US20090219504A1 - Substrate conveyor apparatus, substrate conveyance method and exposure apparatus - Google Patents
Substrate conveyor apparatus, substrate conveyance method and exposure apparatus Download PDFInfo
- Publication number
- US20090219504A1 US20090219504A1 US12/351,500 US35150009A US2009219504A1 US 20090219504 A1 US20090219504 A1 US 20090219504A1 US 35150009 A US35150009 A US 35150009A US 2009219504 A1 US2009219504 A1 US 2009219504A1
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- United States
- Prior art keywords
- reticle
- substrate
- cfp
- cover member
- exposure
- Prior art date
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- Abandoned
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- 238000000034 method Methods 0.000 title description 8
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- 229910052782 aluminium Inorganic materials 0.000 description 2
- 238000007786 electrostatic charging Methods 0.000 description 2
- 238000001900 extreme ultraviolet lithography Methods 0.000 description 2
- 238000007689 inspection Methods 0.000 description 2
- 238000001459 lithography Methods 0.000 description 2
- 230000002745 absorbent Effects 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
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- 230000005284 excitation Effects 0.000 description 1
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Images
Classifications
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- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/67—Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere
- H01L21/677—Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere for conveying, e.g. between different workstations
- H01L21/67739—Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere for conveying, e.g. between different workstations into and out of processing chamber
- H01L21/67742—Mechanical parts of transfer devices
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B25—HAND TOOLS; PORTABLE POWER-DRIVEN TOOLS; MANIPULATORS
- B25J—MANIPULATORS; CHAMBERS PROVIDED WITH MANIPULATION DEVICES
- B25J11/00—Manipulators not otherwise provided for
- B25J11/0095—Manipulators transporting wafers
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y10/00—Nanotechnology for information processing, storage or transmission, e.g. quantum computing or single electron logic
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y40/00—Manufacture or treatment of nanostructures
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- G03F1/00—Originals for photomechanical production of textured or patterned surfaces, e.g., masks, photo-masks, reticles; Mask blanks or pellicles therefor; Containers specially adapted therefor; Preparation thereof
- G03F1/22—Masks or mask blanks for imaging by radiation of 100nm or shorter wavelength, e.g. X-ray masks, extreme ultraviolet [EUV] masks; Preparation thereof
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- G03F1/00—Originals for photomechanical production of textured or patterned surfaces, e.g., masks, photo-masks, reticles; Mask blanks or pellicles therefor; Containers specially adapted therefor; Preparation thereof
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- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
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- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
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- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
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- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/70—Microphotolithographic exposure; Apparatus therefor
- G03F7/708—Construction of apparatus, e.g. environment aspects, hygiene aspects or materials
- G03F7/70908—Hygiene, e.g. preventing apparatus pollution, mitigating effect of pollution or removing pollutants from apparatus
- G03F7/70916—Pollution mitigation, i.e. mitigating effect of contamination or debris, e.g. foil traps
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- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
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- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/67—Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere
- H01L21/67005—Apparatus not specifically provided for elsewhere
- H01L21/67011—Apparatus for manufacture or treatment
- H01L21/67155—Apparatus for manufacturing or treating in a plurality of work-stations
- H01L21/67196—Apparatus for manufacturing or treating in a plurality of work-stations characterized by the construction of the transfer chamber
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/67—Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere
- H01L21/67005—Apparatus not specifically provided for elsewhere
- H01L21/67011—Apparatus for manufacture or treatment
- H01L21/67155—Apparatus for manufacturing or treating in a plurality of work-stations
- H01L21/67207—Apparatus for manufacturing or treating in a plurality of work-stations comprising a chamber adapted to a particular process
- H01L21/67225—Apparatus for manufacturing or treating in a plurality of work-stations comprising a chamber adapted to a particular process comprising at least one lithography chamber
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/67—Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere
- H01L21/683—Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere for supporting or gripping
- H01L21/687—Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere for supporting or gripping using mechanical means, e.g. chucks, clamps or pinches
- H01L21/68707—Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere for supporting or gripping using mechanical means, e.g. chucks, clamps or pinches the wafers being placed on a robot blade, or gripped by a gripper for conveyance
Definitions
- the present invention pertains to a substrate conveyor apparatus that carries a substrate on which patterns are formed to a substrate exposure apparatus equipped with a substrate conveyance method and a substrate conveyor apparatus.
- a common problem is the weakness that a pellicle that prevent the adhering of defect-causing particles onto the reticle pattern face cannot be used.
- the present invention is intended to resolve the conventional problems concerned, therefore the object is to provide a substrate conveyor apparatus and a substrate exposure apparatus equipped with a substrate conveyance method and a substrate conveyor apparatus thereof that can easily and reliably prevent contamination of the inner surface of the protective cover when a substrate is used.
- a substrate conveyor apparatus that, being a substrate conveyor apparatus that carries substrates on which patterns are formed, carries the substrates in a state protected by a protective cover when the substrate is not used, and is characterized by having a cover protection means that covers the inner surface of the protective cover when the substrate is used.
- the cover protection means is characterized by covering the inner surface of the protective cover when the substrate is used in exposure.
- the protective cover comprises a plurality of cover members that cover the substrate and are disposed so as to be attachable and removable, and the cover protective means is characterized by holding the plurality of cover members in a standby position in a closed state.
- the cover protective means is characterized by, after carrying the substrate along with one part of the plurality of cover members to the substrate exposure position, returning the one part of the cover members to the standby position and bringing the plurality of cover members into a closed state.
- the closed state of the plurality of cover members is characterized by being a state in which the plurality of cover members are sealed.
- the protective cover comprises a cover member that covers the pattern on the substrate and is disposed so as to be attachable and removable, and the cover protective means is characterized by holding the cover member in a standby position in a state mounted to a dummy member that is similar to the shape of the substrate.
- the standby position is characterized by being a position wherein the substrate is aligned.
- the standby position is characterized by being a position wherein the cover member is removed from the substrate.
- the standby position is characterized by being a library part that stores the substrate in an exposure atmosphere.
- the standby position is characterized by grounding the protective cover.
- a substrate conveyor apparatus that, being a substrate conveyor apparatus that carries substrates on which patterns are formed, carries the substrate in a state protected by a protective cover when the substrate is not used, and is characterized by having a grounding means that grounds the substrate or the protective cover.
- the grounding means is characterized by being provided on the setting machine that sets the substrate or the protective cover.
- the substrate is characterized by being grounded via the protective cover.
- a substrate conveyance method that, being a substrate conveyance method that carries substrates on which patterns are formed, carries the substrates in a state protected by a protective cover when the substrate is not used, and is characterized by holding the protective cover on standby so that the inner surface of the protective cover is covered when the substrate is used.
- the substrate exposure apparatus is characterized by being equipped with the substrate conveyor apparatus.
- the inner surface of the protective cover is covered by a cover protection means, therefore when the substrate is used, contamination of the inner surface of the protective cover can be easily and reliably prevented.
- the substrate or the protective cover are grounded by a grounding means, therefore electrostatic charging of the substrate or the protective cover can be easily and reliably prevented.
- the protective cover when the substrate is used, the protective cover is held in standby in a state wherein the inner surface of the protective cover is covered, therefore contamination of the inner surface of the protective cover can be easily and reliably prevented.
- a substrate with little contamination is used, obtaining a product with high yield.
- FIG. 1 is an illustration showing a first embodiment of the substrate conveyor apparatus of the present invention.
- FIG. 2 is an illustration showing a reticle carrier from FIG. 1 .
- FIG. 3 is an illustration showing the details of a CFP stage from FIG. 1 .
- FIG. 4 is an illustration showing the state exposing the reticle from the CFP in FIG. 3 .
- FIG. 5 is an illustration showing a state wherein the reticle is conveyed from a CFP stage to a reticle stage of FIG. 1 .
- FIG. 6 is an illustration showing the state in the CFP stage of FIG. 1 where the CFP is in standby.
- FIGS. 7 a - 7 b are illustrations showing a second embodiment of the substrate conveyor apparatus of the present invention.
- FIG. 8 is an illustration showing a third embodiment of the substrate conveyor apparatus of the present invention.
- FIG. 9 is an illustration showing an embodiment of the exposure apparatus of the present invention.
- FIG. 1 shows the first embodiment of the substrate conveyor apparatus of the present invention.
- This substrate conveyor apparatus is provided adjacent to an exposure chamber 13 wherein reticle stage 11 and the like are disposed.
- a robot chamber 17 is provided wherein a vacuum robot 15 is disposed.
- a vacuum reticle library 19 is provided, and on the other side a clean filter pod opener 21 (hereafter called “CFP opener”) is provided.
- Exposure chamber 13 , robot chamber 17 , vacuum reticle library 19 and CFP opener 21 are in vacuum atmosphere.
- a load-lock chamber 23 is disposed in the position where robot chamber 17 faces exposure chamber 13 .
- Load-lock chamber 23 communicates to robot chamber 17 via second gate valve 25 .
- load-lock chamber 23 communicates to atmospheric air via a first gate valve 27 .
- a reticle carrier opener 31 is disposed via a second atmospheric robot 29 .
- an atmospheric reticle library 35 is disposed via a first atmospheric robot 33 .
- CFP 41 has the function of a protective cover protecting reticle 37 in a low-pressure atmosphere.
- the reticle carrier 39 placed in atmospheric reticle library 35 is conveyed by the first atmospheric robot 33 to reticle carrier opener 31 . Then, reticle carrier 39 is identified by reticle carrier ID reader 43 . At this reticle carrier opener 31 reticle carrier 39 is opened and CFP 41 is exposed. The exposed CFP 41 is heated about 2-3 degrees Celsius by temperature compensation lamp 45 . The heated CFP 41 is conveyed by a second atmospheric robot 29 onto load-lock chamber 23 wherein only the first gate valve 27 is opened. Note that the steps from reticle carrier opener 31 to load-lock chamber 23 are in a clean environment.
- load-lock chamber 23 accommodating the CFP 41 , vacuum evacuation occurs in a state where the first gate valve 27 and second gate valve 25 are closed.
- first gate valve 27 and second gate valve 25 are closed.
- second gate valve 25 opens and CFP 41 is conveyed to vacuum reticle library 19 by vacuum robot 15 .
- vacuum reticle library 19 for example around 5 CFP's, each of which houses a reticle, are stored.
- the reticle 37 is held at a specified temperature by a temperature adjustment mechanism (not shown).
- the reticle 37 stored in CFP 41 is identified by reticle ID reader 47 .
- the identified reticle 37 is conveyed by vacuum robot 15 to CFP opener 21 while housed in CFP 41 .
- CFP opener 21 In CFP opener 21 , CFP 41 is opened and reticle 37 exposed.
- CFP 41 conveyed to CFP opener 21 is set on CFP stage 49 .
- CFP 41 comprises upper cover member (upper lid) 51 and lower cover member (lower lid) 53 .
- upper cover member 51 is locked by locking member 57 on the upper end of support member 55 , exposing reticle 37 .
- a reference microscope 59 is disposed for performing prealignment of reticle 37 . Then, a prealignment mark 37 a formed on the lower surface of reticle 37 is detected by reference microscope 59 from a perforating hole 49 a formed in CFP stage 49 and a transparent window 53 a established in lower cover member 53 through transparent window 53 a , and prealignment occurs by driving CFP stage 49 . At this time, the reticle ID can be confirmed by detecting the reticle ID, such as a bar code, through the transparent window 53 a in lower cover member 53 .
- the reticle 37 that has completed prealignment is conveyed housed in the lower cover 53 of CFP 41 to reticle stage 11 by conveyor arm 61 of vacuum robot 15 .
- electrostatic chuck 63 is disposed with chuck surface 63 a facing down. Then, in a state where reticle 37 is pushed to chuck surface 63 a of electrostatic chuck 63 by conveyor arm 61 via lower cover member 53 , the upper surface of reticle 37 is chucked to chuck surface 63 a by turning on electrostatic chuck 63 .
- conveyor arm 61 carries lower cover member 53 to CFP opener 21 , and lower cover member 53 is set on CFP stage 49 , which is in the descended position shown in FIG. 4 . Then, the upper cover member 51 and lower cover member 53 of CFP 41 are attached by raising CFP stage 49 , and the inside of upper cover member 51 and lower cover member 53 is sealed airtight.
- the closed CFP 41 is held during exposure inside CFP opener 21 in that state. Note that if the CFP opener 21 and prealignment part is separately located, it is acceptable to hold closed CFP 41 at the prealignment part. Also, it is acceptable to convey closed CFP 41 to vacuum reticle library 19 and hold the closed CFP 41 at the vacuum reticle library 19 .
- reticle 37 is set on lower cover member 53 by turning off electrostatic chuck 63 .
- reticle 37 is conveyed to CFP opener 21 by conveyor arm 61 and lower cover member 53 , on which is set reticle 37 , is set on CFP stage 49 , which is in the descended position as shown in FIG. 4 .
- CFP stage 49 the upper cover member 51 of CFP 41 and lower cover member 53 are sealed (refer to FIG. 3 ) and CFP 41 is sealed airtight while reticle 37 is contained inside CFP 41 .
- FIG. 7 shows a second embodiment of the substrate conveyor apparatus of the present invention.
- the cover member 65 that is a protective cover is mounted so that it can be attached and removed and so that it covers only pattern 37 b on reticle 37 .
- cover member 65 is conveyed as mounted to cover member 65 by conveyor arm 61 to electrostatic chuck 63 of reticle stage 11 , then only reticle 37 is chucked to electrostatic chuck 63 .
- cover member 65 which remains on conveyor arm 61 , is conveyed to a standby part by conveyor arm 61 .
- a dummy part 67 that is similar to the shape of reticle 37 is disposed, and by mounting cover member 65 to this dummy member 67 , the inner surface of cover member 65 is covered and protected by dummy member 67 .
- cover member 65 is released from dummy member 67 and conveyed to the exchange position of the reticle 37 by conveyor arm 61 . Then, after mounting cover 65 to the reticle 37 chucked to electrostatic chuck 63 , reticle 37 is removed by turning electrostatic chuck 63 off. The removed reticle 37 is conveyed along with cover member 65 by conveyor arm 61 to vacuum reticle library 19 , for example.
- FIG. 8 shows a third embodiment of the substrate conveyor apparatus of the present invention.
- a stage-side conductive layer 69 made of aluminum is formed on the upper surface of CFP stage 49 (setting machine) of CFP opener 21 , for example.
- This stage-side conductive layer 69 is grounded via ground wire 71 .
- conductive layers 51 b and 53 b are formed on upper cover member 51 and lower cover member 53 of CFP 41 and when upper cover member 51 and lower cover member 53 are closed, they create a configuration where both are electrically connected.
- upper cover member 51 and lower cover member 53 are made of conductive material (for example, aluminum), there is no special need to form a conductive layer. Then, just by placing CFP 41 on CFP stage 49 it becomes grounded. However, in case there is an insufficient electrical contact, it is acceptable to dispose a mechanical means of making a reliable electrical contact (for example a conductive needle).
- a reticle-side conductive layer 37 b is formed only on the upper surface of reticle 37 , but it is also acceptable to form a conductive layer on a side surface or lower surface (surface where circuit pattern is formed) of the reticle. In this case, it is necessary to form the conductive layer so that it does not harm exposure, inspection, or various alignments.
- stage-side conductive layer 69 was formed on the entire upper surface of CFP stage 49 , but it is also acceptable to form only a portion of stage-side conductive layer 69 , such that at least reticle 37 or CFP 41 can be grounded.
- grounding of reticle 37 can be made directly from its upper surface, and it is also possible to ground in the same manner as the above example via cover member 65 .
- FIG. 9 shows the patterning of the EUV light lithography system inside the exposure chamber 13 of FIG. 1 .
- EUV light is used as the exposure light.
- EUV light has a wavelength of 0.1 ⁇ 400 nm, and for this embodiment a wavelength of 1 ⁇ 50 nm is preferable.
- the projection image is formed by using an image optics system 101 , and a reduction image of the pattern on the reticle 37 is formed on wafer 103 .
- the pattern exposed onto wafer 103 is determined by the reflective type reticle 37 disposed on the lower side of reticle stage 11 via electrostatic chuck 63 .
- This reflective type reticle 37 is loaded in and out by the vacuum robot 15 of the above embodiment (indication of vacuum robot 15 on the drawing is omitted).
- wafer 103 is set on top of wafer stage 105 .
- exposure is done by step and scanning exposure.
- EUV light used as the illumination light during exposure has low transparency in atmospheric air; for this reason the light path traveled by EUV light is enclosed by vacuum chamber 106 , which maintains a vacuum using an appropriate vacuum pump 107 .
- EUV light is generated by a laser plasma X-ray source.
- the laser plasma X-ray source comprises laser source 108 (operated as an excitation light source) and xenon gas supply apparatus 109 .
- the laser plasma X-ray source is enclosed by vacuum chamber 110 .
- the EUV light generated by the laser plasma X-ray source passes through window 111 of vacuum chamber 110 .
- Laser source 108 generates laser light having a wavelength below ultraviolet, for example using a YAG laser or excimer laser.
- the laser light from laser source 108 is focused and exposed in a flow of xenon gas ejected from nozzle 112 (supplied from xenon supply apparatus 109 ).
- the laser light sufficiently warms the xenon gas, generating plasma.
- EUV light photons are emitted.
- a parabolic mirror 113 is disposed adjacent to the xenon gas ejection part.
- Parabolic mirror 113 forms a condenser optics system and is disposed so that the focus point is adjacent to the position where xenon gas is emitted from nozzle 112 .
- EUV light is reflected on the multi-layer film of parabolic mirror 113 and reaches condenser mirror 114 through window 111 of vacuum chamber 110 .
- Condenser mirror 114 focuses EUV light on reflecting reticle 37 and reflects it. EUV light is reflected by condenser mirror 114 and illuminates a specific portion of reticle 37 . That is to say, parabolic mirror 113 and condenser 114 compose the illumination system of this apparatus.
- Reticle 37 has a multilayer film that reflects EUV light and an absorbent pattern layer for forming a pattern. By reflecting EUV light with reticle 37 , the EUV light is “patternized.” The “patternized” EUV light reaches wafer 103 through projection system 101 .
- the image optics system 101 of this embodiment comprises 4 reflective mirrors: concave first mirror 115 a , convex second mirror 115 b , convex third mirror 115 c and concave fourth mirror 115 d .
- a multilayer film that reflects EUV light is provided on each mirror 115 a ⁇ d.
- the EUV light reflected from reticle 37 is reflected sequentially from first mirror 115 a through to fourth mirror 115 d , forming a reduced (for example, 1 ⁇ 4, 1 ⁇ 5, 1 ⁇ 6) image of the reticle pattern.
- Image optics system 101 is made to be telecentric on the image side (wafer 103 side).
- Reticle 37 is supported on at least the X and Y planes by movable reticle stage 11 .
- Wafer 103 is supported by wafer stage 105 , which is preferably movable in the X, Y, and Z directions.
- EUV light is exposed to a specific region on reticle 37 by illumination system 101 , and reticle 37 and wafer 103 are moved relative to image optics system 101 at a specified speed according to the reduction rate of image optics system 101 . In this manner, the reticle pattern is exposed in the specified exposure area (toward the die) on wafer 103 .
- wafer 103 be disposed behind a partition 116 so that the gas that is generated from the resist on wafer 103 not influence mirrors 115 a ⁇ d of image optics system 101 .
- Partition 116 has an opening 116 a , and EUV light is exposed through it from mirror 115 d to wafer 103 .
- the space inside partition 116 is evacuated by vacuum pump 117 . In this manner, refuse in the form of gas generated by illuminating the resist is prevented from adhering to mirrors 115 a ⁇ d or to reticle 37 . For that reason, deterioration of the optical properties thereof is prevented.
- conveyance of reticle 37 is performed by the above substrate conveyor apparatus; therefore a high yield product can be obtained using a reticle 37 with little contamination.
- the protective cover for reticle 37 is composed of two members which are an upper cover member 51 and a lower cover member 53 , but it is also acceptable for example to be composed of 3 or more members.
Abstract
A substrate conveyor apparatus carries a substrate on which patterns are formed, carries the substrate in a state protected by a protective cover when the substrate is not used, and carries a cover protection means that covers the inner surface of the protective cover when the substrate is used. The substrate conveyor apparatus has a grounding means that grounds the substrate or the protective cover.
Description
- This application is a divisional of application Ser. No. 11/235,130, filed Sep. 27, 2005, which is incorporated in its entirety herein by reference. This application is also based upon and claims priority from Japanese Patent Application No. 2004-310919, filed Oct. 26, 2004.
- The present invention pertains to a substrate conveyor apparatus that carries a substrate on which patterns are formed to a substrate exposure apparatus equipped with a substrate conveyance method and a substrate conveyor apparatus.
- With a reticle (also known as a mask) used in next-generation lithography such as EPL and EUVL, a common problem is the weakness that a pellicle that prevent the adhering of defect-causing particles onto the reticle pattern face cannot be used.
- As a means to resolve this problem, there is a proposal to attach a protective cover when a reticle is not used and only remove it during exposure. For example, refer to U.S. Pat. No. 6,239,863.
- However, in the above method, there was the problem that the protective cover for the reticle used during exposure is left in a state wherein the inner surface of the protective cover is exposed, and it is easy for particles and the like to become adhered to the inner surface of the protective cover.
- The present invention is intended to resolve the conventional problems concerned, therefore the object is to provide a substrate conveyor apparatus and a substrate exposure apparatus equipped with a substrate conveyance method and a substrate conveyor apparatus thereof that can easily and reliably prevent contamination of the inner surface of the protective cover when a substrate is used.
- In the first viewpoint of the present invention, a substrate conveyor apparatus that, being a substrate conveyor apparatus that carries substrates on which patterns are formed, carries the substrates in a state protected by a protective cover when the substrate is not used, and is characterized by having a cover protection means that covers the inner surface of the protective cover when the substrate is used.
- In the second viewpoint of the present invention, the cover protection means is characterized by covering the inner surface of the protective cover when the substrate is used in exposure.
- In the third viewpoint of the present invention, the protective cover comprises a plurality of cover members that cover the substrate and are disposed so as to be attachable and removable, and the cover protective means is characterized by holding the plurality of cover members in a standby position in a closed state.
- In the fourth viewpoint of the present invention, the cover protective means is characterized by, after carrying the substrate along with one part of the plurality of cover members to the substrate exposure position, returning the one part of the cover members to the standby position and bringing the plurality of cover members into a closed state.
- In the fifth viewpoint of the present invention, the closed state of the plurality of cover members is characterized by being a state in which the plurality of cover members are sealed.
- In the sixth viewpoint of the present invention, the protective cover comprises a cover member that covers the pattern on the substrate and is disposed so as to be attachable and removable, and the cover protective means is characterized by holding the cover member in a standby position in a state mounted to a dummy member that is similar to the shape of the substrate.
- In the seventh viewpoint of the present invention, the standby position is characterized by being a position wherein the substrate is aligned.
- In the eighth viewpoint of the present invention, the standby position is characterized by being a position wherein the cover member is removed from the substrate.
- In the ninth viewpoint of the present invention, the standby position is characterized by being a library part that stores the substrate in an exposure atmosphere.
- In the tenth viewpoint of the present invention, the standby position is characterized by grounding the protective cover.
- In the eleventh viewpoint of the present invention, a substrate conveyor apparatus that, being a substrate conveyor apparatus that carries substrates on which patterns are formed, carries the substrate in a state protected by a protective cover when the substrate is not used, and is characterized by having a grounding means that grounds the substrate or the protective cover.
- In the twelfth viewpoint of the present invention, the grounding means is characterized by being provided on the setting machine that sets the substrate or the protective cover.
- In the thirteenth viewpoint of the present invention, the substrate is characterized by being grounded via the protective cover.
- In the fourteenth viewpoint of the present invention, a substrate conveyance method that, being a substrate conveyance method that carries substrates on which patterns are formed, carries the substrates in a state protected by a protective cover when the substrate is not used, and is characterized by holding the protective cover on standby so that the inner surface of the protective cover is covered when the substrate is used.
- In the fifteenth viewpoint of the present invention, the substrate exposure apparatus is characterized by being equipped with the substrate conveyor apparatus.
- In the substrate conveyor apparatus of the present invention, when the substrate is used, the inner surface of the protective cover is covered by a cover protection means, therefore when the substrate is used, contamination of the inner surface of the protective cover can be easily and reliably prevented.
- In addition, in the substrate conveyor apparatus of the present invention, the substrate or the protective cover are grounded by a grounding means, therefore electrostatic charging of the substrate or the protective cover can be easily and reliably prevented.
- In the substrate conveyance method of the present invention, when the substrate is used, the protective cover is held in standby in a state wherein the inner surface of the protective cover is covered, therefore contamination of the inner surface of the protective cover can be easily and reliably prevented.
- In the exposure apparatus of the present invention, a substrate with little contamination is used, obtaining a product with high yield.
-
FIG. 1 is an illustration showing a first embodiment of the substrate conveyor apparatus of the present invention. -
FIG. 2 is an illustration showing a reticle carrier fromFIG. 1 . -
FIG. 3 is an illustration showing the details of a CFP stage fromFIG. 1 . -
FIG. 4 is an illustration showing the state exposing the reticle from the CFP inFIG. 3 . -
FIG. 5 is an illustration showing a state wherein the reticle is conveyed from a CFP stage to a reticle stage ofFIG. 1 . -
FIG. 6 is an illustration showing the state in the CFP stage ofFIG. 1 where the CFP is in standby. -
FIGS. 7 a-7 b are illustrations showing a second embodiment of the substrate conveyor apparatus of the present invention. -
FIG. 8 is an illustration showing a third embodiment of the substrate conveyor apparatus of the present invention. -
FIG. 9 is an illustration showing an embodiment of the exposure apparatus of the present invention. - Below we will explain the details of embodiments of the present invention using drawings. Note that the present invention is not limited to the following embodiments.
-
FIG. 1 shows the first embodiment of the substrate conveyor apparatus of the present invention. - This substrate conveyor apparatus is provided adjacent to an
exposure chamber 13 whereinreticle stage 11 and the like are disposed. On one side ofreticle chamber 13, arobot chamber 17 is provided wherein a vacuum robot 15 is disposed. On one side ofrobot chamber 17, avacuum reticle library 19 is provided, and on the other side a clean filter pod opener 21 (hereafter called “CFP opener”) is provided.Exposure chamber 13,robot chamber 17,vacuum reticle library 19 and CFP opener 21 are in vacuum atmosphere. - In the position where
robot chamber 17 facesexposure chamber 13, a load-lock chamber 23 is disposed. Load-lock chamber 23 communicates torobot chamber 17 viasecond gate valve 25. In addition, load-lock chamber 23 communicates to atmospheric air via afirst gate valve 27. - On the other side of load-lock chamber 23, a
reticle carrier opener 31 is disposed via a secondatmospheric robot 29. On the other side ofreticle carrier opener 31, anatmospheric reticle library 35 is disposed via a firstatmospheric robot 33. - With the above substrate conveyor apparatus, in the
atmospheric reticle library 35, as shown inFIG. 2 , anEUVL reticle 37 used in exposure is placed in a state doubly protected by areticle carrier 39 and a clean filter pod (hereafter called “CFP”) 41.CFP 41 has the function of a protectivecover protecting reticle 37 in a low-pressure atmosphere. - The
reticle carrier 39 placed inatmospheric reticle library 35 is conveyed by the firstatmospheric robot 33 toreticle carrier opener 31. Then,reticle carrier 39 is identified by reticlecarrier ID reader 43. At thisreticle carrier opener 31reticle carrier 39 is opened andCFP 41 is exposed. The exposedCFP 41 is heated about 2-3 degrees Celsius bytemperature compensation lamp 45. The heatedCFP 41 is conveyed by a secondatmospheric robot 29 onto load-lock chamber 23 wherein only thefirst gate valve 27 is opened. Note that the steps fromreticle carrier opener 31 to load-lock chamber 23 are in a clean environment. - In load-lock chamber 23 accommodating the
CFP 41, vacuum evacuation occurs in a state where thefirst gate valve 27 andsecond gate valve 25 are closed. When a specified state of vacuum is achieved in load-lock chamber 23, onlysecond gate valve 25 opens andCFP 41 is conveyed tovacuum reticle library 19 by vacuum robot 15. - In
vacuum reticle library 19, for example around 5 CFP's, each of which houses a reticle, are stored. - The
reticle 37 is held at a specified temperature by a temperature adjustment mechanism (not shown). Thereticle 37 stored inCFP 41 is identified byreticle ID reader 47. The identifiedreticle 37 is conveyed by vacuum robot 15 to CFP opener 21 while housed inCFP 41. - In CFP opener 21,
CFP 41 is opened andreticle 37 exposed. - In this embodiment, as shown in
FIG. 3 , theCFP 41 conveyed to CFP opener 21 is set onCFP stage 49.CFP 41 comprises upper cover member (upper lid) 51 and lower cover member (lower lid) 53. Then, as shown inFIG. 4 , by loweringCFP stage 49 the exterior ofupper cover member 51 is locked by lockingmember 57 on the upper end ofsupport member 55, exposingreticle 37. - In this embodiment, at the lower region of
CFP stage 49, areference microscope 59 is disposed for performing prealignment ofreticle 37. Then, a prealignment mark 37 a formed on the lower surface ofreticle 37 is detected byreference microscope 59 from a perforating hole 49 a formed inCFP stage 49 and a transparent window 53 a established inlower cover member 53 through transparent window 53 a, and prealignment occurs by drivingCFP stage 49. At this time, the reticle ID can be confirmed by detecting the reticle ID, such as a bar code, through the transparent window 53 a inlower cover member 53. - The
reticle 37 that has completed prealignment, as shown inFIG. 5 , is conveyed housed in thelower cover 53 ofCFP 41 toreticle stage 11 byconveyor arm 61 of vacuum robot 15. Inreticle stage 11,electrostatic chuck 63 is disposed with chuck surface 63 a facing down. Then, in a state wherereticle 37 is pushed to chuck surface 63 a ofelectrostatic chuck 63 byconveyor arm 61 vialower cover member 53, the upper surface ofreticle 37 is chucked to chuck surface 63 a by turning onelectrostatic chuck 63. - After chucking
reticle 37,conveyor arm 61 carrieslower cover member 53 to CFP opener 21, andlower cover member 53 is set onCFP stage 49, which is in the descended position shown inFIG. 4 . Then, theupper cover member 51 andlower cover member 53 ofCFP 41 are attached by raisingCFP stage 49, and the inside ofupper cover member 51 andlower cover member 53 is sealed airtight. In this embodiment, theclosed CFP 41 is held during exposure inside CFP opener 21 in that state. Note that if the CFP opener 21 and prealignment part is separately located, it is acceptable to holdclosed CFP 41 at the prealignment part. Also, it is acceptable to conveyclosed CFP 41 tovacuum reticle library 19 and hold theclosed CFP 41 at thevacuum reticle library 19. - When exposure is completed and the exchange of
reticle 37 ofreticle stage 11 occurs, theupper cover member 51 andlower cover member 53 of theCFP 41 held in the state shown inFIG. 6 are separated by loweringCFP stage 49 and lowering the lower cover member 53 (corresponding to the state inFIG. 4 without reticle 37), andlower cover member 53 is conveyed to the exchange position of thereticle 37 byconveyor arm 61. - Then, with the
lower cover member 53 in contact withreticle 37, which is attached to electrostatic chuck 63 (refer toFIG. 5 ),reticle 37 is set onlower cover member 53 by turning offelectrostatic chuck 63. In this state,reticle 37 is conveyed to CFP opener 21 byconveyor arm 61 andlower cover member 53, on which is setreticle 37, is set onCFP stage 49, which is in the descended position as shown inFIG. 4 . Then, by raisingCFP stage 49, theupper cover member 51 ofCFP 41 andlower cover member 53 are sealed (refer toFIG. 3 ) andCFP 41 is sealed airtight whilereticle 37 is contained insideCFP 41. - In the above substrate conveyor apparatus and method, when
reticle 37 is used in exposure, theupper cover member 51 andlower cover member 53 ofCFP 41 are closed and the inner surfaces ofupper cover member 51 andlower cover member 53 are covered; therefore, whenreticle 37 is used in exposure, contamination of the inner surface ofCFP 41 can be easily and reliably prevented. Then, because the inner surface ofCFP 41 is not contaminated, there is very little contamination ofreticle 37. -
FIG. 7 shows a second embodiment of the substrate conveyor apparatus of the present invention. - Note that in this embodiment, the same members as in the first embodiment are assigned the same symbols, so detailed explanation has been omitted.
- In this embodiment, as shown in
FIG. 7( a), thecover member 65 that is a protective cover is mounted so that it can be attached and removed and so that it covers onlypattern 37 b onreticle 37. - Then, as shown in
FIG. 7 (b),cover member 65 is conveyed as mounted to covermember 65 byconveyor arm 61 toelectrostatic chuck 63 ofreticle stage 11, then only reticle 37 is chucked toelectrostatic chuck 63. - On the other hand, as shown in
FIG. 7( c)cover member 65, which remains onconveyor arm 61, is conveyed to a standby part byconveyor arm 61. In the standby part, as shown inFIG. 7( d), adummy part 67 that is similar to the shape ofreticle 37 is disposed, and by mountingcover member 65 to thisdummy member 67, the inner surface ofcover member 65 is covered and protected bydummy member 67. - Then, when exposure is completed and the exchange of
reticle 37 ofreticle stage 11 occurs,cover member 65 is released fromdummy member 67 and conveyed to the exchange position of thereticle 37 byconveyor arm 61. Then, after mountingcover 65 to thereticle 37 chucked toelectrostatic chuck 63,reticle 37 is removed by turningelectrostatic chuck 63 off. The removedreticle 37 is conveyed along withcover member 65 byconveyor arm 61 tovacuum reticle library 19, for example. - In this embodiment the similar result as in the first embodiment can be obtained.
-
FIG. 8 shows a third embodiment of the substrate conveyor apparatus of the present invention. - Note that in this embodiment, the same members as in the first embodiment are assigned the same symbols, so detailed explanation has been omitted.
- In this embodiment, a stage-side conductive layer 69 made of aluminum is formed on the upper surface of CFP stage 49 (setting machine) of CFP opener 21, for example. This stage-side conductive layer 69 is grounded via
ground wire 71. - On the other hand, on the side surface of
lower cover member 53 ofCFP 41, whenlower cover member 53 is set on stage-side conductive layer 69, a lower cover conductive layer 53 b that contacts stage-side conductive layer 69 is formed. This lower cover conductive layer 53 b contacts an upper cover conductive layer 51 b formed onupper cover member 51 whenupper cover member 51 is set onlower cover member 53. Also, on the upper surface ofreticle 37, whenupper cover member 51 is set, a reticleconductive layer 37 b is formed that contacts upper cover conductive layer 51 b. - With this embodiment, the similar result as in the first embodiment can be obtained, but in this embodiment, at
CFP stage 49,lower cover member 53 ofCFP 41,upper cover member 51, orreticle 37 are grounded, therefore electrostatic charging oflower cover member 53,upper cover member 51, orreticle 37 can be easily, reliably prevented. Accordingly, adhesion of particles to these members and the like can be reduced. - Note that in this embodiment, we explained an example where
lower cover member 53,upper cover member 51, orreticle 37 are grounded atCFP stage 49; however, it is acceptable for example to ground the plate ofvacuum reticle library 19 on whichCFP 41 is set, the setting machine of load-lock chamber 23, or the parts (end effectors) of vacuum robot 15 oratmospheric robot 29 that contactCFP 41. In these cases, there are no need to ground at every location; it is acceptable to ground just those locations where one wants to prevent charging ofCFP 41 andreticle 37. - Also, in the above embodiment, conductive layers 51 b and 53 b are formed on
upper cover member 51 andlower cover member 53 ofCFP 41 and whenupper cover member 51 andlower cover member 53 are closed, they create a configuration where both are electrically connected. However, ifupper cover member 51 andlower cover member 53 are made of conductive material (for example, aluminum), there is no special need to form a conductive layer. Then, just by placingCFP 41 onCFP stage 49 it becomes grounded. However, in case there is an insufficient electrical contact, it is acceptable to dispose a mechanical means of making a reliable electrical contact (for example a conductive needle). - The same applies to conductive layer 51 b of
CFP 41upper cover member 51 andconductive layer 37 b ofreticle 37. - Also, in the above embodiment, a reticle-side
conductive layer 37 b is formed only on the upper surface ofreticle 37, but it is also acceptable to form a conductive layer on a side surface or lower surface (surface where circuit pattern is formed) of the reticle. In this case, it is necessary to form the conductive layer so that it does not harm exposure, inspection, or various alignments. Also, stage-side conductive layer 69 was formed on the entire upper surface ofCFP stage 49, but it is also acceptable to form only a portion of stage-side conductive layer 69, such that atleast reticle 37 orCFP 41 can be grounded. - Also, as shown in
FIG. 7 , in the case that covermember 65 is established only on thepattern surface 37 b ofreticle 37, because the upper surface ofreticle 37 is exposed, grounding ofreticle 37 can be made directly from its upper surface, and it is also possible to ground in the same manner as the above example viacover member 65. -
FIG. 9 shows the patterning of the EUV light lithography system inside theexposure chamber 13 ofFIG. 1 . Note that in this embodiment, the same members as in the first embodiment are assigned the same symbols. In this embodiment, EUV light is used as the exposure light. EUV light has a wavelength of 0.1˜400 nm, and for this embodiment a wavelength of 1˜50 nm is preferable. The projection image is formed by using animage optics system 101, and a reduction image of the pattern on thereticle 37 is formed onwafer 103. - The pattern exposed onto
wafer 103 is determined by thereflective type reticle 37 disposed on the lower side ofreticle stage 11 viaelectrostatic chuck 63. Thisreflective type reticle 37 is loaded in and out by the vacuum robot 15 of the above embodiment (indication of vacuum robot 15 on the drawing is omitted). Also,wafer 103 is set on top ofwafer stage 105. Typically, exposure is done by step and scanning exposure. - The EUV light used as the illumination light during exposure has low transparency in atmospheric air; for this reason the light path traveled by EUV light is enclosed by
vacuum chamber 106, which maintains a vacuum using anappropriate vacuum pump 107. Also, EUV light is generated by a laser plasma X-ray source. The laser plasma X-ray source comprises laser source 108 (operated as an excitation light source) and xenongas supply apparatus 109. The laser plasma X-ray source is enclosed byvacuum chamber 110. The EUV light generated by the laser plasma X-ray source passes throughwindow 111 ofvacuum chamber 110. - Laser source 108 generates laser light having a wavelength below ultraviolet, for example using a YAG laser or excimer laser. The laser light from laser source 108 is focused and exposed in a flow of xenon gas ejected from nozzle 112 (supplied from xenon supply apparatus 109). When laser light is exposed in the xenon flow, the laser light sufficiently warms the xenon gas, generating plasma. When the xenon gas molecules excited by the laser fall into a low energy state, EUV light photons are emitted.
- A
parabolic mirror 113 is disposed adjacent to the xenon gas ejection part.Parabolic mirror 113 forms a condenser optics system and is disposed so that the focus point is adjacent to the position where xenon gas is emitted fromnozzle 112. EUV light is reflected on the multi-layer film ofparabolic mirror 113 and reachescondenser mirror 114 throughwindow 111 ofvacuum chamber 110.Condenser mirror 114 focuses EUV light on reflectingreticle 37 and reflects it. EUV light is reflected bycondenser mirror 114 and illuminates a specific portion ofreticle 37. That is to say,parabolic mirror 113 andcondenser 114 compose the illumination system of this apparatus. -
Reticle 37 has a multilayer film that reflects EUV light and an absorbent pattern layer for forming a pattern. By reflecting EUV light withreticle 37, the EUV light is “patternized.” The “patternized” EUV light reacheswafer 103 throughprojection system 101. - The
image optics system 101 of this embodiment comprises 4 reflective mirrors: concavefirst mirror 115 a, convex second mirror 115 b, convexthird mirror 115 c and concavefourth mirror 115 d. A multilayer film that reflects EUV light is provided on eachmirror 115 a˜d. - The EUV light reflected from
reticle 37 is reflected sequentially fromfirst mirror 115 a through tofourth mirror 115 d, forming a reduced (for example, ¼, ⅕, ⅙) image of the reticle pattern.Image optics system 101 is made to be telecentric on the image side (wafer 103 side). -
Reticle 37 is supported on at least the X and Y planes bymovable reticle stage 11.Wafer 103 is supported bywafer stage 105, which is preferably movable in the X, Y, and Z directions. When the die onwafer 103 is exposed, EUV light is exposed to a specific region onreticle 37 byillumination system 101, andreticle 37 andwafer 103 are moved relative toimage optics system 101 at a specified speed according to the reduction rate ofimage optics system 101. In this manner, the reticle pattern is exposed in the specified exposure area (toward the die) onwafer 103. - At time of exposure, it is desirable that
wafer 103 be disposed behind apartition 116 so that the gas that is generated from the resist onwafer 103 not influencemirrors 115 a˜d ofimage optics system 101.Partition 116 has anopening 116 a, and EUV light is exposed through it frommirror 115 d towafer 103. The space insidepartition 116 is evacuated byvacuum pump 117. In this manner, refuse in the form of gas generated by illuminating the resist is prevented from adhering tomirrors 115 a˜d or toreticle 37. For that reason, deterioration of the optical properties thereof is prevented. - With the exposure apparatus of this embodiment, conveyance of
reticle 37 is performed by the above substrate conveyor apparatus; therefore a high yield product can be obtained using areticle 37 with little contamination. - In the above we explained the present invention by means of the above embodiments, but the technical scope of the present invention is not limited to the above embodiments. For example, the following forms are acceptable.
- (1) For the above embodiment, we explained an example where the inner surface of
CFP 41 is covered whenreticle 37 is used in exposure, but it is also acceptable for example to cover the inner surface ofCFP 41 whenreticle 37 is used in inspection, cleaning, etc. - (2) For the above first embodiment, we explained an example where the protective cover for
reticle 37 is composed of two members which are anupper cover member 51 and alower cover member 53, but it is also acceptable for example to be composed of 3 or more members. - For the above embodiment, we explained an example of an exposure apparatus that uses EUV light, but other than this it is also acceptable to broadly apply an exposure apparatus using charged particle beams, i-line, g-line, KrF, ArF, F2 and the like.
Claims (8)
1-14. (canceled)
15. A substrate conveyor apparatus for carrying a substrate on which patterns are formed, the substrate conveyor apparatus comprising: a protective cover for protecting the substrate when the substrate is not used, and a grounding means for grounding the substrate or the protective cover.
16. The substrate conveyor apparatus described in claim 15 , wherein the grounding means is provided on a setting machine that sets the substrate or the protective cover.
17. The substrate conveyor apparatus described in claim 15 , wherein the substrate is grounded via the protective cover.
18. (canceled)
19. (canceled)
20. An exposure apparatus comprising the substrate conveyor apparatus described in claim 15 .
21. (canceled)
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US12/351,500 US20090219504A1 (en) | 2004-10-26 | 2009-01-09 | Substrate conveyor apparatus, substrate conveyance method and exposure apparatus |
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JP2004-310919 | 2004-10-26 | ||
JP2004310919A JP2006128188A (en) | 2004-10-26 | 2004-10-26 | Substrate carrying apparatus, substrate carrying method and exposure apparatus |
US11/235,130 US7483123B2 (en) | 2004-10-26 | 2005-09-27 | Substrate conveyor apparatus, substrate conveyance method and exposure apparatus |
US12/351,500 US20090219504A1 (en) | 2004-10-26 | 2009-01-09 | Substrate conveyor apparatus, substrate conveyance method and exposure apparatus |
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US11/235,130 Division US7483123B2 (en) | 2004-10-26 | 2005-09-27 | Substrate conveyor apparatus, substrate conveyance method and exposure apparatus |
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US12/351,500 Abandoned US20090219504A1 (en) | 2004-10-26 | 2009-01-09 | Substrate conveyor apparatus, substrate conveyance method and exposure apparatus |
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JP (1) | JP2006128188A (en) |
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Also Published As
Publication number | Publication date |
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KR20130123456A (en) | 2013-11-12 |
KR101496076B1 (en) | 2015-02-25 |
EP3439018A1 (en) | 2019-02-06 |
WO2006046488A1 (en) | 2006-05-04 |
EP1806767A1 (en) | 2007-07-11 |
TWI383938B (en) | 2013-02-01 |
JP2006128188A (en) | 2006-05-18 |
KR20070069141A (en) | 2007-07-02 |
US7483123B2 (en) | 2009-01-27 |
EP1806767A4 (en) | 2010-01-27 |
TW200613208A (en) | 2006-05-01 |
CN101006573A (en) | 2007-07-25 |
EP1806767B1 (en) | 2018-07-04 |
US20060087638A1 (en) | 2006-04-27 |
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Legal Events
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