|Publication number||US20090086331 A1|
|Application number||US 12/235,697|
|Publication date||Apr 2, 2009|
|Filing date||Sep 23, 2008|
|Priority date||Apr 30, 2004|
|Also published as||US7359124, US7440193, US20080144187|
|Publication number||12235697, 235697, US 2009/0086331 A1, US 2009/086331 A1, US 20090086331 A1, US 20090086331A1, US 2009086331 A1, US 2009086331A1, US-A1-20090086331, US-A1-2009086331, US2009/0086331A1, US2009/086331A1, US20090086331 A1, US20090086331A1, US2009086331 A1, US2009086331A1|
|Inventors||R. A. Gunasekaran, Mangilal Agarwal, Ji Fang, Jackie Chen, Weisong Wang, Kody Varahramyan|
|Original Assignee||Gunasekaran R A, Mangilal Agarwal, Ji Fang, Jackie Chen, Weisong Wang, Kody Varahramyan|
|Export Citation||BiBTeX, EndNote, RefMan|
|Referenced by (30), Classifications (8)|
|External Links: USPTO, USPTO Assignment, Espacenet|
This application claims the benefit under 35 USC § 119(e) to U.S. Provisional Application No. 60/567,274 filed Apr. 30, 2004, which is incorporated by reference herein in its entirety.
The invention described herein was made with support of the U.S. Government, and the U.S. Government may have certain rights in the invention as provided for by the terms of Grant Nos. 32096756141 and BAA 01-42-#427 awarded by the Defense Advanced Research Projects Agency.
The present invention relates to flexible lens systems, in particular lens systems wherein certain optical parameters are selectively adjustable.
Optical systems often require variable focal length to allow the field of view (FOV) or the magnification to be altered. These systems with lenses and mirrors as conventional optical elements of fixed focal length use focusing mechanisms which are complicated and consist of many moving parts such as gears, motors and sliders to image a moving object or objects with high irregular shape. These mechanical focusing mechanisms become particularly difficult to employ when dealing with microlens systems for micro-electrical mechanical systems (MEMS).
The study of variable focal length microlens has been an area of activity for many years. Variable focal length is a necessary attribute in many optical applications if the object being imaged is not in a fixed position. Several recent publications have recognized that the potential for variable microlens impact significantly the field of optical applications . The variation of focal length can be provided by a focalizing mechanism to cause the focal plane shift. The different approaches using liquid crystal methods  and electrowetting methods  have been investigated by other researchers, but the liquid crystal lens has limited application in the microlens area and the electrowetting liquid concept lens requires a high voltage source. Both methods required electrodes, which are immersed in the electrolyte solution and cause severe optical distortion. A variable microlens system overcoming these disadvantages is needed in the art.
One embodiment of the present invention comprises a microlens system or apparatus which will allow for the relatively rapid alteration of various optical parameters such as focal length, field of view (FOV), and numerical aperture. As used herein, the term “mircolens” will typically refer to a lens having a diameter of less than 5 mm, however, the present invention is not necessarily limited to such lens sizes.
One embodiment of the microlens system is illustrated in
Lens section 5 will be formed of a flexible, substantially transparent polymer material. In the embodiment of
Although the present invention encompasses any conventional process for manufacturing lens sections 5, one preferred embodiment employs a PDMS casting process, including a photo-resist reflow technique which uses liquid surface tension to form a spherical structure when the photoresist is melted.
Next, the photoresist layer is thermally reflowed (for example by heating on a hot plate) to convert the photoresist mesa structures into the deformed photoresist mounds. To help create a uniformly deformed photoresist mound, one embodiment of the invention places the sample in a chamber containing acetone vapor for approximately one minute prior to beginning the thermal reflow process. In this embodiment, the silicon wafer is placed on a hot plate at a temperature of 95° C. for approximately 10 minutes to uniformly deformed the polymeric mesas. The acetone vapor and moisture absorbed inside the polymeric mesa are removed during the heating step and final hard curing of the mesas is carried out at a temperature of approximately 120° C. to 150° C. in order to stabilized the mesa and prevent further reflow during subsequent fabrication steps. Thus, a photoresist “mother lens” is created on the wafer as suggested in
After completing the photoresist mother lens, the next step is the transfer of photoresist microstructure to a master mold. A PDMS material (e.g. Dow Corning Sylgard 186 silicone) may be used as the master mold material. As a first step, the photoresist mold is treated by exposing it to a vapor of tridecafluoro-(1,1,2,2,tetrahydrooctyl)-1-trichlorosilane (available from United Chemical Technologies of Horsham, Pa.) in order to reduce the adhesion of the cured PDMS to the photoresist. Next, the photoresist mold is placed in a shallow container (such as a petri dish) with the lens pattern facing upward. A sufficient amount of uncured PDMS mixture is poured into the dish to completely cover the photoresist mold and provide an adequate base for the mold The PDMS master mold is dried in a vacuum oven for 2 hours at 5 mtorr of pressure and 75° C. and then the mold is peeled off from the mother lens wafer. The PDMS master consists of a concave microlens array as suggested by
The final step in this particular fabrication process is spin coating a separate PDMS layer (the ultimate lens section 5) onto the PDMS master. In this embodiment, the ultimate lens material may also be Dow Corning Sylgard 186. Vapor application of a trichlorosilane compound to the PDMS master may again be used to reduce adhesion of the final PDMS film to PDMS mold. The spinning speed of the spin coating process is adjusted to obtain the desired thickness of the microlens section. In this embodiment, the thickness of the spun on PDMS layer may be between 30 and 150 um. The spun-on PDMS film is completely cured and the PDMS film forming the lens section is peeled out from the master mold. Because the PDMS master mold was completely cured prior to coating with the PDMS lens film, the PDMS lens film does not crosslink with the previously cured PDMS master mold and the lens film is readily removed from the master mold. Although the above lens section fabrication process is well adapted to producing the PDMS lens sections of the illustrated embodiments, it will be understood that many alternative fabrication processes also come within scope of the present invention.
The embodiment of
To assemble the microlens system 1 seen in
The operation of microlens system 1 will be readily understood with reference to
where V is equal to lens' volume and θ is contact angle. The back focal length (fB) of the microlens can be obtained by the following equation:
where n1, and n2 are the refractive index for the PDMS microlens and pumped-in fluid, which is water, respectively (n1=1.43 for Sylgard 186, and n2=1.33 for water). In addition, the numerical aperture can be calculated by the following equation:
From the above, it will readily be understood that the change in shape of convex portion 5 a will alter the focal length of microlens system 1 and accurate metering of fluid into fluid chamber 3 will allow precise control of the focal length.
Another embodiment of the present invention is seen in
Lens section 5 may be formed as described above. Lens frame 31 may be formed of any suitable material, but in the embodiment of
A still further embodiment of the present invention is seen in
In one embodiment, the diaphragm 47 with the PZT ring 48 will be constructed as follows. After the PDMS diaphragm 47 having a thickness of approximately 100 um to 200 um is bonded to frame 46 with a conventional adhesive such as epoxy, a thin top conductive layer is applied onto the PDMS layer as an electrode 50. The electrode material can be gold, platinum, or another metal applied in a fine layer (less than 1 um thick) by a conventional sputtering process. Alternatively, the electrode could be a conductive polymer such as conductive PDMS applied in an about 20 um thick layer by brush coating. Then, using a conventional chemical solution deposition method, a PZT layer about 2 um to 5 um thick is applied on the electrode 50 and allowed to cure to form the ultimate PZT ring 48. Next, another electrode 51 is coated on the exposed surface of the PZT film by one of the same methods as above. Thereafter, electrical leads may be attached to the electrodes 50 and 51 in any conventional manner. An electric field applied perpendicular to the PZT layer plane induces a contraction in the lateral direction, thereby producing a large out-of plane deflection of the PZT layer because of its unimorph geometry.
A still further embodiment of the present invention is seen in
The manufacturing steps of one embodiment of thermally activated lens system 60 are illustrated in
Then the second side of the wafer 65 is coated with photoresist and patterned with a circular area which will correspond to the through hole over which convex lens portion 5 a (
One embodiment of the present invention accomplishes the assembly of frame 61 and bottom plate 62 using conventional anodic bonding. Anodic bonding or field assisted glass-silicon sealing, is a process which permits the sealing of silicon to glass well below the softening point of the glass. The frame 61 and bottom plate 62 are positioned with the fluid chamber 68 facing the heating/sensor elements as suggested in
Once frame 61 and bottom plate 62 are bonded together, the PDMS lens section 5 will be bonded onto frame 61 using a convention oxygen plasma treatment (explained below). Next, the accessorial opening 68 a will be plugged with a small portion of PDMS material and the area covered with epoxy to form a complete seal. The liquid chamber 68 is then filled through the fill hole 70 (
In certain of the embodiments of the present invention described herein, the PDMS lens section and the silicon based frame may be bonded together using an oxygen plasma treatment. A strong covalent siloxane (Si—O—Si) bond is formed when two plasma oxidized surfaces are brought into contact. The surface activation may be accomplished with a conventional Micro Reactive Ion Etching (Micro-RIE) unit.
The silicon frame and the spin coated PDM lens section (still on the master mold) are loaded into the top chamber of the Micro-RIE unit. After pumping down the chamber to 50 mtorr, the RF power is turned on (320 W), establishing a pale blue plasma. The inlet valve on the chamber is then slowly opened to let in a small stream of oxygen (5.5 sccm), turning the plasma pink. A 30 second exposure to the oxygen plasma (after it has turned pink) consistently yields strong bonds. After 30 seconds, the RF power is turned off, and the chamber is vented, and the samples removed. Within two to three minutes of surface activation, the silicon frame and PDMS lens section must be brought into contact to form a permanent bond between them. The silicon frame and PDMS lens section then only need be left undisturbed for a short period of time (approximately 30 minutes) in order to complete the procedure and form a strong, durable, fluid tight bond between the silicon frame and the PDMS lens section.
Another embodiment of the present invention utilizes the fluid activated lens concept to create a variable focal length microlens system having an increased field of view (FOV). In one embodiment, the increase in the FOV is accomplished through the lens system having the ability to adjustably form a double convex (DCX) lens or a double concave (DCV) lens.
One process for fabricating DCV/DCX lens system 80 is seen in
As seen in
One manner of increasing the FOV in a lens system is to utilize multiple DCV or DCX lenses in series. Therefore, in addition to the single pair of frame halves shown in
Another embodiment of the present invention utilizes electroactive polymer (EAP) materials as the actuator of a variable focal length lens system rather than using fluid as described in the above embodiments. One class of EAP actuators are dielectric elastomer actuators. If a polymer film is relatively soft (i.e., has a relatively low modulus of elasticity), then large motions can be produced simply from Maxwell stress. When a voltage is applied across the polymer film, unlike charges on the opposing electrodes will attract each other and tend to squeeze the film and decrease its thickness while like charges on each electrode will tend to repel each other and increase the film thickness. The stress induced in the film is equal to the permittivity of the film multiplied by the square of the applied electric field.
One embodiment of the present invention is illustrated with the circular diaphragm actuator shown in
For each electrode unit 101 seen in the array embodiment of
These electrode shaped impressions are next filled with a compliant, electrically conducive material to form the electrodes. In the embodiment shown, the material for the compliant electrodes is an electrically conductive PDMS provided by GE® under the tradename Baysilone® LSR 2345/06. The conductive PDMS is brushed into the electrode impressions on both sides of the PDMS film and then the film is placed in the oven or on a hot plate at 70° C. to cure the conductive PDMS. In place of metal leads, the conductive PDMS is also used to form the connection with the outside circuit for testing and/or operation. Because of its flexibility and conductivity, conductive PDMS can be easily used to form connecting circuits by brushing it onto a dielectric platform without affecting the performance of the PDMS actuator. If the PDMS film is in a 4×4 array of single units with connections to each other (such as seen in
The operation of EAP actuated microlens system 120 can be illustrated in conjunction with
In another embodiment of the present invention, the EAP actuator could be combined with a gradient refractive-index (GRIN) lens. This is accomplished by formulating the PDMS of the EAP actuator as a GRIN material. A GRIN material is an optical medium with a parabolic refractive distribution. For example, in a converging GRIN lens, the refractive index is highest on the circular lens' axis and decreases toward the periphery with the square of the radial distance from the optical axis. The area of PDMS/GRIN material enclosed by the electrodes forms an adjustable GRIN lens. By applying voltage across the electrodes to thin or thicken the PDMS/GRIN material, the focal length of the lens may be adjusted.
For a GRIN lens, the refractive index at any distance r from the optical axis is given by
where n(r) is the refractive index at any distance r, n0 is the refractive index of the optical axis, A is the positive gradient constant, and r is the radial distance from the optical axis.
Several methods are know in the art for preparing GRIN polymeric optical lens such as two-step copolymerization [8,9], the extrusion method , interfacial-gel copolymerization , and photopolymerization . In the two-step copolymerization method, a lower-refractive-index monomer diffuses into a crosslinking matrix to form a GRIN distribution.
While the GRIN plastics and their fabrication methods have been studied, a flexible GRIN lens has not been developed. Most GRIN plastic provides only a rigid plastic lens structure and a rigid lens structures cannot provide the change of the focal length. Therefore, the present invention provides a flexible and dielectric polymeric lens.
Silicone-base polymers provide many special characteristics which can meet both the optical and mechanical requirements of the present invention. A silicone-based lens is elastic and deformable under stresses. Moreover, a silicone-base polymer, such as polydimethyl-siloxane (PDMS), is a dielectric material which can be integrated with the EAP actuation system. A flexible GRIN silicone lens comprises a cross-linked silicone polymer matrix, a homogeneously embedded photosensitive macromer, and a photoinitiator. The polymer matrix forms the basic optical element framework and is generally responsible for many of its material, mechanical, and optical properties. The macromer is a low-molecular-weight polymer linked to a photo sensitive group. The photo-initiator is an organic molecule that undergoes dissociation into reactive radicals that begin the polymerization process on exposure to a specific wavelength of light.
After the polymer matrix is formed, the refractive power of the lens may be selectively adjusted by exposing the lens to an ultraviolet (UV) light. On UV irradiation, polymerization of the photosensitive polymer occurs. The application of ultraviolet light to a portion of the lens optic results in disassociation of the photoinitiator to form reactive radicals that initiate polymerization of the photosensitive macromers within the irradiated region of the silicone matrix. Polymerization itself does not result in changes in lens power; it does, however, create a concentration gradient within the lens resulting in the migration of non-irradiated macromers into the region now devoid of macromer as a result of polymerization. The resulting chemical potential causes migration of unpolymerized macromers and photo initiators down a diffusion gradient into the irradiated area of the lens to form a gradient-index distribution. Once the desired power change is achieved, irradiation of the entire lens to polymerize all remaining macromers “locks in” the adjustment so that no further power changes can occur.
The polymeric GRIN lens comprises a photosensitive macromer dispersed in a polymer matrix. The polymer matrix forms the optical element framework. The photosensitive macromer may be a single compound or a combination of compounds that is capable of photo-polymerization. As a general rule, the polymer matrix and the photosensitive macromer are selected such that the components that comprise the photosensitive macromer are capable of diffusion within the polymer matrix. Thus, a loose polymer matrix will tend to be paired with larger photosensitive macromer components, and a tight polymer matrix will tend to be paired with smaller macromer components.
Upon exposure to an appropriate UV light, the photosensitive macromer typically forms a second polymer matrix in the exposed region of the optical element. The presence of the second polymer matrix changes the material characteristics of this portion of the optical element to modulate its refraction capabilities. In general, the formation of the second polymer matrix changes the refractive index of the affected portion of the optical element. After exposure, the photosensitive macromer in the unexposed region will migrate into the exposed region over time. The amount of photosensitive macromer migration into the exposed region is time dependent and may be precisely controlled by diffusion time. If enough diffusion time is permitted, the photosensitive macromer components will re-equilibrate and redistribute the refractive index profile throughout optical element of the first polymer matrix, including the exposed region. When the region is re-exposed to the energy source, the photosensitive macromer that has since migrated into the region, which may be less than if the photosensitive macromer is allowed to re-equilibrate, polymerizes to further increase the formation of the second polymer matrix. After the diffusion step is finished, the entire optical element is exposed to the UV-light to “lock in” the desired lens property by polymerizing the remaining photosensitive macromer components that are outside the exposed region before the components can migrate into the exposed region. Because freely diffusable photosensitive macromer components are no longer available, subsequent exposure of the optical element to UV light cannot further change its power.
There are two different combinations for diverging and converging GRIN lenses. By selecting the proper silicones for matrix and macromer, diverging and converging GRIN lens can be fabricated. If the matrix has a lower refractive index than macromer, the higher refractive index macromer can diffuse into the lens from periphery toward the lens center. The refractive distribution is a parabolic profile in which the refractive index is highest on the lens periphery and decreases toward the center with the square of the radial distance from the optical axis. This refractive distribution induces a diverging GRIN lens. On the other hand, if the macromer's refractive index is lower than the matrix's, the refractive distribution can be changed to the higher refractive index on the lens axis, and it decreases toward the periphery. Thus, this kind of lens is a converging GRIN lens.
A flexible PDMS lens array was fabricated using the photoresist thermal treatment process described above in reference to
Next, the photoresist microstructure was transferred to a PDMS master by the casting method described above. PDMS was chosen as a master material because it provides high dimensional accuracy and easy fabrication. Dow Corning® Sylgard 184 silicone was the particular PDMS used. After the PDMS master was dried in a vacuum oven at 75° C., the mold was peeled away from the mother lens wafer. The PDMS master formed a concave microlens array. SEM images of the master showed well formed concave surfaces with diameters of 1500 μm.
Spin-coat molding was used to fabricate a polymeric microlens by spin coating a PDMS layer on the sacrificial PDMS master. Depending on the spin speed, a thick or thin film with a unique dimension microlens could be obtained. The PDMS film was then cured under vacuum in an oven at 75° C. for 2 hours, and then peeled away from the PDMS master. The topography of the PDMS microlens film as shown in SEM pictures had convex microlens structures with a diameter of 1500 μm and a maximum height in the center of lens of 85 μm.
The mother lens, the PDMS master and final PDMS microlens film were observed by Scanning Electron Microscopy (SEM). In addition, two techniques were used to characterize the surface profiles of the molds and microlens film. The surface profile of the melted photoresist microlens was measured using a Tencor Alpha Step 500 System. The equipment uses a stylus with a ˜2 μm chisel head in contact with the sample which confirmed the surface profile of the photoresist mother lens as having a height of 85 μm and a diameter of 1500 μm. An atomic force microscope (AFM, such as a Quesant Instruments scanning probe microscope) was also used to examine the microlens profiles. The AFM provided true 3-D topographic images, which also yielded surface roughness data on the nanometer scale. In the analysis, the AFM was used to measure surface roughness on an area of 10 μm×10 μm of sample surface. The analysis results for AFM 3-D topography of photoresist microlens, PDMS master, and final PDMS lens film are shown in the Table 1. The changes in surface roughness vary during PDMS coating and peel-off processes. Table 1 shows the surface roughness increases from the original reflowed photoresist to the PDMS concave master. However, the surface roughness between the PDMS master and final PDMS microlens film does not significantly change. The roughness for both master mold and final PDMS microlens film was about 17-18.6 nm. This surface roughness is still in an acceptable range for optical requirements.
Comparison of surface roughness for photoresist
microlens, PDMS master and final PDMS microlens
Scanned Area (μm × μm)
10 × 10
10 × 10
10 × 10
Average Roughness (nm)
After obtaining the final PDMS lens film (about 100 μm thick), the film was bonded onto the surface of a silicon wafer, which consists of through holes as chambers for the microfluidic system such as seen in
Mechanical properties of the PDMS film were examined by applying a point load in the center of the PDMS film. The corresponding deflections with various loads were measured. Testing showed that there is a linear relationship between applied force and deformation before reaching the maximum mechanical strength of the PDMS film. The maximum force to which the 100 μm thick PDMS film could be loaded before rupturing the film was about 20 g. Within the range of maximum applied force, the film was linearly deformed.
The final assembled optical module with a lens film, a microchamber, and a channel as seen in
A microlens on microfluidic channel is considered as a piano convex refractive lens assuming that the lens profile is spherical. The curvature of the microlens and back focal length (fB) can be obtained by equation 2 above. The summary of optical properties of the variable focal microlens is shown in Table 2. The range of back focal length was from 3.82 mm to 10.64 mm.
Summary of optical properties of variable focal microlens
In addition, the numerical aperture can be calculated by equation 3 above. The numerical apertures with various focal lengths were determined and listed in Table 2. The numerical aperture can be tunable between 0.087 and 0.24.
A circular diaphragm actuator such as shown in
A mask for a circular actuator array was designed for a 4-inch substrate as suggested by
The PDMS actuator was fabricated based on a mold-casting process. The fabrication process is shown in
The mold for the actuator was made of SU8 (from MicroChem Inc. of Newton, Mass.), which is a negative photoresist for high-aspect-ratio structures. SU8-5 was chosen for 10 μm structures and SU8-10 for 30 μm structures in the experiments to fabricate different actuator film thicknesses. The fabrication process of the SU8 pattern follows the procedure that is described in the instruction from MicroChem. In order to easily fabricate the PDMS actuator before PDMS casting, two molds of the actuator pattern were made on two different substrates, one was Pyrex® glass; the other was a copper substrate. Because the glass substrate was transparent, it made it easier to align the patterns of the two substrates. The copper substrate had good flexibility, which made it easier to release the PDMS actuator. When patterning onto a copper substrate, pretreatment was important in order to increase the adhesion of SU8. The copper substrate was lapped with very fine sand paper (25 μm) and cleaned with acetone after lapping and before coating with SU8.
The casting PDMS was Dow Corning® Sylgard 184 silicone which has good elasticity and is transparent. After peeling the PDMS film off the substrate, the thickness of the PDMS film was normally a little thicker than the thickness of the spacer because of the challenge of sealing. The material for compliant electrodes was electrically conductive PDMS purchased from GE. When the PDMS actuator structure was ready, the conductive PDMS was brushed into the electrode impressions that were formed in the mold transfer. And then the actuator was placed in an oven or on a hot plate at 70° C. to cure the conductive PDMS. Instead of copper wires, the conductive PDMS was also used to form the connection with the outside circuit for testing. Because of its flexibility and conductivity, conductive PDMS could be easily used to form connecting circuits by brushing it onto the dielectric platform without affecting the performance of the PDMS actuator. Several PDMS actuators with different thickness ranging from 60 μm to 130 μm are prepared based on the above fabrication process.
After pasting conductive PDMS onto both sides of the PDMS film, the PDMS actuator was glued on a dielectric platform which included a hole drilled therethrough. The center of the actuator was placed in the center of the hole and the connecting circuit (see
Deformation tests were conducted by measuring the change of contact angles of the PDMS lens section of the film. When voltage was applied, the PDMS film would deform and the contact angle would change during actuation. The deformation could be calculated based on the contact angle (θ) and the diameter of actuater (d). The curvature (R) could be obtained by:
The height of deformed structure was
h=R(1−cos θ) (6)
And it could be derived as
Based on the above deviation, the deformation of actuated PDMS film could be calculated as D=h−h0, where ho was the initial height when the PDMS film was in a relaxed condition. Several PDMS actuators with different thicknesses and different diameters of actuated sizes were tested. Table 3 summarizes the deformation of the PDMS actuator with an average 120 μm thickness and 4.7 mm in diameter.
Summary of deformation of the PDMS actuator
Two samples with two different opening diameters and same thickness were tested. The results indicated that with a larger diameter, the PDMS actuator could obtain more deformation and a higher starting voltage. Once the PDMS actuator starts to deform, the deformation is proportional to the applied DC voltage. Tests also showed that for the same-thickness film, the linear relationship was same even if the opening diameters were different. See Table 4. The only difference was that the film with the larger diameter could have greater deformation.
Deformation of the PDMS thin film
Contact Angle (°)
Materials comprising various amount of (a) poly-dimethylsiloxane (PDMS) (Vinyl-addition silicone) as matrix, (b) Methacryloxypropyl Terminated PolyDimethylsiloxanes as photo-sensitive macromer, (c) a UV photoinitiator, 2-Hydroxy-2-methyl-1-phenyl-1-propanone (Ciba Darocur 1173), (d) a crosslinker (Gelest HMS-301), and (e) a Pt initiator for Vinyl-addition silicone cure (SIP6830.3), were made and tested. The first four components (a, b, c & d) were blended together initially. PDMS with the crosslinker HMS-301 was polymerized by addition of platinum catalyst as an initiator. PDMS was the polymeric matrix while the macromer and Darocur 1173 together formed the photo-sensitive macromer composition. Table 5 shows the samples' preparation and testing.
TABLE 5 Material composition for making GRIN lenses Initiator Diverging GRIN Lens Converging GRIN Lens Crosslinker Photoinitiator Platinum Matrix Macromer Matrix Macromer HMS-301 Darocur 1173 Catalyst PDV-0325 SIB 1402.0 PDV-1625 SIB 1400.0 (wt %) (wt %) (wt %) Test (wt %) (wt %) (wt %) (wt %) Respect to Respect to Respect to No. RI: 1.420 RI: 1.450 RI: 1.465 RI: 1.432 Matrix Macromer macromer Results 1 90 10 — — 10 1.5 0.15 No Diffusion 2 80 20 — — 10 1.5 0.15 No Diffusion 3 70 30 — — 10 1.5 0.15 Good Diffusion 4 60 40 — — 10 1.5 0.15 Good Diffusion 5 — — 90 10 10 1.5 0.15 No Diffusion 6 — — 80 20 10 1.5 0.15 Little Diffusion 7 — — 70 30 10 1.5 0.15 Good Diffusion 8 — — 60 40 10 1.5 0.15 Good Diffusion
Appropriate amounts of matrix, macromer, Darocur 1173, and HMS-301 were weighed together in a plastic pan, then manually stirred at room temperature until all materials were well-mixed. These initial mixtures were stirred mechanically for 20 minutes before a platinum catalyst was added. Then 0.15% of platinum catalyst with respect to the matrix was added into this mixture, and stirred manually. During stirring of the mixture, many bubbles were generated due to the platinum catalyzed reaction. The mixture was not disturbed and allowed to rest at room temperature for 5 minutes. All bubbles moved toward the surface of the mixture surface, and disappeared when they reached the surface. Due to the fast curing rate of this polymerization process, the reaction was about 10 minutes after a platinum catalyst was added into the mixture. The material handling was very critical after platinum catalyst has been added. The resulting silicone composition was poured into a mold which was made by transparent poly(methyl methacrylate) (PMMA). The mold was a small flat square sample holder. The base area was 105×105 mm2 and the depth was 1.4 mm. The amount of photo initiator (1.5 wt. %) was based on the data provided from the company (Ciba Specialty Corporation). Darocur 1173 is a versatile highly efficient liquid photoinitiator, used to initiate the photopolymerisation of chemically prepolymers. Darocur 1173 is 2-Hydroxy-2-methyl-1-phenyl-propan-1-one. Its chemical structure has a molecular weight of 164.2 g/mol.
According to the data analysis of absorption spectrum from Ciba, 1.5 wt. % of Darocur 1173 is the suggested addition to the samples to initiate the polymerization chain reaction for a better polymer. The cure time for the first matrix to be formed took about 30 minutes after the platinum (Pt) catalyst was added. The matrix with unpolymerized macromer composition in the mold was moisture cured and stored in the dark at room temperature for a period of 30 minutes to ensure that the resulting first matrix was non-sticky, clear, and transparent.
Although the present invention has been described in terms of certain specific embodiments shown above, such embodiments should only be considered illustrative and there are many other variations and modifications which will come within the scope of the present invention. For example, the present invention includes a method of producing a polymer microlens apparatus comprising the steps of: a) using a lithography process to form a lens base of a thermally reflowable first material; b) heating said reflowable first material to formed a convex mother lens; c) transferring the shape of said mother lens to a mold master of a second material; d.) coating a substantially transparent polymer lens material onto said mold master; and e) releasing said transparent polymer lens material from said mold master. This method also includes the polymer lens material being a PMDS material or wherein a reflowable material is photo-resist. This method includes the step of coating the lens material being a spin coating process and the second material of the master mold being a PDMS material.
The invention also includes a variable focal length microlens apparatus having: a) a lens frame comprising a first surface and a second surface, with a view aperture formed through the first and second surfaces; b) a fluid chamber formed between the first and second surface; c) a flexible, substantially transparent polymer lens section positioned over the view aperture on each of the first and second surfaces; and d) a fluid pressurization mechanism capable of causing an increase or a decrease of fluid pressure in the fluid chamber, thereby adjustably forming a DCV lens or a DCX lens. This embodiment includes the fluid pressurization mechanism comprising a fluid channel connecting the fluid chamber to an exterior of the lens frame. This embodiment includes the fluid channel being connected to a fluid pump exterior to the lens frame or an embodiment wherein multiple lens frames are positioned adjacent to one another in order to form a series of DCV and/or DCX lens. This embodiment further includes a variable focal length microlens wherein the lens frames are interconnected by a common fluid transfer path.
The invention includes a variable focal length microlens apparatus comprising: a) an electrode active polymer section with a lens formed thereon; b) a flexible electrode substantially surrounding an area of the electro active polymer section on which said lens is formed; and c) a power source for supplying electricity to said electrode. This embodiment includes the flexible electrode being ring shaped; or alternatively the electrode active polymer section being substantially planar with a first flexible electrode on a first side of the section and a second electrode on a second side of the section; or alternatively the lens being a GRIN type lens; or alternatively the lens being formed of a flexible polymer and having a convex surface when in an unstrained state.
All such variations and modifications are intended to come within the scope of the following claims.
All of the following references are incorporated by reference herein in their entirety.
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|Cooperative Classification||G02B3/14, G02B15/00, G02B1/06|
|European Classification||G02B3/14, G02B15/00, G02B1/06|