US 20120055332 A1
A method for extraction of gas from liquid provides for reliable and accurate extraction of gases dissolved in fluids and routing the extracted gas to an analytical instrument. An extraction module comprises one or more fluorosilicone membranes molded into the shape of a flattened disk. The membranes are retained in a housing in a spaced apart relationship. The membrane is permeable to target gas(es), but not to the fluid. Porous support members support the membranes and prevent damage to them and the housing defines separate fluid flow paths for the fluid and the gas extracted from it. Fluid is passed over the membrane in a first fluid phase; target compounds in the fluid diffuse across the membrane to a second fluid phase until equilibrium is achieved.
1. A method of removing gas in a first fluid phase and routing the removed gas into a second fluid phase, comprising the steps of:
a) defining a first fluid flow path through a housing;
b) defining a second fluid flow path through the housing, the second fluid flow path being isolated from the first fluid flow path;
c) installing a separator membrane in the housing such that the separator membrane separates the first and second fluid flow paths and such that the separator membrane is in a stretched condition and has a variable thickness;
d) causing a first fluid containing target compounds to flow through the first fluid flow path and over a first side of the separator membrane, and causing a second fluid to flow through the second fluid flow path and over a second side of the separator membrane, wherein the first fluid is at a higher pressure than the second fluid; and
e) causing target compounds from the first fluid to pass through the separator membrane and routing said target compounds into said second fluid flow path.
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14. A method of removing gas in a first fluid phase and routing the removed gas into a second fluid phase, comprising the steps of:
a) delivering under positive pressure a first fluid a containing a concentration of a target compound to a first fluid flow path, said first fluid flow path including a flow section that passes over a first side of a membrane defining a generally flattened disk that is thicker at peripheral portion thereof and thinner at the center of the flattened disk, said membrane further defining a selectively porous barrier between said first fluid flow path and a second fluid flow path;
b) causing a second fluid in the second fluid flow path to flow over a second side of said membrane;
c) allowing said target compound to diffuse across said membrane from said first fluid flow path to said second fluid flow path;
d) continuing step c) until the concentration of the target compound in the first fluid flow path is in equilibrium with the concentration of the target compound in the second fluid flow path.
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18. A method of removing gas in a first fluid phase and routing the removed gas into a second fluid phase, comprising the steps of:
a) withdrawing fluid defining said first fluid phase from an electrical device;
b) causing said fluid to flow through a first flow path and over a selectively porous fluorosilicone membrane, said first flow path being isolated from a second fluid flow path by said selectively porous fluorosilicone membrane and wherein said selectively porous fluorosilicone membrane has a variable thickness where said fluid flows over said selectively porous fluorosilicone membrane;
c) allowing gas in the fluid phase to diffuse across said selectively porouse fluorosilicone membrane from said first fluid flow path to said second fluid flow path until the concentration of gas in said second fluid flow path is in equilibrium with the concentration of gas in said insulating fluid;
d) analyzing the gas in said second fluid flow path.
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The present invention relates to apparatus and methods for extracting dissolved gases from liquid, and more particularly, the invention relates to an apparatus for extracting gases dissolved in electrical insulating oils.
The electric power industry has for many years recognized that thermal decomposition of the oil and other insulating materials within oil-insulated electrical apparatus can lead to the generation of a number of “fault gases. These phenomena occur in equipment such as oil filled transformers (both conservator and gas-blanketed types), load tap changers, transformer windings, bushings and the like. The presence of fault gases may be a measure of the condition of the equipment. As such, detection of the presence of specific fault gases in electrical apparatus, and quantification of those gases can be an important part of a preventative maintenance program.
The presence of fault gases in oil-blanketed transformers with conservators and other utility assets has well documented implications relating to the performance and operating safety of the transformer. There is a substantial body of knowledge available correlating the presence of gases with certain, identified transformer conditions and faults. It is therefore beneficial to monitor the condition of dielectric fluids in electric equipment as a means to maximize performance, and at the same time minimize wear and tear on the equipment, and to thereby minimize maintenance costs and down time. Thus, information relating to the presence or absence of certain fault gases in transformer oil can lead to greatly increased efficiency in the operation of the transformer.
As an example, it is known that the presence of certain fault gases in transformer oil can be indicative of transformer malfunctions, such as arcing, partial or coronal discharge. These conditions can cause mineral transformer oils to decompose generating relatively large quantities of low molecular weight hydrocarbons such as methane, in addition to some higher molecular weight gases such as ethylene and acetylene. Such compounds are highly volatile, and in some instances they may accumulate in a transformer under relatively high pressure. This is a recipe for disaster. Left undetected or uncorrected, equipment faults can lead to an increased rate of degradation, and even to catastrophic explosion of the transformer. Transformer failure is a significantly expensive event for an electric utility, not only in terms of down time and the costs of replacement equipment, but also in terms of the costs associated with lost power transmission. On the other hand, by closely monitoring dissolved gases in transformer oil, the most efficient operating conditions for a given transformer can be actively monitored and the transformer load may be run at or near its optimum peak. Moreover, when dangerous operating conditions are detected the transformer can be taken off line for maintenance.
Despite the known need for reliable equipment to monitor gas in oil, designing equipment that holds up to the rigors of on-site conditions has been problematic for a variety of reasons. That said, there are a number of solutions known in the art. For example, mechanical/vacuum and membrane extraction methods and apparatus for degassing transformer oil are well known, as exemplified by U.S. Pat. No. 5,659,126. This patent discloses a method of sampling headspace gas in an electrical transformer, analyzing such gases according to a temperature and pressure dependent gas partition function, and based on the derived analysis predicting specific transformer faults.
An example of a gas extraction apparatus that relies upon a membrane tube for extraction of gas from transformer oil is disclosed in U.S. Pat. No. 4,112,737. This patent depicts a plurality of hollow membrane fibers, which are inserted directly into transformer oil in the transformer housing. The material used for the membrane is impermeable to oil, but gases dissolved in the oil permeate through the membrane into the hollow interior of the fibers. A portable analytical device such as a gas chromatograph is temporarily connected to the probe so that the test sample is swept from the extraction probe into the analytical device for analysis.
Although these devices have provided benefits, there are numerous practical problems remaining to the development of reliable apparatus for extraction, monitoring and analysis of fault gases in transformer oils. Many of these problems relate to the design of reliable fluid routing systems that are redundant enough to provide a relatively maintenance free unit. Since transformers are often located in exceedingly harsh environmental conditions, fluid routing problems are magnified. This is especially true given that the instruments needed to reliably analyze the gases are complex analytical instruments. Two patents that describe the difficulties of these engineering challenges are U.S. Pat. Nos. 6,391,096 and 6,365,105, which are owned by the assignee of this invention and both of which are incorporated herein by this reference. These two patents illustrate not only the complexities of the fluid routing systems needed, but solutions that have proved very reliable.
One of the most critical points in the analytical process is the extraction apparatus, where gas is actually separated from the electrical insulating oil. While there are several known apparatus for accomplishing this task, experience has shown that the extractor is one point where failure can occur. Stated another way, extraction devices to date have been more fragile than desired and cannot fully withstand the extreme conditions that are routinely encountered in field applications. As a result, additional support equipment or operation constraints are added to compensate for the performance shortcomings and to protect the extraction technology, which adds considerably to the cost. Despite advances in the technological solutions surrounding the extraction devices, especially those described in the '096 and '105 patents, there is a need for an extractor that is reliable and performs accurately under all conditions for substantial lengths of time without being monitored.
The advantages of the present invention are achieved in a first preferred and illustrated embodiment of a gas extraction apparatus that provides for reliable and accurate extraction of dissolved gases and for fluid-tight handling of both oil and extracted gas. The apparatus utilizes an extraction module comprising paired fluorosilicone membrane disks held in a housing. The membranes are permeable to target gas, but not to the insulating oil. The housing defines isolated oil and gas flow paths. The extraction module is connected to an analytical instrument such as a gas chromatograph for qualitative and quantitative analysis of the extracted gases.
In alternative embodiments, the extraction module may be built with multiple pairs of membrane disks, or a single membrane disk.
The invention will be better understood and its numerous objects and advantages will be apparent by reference to the following detailed description of the invention when taken in conjunction with the following drawings.
The basic environment in which the gas extraction apparatus of the present invention is used and the significant components with which it is used will be described generally first to provide context, then a more detailed description of certain components will follow. With reference to
Following generally the flow of sample fluid within housing 2, fluid is routed into extractor assembly 10. Sample containing fluid (i.e. oil) flows through extractor assembly or module 10 in a manner detailed below, where gas dissolved in the oil is extracted into a second fluid phase for further processing. The oil from which gas has been extracted is returned to electrical device 3 through fluid return line 5. The gas that is extracted from the oil may be analyzed to determine the nature of the gases in the oil, or the extraction apparatus may be used to remove contaminants from the oil and thereby purify the oil.
Sample line 4 is preferably attached to electrical device 3 at a point of high oil flow to insure that a representative sample of fluid is always provided to extractor assembly 10. The location of the connection of the fluid return line 5 to electrical device 3 is not critical other than it being separated by a sufficient distance from the fluid supply line to not exchange substantially the same fluid. Specifically the fluid sample line can be attached to the oil fill valve on a transformer, a drain valve on an oil radiator, or an oil by-pass loop, for example. The fluid return line, on the other hand, may be attached to the bottom drain valve to return the oil to the transformer, or other suitable positions. Typically, there is no need to tap special ports into the transformer since the oil supply and return lines may be ported into existing locations.
As described below, the present invention relies upon principles of diffusion across a membrane to extract gases from a first fluid phase where the dissolved gases are in a relatively higher concentration, compared with a second fluid phase where the gases are in a relatively lower concentration. Typically, the first fluid phase is the transformer insulating oil and the second fluid phase is the gas volume contained within analysis components of the system.
Sample gas extracted from sample fluid flowing through the extractor assembly 10 is routed through tubing 12 to analytical instrument 14, which is an instrument configured for running automated qualitative and quantitative analysis of the gas samples delivered to it. Analytical instrument 14 may be one of several kinds of laboratory gas detection instrumentation, and is preferably a gas chromatograph that is designed for installation in a remote location and is automated by the control of a programmed computer. Analytical instrument 14 is thus referred to on occasion as gas chromatograph 14. Sample gas from analytical instrument 14 may be returned to extractor assembly 10 via tubing 13.
With reference to
As illustrated in
Distribution manifold assembly 22 does not form a part of the present invention and is not described in detail herein. However, a manifold assembly suitable for use with the present invention is described in detail in U.S. Pat. No. 6,391,096, which as noted above is incorporated herein by reference. Several components of the invention, including active fluid handling and control components are under the active control of a computer 26. Computer 26 is connected to and sends command signals to and receives data from components associated with distribution manifold assembly 22 by way of data lines 28. Computer 26 also controls operation of analytical instrument 14 through data lines 30. Computer 26 is connected to telephony or other remote or external communications systems equipment 32 so that computer 26 may be operated from a remote location, which thus allows the analytical instrument to be operated remotely and for data from the instrument to be acquired from a remote location. Computer 26 also controls the extractor control components which include circuitry and state machines that monitor and control the gas extraction module 10.
The word computer is used generically herein for a programmed device capable of controlling operations of extractor assembly 10 and gas chromatograph 14. Computer 26 will be appreciated therefore to encompass any microprocessor, microcontroller or other processor and associated hardware and software.
Sample aliquots of fluid that are to be analyzed are acquired and controlled by the fluid control and handling components of extractor/analyzer 1 and are injected into a gas chromatograph 14. The chromatograph 14 shown schematically in
Analyte separation in chromatograph 14 is carried on under controlled conditions as is well known in the art. For instance, the separation columns in the chromatograph are contained within a temperature-controlled cabinet. Likewise, all components of chromatograph 14 are contained within appropriate housings, none of which are shown in the figures but which will be understood as being necessary to perform reproducible and accurate analysis.
Gas chromatograph 14, as shown schematically in
Analytical data compiled by gas chromatograph 14 from the analyzed sample is transmitted to computer 26 via data lines 30 where it is further processed according to software stored in the computer. Analytical results may then be transmitted from the computer 26 through remote communications equipment 32 on an automated basis, or the data may be acquired on prompt from a remote location.
The construction of extractor assembly 10 will now be explained in detail with reference to
Shown schematically in
All fittings and connections to housing 50 are leak free and utilize appropriate fittings and fluid-tight seal components such as O-rings and the like to ensure that there are no leaks.
Turning now to
Identical components are stacked in a mirror image of those just described on the opposite side of scarfing ring 56. Thus, with continuing reference to
A second frit 88, which is an identical material to that described above with respect to first frit 74 is attached to second plate 54, again in a manner identical to that described above with respect to first frit 74.
The components just described and shown in exploded format in
The first and second membranes 78 and 86, respectively, will now be described with particular reference to
More specifically, a predetermined mass of fluorosilicone material is preformed into a flattened disk. This pancake-shaped disk is then inserted into a compression mold where it is heated, squeezed and pressed into a very thin disk shape having the thickness attributes desired. The mold is maintained at an elevated pressure and temperature until the fluorosilicone material cures, at which time the part is removed from the mold.
The membrane 78 defines a generally flattened circular disk that has a lip 100 defined around the outer peripheral edge 102. As best shown in
The lip 100 is configured to attach and seal to a cooperatively formed lip 104 on the inner-facing periphery of plates 52 and 54 (
Extractor assembly 10 is assembled with the components described above in the manner shown in
Oil is delivered from electrical device 3 through sample line 4 and into extractor assembly 10 via oil inlet 66 and by virtue of operation of pump 58, which is fluidly connected to the oil bores through extractor assembly 10. In
The oil flow through extractor assembly 10 defines a first phase. Gas extracted from the oil in the first phase forms a second phase; the flow path for the gas is illustrated in
If a diffusion gradient is created across the two different phase sides, which are separated by first membrane 78 and second membrane 86, compounds of interest that exist in a higher concentration on one side of the membrane will diffuse across the membrane into the second phase side—the side with the lower concentration of that compound. That is, where oil in the first phase contains contaminants (such as fault gases) that are in relatively higher concentration on the first phase side than in the second phase, the contaminants diffuse across the phase barrier defined by the membranes to the second phase side (into the space 122 occupied by the porous paper spacer 82). Said another way, the contaminants in the first phase diffuse across the phase barrier defined by the membranes and into the second phase, where they reliably and reproducibly accumulate and are representative of and proportional to the concentration of the contaminants in the first phase. This is schematically illustrated by the “bold-line” arrows representing oil phase flow path 111 and the dashed arrows 130 representing the second phase side, or gas phase flow 130. As oil under pressure circulates through extraction apparatus 10, and more specifically, as the oil flows along the surfaces of the membranes, contaminants in the oil diffuse through the membranes and enter the gas phase 130. The contaminant (i.e., gas) diffusion across membranes 78 and 86 is illustrated with dashed arrows 132. The gas phase flow path 130 is isolated from oil phase flow path 111 and is defined by bores defined in plates 52 and 54, and scarfing ring 56. As noted earlier, spacer 82 between the adjacent membranes 78 and 86 maintains a space 122 into which the gas diffuses. Gas flow is initiated and maintained by a pump 60(
Operation of the system will now be detailed. As noted, oil flow is initiated by operation of pump 58, causing oil to flow in a circulating loop through oil phase flow path 111. As oil flows through the frits 74 and 88 and thus past and over the outer-facing surfaces or sides of membranes 78 and 86, gas diffuses through the membranes (reference number 132) into the space 122, which is defined by the spacer 82, and thus into gas phase flow path 130. The gas phase resulting from diffusion of gas molecules from the oil phase into the gas phase flows in a circulating loop through gas chromatograph 14; gas is circulated with the gas pump 60. Circulation of the oil phase and gas phase is allowed to continue until equilibrium in the concentration of gas exists on both sides of the phase barriers defined by membranes 78 and 86.
During the normal operation it is possible for the oil phase pressure to be less than the gas phase pressure. This may occur for several reasons, including aberrations in the operating conditions of the oil pump, external interference, etc. If a negative pressure does occur on the oil phase side, the membranes 78 and 86 tend to be “pulled” toward frits 74 and 88, respectively. The frits support the membranes and prevent membrane rupture if the membranes are pulled toward the frits.
Diffusion of compounds across the membranes is driven primarily by concentration gradients across the membranes. The time required to reach equilibrium or near equilibrium conditions depends upon factors such as gas concentration gradients and temperature, the volume of the gas being equilibrated, the thickness of the membrane, and the membrane surface area that is exposed to the oil. In addition, the flow rate of the oil carrying the gases affects the diffusion rate and thus the time required to reach equilibrium.
As noted earlier, contaminants of interest contained in oil filled device 3 are allowed to diffuse from the first liquid phase into the second fluid phase in extractor assembly 10. In this regard, during a sample equilibrium and acquisition phase oil is continuously circulated through the extractor assembly 10, returning as described earlier to the oil filled device 3. As the oil flows through the extractor assembly, dissolved gas contained in the oil diffuses across the membranes 78 and 86 into the second phase. This second phase, which comprises gaseous fluid, is circulated in either set time intervals or continuously to assure that all fluid in the second phase is homogeneous and until equilibrium conditions are reached. Stated otherwise, principles of diffusion dictate that the contaminants in the oil diffuse across the membrane from an area of relatively higher concentration to an area of relatively lower concentration until equilibrium (or conditions near to equilibrium) is reached.
As noted above, equilibrium and the rate of diffusion across the membranes are influenced by many different factors. In practice, it has been found that equilibrium using the extractor assembly 10 described herein is achieved in about 15 minutes with a total nominal gas volume of less than 7 cm3I. This may be contrasted with the gas extraction apparatus described in the '105 and '096 patents, which required up to and greater than 1 hour with a nominal gas volume of up to 65 ml. It is apparent therefore that the present invention requires magnitudes less time to equilibrate, and magnitudes less volume of gas extracted from the oil phase than required by the patents just mentioned.
When computer 26 determines that it is appropriate to inject a sample of gas from the second phase into analytical instrument 14, or when computer 26 is prompted to do so externally, the continuous circulating loop of gas 130 is switched in distribution manifold 22 so that the sample gas is routed to the analytical instrument 14.
Typically simultaneously with the equilibration and sample acquisition step, and prior to operation of chromatograph 14, the system allows equilibration of the chromatograph 14 with pure carrier fluid 20, which as noted is typically an inert gas such as helium. This allows any fluid in the separation columns to elute and be flushed through the instrument and to be vented to atmosphere at 34. Sample gas is then injected into the chromatograph and gases present in the sample are qualitatively and quantitatively analyzed.
In the illustrated embodiment of the extractor 10 described above and shown in the attached drawings, the extractor uses two membranes housed in a housing defined by two plates and a scarfing ring. It will be appreciated that the fluid flow paths through the plates are configured so that additional pairs of plates, membranes and a scarfing ring may be stacked so that the capacity of the system and its speed increase. Thus, an extractor module may be defined as two membranes, two plates and a single scarfing ring. Multiple extractor modules may be stacked with the fluid pathways between modules communicating.
Similarly, an extractor module according to the present invention may be made using a single membrane. In this case, the extractor module is configured as shown in the figures with only a single membrane. The oil phase containing contaminants flows over the first side of a single membrane and the contaminants diffuse through the membrane 78 into a space defined by a spacer layer 82 that is positioned on the opposite side of membrane 78, thereby defining the physical separation between the single membrane 78 and the opposite wall of the module housing. As with the embodiment of
In view of the many possible embodiments to which the principles of our invention may be applied, it should be recognized that the detailed embodiments are illustrative only and should not be taken as limiting the scope of the invention. Rather, we claim as our invention all such embodiments as may come within the scope and spirit of the following claims and equivalents thereto.