 d is radially inward of the outer wall 222 (shown in broken lines) of the outer container 220 ( FIG. 4 ), and each of the interior steps 312 a - c can carry annular wall (shown in broken lines) of the field shaping unit 500 in a corresponding groove 314 .
  • the distributor 300 can also include a first inlet 320 for receiving the primary flow F p and a plenum 330 for receiving the secondary flow F 2 .
  • the first inlet 320 can have an inclined, annular cavity 322 to form a passageway 324 (best shown in FIG. 4 ) for directing the primary fluid flow F p under the primary flow guide 400 .
  • the distributor 300 can also have a plurality of upper orifices 332 along an upper part of the plenum 330 and a plurality of lower orifices 334 along a lower part of the plenum 330 .
  • the upper and lower orifices are open to channels through the body 310 to distribute the secondary flow F 2 to the risers of the steps 312 .
  • the distributor 300 can also have other configurations, such as a “step-less” disk or non-circular shapes.
  • FIGS. 5A-5D further illustrate one configuration of channels through the body 310 of the distributor 300 .
  • a number of first channels 340 extend from some of the lower orifices 334 to openings at the riser of the first step 312 a.
  • FIG. 5B shows a number of second channels 342 extending from the upper orifices 332 to openings at the riser of the second step 312 b
  • FIG. 5C shows a number of third channels 344 extending from the upper orifices 332 to openings at the riser of the third step 312 c.
  • FIG. 5D illustrates a number of fourth channels 346 extending from the lower orifices 334 to the riser of the fourth step 312 d.
  • the particular embodiment of the channels 340 - 346 in FIGS. 5A-5D are configured to transport bubbles that collect in the plenum 330 radially outward as far as practical so that these bubbles can be captured and removed from the secondary flow F 2 .
  • a bubble B in the compartment above the first step 312 a can sequentially cascade through the compartments over the second and third steps 312 b - c, and then be removed from the compartment above the fourth step 312 d.
  • the first channel 340 ( FIG.
  • the 5A accordingly carries fluid from the lower orifices 334 where bubbles are less likely to collect to reduce the amount of gas that needs to cascade from the inner compartment above the first step 312 a all the way out to the outer compartment.
  • the bubbles in the secondary flow F 2 are more likely to collect at the top of the plenum 330 before passing through the channels 340 - 346 .
  • the upper orifices 332 are accordingly coupled to the second channel 342 and the third channel 344 to deliver these bubbles outward beyond the first step 312 a so that they do not need to cascade through so many compartments.
  • the upper orifices 332 are not connected to the fourth channels 346 because this would create a channel that inclines downwardly from the common axis such that it may conflict with the groove 314 in the third step 312 c.
  • the fourth channel 346 extends from the lower orifices 334 to the fourth step 312 d.
  • the primary flow guide 400 receives the primary fluid flow F p via the first inlet 320 of the distributor 300 .
  • the primary flow guide 400 includes an inner baffle 410 and an outer baffle 420 .
  • the inner baffle can have a base 412 and a wall 414 projecting upward and radially outward from the base 412 .
  • the wall 414 for example, can have an inverted frusto-conical shape and a plurality of apertures 416 .
  • the apertures 416 can be holes, elongated slots or other types of openings.
  • the apertures 416 are annularly extending radial slots that slant upward relative to the common axis to project the primary flow radially inward and upward relative to the common axis along a plurality of diametrically opposed vectors.
  • the inner baffle 410 can also includes a locking member 418 that couples the inner baffle 410 to the distributor 300 .
  • the outer baffle 420 can include an outer wall 422 with a plurality of apertures 424 .
  • the apertures 424 are elongated slots extending in a direction transverse to the apertures 416 of the inner baffle 410 .
  • the primary flow F p flows through (a) the first inlet 320 , (b) the passageway 324 under the base 412 of the inner baffle 410 , (c) the apertures 424 of the outer baffle 420 , and then (d) the apertures 416 of the inner baffles 410 .
  • the combination of the outer baffle 420 and the inner baffle 410 conditions the direction of the flow at the exit of the apertures 416 in the inner baffle 410 .
  • the primary flow guide 400 can thus project the primary flow along diametrically opposed vectors that are inclined upward relative to the common axis to create a fluid flow that has a highly uniform velocity.
  • the apertures 416 do not slant upward relative to the common axis such that they can project the primary flow normal, or even downward, relative to the common axis.
  • FIG. 4 also illustrates an embodiment of the field shaping unit 500 that receives the primary fluid flow F p downstream from the primary flow guide 400 .
  • the field shaping unit 500 also contains the second fluid flow F 2 and shapes the electrical field within the reaction vessel 204 .
  • the field shaping unit 500 has a compartment structure with a plurality of walls 510 (identified individually by reference numbers 510 a - d ) that define electrode compartments 520 (identified individually by reference numbers 520 a - d ).
  • the walls 510 can be annular skirts or dividers, and they can be received in one of the annular grooves 314 in the distributor 300 .
  • the walls 510 are not fixed to the distributor 300 so that the field shaping unit 500 can be quickly removed from the distributor 300 . This allows easy access to the electrode compartments 520 and/or quick removal of the field shaping unit 500 to change the shape of the electric field.
  • the field shaping unit 500 can have at least one wall 510 outward from the primary flow guide 400 to prevent the primary flow F p from contacting an electrode.
  • the field shaping unit 500 has a first electrode compartment 520 a defined by a first wall 510 a and a second wall 510 b, a second electrode compartment 520 b defined by the second wall 510 b and a third wall 510 c, a third electrode compartment 520 c defined by the third wall 510 c and a fourth wall 510 d, and a fourth electrode compartment 520 d defined by the fourth wall 510 d and the outer wall of the container 220 .
  • the walls 510 a - d of this embodiment are concentric annular dividers that define annular electrode compartments 520 a - d.
  • Alternate embodiments of the field shaping unit can have walls with different configurations to create non-annular electrode compartments and/or each electrode compartment can be further divided into cells.
  • the second-fourth walls 510 b - d can also include holes 522 for allowing bubbles in the first-third electrode compartments 520 a - c to “cascade” radially outward to the next outward electrode compartment 520 as explained above with respect to FIGS. 5A-5D .
  • the bubbles can then exit the fourth electrode compartment 520 d through an exit hole 525 through the outer wall 222 .
  • the bubbles can exit through an exit hole 524 .
  • the electrode compartments 520 provide electrically discrete compartments to house an electrode assembly having at least one electrode and generally two or more electrodes 600 (identified individually by reference numbers 600 a - d ).
  • the electrodes 600 can be annular members (e.g., annular rings or arcuate sections) that are configured to fit within annular electrode compartments, or they can have other shapes appropriate for the particular workpiece (e.g., rectilinear).
  • the electrode assembly includes a first annular electrode 600 a in the first electrode compartment 520 a, a second annular electrode 600 b in the second electrode compartment 520 b, a third annular electrode 600 c in the third electrode compartment 520 c, and a fourth annular electrode 600 d in the fourth electrode compartment 520 d.
  • each of the electrodes 600 a - d can be biased with the same or different potentials with respect to the workpiece to control the current density across the surface of the workpiece.
  • the electrodes 600 can be non-circular shapes or sections of other shapes.
  • Embodiments of the reaction vessel 204 that include a plurality of electrodes provide several benefits for plating or electropolishing.
  • the electrodes 600 can be biased with respect to the workpiece at different potentials to provide uniform plating on different workpieces even though the seed layers vary from one another or the bath(s) of electroprocessing solution have different conductivities and/or concentrations of constituents.
  • another the benefit of having a multiple electrode design is that plating can be controlled to achieve different final fill thicknesses of plated layers or different plating rates during a plating cycle or in different plating cycles.
  • the current density can be controlled to (a) provide a uniform current density during feature filling and/or (b) achieve plating to specific film profiles across a workpiece (e.g., concave, convex, flat).
  • the multiple electrode configurations in which the electrodes are separate from one another provide several benefits for controlling the electrochemical process to (a) compensate for deficiencies or differences in seed layers between workpieces, (b) adjust for variances in baths of electroprocessing solutions, and/or (c) achieve predetermined feature filling or film profiles.
  • the field shaping unit 500 can also include a virtual electrode unit coupled to the walls 510 of the compartment assembly for individually shaping the electrical fields produced by the electrodes 600 .
  • the virtual electrode unit includes first-fourth partitions 530 a - 530 d, respectively.
  • the first partition 530 a can have a first section 532 a coupled to the second wall 510 b, a skirt 534 depending downward above the first wall 510 a, and a lip 536 a projecting upwardly.
  • the lip 536 a has an interior surface 537 that directs the primary flow F p exiting from the primary flow guide 400 .
  • the second partition 530 b can have a first section 532 b coupled to the third wall 510 c and a lip 536 b projecting upward from the first section 532 b
  • the third partition 530 c can have a first section 532 c coupled to the fourth wall 510 d and a lip 536 c projecting upward from the first section 532 c
  • the fourth partition 530 d can have a first section 532 d carried by the outer wall 222 of the container 220 and a lip 536 d projecting upward from the first section 532 d.
  • the fourth partition 530 d may not be connected to the outer wall 222 so that the field shaping unit 500 can be quickly removed from the vessel 204 by simply lifting the virtual electrode unit.
  • the interface between the fourth partition 530 d and the outer wall 222 is sealed by a seal 527 to inhibit both the fluid and the electrical current from leaking out of the fourth electrode compartment 520 d.
  • the seal 527 can be a lip seal.
  • each of the sections 532 a - d can be lateral sections extending transverse to the common axis.
  • the individual partitions 530 a - d can be machined from or molded into a single piece of dielectric material, or they can be individual dielectric members that are welded together. In alternate embodiments, the individual partitions 530 a - d are not attached to each other and/or they can have different configurations. In the particular embodiment shown in FIG. 4 , the partitions 530 a - d are annular horizontal members, and each of the lips 536 a - d are annular vertical members arranged concentrically about the common axis.
  • the walls 510 and the partitions 530 a - d are generally dielectric materials that contain the second flow F 2 of the processing solution for shaping the electric fields generated by the electrodes 600 a - d.
  • the second flow F 2 can pass (a) through each of the electrode compartments 520 a - d, (b) between the individual partitions 530 a - d, and then (c) upward through the annular openings between the lips 536 a - d.
  • the secondary flow F 2 through the first electrode compartment 520 a can join the primary flow F p in an antechamber just before the primary flow guide 400
  • the secondary flow through the second-fourth electrode compartments 520 b - d can join the primary flow F p beyond the top edges of the lips 536 a - d.
  • the flow of electroprocessing solution then flows over a shield weir attached at rim 538 and into the gap between the housing 202 and the outer wall 222 of the container 220 as disclosed in International Application No. PCT/US00/10120.
  • the fluid in the secondary flow F 2 can be prevented from flowing out of the electrode compartments 520 a - d to join the primary flow F p while still allowing electrical current to pass from the electrodes 600 to the primary flow.
  • the secondary flow F 2 can exit the reaction vessel 204 through the holes 522 in the walls 510 and the hole 525 in the outer wall 222 .
  • a duct can be coupled to the exit hole 525 in the outer wall 222 so that a return flow of the secondary flow passing out of the field shaping unit 500 does not mix with the return flow of the primary flow passing down the spiral ramp outside of the outer wall 222 .
  • the field shaping unit 500 can have other configurations that are different than the embodiment shown in FIG. 4 .
  • the electrode compartment assembly can have only a single wall 510 defining a single electrode compartment 520
  • the reaction vessel 204 can include only a single electrode 600 .
  • the field shaping unit of either embodiment still separates the primary and secondary flows so that the primary flow does not engage the electrode, and thus it shields the workpiece from the single electrode.
  • One advantage of shielding the workpiece from the electrodes 600 a - d is that the electrodes can accordingly be much larger than they could be without the field shaping unit because the size of the electrodes does not have an effect on the electrical field presented to the workpiece. This is particularly useful in situations that use consumable electrodes because increasing the size of the electrodes prolongs the life of each electrode, which reduces downtime for servicing and replacing electrodes.
  • reaction vessel 204 shown in FIG. 4 can accordingly have a first conduit system for conditioning and directing the primary fluid flow F p to the workpiece, and a second conduit system for conditioning and directing the secondary fluid flow F 2 .
  • the first conduit system can include the inlet 320 of the distributor 300 ; the channel 324 between the base 412 of the primary flow guide 400 and the inclined cavity 322 of the distributor 300 ; a plenum between the wall 422 of the outer baffle 420 and the first wall 510 a of the field shaping unit 500 ; the primary flow guide 400 ; and the interior surface 537 of the first lip 536 a.
  • the first conduit system conditions the direction of the primary fluid flow F p by passing it through the primary flow guide 400 and along the interior surface 537 so that the velocity of the primary flow F p normal to the workpiece is at least substantially uniform across the surface of the workpiece.
  • the primary flow F p and the rotation of the workpiece can accordingly be controlled to dominate the mass transfer of electroprocessing medium at the workpiece.
  • the second conduit system can include the plenum 330 and the channels 340 - 346 of the distributor 300 , the walls 510 of the field shaping unit 500 , and the partitions 530 of the field shaping unit 500 .
  • the secondary flow F 2 contacts the electrodes 600 to establish individual electrical fields in the field shaping unit 500 that are electrically coupled to the primary flow F p .
  • the field shaping unit 500 separates the individual electrical fields created by the electrodes 600 a - d to create “virtual electrodes” at the top of the openings defined by the lips 536 a - d of the partitions.
  • the central opening inside the first lip 536 a defines a first virtual electrode
  • the annular opening between the first and second lips 536 a - b defines a second virtual electrode
  • the annular opening between the second and third lips 536 b - c defines a third virtual electrode
  • the annular opening between the third and fourth lips 536 c - d defines a fourth virtual electrode.
  • These are “virtual electrodes” because the field shaping unit 500 shapes the individual electrical fields of the actual electrodes 600 a - d so that the effect of the electrodes 600 a - d acts as if they are placed between the top edges of the lips 536 a - d. This allows the actual electrodes 600 a - d to be isolated from the primary fluid flow, which can provide several benefits as explained in more detail below.
  • An additional embodiment of the processing chamber 200 includes at least one interface member 700 (identified individually by reference numbers 700 a - d ) for further conditioning the secondary flow F 2 of electroprocessing solution.
  • the interface members 700 can be filters that capture particles in the secondary flow that were generated by the electrodes (i.e., anodes) or other sources of particles.
  • the filter-type interface members 700 can also inhibit bubbles in the secondary flow F 2 from passing into the primary flow F p of electroprocessing solution. This effectively forces the bubbles to pass radially outwardly through the holes 522 in the walls 510 of the field shaping unit 500 .
  • the interface members 700 can be ion-membranes that allow ions in the secondary flow F 2 to pass through the interface members 700 .
  • the ion-membrane interface members 700 can be selected to (a) allow the fluid of the electroprocessing solution and ions to pass through the interface member 700 , or (b) allow only the desired ions to pass through the interface member such that the fluid itself is prevented from passing beyond the ion-membrane.
  • FIG. 6 is another isometric view of the reaction vessel 204 of FIG. 4 showing a cross-sectional portion taken along a different cross-section. More specifically, the cross-section of FIG. 4 is shown in FIG. 8A and the cross-section of FIG. 6 is shown in FIG. 8B .
  • this illustration further shows one embodiment for configuring a plurality of interface members 700 a - d relative to the partitions 530 a - d of the field shaping unit 500 .
  • a first interface member 700 a can be attached to the skirt 534 of the first partition 530 a so that a first portion of the secondary flow F 2 flows past the first electrode 600 a, through an opening 535 in the skirt 534 , and then to the first interface member 700 a.
  • Another portion of the secondary flow F 2 can flow past the second electrode 600 b to the second interface member 700 b. Similarly, portions of the secondary flow F 2 can flow past the third and fourth electrodes 600 c - d to the third and fourth interface members 700 c - d.
  • the secondary flow F 2 joins the primary fluid flow F p .
  • the portion of the secondary flow F 2 in the first electrode compartment 520 a can pass through the opening 535 in the skirt 534 and the first interface member 700 a, and then into a plenum between the first wall 510 a and the outer wall 422 of the baffle 420 .
  • This portion of the secondary flow F 2 accordingly joins the primary flow F p and passes through the primary flow guide 400 .
  • the other portions of the secondary flow F 2 in this particular embodiment pass through the second-fourth electrode compartments 520 b - d and then through the annular openings between the lips 536 a - d.
  • the second-fourth interface members 700 b - d can accordingly be attached to the field shaping unit 500 downstream from the second-fourth electrodes 600 b - d.
  • the second interface member 700 b is positioned vertically between the first and second partitions 530 a - b
  • the third interface member 700 c is positioned vertically between the second and third partitions 530 b - c
  • the fourth interface member 700 d is positioned vertically between the third and fourth partitions 530 c - d.
  • the interface assemblies 710 a - d are generally installed vertically, or at least at an upwardly inclined angle relative to horizontal, to force the bubbles to rise so that they can escape through the holes 522 in the walls 510 a - d ( FIG. 4 ). This prevents aggregations of bubbles that could potentially disrupt the electrical field from an individual electrode.
  • FIGS. 7A and 7B illustrate an interface assembly 710 for mounting the interface members 700 to the field shaping unit 500 in accordance with an embodiment of the invention.
  • the interface assembly 710 can include an annular interface member 700 and a fixture 720 for holding the interface member 700 .
  • the fixture 720 can include a first frame 730 having a plurality of openings 732 and a second frame 740 having a plurality of openings 742 (best shown in FIG. 7A ).
  • the holes 732 in the first frame can be aligned with the holes 742 in the second frame 740 .
  • the second frame can further include a plurality of annular teeth 744 extending around the perimeter of the second frame.
  • the teeth 744 can alternatively extend in a different direction on the exterior surface of the second frame 740 in other embodiments, but the teeth 744 generally extend around the perimeter of the second frame 740 in a top annular band and a lower annular band to provide annular seals with the partitions 536 a - d ( FIG. 6 ).
  • the interface member 700 can be pressed between the first frame 730 and the second frame 740 to securely hold the interface member 700 in place.
  • the interface assembly 710 can also include a top band 750 a extending around the top of the frames 730 and 740 and a bottom band 750 b extending around the bottom of the frames 730 and 740 .
  • the top and bottom bands 750 a - b can be welded to the frames 730 and 740 by annular welds 752 . Additionally, the first and second frames 730 and 740 can be welded to each other by welds 754 . It will be appreciated that the interface assembly 710 can have several different embodiments that are defined by the configuration of the field shaping unit 500 ( FIG. 6 ) and the particular configuration of the electrode compartments 520 a - d ( FIG. 6 ).
  • the interface member 700 is a filter material that allows the secondary flow F 2 of electroprocessing solution to pass through the holes 732 in the first frame 730 , the post-filtered portion of the solution continues along a path (arrow Q) to join the primary fluid flow F p as described above.
  • a filter-type interface member 700 is POREX®, which is a porous plastic that filters particles to prevent them from passing through the interface member.
  • the interface member 700 can prevent the particles generated by the anodes from reaching the plating surface of the workpiece.
  • the interface member 700 can be permeable to preferred ions to allow these ions to pass through the interface member 700 and into the primary fluid flow F p .
  • One suitable ion-membrane is NAFION® perfluorinated membranes manufactured by DuPont®. In one application for copper plating, a NAFION 450 ion-selective membrane is used.
  • Other suitable types of ion-membranes for plating can be polymers that are permeable to many cations, but reject anions and non-polar species. It will be appreciated that in electropolishing applications, the interface member 700 may be selected to be permeable to anions, but reject cations and non-polar species.
  • the preferred ions can be transferred through the ion-membrane interface member 700 by a driving force, such as a difference in concentration of ions on either side of the membrane, a difference in electrical potential, or hydrostatic pressure.
  • the primary fluid flow F p that contacts the workpiece can be a catholyte and the secondary fluid flow F 2 that does not contact the workpiece can be a separate anolyte because these fluids do not mix in this embodiment.
  • a benefit of having separate anolyte and catholyte fluid flows is that it eliminates the consumption of additives at the anodes and thus the need to replenish the additives as often.
  • this feature combined with the “virtual electrode” aspect of the reaction vessel 204 reduces the need to “burn-in” anodes for insuring a consistent black film over the anodes for predictable current distribution because the current distribution is controlled by the configuration of the field shaping unit 500 .
  • Another advantage is that it also eliminates the need to have a predictable consumption of additives in the secondary flow F 2 because the additives to the secondary flow F 2 do not effect the primary fluid flow F p when the two fluids are separated from each other.

Abstract

An apparatus and method for electrochemical processing of microelectronic workpieces in a reaction vessel. In one embodiment, the reaction vessel includes: an outer container having an outer wall; a distributor coupled to the outer container, the distributor having a first outlet configured to introduce a primary flow into the outer container and at least one second outlet configured to introduce a secondary flow into the outer container separate from the primary flow; a primary flow guide in the outer container coupled to the distributor to receive the primary flow from the first outlet and direct it to a workpiece processing site; a dielectric field shaping unit in the outer container coupled to the distributor to receive the secondary flow from the second outlet, the field shaping unit being configured to contain the secondary flow separate from the primary flow through at least a portion of the outer container, and the field shaping unit having at least one electrode compartment through which the secondary flow can pass while the secondary flow is separate from the primary flow; an electrode in the electrode compartment; and an interface member carried by the field shaping unit downstream from the electrode, the interface member being in fluid communication with the secondary flow in the electrode compartment, and the interface member being configured to prevent selected matter of the secondary flow from passing to the primary flow.

Description

    CROSS-REFERENCE TO RELATED APPLICATIONS
  • This application is a continuation-in-part of U.S. application Ser. No. 09/804,697, entitled “SYSTEM FOR ELECTROCHEMICALLY PROCESSING A WORKPIECE,” filed on Mar. 12, 2001; which is a continuation of International Application No. PCT/US00/10120, filed on Apr. 13, 2000, in the English language and published in the English language as International Publication No. WO00/61498, which claims the benefit of Provisional Application No. 60/129,055, filed on Apr. 13, 1999, all of which are herein incorporated by reference. Additionally, this application is related to the following:
      • (a) U.S. patent application entitled “TRANSFER DEVICES FOR HANDLING MICROELECTRONIC WORKPIECES WITHIN AN ENVIRONMENT OF A PROCESSING MACHINE AND METHODS OF MANUFACTURING AND USING SUCH DEVICES IN THE PROCESSING OF MICROELECTRONIC WORKPIECES,” filed on Jun. 1, 2001, and identified by Perkins Coie LLP Docket No. 29195.8153US00;
      • (b) U.S. patent application entitled “INTEGRATED TOOLS WITH TRANSFER DEVICES FOR HANDLING MICROELECTRONIC WORKPIECES,” filed on Jun. 1, 2001, and identified by Perkins Coie Docket No. 29195.8153US01;
      • (c) U.S. patent application entitled “DISTRIBUTED POWER SUPPLIES FOR MICROELECTRONIC WORKPIECE PROCESSING TOOLS,” filed on Jun. 1, 2001, and identified by Perkins Coie Docket No. 29195.8155US00;
      • (d) U.S. patent application entitled “ADAPTABLE ELECTROCHEMICAL PROCESSING CHAMBER,” filed on Jun. 1, 2001, and identified by Perkins Coie LLP Docket No. 29195.8156US00;
      • (e) U.S. patent application entitled “LIFT AND ROTATE ASSEMBLY FOR USE IN A WORKPIECE PROCESSING STATION AND A METHOD OF ATTACHING THE SAME,” filed on Jun. 1, 2001, and identified by Perkins Coie Docket No. 29195.8154US00;
      • (f) U.S. patent applications entitled “TUNING ELECTRODES USED IN A REACTOR FOR ELECTROCHEMICALLY PROCESSING A MICROELECTRONIC WORKPIECE,” one filed on May 4, 2001, and identified by U.S. application Ser. No. 09/849,505, and two additional applications filed on May 24, 2001, and identified separately by Perkins Coie Docket Nos. 29195.8157US02 and 29195.8157US03.
  • All of the foregoing U.S. patent applications in paragraphs (a)-(f) above are herein incorporated by reference.
  • TECHNICAL FIELD
  • This application relates to reaction vessels and methods of making and using such vessels in electrochemical processing of microelectronic workpieces.
  • BACKGROUND
  • Microelectronic devices, such as semiconductor devices and field emission displays, are generally fabricated on and/or in microelectronic workpieces using several different types of machines (“tools”). Many such processing machines have a single processing station that performs one or more procedures on the workpieces. Other processing machines have a plurality of processing stations that perform a series of different procedures on individual workpieces or batches of workpieces. In a typical fabrication process, one or more layers of conductive materials are formed on the workpieces during deposition stages. The workpieces are then typically subject to etching and/or polishing procedures (i.e., planarization) to remove a portion of the deposited conductive layers for forming electrically isolated contacts and/or conductive lines.
  • Plating tools that plate metals or other materials on the workpieces are becoming an increasingly useful type of processing machine. Electroplating and electroless plating techniques can be used to deposit copper, solder, permalloy, gold, silver, platinum and other metals onto workpieces for forming blanket layers or patterned layers. A typical copper plating process involves depositing a copper seed layer onto the surface of the workpiece using chemical vapor deposition (CVD), physical vapor deposition (PVD), electroless plating processes, or other suitable methods. After forming the seed layer, a blanket layer or patterned layer of copper is plated onto the workpiece by applying an appropriate electrical potential between the seed layer and an anode in the presence of an electroprocessing solution. The workpiece is then cleaned, etched and/or annealed in subsequent procedures before transferring the workpiece to another processing machine.
  • FIG. 1 illustrates an embodiment of a single-wafer processing station 1 that includes a container 2 for receiving a flow of electroplating solution from a fluid inlet 3 at a lower portion of the container 2. The processing station 1 can include an anode 4, a plate-type diffuser 6 having a plurality of apertures 7, and a workpiece holder 9 for carrying a workpiece 5. The workpiece holder. 9 can include a plurality of electrical contacts for providing electrical current to a seed layer on the surface of the workpiece 5. When the seed layer is biased with a negative potential relative to the anode 4, it acts as a cathode. In operation the electroplating fluid flows around the anode 4, through the apertures 7 in the diffuser 6 and against the plating surface of the workpiece 5. The electroplating solution is an electrolyte that conducts electrical current between the anode 4 and the cathodic seed layer on the surface of the workpiece 5. Therefore, ions in the electroplating solution plate the surface of the workpiece 5.
  • The plating machines used in fabricating microelectronic devices must meet many specific performance criteria. For example, many processes must be able to form small contacts in vias that are less than 0.5 μm wide, and are desirably less than 0.1 μm wide. The plated metal layers accordingly often need to fill vias or trenches that are on the order of 0.1 μm wide, and the layer of plated material should also be deposited to a desired, uniform thickness across the surface of the workpiece 5. One factor that influences the uniformity of the plated layer is the mass transfer of electroplating solution at the surface of the workpiece. This parameter is generally influenced by the velocity of the flow of the electroplating solution perpendicular to the surface of the workpiece. Another factor that influences the uniformity of the plated layer is the current density of the electrical field across the surface of the wafer.
  • One concern of existing electroplating equipment is providing a uniform mass transfer at the surface of the workpiece. Referring to FIG. 1, existing plating tools generally use the diffuser 6 to enhance the uniformity of the fluid flow perpendicular to the face of the workpiece. Although the diffuser 6 improves the uniformity of the fluid flow, it produces a plurality of localized areas of increased flow velocity perpendicular to the surface of the workpiece 5 (indicated by arrows 8). The localized areas generally correspond to the position of the apertures 7 in the diffuser 6. The increased velocity of the fluid flow normal to the substrate in the localized areas increases the mass transfer of the electroplating solution in these areas. This typically results in faster plating rates in the localized areas over the apertures 7. Although many different configurations of apertures have been used in plate-type diffusers, these diffusers may not provide adequate uniformity for the precision required in many current applications.
  • Another concern of existing plating tools is that the diffusion layer in the electroplating solution adjacent to the surface of the workpiece 5 can be disrupted by gas bubbles or particles. For example, bubbles can be introduced to the plating solution by the plumbing and pumping system of the processing equipment, or they can evolve from inert anodes. Consumable anodes are often used to prevent or reduce the evolvement of gas bubbles in the electroplating solution, but these anodes erode and they can form a passivated film surface that must be maintained. Consumable anodes, moreover, often generate particles that can be carried in the plating solution. As a result, gas bubbles and/or particles can flow to the surface of the workpiece 5, which disrupts the uniformity and affects the quality of the plated layer.
  • Still another challenge of plating uniform layers is providing a desired electrical field at the surface of the workpiece 5. The distribution of electrical current in the plating solution is a function of the uniformity of the seed layer across the contact surface, the configuration/condition of the anode, and the configuration of the chamber. However, the current density profile on the plating surface can change. For example, the current density profile typically changes during a plating cycle because plating material covers the seed layer, or it can change over a longer period of time because the shape of consumable anodes changes as they erode and the concentration of constituents in the plating solution can change. Therefore, it can be difficult to maintain a desired current density at the surface of the workpiece 5.
  • SUMMARY
  • The present invention is directed toward reaction vessels for electrochemical processing of microelectronic workpieces, processing stations including such reaction vessels, and methods for using these devices. Several embodiments of reaction vessels in accordance with the invention solve the problem of providing a desired mass transfer at the workpiece by configuring the electrodes so that a primary flow guide and/or a field shaping unit in the reaction vessel direct a substantially uniform primary fluid flow toward the workpiece. Additionally, field shaping units in accordance with several embodiments of the invention create virtual electrodes such that the workpiece is shielded from the electrodes. This allows for the use of larger electrodes to increase electrode life, eliminates the need to “burn-in” electrodes to decrease downtime, and/or provides the capability of manipulating the electrical field by merely controlling the electrical current to one or more of the electrodes in the vessel. Furthermore, additional embodiments of the invention include interface members in the reaction vessel that inhibit particulates, bubbles and other undesirable matter in the reaction vessel from contacting the workpiece to enhance the uniformity and the quality of the finished surface on the workpieces. The interface members can also allow two different types of fluids to be used in the reaction vessel, such as a catholyte and an anolyte, to reduce the need to replenish additives as often and to add more flexibility to designing electrodes and other components in the reaction vessel.
  • In one embodiment of the invention, a reaction vessel includes an outer container having an outer wall, a first outlet configured to introduce a primary fluid flow into the outer container, and at least one second outlet configured to introduce a secondary fluid flow into the outer container separate from the primary fluid flow. The reaction vessel can also include a field shaping unit in the outer container and at least one electrode. The field shaping unit can be a dielectric assembly coupled to the second outlet to receive the secondary flow and configured to contain the secondary flow separate from the primary flow through at least a portion of the outer container. The field shaping unit also has at least one electrode compartment through which the secondary flow can pass separately from the primary flow. The electrode is positioned in the electrode compartment.
  • In a particular embodiment, the field shaping unit has a compartment assembly having a plurality of electrode compartments and a virtual electrode unit. The compartment assembly can include a plurality of annular walls including an inner or first annular wall centered on a common axis and an outer or second annular wall concentric with the first annular wall and spaced radially outward. The annular walls of the field shaping unit can be positioned inside of outer wall of the outer container so that an annular space between the first and second walls defines a first electrode compartment and an annular space between the second wall and the outer wall defines a second electrode compartment. The reaction vessel of this particular embodiment can have a first annular electrode in the first electrode compartment and/or a second annular electrode in the second electrode compartment.
  • The virtual electrode unit can include a plurality of partitions that have lateral sections attached to corresponding annular walls of the electrode compartment and lips that project from the lateral sections. In one embodiment, the first partition has an annular first lip that defines a central opening, and the second partition has an annular second lip surrounding the first lip that defines an annular opening.
  • In additional embodiments, the reaction vessel can further include a distributor coupled to the outer container and a primary flow guide in the outer container. The distributor can include the first outlet and the second outlet such that the first outlet introduces the primary fluid flow into the primary flow guide and the second outlet introduces the secondary fluid flow into the field shaping unit separately from the primary flow. The primary flow guide can condition the primary flow for providing a desired fluid flow to a workpiece processing site. In one particular embodiment, the primary flow guide directs the primary flow through the central opening of the first annular lip of the first partition. The secondary flow is distributed to the electrode compartments of the field shaping unit to establish an electrical field in the reaction vessel.
  • In the operation of one embodiment, the primary flow can pass through a first flow channel defined, at least in part, by the primary flow guide and the lip of the first partition. The primary flow can be the dominant flow through the reaction vessel so that it controls the mass transfer at the workpiece. The secondary flow can generally be contained within the field shaping unit so that the electrical field(s) of the electrode(s) are shaped by the virtual electrode unit and the electrode compartments. For example, in the embodiment having first and second annular electrodes, the electrical effect of the first electrode can act as if it is placed in the central opening defined by the lip of the first partition, and the electrical effect of the second electrode can act as if it is placed in the annular opening between the first and second lips. The actual electrodes, however, can be shielded from the workpiece by the field shaping unit such that the size and shape of the actual electrodes does not affect the electrical field perceived by the workpiece.
  • One feature of several embodiments is that the field shaping unit shields the workpiece from the electrodes. As a result, the electrodes can be much larger than they could without the field shaping unit because the size and configuration of the actual electrodes does not appreciably affect the electrical field perceived by the workpiece. This is particularly useful when the electrodes are consumable anodes because the increased size of the anodes prolongs their life, which reduces downtime for servicing a tool. Additionally, this reduces the need to “burn-in” anodes because the field shaping element reduces the impact that films on the anodes have on the shape of the electrical field perceived by the workpiece. Both of these benefits significantly improve the operating efficiency of the reaction vessel.
  • Another feature of several embodiments of the invention is that they provide a uniform mass transfer at the surface of the workpiece. Because the field shaping unit separates the actual electrodes from the effective area where they are perceived by the workpiece, the actual electrodes can be configured to accommodate internal structure that guides the flow along a more desirable flow path. For example, this allows the primary flow to flow along a central path. Moreover, a particular embodiment includes a central primary flow guide that projects the primary flow radially inward along diametrically opposed vectors that create a highly uniform primary flow velocity in a direction perpendicular to the surface of the workpiece.
  • The reaction vessel can also include an interface member carried by the field shaping unit downstream from the electrode. The interface member can be in fluid communication with the secondary flow in the electrode compartment. The interface member, for example, can be a filter and/or an ion-membrane. In either case, the interface member can inhibit particulates (e.g., particles from an anode) and bubbles in the secondary flow from reaching the surface of the workpiece to reduce non-uniformities on the processed surface. This accordingly increases the quality of the surface of the workpiece. Additionally, in the case of an ion-membrane, the interface member can be configured to prevent fluids from passing between the secondary flow and the primary flow while allowing preferred ions to pass between the flows. This allows the primary flow and the secondary flow to be different types of fluids, such as a catholyte and an anolyte, which reduces the need to replenish additives as often and adds more flexibility to designing electrodes and other features of the reaction vessel.
  • BRIEF DESCRIPTION OF THE DRAWINGS
  • FIG. 1 is a schematic diagram of an electroplating chamber in accordance with the prior art.
  • FIG. 2 is an isometric view of an electroprocessing machine having electroprocessing stations for processing microelectronic workpieces in accordance with an embodiment of the invention.
  • FIG. 3 is a cross-sectional view of an electroprocessing station having a processing chamber for use in an electroprocessing machine in accordance with an embodiment of the invention. Selected components in FIG. 3 are shown schematically.
  • FIG. 4 is an isometric view showing a cross-sectional portion of a processing chamber taken along line 4-4 of FIG. 8A.
  • FIGS. 5A-5D are cross-sectional views of a distributor for a processing chamber in accordance with an embodiment of the invention.
  • FIG. 6 is an isometric view showing a different cross-sectional portion of the processing chamber of FIG. 4 taken along line 6-6 of FIG. 8B.
  • FIG. 7A is an isometric view of an interface assembly for use in a processing chamber in accordance with an embodiment of the invention.
  • FIG. 7B is a cross-sectional view of the interface assembly of FIG. 7A.
  • FIGS. 8A and 8B are top plan views of a processing chamber that provide a reference for the isometric, cross-sectional views of FIGS. 4 and 6, respectively.
  • DETAILED DESCRIPTION
  • The following description discloses the details and features of several embodiments of electrochemical reaction vessels for use in electrochemical processing stations and integrated tools to process microelectronic workpieces. The term “microelectronic workpiece” is used throughout to include a workpiece formed from a substrate upon which and/or in which microelectronic circuits or components, data storage elements or layers, and/or micro-mechanical elements are fabricated. It will be appreciated that several of the details set forth below are provided to describe the following embodiments in a manner sufficient to enable a person skilled in the art to make and use the disclosed embodiments. Several of the details and advantages described below, however, may not be necessary to practice certain embodiments of the invention. Additionally, the invention can also include additional embodiments that are within the scope of the claims, but are not described in detail with respect to FIGS. 2-8B.
  • The operation and features of electrochemical reaction vessels are best understood in light of the environment and equipment in which they can be used to electrochemically process workpieces (e.g., electroplate and/or electropolish). As such, embodiments of integrated tools with processing stations having the electrochemical reaction vessels are initially described with reference to FIGS. 2 and 3. The details and features of several embodiments of electrochemical reaction vessels are then described with reference to FIGS. 4-8B.
  • A. Selected Embodiments of Integrated Tools with Electrochemical Processing Stations
  • FIG. 2 is an isometric view of a processing machine 100 having an electrochemical processing station 120 in accordance with an embodiment of the invention. A portion of the processing machine 100 is shown in a cut-away view to illustrate selected internal components. In one aspect of this embodiment, the processing machine 100 can include a cabinet 102 having an interior region 104 defining an interior enclosure that is at least partially isolated from an exterior region 105. The cabinet 102 can also include a plurality of apertures 106 (only one shown in FIG. 1) through which microelectronic workpieces 101 can ingress and egress between the interior region 104 and a load/unload station 110.
  • The load/unload station 110 can have two container supports 112 that are each housed in a protective shroud 113. The container supports 112 are configured to position workpiece containers 114 relative to the apertures 106 in the cabinet 102. The workpiece containers 114 can each house a plurality of microelectronic workpieces 101 in a “mini” clean environment for carrying a plurality of workpieces through other environments that are not at clean room standards. Each of the workpiece containers 114 is accessible from the interior region 104 of the cabinet 102 through the apertures 106.
  • The processing machine 100 can also include a plurality of electrochemical processing stations 120 and a transfer device 130 in the interior region 104 of the cabinet 102. The processing machine 100, for example, can be a plating tool that also includes clean/etch capsules 122, electroless plating stations, annealing stations, and/or metrology stations.
  • The transfer device 130 includes a linear track 132 extending in a lengthwise direction of the interior region 104 between the processing stations. The transfer device 130 can further include a robot unit 134 carried by the track 132. In the particular embodiment shown in FIG. 2, a first set of processing stations is arranged along a first row R1-R1 and a second set of processing stations is arranged long a second row R2-R2. The linear track 132 extends between the first and second rows of processing stations, and the robot unit 134 can access any of the processing stations along the track 132.
  • FIG. 3 illustrates an embodiment of an electrochemical-processing chamber 120 having a head assembly 150 and a processing chamber 200. The head assembly 150 includes a spin motor 152, a rotor 154 coupled to the spin motor 152, and a contact assembly 160 carried by the rotor 154. The rotor 154 can have a backing plate 155 and a seal 156. The backing plate 155 can move transverse to a workpiece 101 (arrow T) between a first position in which the backing plate 155 contacts a backside of the workpiece 101 (shown in solid lines in FIG. 3) and a second position in which it is spaced apart from the backside of the workpiece 101 (shown in broken lines in FIG. 3). The contact assembly 160 can have a support member 162, a plurality of contacts 164 carried by the support member 162, and a plurality of shafts 166 extending between the support member 162 and the rotor 154. The contacts 164 can be ring-type spring contacts or other types of contacts that are configured to engage a portion of the seed-layer on the workpiece 101. Commercially available head assemblies 150 and contact assemblies 160 can be used in the electroprocessing chamber 120. Particular suitable head assemblies 150 and contact assemblies 160 are disclosed in U.S. Pat. Nos. 6,228,232 and 6,080,691; and U.S. application Ser. Nos. 09/385,784; 09/386,803; 09/386,610; 09/386,197; 09/501,002; 09/733,608; and 09/804,696, all of which are herein incorporated by reference.
  • The processing chamber 200 includes an outer housing 202 (shown schematically in FIG. 3) and a reaction vessel 204 (also shown schematically in FIG. 3) in the housing 202. The reaction vessel 204 carries at least one electrode (not shown in FIG. 3) and directs a flow of electroprocessing solution to the workpiece 101. The electroprocessing solution, for example, can flow over a weir (arrow F) and into the external housing 202, which captures the electroprocessing solution and sends it back to a tank. Several embodiments of reaction vessels 204 are shown and described in detail with reference to FIGS. 4-8B.
  • In operation the head assembly 150 holds the workpiece at a workpiece-processing site of the reaction vessel 204 so that at least a plating surface of the workpiece engages the electroprocessing solution. An electrical field is established in the solution by applying an electrical potential between the plating surface of the workpiece via the contact assembly 160 and one or more electrodes in the reaction vessel 204. For example, the contact assembly 160 can be biased with a negative potential with respect to the electrode(s) in the reaction vessel 204 to plate materials onto the workpiece. On the other hand the contact assembly 160 can be biased with a positive potential with respect to the electrode(s) in the reaction vessel 204 to (a) de-plate or electropolish plated material from the workpiece or (b) deposit other materials (e.g., electrophoric resist). In general, therefore, materials can be deposited on or removed from the workpiece with the workpiece acting as a cathode or an anode depending upon the particular type of material used in the electrochemical process.
  • B. Selected Embodiments of Reaction Vessels for use in Electrochemical Processing Chambers
  • FIGS. 4-8B illustrate several embodiments of reaction vessels 204 for use in the processing chamber 200. As explained above, the housing 202 carries the reaction vessel 204. The housing 202 can have a drain 210 for returning the processing fluid that flows out of the reaction vessel 204 to a storage tank, and a plurality of openings for receiving inlets and electrical fittings. The reaction vessel 204 can include an outer container 220 having an outer wall 222 spaced radially inwardly of the housing 202. The outer container 220 can also have a spiral spacer 224 between the outer wall 222 and the housing 202 to provide a spiral ramp (i.e., a helix) on which the processing fluid can flow downward to the bottom of the housing 202. The spiral ramp reduces the turbulence of the return fluid to inhibit entrainment of gasses in the return fluid.
  • The particular embodiment of the reaction vessel 204 shown in FIG. 4 can include a distributor 300 for receiving a primary fluid flow Fp and a secondary fluid flow F2, a primary flow guide 400 coupled to the distributor 300 to condition the primary fluid flow Fp, and a field shaping unit 500 coupled to the distributor 300 to contain the secondary flow F2 in a manner that shapes the electrical field in the reaction vessel 204. The reaction vessel 204 can also include at least one electrode 600 in a compartment of the field shaping unit 500 and at least one filter or other type of interface member 700 carried by the field shaping unit 500 downstream from the electrode. The primary flow guide 400 can condition the primary flow Fp by projecting this flow radially inwardly relative to a common axis A-A, and a portion of the field shaping unit 500 directs the conditioned primary flow Fp toward the workpiece. In several embodiments, the primary flow passing through the primary flow guide 400 and the center of the field shaping unit 500 controls the mass transfer of processing solution at the surface of the workpiece. The field shaping unit 500 also defines the shape the electric field, and it can influence the mass transfer at the surface of the workpiece if the secondary flow passes through the field shaping unit. The reaction vessel 204 can also have other configurations of components to guide the primary flow Fp and the secondary flow F2 through the processing chamber 200. The reaction vessel 204, for example, may not have a distributor in the processing chamber, but rather separate fluid lines with individual flows can be coupled to the vessel 204 to provide a desired distribution of fluid through the primary flow guide 400 and the field shaping unit. For example, the reaction vessel 204 can have a first outlet in the outer container 220 for introducing the primary flow into the reaction vessel and a second outlet in the outer container for introducing the secondary flow into the reaction vessel 204. Each of these components is explained in more detail below.
  • FIGS. 5A-5D illustrate an embodiment of the distributor 300 for directing the primary fluid flow to the primary flow guide 400 and the secondary fluid flow to the field shaping unit 500. Referring to FIG. 5A, the distributor 300 can include a body 310 having a plurality of annular steps 312 (identified individually by reference numbers 312 a-d) and annular grooves 314 in the steps 312. The outermost step 312 d is radially inward of the outer wall 222 (shown in broken lines) of the outer container 220 (FIG. 4), and each of the interior steps 312 a-c can carry annular wall (shown in broken lines) of the field shaping unit 500 in a corresponding groove 314. The distributor 300 can also include a first inlet 320 for receiving the primary flow Fp and a plenum 330 for receiving the secondary flow F2. The first inlet 320 can have an inclined, annular cavity 322 to form a passageway 324 (best shown in FIG. 4) for directing the primary fluid flow Fp under the primary flow guide 400. The distributor 300 can also have a plurality of upper orifices 332 along an upper part of the plenum 330 and a plurality of lower orifices 334 along a lower part of the plenum 330. As explained in more detail below, the upper and lower orifices are open to channels through the body 310 to distribute the secondary flow F2 to the risers of the steps 312. The distributor 300 can also have other configurations, such as a “step-less” disk or non-circular shapes.
  • FIGS. 5A-5D further illustrate one configuration of channels through the body 310 of the distributor 300. Referring to FIG. 5A, a number of first channels 340 extend from some of the lower orifices 334 to openings at the riser of the first step 312 a. FIG. 5B shows a number of second channels 342 extending from the upper orifices 332 to openings at the riser of the second step 312 b, and FIG. 5C shows a number of third channels 344 extending from the upper orifices 332 to openings at the riser of the third step 312 c. Similarly, FIG. 5D illustrates a number of fourth channels 346 extending from the lower orifices 334 to the riser of the fourth step 312 d.
  • The particular embodiment of the channels 340-346 in FIGS. 5A-5D are configured to transport bubbles that collect in the plenum 330 radially outward as far as practical so that these bubbles can be captured and removed from the secondary flow F2. This is beneficial because the field shaping unit 500 removes bubbles from the secondary flow F2 by sequentially transporting the bubbles radially outwardly through electrode compartments. For example, a bubble B in the compartment above the first step 312 a can sequentially cascade through the compartments over the second and third steps 312 b-c, and then be removed from the compartment above the fourth step 312 d. The first channel 340 (FIG. 5A) accordingly carries fluid from the lower orifices 334 where bubbles are less likely to collect to reduce the amount of gas that needs to cascade from the inner compartment above the first step 312 a all the way out to the outer compartment. The bubbles in the secondary flow F2 are more likely to collect at the top of the plenum 330 before passing through the channels 340-346. The upper orifices 332 are accordingly coupled to the second channel 342 and the third channel 344 to deliver these bubbles outward beyond the first step 312 a so that they do not need to cascade through so many compartments. In this embodiment, the upper orifices 332 are not connected to the fourth channels 346 because this would create a channel that inclines downwardly from the common axis such that it may conflict with the groove 314 in the third step 312 c. Thus, the fourth channel 346 extends from the lower orifices 334 to the fourth step 312 d.
  • Referring again to FIG. 4, the primary flow guide 400 receives the primary fluid flow Fp via the first inlet 320 of the distributor 300. In one embodiment, the primary flow guide 400 includes an inner baffle 410 and an outer baffle 420. The inner baffle can have a base 412 and a wall 414 projecting upward and radially outward from the base 412. The wall 414, for example, can have an inverted frusto-conical shape and a plurality of apertures 416. The apertures 416 can be holes, elongated slots or other types of openings. In the illustrated embodiment, the apertures 416 are annularly extending radial slots that slant upward relative to the common axis to project the primary flow radially inward and upward relative to the common axis along a plurality of diametrically opposed vectors. The inner baffle 410 can also includes a locking member 418 that couples the inner baffle 410 to the distributor 300.
  • The outer baffle 420 can include an outer wall 422 with a plurality of apertures 424. In this embodiment, the apertures 424 are elongated slots extending in a direction transverse to the apertures 416 of the inner baffle 410. The primary flow Fp flows through (a) the first inlet 320, (b) the passageway 324 under the base 412 of the inner baffle 410, (c) the apertures 424 of the outer baffle 420, and then (d) the apertures 416 of the inner baffles 410. The combination of the outer baffle 420 and the inner baffle 410 conditions the direction of the flow at the exit of the apertures 416 in the inner baffle 410. The primary flow guide 400 can thus project the primary flow along diametrically opposed vectors that are inclined upward relative to the common axis to create a fluid flow that has a highly uniform velocity. In alternate embodiments, the apertures 416 do not slant upward relative to the common axis such that they can project the primary flow normal, or even downward, relative to the common axis.
  • FIG. 4 also illustrates an embodiment of the field shaping unit 500 that receives the primary fluid flow Fp downstream from the primary flow guide 400. The field shaping unit 500 also contains the second fluid flow F2 and shapes the electrical field within the reaction vessel 204. In this embodiment, the field shaping unit 500 has a compartment structure with a plurality of walls 510 (identified individually by reference numbers 510 a-d) that define electrode compartments 520 (identified individually by reference numbers 520 a-d). The walls 510 can be annular skirts or dividers, and they can be received in one of the annular grooves 314 in the distributor 300. In one embodiment, the walls 510 are not fixed to the distributor 300 so that the field shaping unit 500 can be quickly removed from the distributor 300. This allows easy access to the electrode compartments 520 and/or quick removal of the field shaping unit 500 to change the shape of the electric field.
  • The field shaping unit 500 can have at least one wall 510 outward from the primary flow guide 400 to prevent the primary flow Fp from contacting an electrode. In the particular embodiment shown in FIG. 4, the field shaping unit 500 has a first electrode compartment 520 a defined by a first wall 510 a and a second wall 510 b, a second electrode compartment 520 b defined by the second wall 510 b and a third wall 510 c, a third electrode compartment 520 c defined by the third wall 510 c and a fourth wall 510 d, and a fourth electrode compartment 520 d defined by the fourth wall 510 d and the outer wall of the container 220. The walls 510 a-d of this embodiment are concentric annular dividers that define annular electrode compartments 520 a-d. Alternate embodiments of the field shaping unit can have walls with different configurations to create non-annular electrode compartments and/or each electrode compartment can be further divided into cells. The second-fourth walls 510 b-d can also include holes 522 for allowing bubbles in the first-third electrode compartments 520 a-c to “cascade” radially outward to the next outward electrode compartment 520 as explained above with respect to FIGS. 5A-5D. The bubbles can then exit the fourth electrode compartment 520 d through an exit hole 525 through the outer wall 222. In an alternate embodiment, the bubbles can exit through an exit hole 524.
  • The electrode compartments 520 provide electrically discrete compartments to house an electrode assembly having at least one electrode and generally two or more electrodes 600 (identified individually by reference numbers 600 a-d). The electrodes 600 can be annular members (e.g., annular rings or arcuate sections) that are configured to fit within annular electrode compartments, or they can have other shapes appropriate for the particular workpiece (e.g., rectilinear). In the illustrated embodiment, for example, the electrode assembly includes a first annular electrode 600 a in the first electrode compartment 520 a, a second annular electrode 600 b in the second electrode compartment 520 b, a third annular electrode 600 c in the third electrode compartment 520 c, and a fourth annular electrode 600 d in the fourth electrode compartment 520 d. As explained in U.S. Application Nos. 60/206,661, 09/845,505, and 09/804,697, all of which are incorporated herein by reference, each of the electrodes 600 a-d can be biased with the same or different potentials with respect to the workpiece to control the current density across the surface of the workpiece. In alternate embodiments, the electrodes 600 can be non-circular shapes or sections of other shapes.
  • Embodiments of the reaction vessel 204 that include a plurality of electrodes provide several benefits for plating or electropolishing. In plating applications, for example, the electrodes 600 can be biased with respect to the workpiece at different potentials to provide uniform plating on different workpieces even though the seed layers vary from one another or the bath(s) of electroprocessing solution have different conductivities and/or concentrations of constituents. Additionally, another the benefit of having a multiple electrode design is that plating can be controlled to achieve different final fill thicknesses of plated layers or different plating rates during a plating cycle or in different plating cycles. Other benefits of particular embodiments are that the current density can be controlled to (a) provide a uniform current density during feature filling and/or (b) achieve plating to specific film profiles across a workpiece (e.g., concave, convex, flat). Accordingly, the multiple electrode configurations in which the electrodes are separate from one another provide several benefits for controlling the electrochemical process to (a) compensate for deficiencies or differences in seed layers between workpieces, (b) adjust for variances in baths of electroprocessing solutions, and/or (c) achieve predetermined feature filling or film profiles.
  • The field shaping unit 500 can also include a virtual electrode unit coupled to the walls 510 of the compartment assembly for individually shaping the electrical fields produced by the electrodes 600. In the particular embodiment illustrated in FIG. 4, the virtual electrode unit includes first-fourth partitions 530 a-530 d, respectively. The first partition 530 a can have a first section 532 a coupled to the second wall 510 b, a skirt 534 depending downward above the first wall 510 a, and a lip 536 a projecting upwardly. The lip 536 a has an interior surface 537 that directs the primary flow Fp exiting from the primary flow guide 400. The second partition 530 b can have a first section 532 b coupled to the third wall 510 c and a lip 536 b projecting upward from the first section 532 b, the third partition 530 c can have a first section 532 c coupled to the fourth wall 510 d and a lip 536 c projecting upward from the first section 532 c, and the fourth partition 530 d can have a first section 532 d carried by the outer wall 222 of the container 220 and a lip 536 d projecting upward from the first section 532 d. The fourth partition 530 d may not be connected to the outer wall 222 so that the field shaping unit 500 can be quickly removed from the vessel 204 by simply lifting the virtual electrode unit. The interface between the fourth partition 530 d and the outer wall 222 is sealed by a seal 527 to inhibit both the fluid and the electrical current from leaking out of the fourth electrode compartment 520 d. The seal 527 can be a lip seal. Additionally, each of the sections 532 a-d can be lateral sections extending transverse to the common axis.
  • The individual partitions 530 a-d can be machined from or molded into a single piece of dielectric material, or they can be individual dielectric members that are welded together. In alternate embodiments, the individual partitions 530 a-d are not attached to each other and/or they can have different configurations. In the particular embodiment shown in FIG. 4, the partitions 530 a-d are annular horizontal members, and each of the lips 536 a-d are annular vertical members arranged concentrically about the common axis.
  • The walls 510 and the partitions 530 a-d are generally dielectric materials that contain the second flow F2 of the processing solution for shaping the electric fields generated by the electrodes 600 a-d. The second flow F2, for example, can pass (a) through each of the electrode compartments 520 a-d, (b) between the individual partitions 530 a-d, and then (c) upward through the annular openings between the lips 536 a-d. In this embodiment, the secondary flow F2 through the first electrode compartment 520 a can join the primary flow Fp in an antechamber just before the primary flow guide 400, and the secondary flow through the second-fourth electrode compartments 520 b-d can join the primary flow Fp beyond the top edges of the lips 536 a-d. The flow of electroprocessing solution then flows over a shield weir attached at rim 538 and into the gap between the housing 202 and the outer wall 222 of the container 220 as disclosed in International Application No. PCT/US00/10120. The fluid in the secondary flow F2 can be prevented from flowing out of the electrode compartments 520 a-d to join the primary flow Fp while still allowing electrical current to pass from the electrodes 600 to the primary flow. In this alternate embodiment, the secondary flow F2 can exit the reaction vessel 204 through the holes 522 in the walls 510 and the hole 525 in the outer wall 222. In still additional embodiments in which the fluid of the secondary flow does not join the primary flow, a duct can be coupled to the exit hole 525 in the outer wall 222 so that a return flow of the secondary flow passing out of the field shaping unit 500 does not mix with the return flow of the primary flow passing down the spiral ramp outside of the outer wall 222. The field shaping unit 500 can have other configurations that are different than the embodiment shown in FIG. 4. For example, the electrode compartment assembly can have only a single wall 510 defining a single electrode compartment 520, and the reaction vessel 204 can include only a single electrode 600. The field shaping unit of either embodiment still separates the primary and secondary flows so that the primary flow does not engage the electrode, and thus it shields the workpiece from the single electrode. One advantage of shielding the workpiece from the electrodes 600 a-d is that the electrodes can accordingly be much larger than they could be without the field shaping unit because the size of the electrodes does not have an effect on the electrical field presented to the workpiece. This is particularly useful in situations that use consumable electrodes because increasing the size of the electrodes prolongs the life of each electrode, which reduces downtime for servicing and replacing electrodes.
  • An embodiment of reaction vessel 204 shown in FIG. 4 can accordingly have a first conduit system for conditioning and directing the primary fluid flow Fp to the workpiece, and a second conduit system for conditioning and directing the secondary fluid flow F2. The first conduit system, for example, can include the inlet 320 of the distributor 300; the channel 324 between the base 412 of the primary flow guide 400 and the inclined cavity 322 of the distributor 300; a plenum between the wall 422 of the outer baffle 420 and the first wall 510 a of the field shaping unit 500; the primary flow guide 400; and the interior surface 537 of the first lip 536 a. The first conduit system conditions the direction of the primary fluid flow Fp by passing it through the primary flow guide 400 and along the interior surface 537 so that the velocity of the primary flow Fp normal to the workpiece is at least substantially uniform across the surface of the workpiece. The primary flow Fp and the rotation of the workpiece can accordingly be controlled to dominate the mass transfer of electroprocessing medium at the workpiece.
  • The second conduit system, for example, can include the plenum 330 and the channels 340-346 of the distributor 300, the walls 510 of the field shaping unit 500, and the partitions 530 of the field shaping unit 500. The secondary flow F2 contacts the electrodes 600 to establish individual electrical fields in the field shaping unit 500 that are electrically coupled to the primary flow Fp. The field shaping unit 500, for example, separates the individual electrical fields created by the electrodes 600 a-d to create “virtual electrodes” at the top of the openings defined by the lips 536 a-d of the partitions. In this particular embodiment, the central opening inside the first lip 536 a defines a first virtual electrode, the annular opening between the first and second lips 536 a-b defines a second virtual electrode, the annular opening between the second and third lips 536 b-c defines a third virtual electrode, and the annular opening between the third and fourth lips 536 c-d defines a fourth virtual electrode. These are “virtual electrodes” because the field shaping unit 500 shapes the individual electrical fields of the actual electrodes 600 a-d so that the effect of the electrodes 600 a-d acts as if they are placed between the top edges of the lips 536 a-d. This allows the actual electrodes 600 a-d to be isolated from the primary fluid flow, which can provide several benefits as explained in more detail below.
  • An additional embodiment of the processing chamber 200 includes at least one interface member 700 (identified individually by reference numbers 700 a-d) for further conditioning the secondary flow F2 of electroprocessing solution. The interface members 700, for example, can be filters that capture particles in the secondary flow that were generated by the electrodes (i.e., anodes) or other sources of particles. The filter-type interface members 700 can also inhibit bubbles in the secondary flow F2 from passing into the primary flow Fp of electroprocessing solution. This effectively forces the bubbles to pass radially outwardly through the holes 522 in the walls 510 of the field shaping unit 500. In alternate embodiments, the interface members 700 can be ion-membranes that allow ions in the secondary flow F2 to pass through the interface members 700. The ion-membrane interface members 700 can be selected to (a) allow the fluid of the electroprocessing solution and ions to pass through the interface member 700, or (b) allow only the desired ions to pass through the interface member such that the fluid itself is prevented from passing beyond the ion-membrane.
  • FIG. 6 is another isometric view of the reaction vessel 204 of FIG. 4 showing a cross-sectional portion taken along a different cross-section. More specifically, the cross-section of FIG. 4 is shown in FIG. 8A and the cross-section of FIG. 6 is shown in FIG. 8B. Returning now to FIG. 6, this illustration further shows one embodiment for configuring a plurality of interface members 700 a-d relative to the partitions 530 a-d of the field shaping unit 500. A first interface member 700 a can be attached to the skirt 534 of the first partition 530 a so that a first portion of the secondary flow F2 flows past the first electrode 600 a, through an opening 535 in the skirt 534, and then to the first interface member 700 a. Another portion of the secondary flow F2 can flow past the second electrode 600 b to the second interface member 700 b. Similarly, portions of the secondary flow F2 can flow past the third and fourth electrodes 600 c-d to the third and fourth interface members 700 c-d.
  • When the interface members 700 a-d are filters or ion-membranes that allow the fluid in the secondary flow F2 to pass through the interface members 700 a-d, the secondary flow F2 joins the primary fluid flow Fp. The portion of the secondary flow F2 in the first electrode compartment 520 a can pass through the opening 535 in the skirt 534 and the first interface member 700 a, and then into a plenum between the first wall 510 a and the outer wall 422 of the baffle 420. This portion of the secondary flow F2 accordingly joins the primary flow Fp and passes through the primary flow guide 400. The other portions of the secondary flow F2 in this particular embodiment pass through the second-fourth electrode compartments 520 b-d and then through the annular openings between the lips 536 a-d. The second-fourth interface members 700 b-d can accordingly be attached to the field shaping unit 500 downstream from the second-fourth electrodes 600 b-d.
  • In the particular embodiment shown in FIG. 6, the second interface member 700 b is positioned vertically between the first and second partitions 530 a-b, the third interface member 700 c is positioned vertically between the second and third partitions 530 b-c, and the fourth interface member 700 d is positioned vertically between the third and fourth partitions 530 c-d. The interface assemblies 710 a-d are generally installed vertically, or at least at an upwardly inclined angle relative to horizontal, to force the bubbles to rise so that they can escape through the holes 522 in the walls 510 a-d (FIG. 4). This prevents aggregations of bubbles that could potentially disrupt the electrical field from an individual electrode.
  • FIGS. 7A and 7B illustrate an interface assembly 710 for mounting the interface members 700 to the field shaping unit 500 in accordance with an embodiment of the invention. The interface assembly 710 can include an annular interface member 700 and a fixture 720 for holding the interface member 700. The fixture 720 can include a first frame 730 having a plurality of openings 732 and a second frame 740 having a plurality of openings 742 (best shown in FIG. 7A). The holes 732 in the first frame can be aligned with the holes 742 in the second frame 740. The second frame can further include a plurality of annular teeth 744 extending around the perimeter of the second frame. It will be appreciated that the teeth 744 can alternatively extend in a different direction on the exterior surface of the second frame 740 in other embodiments, but the teeth 744 generally extend around the perimeter of the second frame 740 in a top annular band and a lower annular band to provide annular seals with the partitions 536 a-d (FIG. 6). The interface member 700 can be pressed between the first frame 730 and the second frame 740 to securely hold the interface member 700 in place. The interface assembly 710 can also include a top band 750 a extending around the top of the frames 730 and 740 and a bottom band 750 b extending around the bottom of the frames 730 and 740. The top and bottom bands 750 a-b can be welded to the frames 730 and 740 by annular welds 752. Additionally, the first and second frames 730 and 740 can be welded to each other by welds 754. It will be appreciated that the interface assembly 710 can have several different embodiments that are defined by the configuration of the field shaping unit 500 (FIG. 6) and the particular configuration of the electrode compartments 520 a-d (FIG. 6).
  • When the interface member 700 is a filter material that allows the secondary flow F2 of electroprocessing solution to pass through the holes 732 in the first frame 730, the post-filtered portion of the solution continues along a path (arrow Q) to join the primary fluid flow Fp as described above. One suitable material for a filter-type interface member 700 is POREX®, which is a porous plastic that filters particles to prevent them from passing through the interface member. In plating systems that use consumable anodes (e.g., phosphorized copper or nickel sulfamate), the interface member 700 can prevent the particles generated by the anodes from reaching the plating surface of the workpiece.
  • In alternate embodiments in which the interface member 700 is an ion-membrane, the interface member 700 can be permeable to preferred ions to allow these ions to pass through the interface member 700 and into the primary fluid flow Fp. One suitable ion-membrane is NAFION® perfluorinated membranes manufactured by DuPont®. In one application for copper plating, a NAFION 450 ion-selective membrane is used. Other suitable types of ion-membranes for plating can be polymers that are permeable to many cations, but reject anions and non-polar species. It will be appreciated that in electropolishing applications, the interface member 700 may be selected to be permeable to anions, but reject cations and non-polar species. The preferred ions can be transferred through the ion-membrane interface member 700 by a driving force, such as a difference in concentration of ions on either side of the membrane, a difference in electrical potential, or hydrostatic pressure.
  • Using an ion-membrane that prevents the fluid of the electroprocessing solution from passing through the interface member 700 allows the electrical current to pass through the interface member while filtering out particles, organic additives and bubbles in the fluid. For example, in plating applications in which the interface member 700 is permeable to cations, the primary fluid flow Fp that contacts the workpiece can be a catholyte and the secondary fluid flow F2 that does not contact the workpiece can be a separate anolyte because these fluids do not mix in this embodiment. A benefit of having separate anolyte and catholyte fluid flows is that it eliminates the consumption of additives at the anodes and thus the need to replenish the additives as often. Additionally, this feature combined with the “virtual electrode” aspect of the reaction vessel 204 reduces the need to “burn-in” anodes for insuring a consistent black film over the anodes for predictable current distribution because the current distribution is controlled by the configuration of the field shaping unit 500. Another advantage is that it also eliminates the need to have a predictable consumption of additives in the secondary flow F2 because the additives to the secondary flow F2 do not effect the primary fluid flow Fp when the two fluids are separated from each other.
  • From the foregoing, it will be appreciated that specific embodiments of the invention have been described herein for purposes of illustration, but that various modifications may be made without deviating from the spirit and scope of the invention. Accordingly, the invention is not limited except as by the appended claims.

Claims (16)

1-90. (canceled)
91. A method of electrochemically processing a microelectronic workpiece in a reaction vessel having a workpiece processing zone, the method comprising:
directing a first fluid flow of one of a catholyte or an anlolyte through a first portion of the reaction vessel and to the processing zone;
contacting a surface of a microelectronic workpiece with the first fluid flow;
directing a second fluid flow of the other of the catholyte or the anolyte through a first electrode compartment in the reaction vessel in which a first electrode is positioned and through a second electrode compartment in the reaction vessel in which a second electrode is positioned;
inhibiting the first fluid flow from flowing into the second fluid flow; and
passing selected ions between the first and second fluid flows.
92. The method of claim 91, further comprising:
applying a first electrical potential to the first electrode and applying a second electrical potential to the second electrode; and
changing at least one of the first electrical potential and/or the second electrical potential while the surface of the workpiece contacts the first fluid flow.
93. The method of claim 91 wherein inhibiting the first fluid flow from flowing into the second fluid flow comprises positioning an interface member between the first fluid flow and the second fluid flow.
94. The method of claim 93 wherein the interface member comprises a filter in the reaction vessel between the processing zone and at least one of the first and second electrode compartments.
95. The method of claim 93 wherein:
the first fluid flow comprises a catholyte and the second fluid flow comprises an anolyte;
the interface member comprises a porous filter; and
passing ions between the first fluid flow and the second fluid flow comprises passing ions and fluids through the porous filter.
96. The method of claim 93 wherein the interface member comprises an ion-membrane in the reaction vessel located between the processing zone and at least one of the first and second electrode compartments.
97. The method of claim 93 wherein:
the first fluid flow comprises a catholyte and the second fluid flow comprises an anolyte;
the interface member comprises an ion-membrane in the reaction vessel between the processing zone and at least one of the first and second electrode compartments; and
passing ions between the first fluid flow and the second fluid flow comprises moving ions through the ion-membrane while preventing fluids from crossing the membrane.
98. A method of electrochemically processing a microelectronic workpiece in a reaction vessel having a workpiece processing zone, the method comprising:
directing a first fluid flow of a catholyte through an upper portion of the reaction vessel and to the processing zone;
contacting a surface of a microelectronic workpiece with the first fluid flow;
directing a second fluid flow of an anolyte through a first electrode compartment in the reaction vessel in which a first electrode is positioned and through a second electrode compartment in the reaction vessel in which a second electrode is positioned;
preventing the first fluid flow from contacting the second fluid flow; and
passing selected ions between the first and second fluid flows.
99. The method of claim 98, further comprising:
applying a first electrical potential to the first electrode and applying a second electrical potential to the second electrode; and
changing at least one of the first electrical potential and/or the second electrical potential while the surface of the workpiece contacts the first fluid flow.
100. The method of claim 98 wherein preventing the first fluid flow from contacting the second fluid flow comprises positioning an interface member between the first fluid flow and the second fluid flow.
101. The method of claim 100 wherein the interface member comprises an ion-membrane in the reaction vessel located between the processing zone and at least one of the first and second electrode compartments.
102. The method of claim 100 wherein:
the first fluid flow comprises a catholyte and the second fluid flow comprises an anolyte;
the interface member comprises an ion-membrane in the reaction vessel between the processing zone and at least one of the first and second electrode compartments; and
passing ions between the first fluid flow and the second fluid flow comprises moving ions through the ion-membrane while preventing fluids from crossing the membrane.
103. A method of electrochemically processing a microelectronic workpiece in a reaction vessel having a workpiece processing zone, the method comprising:
directing a first fluid flow of a catholyte through an upper portion of the reaction vessel and to the processing zone;
contacting a surface of a microelectronic workpiece with the first fluid flow;
directing a second fluid flow of an anolyte through a first electrode compartment in the reaction vessel in which a first electrode is positioned and through a second electrode compartment in the reaction vessel in which a second electrode is positioned;
establishing an electrical field in the first fluid flow having a first field component generated by the first electrode and a second field component generated by the second electrode; and
passing selected ions across an ion-membrane between the catholyte and the anolyte.
104. The method of claim 103, further comprising:
applying a first electrical potential to the first electrode and applying a second electrical potential to the second electrode; and
changing at least one of the first electrical potential and/or the second electrical potential while the surface of the workpiece contacts the first fluid flow.
105. The method of claim 103 wherein passing ions across the ion-membrane comprises moving ions through the ion-membrane while preventing fluids from passing thought the membrane.
US11/096,428 1999-04-13 2005-03-29 Apparatus and methods for electrochemical processing of microelectronic workpieces Abandoned US20080217165A9 (en)

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US29469001P 2001-05-30 2001-05-30
US09/872,151 US7264698B2 (en) 1999-04-13 2001-05-31 Apparatus and methods for electrochemical processing of microelectronic workpieces
US10/158,220 US20030038035A1 (en) 2001-05-30 2002-05-29 Methods and systems for controlling current in electrochemical processing of microelectronic workpieces
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Families Citing this family (45)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6752584B2 (en) * 1996-07-15 2004-06-22 Semitool, Inc. Transfer devices for handling microelectronic workpieces within an environment of a processing machine and methods of manufacturing and using such devices in the processing of microelectronic workpieces
US6749391B2 (en) 1996-07-15 2004-06-15 Semitool, Inc. Microelectronic workpiece transfer devices and methods of using such devices in the processing of microelectronic workpieces
US6749390B2 (en) 1997-12-15 2004-06-15 Semitool, Inc. Integrated tools with transfer devices for handling microelectronic workpieces
US20060157355A1 (en) * 2000-03-21 2006-07-20 Semitool, Inc. Electrolytic process using anion permeable barrier
US6916412B2 (en) * 1999-04-13 2005-07-12 Semitool, Inc. Adaptable electrochemical processing chamber
US8236159B2 (en) 1999-04-13 2012-08-07 Applied Materials Inc. Electrolytic process using cation permeable barrier
EP1192298A4 (en) * 1999-04-13 2006-08-23 Semitool Inc System for electrochemically processing a workpiece
US8852417B2 (en) 1999-04-13 2014-10-07 Applied Materials, Inc. Electrolytic process using anion permeable barrier
US7264698B2 (en) * 1999-04-13 2007-09-04 Semitool, Inc. Apparatus and methods for electrochemical processing of microelectronic workpieces
US7438788B2 (en) * 1999-04-13 2008-10-21 Semitool, Inc. Apparatus and methods for electrochemical processing of microelectronic workpieces
US6623609B2 (en) 1999-07-12 2003-09-23 Semitool, Inc. Lift and rotate assembly for use in a workpiece processing station and a method of attaching the same
US20060189129A1 (en) * 2000-03-21 2006-08-24 Semitool, Inc. Method for applying metal features onto barrier layers using ion permeable barriers
WO2003018874A2 (en) * 2001-08-31 2003-03-06 Semitool, Inc. Apparatus and methods for electrochemical processing of microelectronic workpieces
US7125453B2 (en) * 2002-01-31 2006-10-24 General Electric Company High temperature high pressure capsule for processing materials in supercritical fluids
US20030159921A1 (en) * 2002-02-22 2003-08-28 Randy Harris Apparatus with processing stations for manually and automatically processing microelectronic workpieces
US6991710B2 (en) * 2002-02-22 2006-01-31 Semitool, Inc. Apparatus for manually and automatically processing microelectronic workpieces
US7063741B2 (en) * 2002-03-27 2006-06-20 General Electric Company High pressure high temperature growth of crystalline group III metal nitrides
US6893505B2 (en) 2002-05-08 2005-05-17 Semitool, Inc. Apparatus and method for regulating fluid flows, such as flows of electrochemical processing fluids
US20060043750A1 (en) * 2004-07-09 2006-03-02 Paul Wirth End-effectors for handling microfeature workpieces
US20040026255A1 (en) * 2002-08-06 2004-02-12 Applied Materials, Inc Insoluble anode loop in copper electrodeposition cell for interconnect formation
US7563348B2 (en) * 2004-06-28 2009-07-21 Lam Research Corporation Electroplating head and method for operating the same
US20070020080A1 (en) * 2004-07-09 2007-01-25 Paul Wirth Transfer devices and methods for handling microfeature workpieces within an environment of a processing machine
US20060045666A1 (en) * 2004-07-09 2006-03-02 Harris Randy A Modular tool unit for processing of microfeature workpieces
US7531060B2 (en) * 2004-07-09 2009-05-12 Semitool, Inc. Integrated tool assemblies with intermediate processing modules for processing of microfeature workpieces
JP4276627B2 (en) * 2005-01-12 2009-06-10 ソルボサーマル結晶成長技術研究組合 Pressure vessel for single crystal growth and method for producing the same
US7704324B2 (en) * 2005-01-25 2010-04-27 General Electric Company Apparatus for processing materials in supercritical fluids and methods thereof
US7165768B2 (en) * 2005-04-06 2007-01-23 Chih-Chung Fang Variable three-dimensional labyrinth
US20080029400A1 (en) * 2005-05-13 2008-02-07 Stephen Mazur Selective electroplating onto recessed surfaces
US7942970B2 (en) 2005-12-20 2011-05-17 Momentive Performance Materials Inc. Apparatus for making crystalline composition
US7842173B2 (en) * 2007-01-29 2010-11-30 Semitool, Inc. Apparatus and methods for electrochemical processing of microfeature wafers
US8829663B2 (en) * 2007-07-02 2014-09-09 Infineon Technologies Ag Stackable semiconductor package with encapsulant and electrically conductive feed-through
CN102147391A (en) * 2011-01-11 2011-08-10 哈尔滨工业大学 Electrochemical testing device provided with array electrodes, reference electrode and circulation system
US9005409B2 (en) 2011-04-14 2015-04-14 Tel Nexx, Inc. Electro chemical deposition and replenishment apparatus
US9017528B2 (en) 2011-04-14 2015-04-28 Tel Nexx, Inc. Electro chemical deposition and replenishment apparatus
US8496789B2 (en) 2011-05-18 2013-07-30 Applied Materials, Inc. Electrochemical processor
US8496790B2 (en) 2011-05-18 2013-07-30 Applied Materials, Inc. Electrochemical processor
US8968532B2 (en) * 2011-10-06 2015-03-03 Applied Materials, Inc. Electrochemical processor alignment system
EP2894642B1 (en) 2012-08-31 2018-05-02 Shin-Etsu Chemical Co., Ltd. Production method for rare earth permanent magnet
BR112015004500A2 (en) 2012-08-31 2017-07-04 Shinetsu Chemical Co Production method for rare earth permanent magnet
CN104584157B (en) 2012-08-31 2017-12-22 信越化学工业株式会社 The manufacture method of rare-earth permanent magnet
US9303329B2 (en) 2013-11-11 2016-04-05 Tel Nexx, Inc. Electrochemical deposition apparatus with remote catholyte fluid management
JP6090589B2 (en) 2014-02-19 2017-03-08 信越化学工業株式会社 Rare earth permanent magnet manufacturing method
JP6191497B2 (en) * 2014-02-19 2017-09-06 信越化学工業株式会社 Electrodeposition apparatus and method for producing rare earth permanent magnet
CN104947172B (en) * 2014-03-28 2018-05-29 通用电气公司 Plating tool and the method using the plating tool
CN104313668B (en) * 2014-09-30 2017-03-15 苏州芯航元电子科技有限公司 Electronics producing line electrochemical processing cell

Citations (98)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1526644A (en) * 1922-10-25 1925-02-17 Williams Brothers Mfg Company Process of electroplating and apparatus therefor
US3124520A (en) * 1959-09-28 1964-03-10 Electrode
US3309263A (en) * 1964-12-03 1967-03-14 Kimberly Clark Co Web pickup and transfer for a papermaking machine
US3716462A (en) * 1970-10-05 1973-02-13 D Jensen Copper plating on zinc and its alloys
US3798033A (en) * 1971-05-11 1974-03-19 Spectral Data Corp Isoluminous additive color multispectral display
US3798003A (en) * 1972-02-14 1974-03-19 E Ensley Differential microcalorimeter
US3930963A (en) * 1971-07-29 1976-01-06 Photocircuits Division Of Kollmorgen Corporation Method for the production of radiant energy imaged printed circuit boards
US4072557A (en) * 1974-12-23 1978-02-07 J. M. Voith Gmbh Method and apparatus for shrinking a travelling web of fibrous material
US4073708A (en) * 1976-06-18 1978-02-14 The Boeing Company Apparatus and method for regeneration of chromosulfuric acid etchants
US4132567A (en) * 1977-10-13 1979-01-02 Fsi Corporation Apparatus for and method of cleaning and removing static charges from substrates
US4134802A (en) * 1977-10-03 1979-01-16 Oxy Metal Industries Corporation Electrolyte and method for electrodepositing bright metal deposits
US4137867A (en) * 1977-09-12 1979-02-06 Seiichiro Aigo Apparatus for bump-plating semiconductor wafers
US4246088A (en) * 1979-01-24 1981-01-20 Metal Box Limited Method and apparatus for electrolytic treatment of containers
US4259166A (en) * 1980-03-31 1981-03-31 Rca Corporation Shield for plating substrate
US4310391A (en) * 1979-12-21 1982-01-12 Bell Telephone Laboratories, Incorporated Electrolytic gold plating
US4378283A (en) * 1981-07-30 1983-03-29 National Semiconductor Corporation Consumable-anode selective plating apparatus
US4431361A (en) * 1980-09-02 1984-02-14 Heraeus Quarzschmelze Gmbh Methods of and apparatus for transferring articles between carrier members
US4437943A (en) * 1980-07-09 1984-03-20 Olin Corporation Method and apparatus for bonding metal wire to a base metal substrate
US4439243A (en) * 1982-08-03 1984-03-27 Texas Instruments Incorporated Apparatus and method of material removal with fluid flow within a slot
US4439244A (en) * 1982-08-03 1984-03-27 Texas Instruments Incorporated Apparatus and method of material removal having a fluid filled slot
US4495153A (en) * 1981-06-12 1985-01-22 Nissan Motor Company, Limited Catalytic converter for treating engine exhaust gases
US4495453A (en) * 1981-06-26 1985-01-22 Fujitsu Fanuc Limited System for controlling an industrial robot
US4500394A (en) * 1984-05-16 1985-02-19 At&T Technologies, Inc. Contacting a surface for plating thereon
US4566847A (en) * 1982-03-01 1986-01-28 Kabushiki Kaisha Daini Seikosha Industrial robot
US4576689A (en) * 1979-06-19 1986-03-18 Makkaev Almaxud M Process for electrochemical metallization of dielectrics
US4576685A (en) * 1985-04-23 1986-03-18 Schering Ag Process and apparatus for plating onto articles
US4634503A (en) * 1984-06-27 1987-01-06 Daniel Nogavich Immersion electroplating system
US4639028A (en) * 1984-11-13 1987-01-27 Economic Development Corporation High temperature and acid resistant wafer pick up device
US4648944A (en) * 1985-07-18 1987-03-10 Martin Marietta Corporation Apparatus and method for controlling plating induced stress in electroforming and electroplating processes
US4652345A (en) * 1983-12-19 1987-03-24 International Business Machines Corporation Method of depositing a metal from an electroless plating solution
US4732785A (en) * 1986-09-26 1988-03-22 Motorola, Inc. Edge bead removal process for spin on films
US4800818A (en) * 1985-11-02 1989-01-31 Hitachi Kiden Kogyo Kabushiki Kaisha Linear motor-driven conveyor means
US4898647A (en) * 1985-12-24 1990-02-06 Gould, Inc. Process and apparatus for electroplating copper foil
US4902398A (en) * 1988-04-27 1990-02-20 American Thim Film Laboratories, Inc. Computer program for vacuum coating systems
US4903717A (en) * 1987-11-09 1990-02-27 Sez Semiconductor-Equipment Zubehoer Fuer die Halbleiterfertigung Gesellschaft m.b.H Support for slice-shaped articles and device for etching silicon wafers with such a support
US4906341A (en) * 1987-09-24 1990-03-06 Kabushiki Kaisha Toshiba Method of manufacturing semiconductor device and apparatus therefor
US4906340A (en) * 1989-05-31 1990-03-06 Eco-Tec Limited Process for electroplating metals
US4982215A (en) * 1988-08-31 1991-01-01 Kabushiki Kaisha Toshiba Method and apparatus for creation of resist patterns by chemical development
US4982753A (en) * 1983-07-26 1991-01-08 National Semiconductor Corporation Wafer etching, cleaning and stripping apparatus
US4988533A (en) * 1988-05-27 1991-01-29 Texas Instruments Incorporated Method for deposition of silicon oxide on a wafer
US5000827A (en) * 1990-01-02 1991-03-19 Motorola, Inc. Method and apparatus for adjusting plating solution flow characteristics at substrate cathode periphery to minimize edge effect
US5078852A (en) * 1990-10-12 1992-01-07 Microelectronics And Computer Technology Corporation Plating rack
US5083364A (en) * 1987-10-20 1992-01-28 Convac Gmbh System for manufacturing semiconductor substrates
US5096550A (en) * 1990-10-15 1992-03-17 The United States Of America As Represented By The United States Department Of Energy Method and apparatus for spatially uniform electropolishing and electrolytic etching
US5178639A (en) * 1990-06-28 1993-01-12 Tokyo Electron Sagami Limited Vertical heat-treating apparatus
US5178512A (en) * 1991-04-01 1993-01-12 Equipe Technologies Precision robot apparatus
US5180273A (en) * 1989-10-09 1993-01-19 Kabushiki Kaisha Toshiba Apparatus for transferring semiconductor wafers
US5183377A (en) * 1988-05-31 1993-02-02 Mannesmann Ag Guiding a robot in an array
US5186594A (en) * 1990-04-19 1993-02-16 Applied Materials, Inc. Dual cassette load lock
US5377708A (en) * 1989-03-27 1995-01-03 Semitool, Inc. Multi-station semiconductor processor with volatilization
US5388945A (en) * 1992-08-04 1995-02-14 International Business Machines Corporation Fully automated and computerized conveyor based manufacturing line architectures adapted to pressurized sealable transportable containers
US5391517A (en) * 1993-09-13 1995-02-21 Motorola Inc. Process for forming copper interconnect structure
US5391285A (en) * 1994-02-25 1995-02-21 Motorola, Inc. Adjustable plating cell for uniform bump plating of semiconductor wafers
US5393624A (en) * 1988-07-29 1995-02-28 Tokyo Electron Limited Method and apparatus for manufacturing a semiconductor device
US5489341A (en) * 1993-08-23 1996-02-06 Semitool, Inc. Semiconductor processing with non-jetting fluid stream discharge array
US5500081A (en) * 1990-05-15 1996-03-19 Bergman; Eric J. Dynamic semiconductor wafer processing using homogeneous chemical vapors
US5501768A (en) * 1992-04-17 1996-03-26 Kimberly-Clark Corporation Method of treating papermaking fibers for making tissue
US5591262A (en) * 1994-03-24 1997-01-07 Tazmo Co., Ltd. Rotary chemical treater having stationary cleaning fluid nozzle
US5593545A (en) * 1995-02-06 1997-01-14 Kimberly-Clark Corporation Method for making uncreped throughdried tissue products without an open draw
US5597460A (en) * 1995-11-13 1997-01-28 Reynolds Tech Fabricators, Inc. Plating cell having laminar flow sparger
US5597836A (en) * 1991-09-03 1997-01-28 Dowelanco N-(4-pyridyl) (substituted phenyl) acetamide pesticides
US5600532A (en) * 1994-04-11 1997-02-04 Ngk Spark Plug Co., Ltd. Thin-film condenser
US5609239A (en) * 1994-03-21 1997-03-11 Thyssen Aufzuege Gmbh Locking system
US5711646A (en) * 1994-10-07 1998-01-27 Tokyo Electron Limited Substrate transfer apparatus
US5718763A (en) * 1994-04-04 1998-02-17 Tokyo Electron Limited Resist processing apparatus for a rectangular substrate
US5719495A (en) * 1990-12-31 1998-02-17 Texas Instruments Incorporated Apparatus for semiconductor device fabrication diagnosis and prognosis
US5723028A (en) * 1990-08-01 1998-03-03 Poris; Jaime Electrodeposition apparatus with virtual anode
US5731678A (en) * 1996-07-15 1998-03-24 Semitool, Inc. Processing head for semiconductor processing machines
US5860640A (en) * 1995-11-29 1999-01-19 Applied Materials, Inc. Semiconductor wafer alignment member and clamp ring
US5868866A (en) * 1995-03-03 1999-02-09 Ebara Corporation Method of and apparatus for cleaning workpiece
US5872633A (en) * 1996-07-26 1999-02-16 Speedfam Corporation Methods and apparatus for detecting removal of thin film layers during planarization
US5871626A (en) * 1995-09-27 1999-02-16 Intel Corporation Flexible continuous cathode contact circuit for electrolytic plating of C4, TAB microbumps, and ultra large scale interconnects
US5871805A (en) * 1996-04-08 1999-02-16 Lemelson; Jerome Computer controlled vapor deposition processes
US6017820A (en) * 1998-07-17 2000-01-25 Cutek Research, Inc. Integrated vacuum and plating cluster system
US6017437A (en) * 1997-08-22 2000-01-25 Cutek Research, Inc. Process chamber and method for depositing and/or removing material on a substrate
US6025600A (en) * 1998-05-29 2000-02-15 International Business Machines Corporation Method for astigmatism correction in charged particle beam systems
US6028986A (en) * 1995-11-10 2000-02-22 Samsung Electronics Co., Ltd. Methods of designing and fabricating intergrated circuits which take into account capacitive loading by the intergrated circuit potting material
US6027631A (en) * 1997-11-13 2000-02-22 Novellus Systems, Inc. Electroplating system with shields for varying thickness profile of deposited layer
US6168695B1 (en) * 1999-07-12 2001-01-02 Daniel J. Woodruff Lift and rotate assembly for use in a workpiece processing station and a method of attaching the same
US6168693B1 (en) * 1998-01-22 2001-01-02 International Business Machines Corporation Apparatus for controlling the uniformity of an electroplated workpiece
US6174796B1 (en) * 1998-01-30 2001-01-16 Fujitsu Limited Semiconductor device manufacturing method
US6174425B1 (en) * 1997-05-14 2001-01-16 Motorola, Inc. Process for depositing a layer of material over a substrate
US6179983B1 (en) * 1997-11-13 2001-01-30 Novellus Systems, Inc. Method and apparatus for treating surface including virtual anode
US6184068B1 (en) * 1994-06-02 2001-02-06 Semiconductor Energy Laboratory Co., Ltd. Process for fabricating semiconductor device
US6187072B1 (en) * 1995-09-25 2001-02-13 Applied Materials, Inc. Method and apparatus for reducing perfluorocompound gases from substrate processing equipment emissions
US6190234B1 (en) * 1999-01-25 2001-02-20 Applied Materials, Inc. Endpoint detection with light beams of different wavelengths
US6194628B1 (en) * 1995-09-25 2001-02-27 Applied Materials, Inc. Method and apparatus for cleaning a vacuum line in a CVD system
US6193859B1 (en) * 1997-11-13 2001-02-27 Novellus Systems, Inc. Electric potential shaping apparatus for holding a semiconductor wafer during electroplating
US6193802B1 (en) * 1995-09-25 2001-02-27 Applied Materials, Inc. Parallel plate apparatus for in-situ vacuum line cleaning for substrate processing equipment
US20020008036A1 (en) * 1998-02-12 2002-01-24 Hui Wang Plating apparatus and method
US20020008037A1 (en) * 1999-04-13 2002-01-24 Wilson Gregory J. System for electrochemically processing a workpiece
US20020022363A1 (en) * 1998-02-04 2002-02-21 Thomas L. Ritzdorf Method for filling recessed micro-structures with metallization in the production of a microelectronic device
US6350319B1 (en) * 1998-03-13 2002-02-26 Semitool, Inc. Micro-environment reactor for processing a workpiece
US20030020928A1 (en) * 2000-07-08 2003-01-30 Ritzdorf Thomas L. Methods and apparatus for processing microelectronic workpieces using metrology
US20030038035A1 (en) * 2001-05-30 2003-02-27 Wilson Gregory J. Methods and systems for controlling current in electrochemical processing of microelectronic workpieces
US6672820B1 (en) * 1996-07-15 2004-01-06 Semitool, Inc. Semiconductor processing apparatus having linear conveyer system
US6678055B2 (en) * 2001-11-26 2004-01-13 Tevet Process Control Technologies Ltd. Method and apparatus for measuring stress in semiconductor wafers
US20040031693A1 (en) * 1998-03-20 2004-02-19 Chen Linlin Apparatus and method for electrochemically depositing metal on a semiconductor workpiece

Family Cites Families (95)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1881713A (en) 1928-12-03 1932-10-11 Arthur K Laukel Flexible and adjustable anode
US2256274A (en) 1938-06-30 1941-09-16 Firm J D Riedel E De Haen A G Salicylic acid sulphonyl sulphanilamides
NL83873C (en) 1952-05-26
US3308152A (en) * 1963-08-28 1967-03-07 Dow Corning 1, 1, 1, 3, 3, 5, 5, 5-octa-(trimethylsiloxy)-2, 2, 4, 4-tetramethylpentasiloxane
US3328273A (en) 1966-08-15 1967-06-27 Udylite Corp Electro-deposition of copper from acidic baths
US3537961A (en) 1967-12-18 1970-11-03 Mutual Mining & Refining Ltd Process of treating copper ores
US3616284A (en) 1968-08-21 1971-10-26 Bell Telephone Labor Inc Processing arrays of junction devices
US3664933A (en) 1969-06-19 1972-05-23 Udylite Corp Process for acid copper plating of zinc
US3727620A (en) 1970-03-18 1973-04-17 Fluoroware Of California Inc Rinsing and drying device
US3706651A (en) 1970-12-30 1972-12-19 Us Navy Apparatus for electroplating a curved surface
BE791401A (en) 1971-11-15 1973-05-14 Monsanto Co ELECTROCHEMICAL COMPOSITIONS AND PROCESSES
DE2244434C3 (en) 1972-09-06 1982-02-25 Schering Ag, 1000 Berlin Und 4619 Bergkamen Aqueous bath for the galvanic deposition of gold and gold alloys
US4022679A (en) 1973-05-10 1977-05-10 C. Conradty Coated titanium anode for amalgam heavy duty cells
US3968885A (en) 1973-06-29 1976-07-13 International Business Machines Corporation Method and apparatus for handling workpieces
US4001094A (en) 1974-09-19 1977-01-04 Jumer John F Method for incremental electro-processing of large areas
US4000046A (en) 1974-12-23 1976-12-28 P. R. Mallory & Co., Inc. Method of electroplating a conductive layer over an electrolytic capacitor
GB1481663A (en) 1975-01-09 1977-08-03 Parel S Electrowinning of metals
US3953265A (en) 1975-04-28 1976-04-27 International Business Machines Corporation Meniscus-contained method of handling fluids in the manufacture of semiconductor wafers
US4046105A (en) 1975-06-16 1977-09-06 Xerox Corporation Laminar deep wave generator
US4032422A (en) 1975-10-03 1977-06-28 National Semiconductor Corporation Apparatus for plating semiconductor chip headers
US4030015A (en) 1975-10-20 1977-06-14 International Business Machines Corporation Pulse width modulated voltage regulator-converter/power converter having push-push regulator-converter means
US4165252A (en) 1976-08-30 1979-08-21 Burroughs Corporation Method for chemically treating a single side of a workpiece
US4170959A (en) 1978-04-04 1979-10-16 Seiichiro Aigo Apparatus for bump-plating semiconductor wafers
US4341629A (en) 1978-08-28 1982-07-27 Sand And Sea Industries, Inc. Means for desalination of water through reverse osmosis
US4276855A (en) 1979-05-02 1981-07-07 Optical Coating Laboratory, Inc. Coating apparatus
US4222834A (en) 1979-06-06 1980-09-16 Western Electric Company, Inc. Selectively treating an article
US4286541A (en) 1979-07-26 1981-09-01 Fsi Corporation Applying photoresist onto silicon wafers
JPS56102590A (en) 1979-08-09 1981-08-17 Koichi Shimamura Method and device for plating of microarea
US4422915A (en) 1979-09-04 1983-12-27 Battelle Memorial Institute Preparation of colored polymeric film-like coating
US4238310A (en) 1979-10-03 1980-12-09 United Technologies Corporation Apparatus for electrolytic etching
US4269670A (en) 1980-03-03 1981-05-26 Bell Telephone Laboratories, Incorporated Electrode for electrochemical processes
US4323433A (en) 1980-09-22 1982-04-06 The Boeing Company Anodizing process employing adjustable shield for suspended cathode
US4443117A (en) 1980-09-26 1984-04-17 Terumo Corporation Measuring apparatus, method of manufacture thereof, and method of writing data into same
US4304641A (en) 1980-11-24 1981-12-08 International Business Machines Corporation Rotary electroplating cell with controlled current distribution
SE8101046L (en) 1981-02-16 1982-08-17 Europafilm DEVICE FOR PLANTS, Separate for the matrices of gramophone discs and the like
US4360410A (en) 1981-03-06 1982-11-23 Western Electric Company, Inc. Electroplating processes and equipment utilizing a foam electrolyte
US4384930A (en) 1981-08-21 1983-05-24 Mcgean-Rohco, Inc. Electroplating baths, additives therefor and methods for the electrodeposition of metals
US4463503A (en) 1981-09-29 1984-08-07 Driall, Inc. Grain drier and method of drying grain
JPS58154842A (en) 1982-02-03 1983-09-14 Konishiroku Photo Ind Co Ltd Silver halide color photographic sensitive material
US4440597A (en) 1982-03-15 1984-04-03 The Procter & Gamble Company Wet-microcontracted paper and concomitant process
US4475823A (en) 1982-04-09 1984-10-09 Piezo Electric Products, Inc. Self-calibrating thermometer
US4449885A (en) 1982-05-24 1984-05-22 Varian Associates, Inc. Wafer transfer system
US4451197A (en) 1982-07-26 1984-05-29 Advanced Semiconductor Materials Die Bonding, Inc. Object detection apparatus and method
US4838289A (en) 1982-08-03 1989-06-13 Texas Instruments Incorporated Apparatus and method for edge cleaning
US4514269A (en) 1982-08-06 1985-04-30 Alcan International Limited Metal production by electrolysis of a molten electrolyte
US4469564A (en) 1982-08-11 1984-09-04 At&T Bell Laboratories Copper electroplating process
US4585539A (en) 1982-08-17 1986-04-29 Technic, Inc. Electrolytic reactor
US4436243A (en) * 1982-09-27 1984-03-13 Medical Packaging Corporation Storage file for slides and tissue blocks
US4541895A (en) 1982-10-29 1985-09-17 Scapa Inc. Papermakers fabric of nonwoven layers in a laminated construction
JPS59150094A (en) * 1983-02-14 1984-08-28 Teichiku Kk Disc type rotary plating device
US4529480A (en) 1983-08-23 1985-07-16 The Procter & Gamble Company Tissue paper
US4469566A (en) 1983-08-29 1984-09-04 Dynamic Disk, Inc. Method and apparatus for producing electroplated magnetic memory disk, and the like
US4466864A (en) 1983-12-16 1984-08-21 At&T Technologies, Inc. Methods of and apparatus for electroplating preselected surface regions of electrical articles
US4544446A (en) 1984-07-24 1985-10-01 J. T. Baker Chemical Co. VLSI chemical reactor
DE8430403U1 (en) 1984-10-16 1985-04-25 Gebr. Steimel, 5202 Hennef CENTERING DEVICE
US4604178A (en) 1985-03-01 1986-08-05 The Dow Chemical Company Anode
US4685414A (en) 1985-04-03 1987-08-11 Dirico Mark A Coating printed sheets
JPS61178187U (en) 1985-04-26 1986-11-06
US4664133A (en) 1985-07-26 1987-05-12 Fsi Corporation Wafer processing machine
US4760671A (en) 1985-08-19 1988-08-02 Owens-Illinois Television Products Inc. Method of and apparatus for automatically grinding cathode ray tube faceplates
FR2587915B1 (en) 1985-09-27 1987-11-27 Omya Sa DEVICE FOR CONTACTING FLUIDS IN THE FORM OF DIFFERENT PHASES
JPH0444216Y2 (en) 1985-10-07 1992-10-19
US4715934A (en) 1985-11-18 1987-12-29 Lth Associates Process and apparatus for separating metals from solutions
US4761214A (en) 1985-11-27 1988-08-02 Airfoil Textron Inc. ECM machine with mechanisms for venting and clamping a workpart shroud
US4687552A (en) 1985-12-02 1987-08-18 Tektronix, Inc. Rhodium capped gold IC metallization
US4696729A (en) 1986-02-28 1987-09-29 International Business Machines Electroplating cell
US4670126A (en) 1986-04-28 1987-06-02 Varian Associates, Inc. Sputter module for modular wafer processing system
US4770590A (en) 1986-05-16 1988-09-13 Silicon Valley Group, Inc. Method and apparatus for transferring wafers between cassettes and a boat
US4778572A (en) 1987-09-08 1988-10-18 Eco-Tec Limited Process for electroplating metals
US4781800A (en) 1987-09-29 1988-11-01 President And Fellows Of Harvard College Deposition of metal or alloy film
US4828654A (en) 1988-03-23 1989-05-09 Protocad, Inc. Variable size segmented anode array for electroplating
US4982752A (en) * 1989-08-02 1991-01-08 Nicolas Rodriguez Dental floss device
US5256274A (en) * 1990-08-01 1993-10-26 Jaime Poris Selective metal electrodeposition process
US5595460A (en) * 1994-06-06 1997-01-21 The Tensar Corporation Modular block retaining wall system and method of constructing same
TW386235B (en) * 1995-05-23 2000-04-01 Tokyo Electron Ltd Method for spin rinsing
US6749390B2 (en) * 1997-12-15 2004-06-15 Semitool, Inc. Integrated tools with transfer devices for handling microelectronic workpieces
US6921467B2 (en) * 1996-07-15 2005-07-26 Semitool, Inc. Processing tools, components of processing tools, and method of making and using same for electrochemical processing of microelectronic workpieces
US6752584B2 (en) * 1996-07-15 2004-06-22 Semitool, Inc. Transfer devices for handling microelectronic workpieces within an environment of a processing machine and methods of manufacturing and using such devices in the processing of microelectronic workpieces
US5883762A (en) * 1997-03-13 1999-03-16 Calhoun; Robert B. Electroplating apparatus and process for reducing oxidation of oxidizable plating anions and cations
US6921468B2 (en) * 1997-09-30 2005-07-26 Semitool, Inc. Electroplating system having auxiliary electrode exterior to main reactor chamber for contact cleaning operations
US5882498A (en) * 1997-10-16 1999-03-16 Advanced Micro Devices, Inc. Method for reducing oxidation of electroplating chamber contacts and improving uniform electroplating of a substrate
US6126798A (en) * 1997-11-13 2000-10-03 Novellus Systems, Inc. Electroplating anode including membrane partition system and method of preventing passivation of same
US6497801B1 (en) * 1998-07-10 2002-12-24 Semitool Inc Electroplating apparatus with segmented anode array
WO2000032835A2 (en) * 1998-11-30 2000-06-08 Applied Materials, Inc. Electro-chemical deposition system
EP1052311A4 (en) * 1998-11-30 2006-06-21 Ebara Corp Plating machine
US7020537B2 (en) * 1999-04-13 2006-03-28 Semitool, Inc. Tuning electrodes used in a reactor for electrochemically processing a microelectronic workpiece
US7189318B2 (en) * 1999-04-13 2007-03-13 Semitool, Inc. Tuning electrodes used in a reactor for electrochemically processing a microelectronic workpiece
US7264698B2 (en) * 1999-04-13 2007-09-04 Semitool, Inc. Apparatus and methods for electrochemical processing of microelectronic workpieces
US7160421B2 (en) * 1999-04-13 2007-01-09 Semitool, Inc. Turning electrodes used in a reactor for electrochemically processing a microelectronic workpiece
US6916412B2 (en) * 1999-04-13 2005-07-12 Semitool, Inc. Adaptable electrochemical processing chamber
US6780374B2 (en) * 2000-12-08 2004-08-24 Semitool, Inc. Method and apparatus for processing a microelectronic workpiece at an elevated temperature
US6428673B1 (en) * 2000-07-08 2002-08-06 Semitool, Inc. Apparatus and method for electrochemical processing of a microelectronic workpiece, capable of modifying processing based on metrology
US20050061676A1 (en) * 2001-03-12 2005-03-24 Wilson Gregory J. System for electrochemically processing a workpiece
US7794573B2 (en) * 2003-12-05 2010-09-14 Semitool, Inc. Systems and methods for electrochemically processing microfeature workpieces
US20060144712A1 (en) * 2003-12-05 2006-07-06 Klocke John L Systems and methods for electrochemically processing microfeature workpieces

Patent Citations (99)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1526644A (en) * 1922-10-25 1925-02-17 Williams Brothers Mfg Company Process of electroplating and apparatus therefor
US3124520A (en) * 1959-09-28 1964-03-10 Electrode
US3309263A (en) * 1964-12-03 1967-03-14 Kimberly Clark Co Web pickup and transfer for a papermaking machine
US3716462A (en) * 1970-10-05 1973-02-13 D Jensen Copper plating on zinc and its alloys
US3798033A (en) * 1971-05-11 1974-03-19 Spectral Data Corp Isoluminous additive color multispectral display
US3930963A (en) * 1971-07-29 1976-01-06 Photocircuits Division Of Kollmorgen Corporation Method for the production of radiant energy imaged printed circuit boards
US3798003A (en) * 1972-02-14 1974-03-19 E Ensley Differential microcalorimeter
US4072557A (en) * 1974-12-23 1978-02-07 J. M. Voith Gmbh Method and apparatus for shrinking a travelling web of fibrous material
US4073708A (en) * 1976-06-18 1978-02-14 The Boeing Company Apparatus and method for regeneration of chromosulfuric acid etchants
US4137867A (en) * 1977-09-12 1979-02-06 Seiichiro Aigo Apparatus for bump-plating semiconductor wafers
US4134802A (en) * 1977-10-03 1979-01-16 Oxy Metal Industries Corporation Electrolyte and method for electrodepositing bright metal deposits
US4132567A (en) * 1977-10-13 1979-01-02 Fsi Corporation Apparatus for and method of cleaning and removing static charges from substrates
US4246088A (en) * 1979-01-24 1981-01-20 Metal Box Limited Method and apparatus for electrolytic treatment of containers
US4576689A (en) * 1979-06-19 1986-03-18 Makkaev Almaxud M Process for electrochemical metallization of dielectrics
US4310391A (en) * 1979-12-21 1982-01-12 Bell Telephone Laboratories, Incorporated Electrolytic gold plating
US4259166A (en) * 1980-03-31 1981-03-31 Rca Corporation Shield for plating substrate
US4437943A (en) * 1980-07-09 1984-03-20 Olin Corporation Method and apparatus for bonding metal wire to a base metal substrate
US4431361A (en) * 1980-09-02 1984-02-14 Heraeus Quarzschmelze Gmbh Methods of and apparatus for transferring articles between carrier members
US4495153A (en) * 1981-06-12 1985-01-22 Nissan Motor Company, Limited Catalytic converter for treating engine exhaust gases
US4495453A (en) * 1981-06-26 1985-01-22 Fujitsu Fanuc Limited System for controlling an industrial robot
US4378283A (en) * 1981-07-30 1983-03-29 National Semiconductor Corporation Consumable-anode selective plating apparatus
US4566847A (en) * 1982-03-01 1986-01-28 Kabushiki Kaisha Daini Seikosha Industrial robot
US4439244A (en) * 1982-08-03 1984-03-27 Texas Instruments Incorporated Apparatus and method of material removal having a fluid filled slot
US4439243A (en) * 1982-08-03 1984-03-27 Texas Instruments Incorporated Apparatus and method of material removal with fluid flow within a slot
US4982753A (en) * 1983-07-26 1991-01-08 National Semiconductor Corporation Wafer etching, cleaning and stripping apparatus
US4652345A (en) * 1983-12-19 1987-03-24 International Business Machines Corporation Method of depositing a metal from an electroless plating solution
US4500394A (en) * 1984-05-16 1985-02-19 At&T Technologies, Inc. Contacting a surface for plating thereon
US4634503A (en) * 1984-06-27 1987-01-06 Daniel Nogavich Immersion electroplating system
US4639028A (en) * 1984-11-13 1987-01-27 Economic Development Corporation High temperature and acid resistant wafer pick up device
US4576685A (en) * 1985-04-23 1986-03-18 Schering Ag Process and apparatus for plating onto articles
US4648944A (en) * 1985-07-18 1987-03-10 Martin Marietta Corporation Apparatus and method for controlling plating induced stress in electroforming and electroplating processes
US4800818A (en) * 1985-11-02 1989-01-31 Hitachi Kiden Kogyo Kabushiki Kaisha Linear motor-driven conveyor means
US4898647A (en) * 1985-12-24 1990-02-06 Gould, Inc. Process and apparatus for electroplating copper foil
US4732785A (en) * 1986-09-26 1988-03-22 Motorola, Inc. Edge bead removal process for spin on films
US4906341A (en) * 1987-09-24 1990-03-06 Kabushiki Kaisha Toshiba Method of manufacturing semiconductor device and apparatus therefor
US5083364A (en) * 1987-10-20 1992-01-28 Convac Gmbh System for manufacturing semiconductor substrates
US4903717A (en) * 1987-11-09 1990-02-27 Sez Semiconductor-Equipment Zubehoer Fuer die Halbleiterfertigung Gesellschaft m.b.H Support for slice-shaped articles and device for etching silicon wafers with such a support
US4902398A (en) * 1988-04-27 1990-02-20 American Thim Film Laboratories, Inc. Computer program for vacuum coating systems
US4988533A (en) * 1988-05-27 1991-01-29 Texas Instruments Incorporated Method for deposition of silicon oxide on a wafer
US5183377A (en) * 1988-05-31 1993-02-02 Mannesmann Ag Guiding a robot in an array
US5393624A (en) * 1988-07-29 1995-02-28 Tokyo Electron Limited Method and apparatus for manufacturing a semiconductor device
US4982215A (en) * 1988-08-31 1991-01-01 Kabushiki Kaisha Toshiba Method and apparatus for creation of resist patterns by chemical development
US5377708A (en) * 1989-03-27 1995-01-03 Semitool, Inc. Multi-station semiconductor processor with volatilization
US4906340A (en) * 1989-05-31 1990-03-06 Eco-Tec Limited Process for electroplating metals
US5180273A (en) * 1989-10-09 1993-01-19 Kabushiki Kaisha Toshiba Apparatus for transferring semiconductor wafers
US5000827A (en) * 1990-01-02 1991-03-19 Motorola, Inc. Method and apparatus for adjusting plating solution flow characteristics at substrate cathode periphery to minimize edge effect
US5186594A (en) * 1990-04-19 1993-02-16 Applied Materials, Inc. Dual cassette load lock
US5500081A (en) * 1990-05-15 1996-03-19 Bergman; Eric J. Dynamic semiconductor wafer processing using homogeneous chemical vapors
US5178639A (en) * 1990-06-28 1993-01-12 Tokyo Electron Sagami Limited Vertical heat-treating apparatus
US5723028A (en) * 1990-08-01 1998-03-03 Poris; Jaime Electrodeposition apparatus with virtual anode
US5078852A (en) * 1990-10-12 1992-01-07 Microelectronics And Computer Technology Corporation Plating rack
US5096550A (en) * 1990-10-15 1992-03-17 The United States Of America As Represented By The United States Department Of Energy Method and apparatus for spatially uniform electropolishing and electrolytic etching
US5719495A (en) * 1990-12-31 1998-02-17 Texas Instruments Incorporated Apparatus for semiconductor device fabrication diagnosis and prognosis
US5178512A (en) * 1991-04-01 1993-01-12 Equipe Technologies Precision robot apparatus
US5597836A (en) * 1991-09-03 1997-01-28 Dowelanco N-(4-pyridyl) (substituted phenyl) acetamide pesticides
US5501768A (en) * 1992-04-17 1996-03-26 Kimberly-Clark Corporation Method of treating papermaking fibers for making tissue
US5388945A (en) * 1992-08-04 1995-02-14 International Business Machines Corporation Fully automated and computerized conveyor based manufacturing line architectures adapted to pressurized sealable transportable containers
US5489341A (en) * 1993-08-23 1996-02-06 Semitool, Inc. Semiconductor processing with non-jetting fluid stream discharge array
US5391517A (en) * 1993-09-13 1995-02-21 Motorola Inc. Process for forming copper interconnect structure
US5391285A (en) * 1994-02-25 1995-02-21 Motorola, Inc. Adjustable plating cell for uniform bump plating of semiconductor wafers
US5609239A (en) * 1994-03-21 1997-03-11 Thyssen Aufzuege Gmbh Locking system
US5591262A (en) * 1994-03-24 1997-01-07 Tazmo Co., Ltd. Rotary chemical treater having stationary cleaning fluid nozzle
US5718763A (en) * 1994-04-04 1998-02-17 Tokyo Electron Limited Resist processing apparatus for a rectangular substrate
US5600532A (en) * 1994-04-11 1997-02-04 Ngk Spark Plug Co., Ltd. Thin-film condenser
US6184068B1 (en) * 1994-06-02 2001-02-06 Semiconductor Energy Laboratory Co., Ltd. Process for fabricating semiconductor device
US5711646A (en) * 1994-10-07 1998-01-27 Tokyo Electron Limited Substrate transfer apparatus
US5593545A (en) * 1995-02-06 1997-01-14 Kimberly-Clark Corporation Method for making uncreped throughdried tissue products without an open draw
US5868866A (en) * 1995-03-03 1999-02-09 Ebara Corporation Method of and apparatus for cleaning workpiece
US6194628B1 (en) * 1995-09-25 2001-02-27 Applied Materials, Inc. Method and apparatus for cleaning a vacuum line in a CVD system
US6193802B1 (en) * 1995-09-25 2001-02-27 Applied Materials, Inc. Parallel plate apparatus for in-situ vacuum line cleaning for substrate processing equipment
US6187072B1 (en) * 1995-09-25 2001-02-13 Applied Materials, Inc. Method and apparatus for reducing perfluorocompound gases from substrate processing equipment emissions
US5871626A (en) * 1995-09-27 1999-02-16 Intel Corporation Flexible continuous cathode contact circuit for electrolytic plating of C4, TAB microbumps, and ultra large scale interconnects
US6028986A (en) * 1995-11-10 2000-02-22 Samsung Electronics Co., Ltd. Methods of designing and fabricating intergrated circuits which take into account capacitive loading by the intergrated circuit potting material
US5597460A (en) * 1995-11-13 1997-01-28 Reynolds Tech Fabricators, Inc. Plating cell having laminar flow sparger
US5860640A (en) * 1995-11-29 1999-01-19 Applied Materials, Inc. Semiconductor wafer alignment member and clamp ring
US5871805A (en) * 1996-04-08 1999-02-16 Lemelson; Jerome Computer controlled vapor deposition processes
US5731678A (en) * 1996-07-15 1998-03-24 Semitool, Inc. Processing head for semiconductor processing machines
US6672820B1 (en) * 1996-07-15 2004-01-06 Semitool, Inc. Semiconductor processing apparatus having linear conveyer system
US5872633A (en) * 1996-07-26 1999-02-16 Speedfam Corporation Methods and apparatus for detecting removal of thin film layers during planarization
US6174425B1 (en) * 1997-05-14 2001-01-16 Motorola, Inc. Process for depositing a layer of material over a substrate
US6017437A (en) * 1997-08-22 2000-01-25 Cutek Research, Inc. Process chamber and method for depositing and/or removing material on a substrate
US6193859B1 (en) * 1997-11-13 2001-02-27 Novellus Systems, Inc. Electric potential shaping apparatus for holding a semiconductor wafer during electroplating
US6027631A (en) * 1997-11-13 2000-02-22 Novellus Systems, Inc. Electroplating system with shields for varying thickness profile of deposited layer
US6179983B1 (en) * 1997-11-13 2001-01-30 Novellus Systems, Inc. Method and apparatus for treating surface including virtual anode
US6168693B1 (en) * 1998-01-22 2001-01-02 International Business Machines Corporation Apparatus for controlling the uniformity of an electroplated workpiece
US6174796B1 (en) * 1998-01-30 2001-01-16 Fujitsu Limited Semiconductor device manufacturing method
US20020022363A1 (en) * 1998-02-04 2002-02-21 Thomas L. Ritzdorf Method for filling recessed micro-structures with metallization in the production of a microelectronic device
US20020008036A1 (en) * 1998-02-12 2002-01-24 Hui Wang Plating apparatus and method
US6350319B1 (en) * 1998-03-13 2002-02-26 Semitool, Inc. Micro-environment reactor for processing a workpiece
US20040031693A1 (en) * 1998-03-20 2004-02-19 Chen Linlin Apparatus and method for electrochemically depositing metal on a semiconductor workpiece
US6025600A (en) * 1998-05-29 2000-02-15 International Business Machines Corporation Method for astigmatism correction in charged particle beam systems
US6017820A (en) * 1998-07-17 2000-01-25 Cutek Research, Inc. Integrated vacuum and plating cluster system
US6190234B1 (en) * 1999-01-25 2001-02-20 Applied Materials, Inc. Endpoint detection with light beams of different wavelengths
US20020008037A1 (en) * 1999-04-13 2002-01-24 Wilson Gregory J. System for electrochemically processing a workpiece
US6168695B1 (en) * 1999-07-12 2001-01-02 Daniel J. Woodruff Lift and rotate assembly for use in a workpiece processing station and a method of attaching the same
US6342137B1 (en) * 1999-07-12 2002-01-29 Semitool, Inc. Lift and rotate assembly for use in a workpiece processing station and a method of attaching the same
US20030020928A1 (en) * 2000-07-08 2003-01-30 Ritzdorf Thomas L. Methods and apparatus for processing microelectronic workpieces using metrology
US20030038035A1 (en) * 2001-05-30 2003-02-27 Wilson Gregory J. Methods and systems for controlling current in electrochemical processing of microelectronic workpieces
US6678055B2 (en) * 2001-11-26 2004-01-13 Tevet Process Control Technologies Ltd. Method and apparatus for measuring stress in semiconductor wafers

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