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Publication numberUS2108604 A
Publication typeGrant
Publication dateFeb 15, 1938
Filing dateMay 19, 1934
Priority dateAug 2, 1933
Also published asDE626758C
Publication numberUS 2108604 A, US 2108604A, US-A-2108604, US2108604 A, US2108604A
InventorsMason Ralph B
Original AssigneeAluminum Co Of America
Export CitationBiBTeX, EndNote, RefMan
External Links: USPTO, USPTO Assignment, Espacenet
Aluminum reflector
US 2108604 A
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Description  (OCR text may contain errors)

Patented Feb. 15, 1938 UNITED STATES ALUMINUM REFLECTOR Ralph B. Mason, New Remington, Pa., assignor to Aluminum Company of America, Pittsburgh, Pa., a corporation of Pennsylvania No Drawing.

Serial No. 683,344.

Original application August 2, 1933,

Divided and this application May 19, 1934, Serial No. 726,571


This invention relates to the provision of aluminum articles having durable reflecting surfaces. I

The reflecting surfaces herein referred to are those designed to reflect radiant energy, and particularly light reflecting surfaces adapted to the diffuse or specular reflection of light. Thus the invention herein described is directed to the general object of providing an aluminum article having a reflecting surface characterized by its increased and lasting power to reflect radiant energy, although it finds greatest usefulness in the. form of an aluminum article having a surface designed to specularly reflect light.

In the production of various aluminum articles having reflecting surfaces, the reflecting surface is usually produced either by etching, as in the case of surfaces designed to diffusely reflect light, or by mechanically polishing or buffing, as where specular surfaces are desired. Such surfaces are subject to deterioration in reflectivity during handling and use, and are difficult to maintain or restore to their original emciency.

It is a leading object of the present invention to provide aluminum articles having durable reflecting surfaces. A more specific object of the invention is to produce aluminum articles having surfaces of improved reflectivity and provided with a transparent protective coating. A further object of my invention is to provide a durable aluminum light reflector the reflecting surfaces of which are characterized by freedom from dirt and impurities. Other objects of the invention will become apparent from the following description thereof.

To the end that the reflecting power of an aluminum surface be made stable and durable, it has been proposed to provide the prepared aluminum surface with a protective coating such as, for example, an oxide coating or a transparent varnish or lacquer coating. Prior to my invention, however, the reflecting surface so produced and protected has possessed relatively poor reflectivity, for the reason, apparently, that the resulting oxide coating is foggy and translucent. I have found that the impurities which are usually present in an aluminum surface, particularly in a mechanically'polished aluminum surface, are apparently in large. part the cause of foggy and translucent coatings. I have further discovered that such impurities and foreign matter as may be present in the metal surface may be removed from the metal by electrolytic treatment in certain electrolytes, and that if a substantially clean aluminum surface is obtained, it

may thereafter be anodically oxidized without seriously impairing its reflectivity. Other forms of protective coatings may also be applied to the improved, electrolytically brightened reflecting surfaces, such, for example, as clear transparent 5 coatings, such as lacquer or varnish coatings.

A method of producing the article of my invention is described in my copending application for patent, Serial No. 683,344, filed August 2, 1933, of which the present application is a division. 10 The novel characteristics of the aluminum relector which I have provided will be more fully nderstood upon a consideration of the method .Jy which it may be produced. The article which is to be provided with the improved reflecting 15 surface is submitted to a cleaning and brightening step which comprises electrolytically treating the aluminum article in an electrolyte containing a fluoborate. This procedure may or may not, according to the surface conditions of the 20 metal, be preceded by a preliminary cleaning step to remove any superficial dirt and grease which may be present upon the metal surface as a result of the preliminary polishing operation, or whatever operation is originally employed to produce the reflecting surface. Any convenient method of preliminary cleaning may be employed, but a cleaning with a solvent or a chemical without objectionable attack upon the metal is preferable to any preliminary cleaning operation 30 which involves rubbing the surface, since the original surface may be, if it is of the specular variety, highly polished, and any frictional preliminary cleaning operation may mar this polished surface. 35

The metal surface is materially brightened by this treatment in the fluoborate electrolyte and is apparently covered with a thin transparent coating. This coating offers some protection to the bright reflecting surface against deterioration 40 by handling or atmospheric influences. Thus an article is obtained having a clean, bright reflecting surface provided with a thin protective film which is useful as a reflector, particularly where the reflector will not be subject to exces- 45 sive handling or severe exposure.

The reflecting surface may again be electrolytically treated to build thereon by anodic oxidation a comparatively thick, dense oxide coating. By the term oxide coating" as used herein and 50 in the appended claim is meant such coatings concurrently so designated in the art, which consist in substantial part of aluminum oxide, and which are produced by the anodic oxidation of aluminum in electrolytes such as sulfuric acid, 55

chromic acid, or oxalic acid. The oxide-coated reflecting surface may then be subjected to'a hot water treatment to make the coating impervious. The oxide-coated surface thus produced retains the brightness imparted to it by the electrolytic brightening step and is substantially proof against permanent staining and marking by exposure to the weather or by handling, or when being recleaned during use, for example by washing with soap and water. .The hot water treatment is, however, not necessary to the production of useful reflecting surfaces, and satisfactory oxide-coated reflecting surfaces may be produced in accordance with my invention without this treatment. As a flnal treatment, and particularly in the case where the hot water treatment has been employed, a very light polishing with materials such as magnesia, silver polish, or the like, may be desirable, and such polishing treatment may be applied to the oxidecoated reflecting surface to advantage without impairing its reflecting power.

There is thus produced an aluminum article having a clean, bright surface of high reflectivity and provided with a hard, transparent, impervious coating consisting substantially of aluminum oxide formed integral with the bright metal surface, which imparts properties of durability and permanence to the bright reflecting surface of the article.

When a specular reflecting surface is desired, a mechanically polished aluminum surface is flrst subjected to the preliminary cleaning step to remove surface grease and dirt by means of a solvent or a chemical cleaner which does not objectionably attack or pit the metal; then to the electrolytic brightening step in which the polished aluminum article is made an electrode in an electrolyticcell containing a fluoborate solution; then to a coating step in which the now electrolytically brightened aluminum reflecting surface is made the anode in the solution of an electrolyte which will form upon the surface of the metal a comparatively thick and dense oxide coating; and thereafter to a treatment in water at to centigrade to impermeabilize the oxide coating and make it non-adsorptive; and finally to a light polishing operation to remove any superflcial deposit which may have been formed upon the reflecting surface by reason of any of the previous operations. Where a diffusely reflecting surface is desired, the procedure is the same except that the metal is etched or mechanically abraded to produce the diffusing surface instead of being mechanically polished prior to the steps above named, and the preliminary cleaning step to remove superflcial grease and dirt may usually be eliminated.

Variations in the foregoing method of producing the bright reflecting surface of my novel aluminum reflector are described in my copending application hereinabove referred to.

In treating the aluminum reflecting surface in a solution of a fluoborate, the aluminum article is made an electrode in an electrolytic cleaning cell which contains a fluoborate electrolyte. The current impressed upon the cell may be either alternating or direct current. It is preferable, however, to use direct current, as the process may be more readily controlled with this type of current. When direct current is used, it is essential that the aluminum article be made the anode in the electrolytic cell. Graphite cathodes may be used with advantage. Satisfactory operation is usually obtained with mrect current under a potential of about 5 to 25 volts. The voltage used, however, is largely dependent upon the conductivity of the electrolyte, which will vary with its exact composition, concentration, and temperature. Consequently, it may in some cases be desirable to use voltages outside this range, the lesser voltages being used with electrolytes of high conductivity and the greater voltages being used with electrolytes of low conductivity. The desirable temperatures of operation lie usually between about 20 and 60 centigrade, although it may be advantageous to use temperatures outside this range with electrolytes of unusually high or low activity. To obtain the best results I have found that a current density of about 10 to 80 amperes per square foot of anode surface is suitable, although substantially any current density above about 3 amperes per square foot may be used. The time of treatment in the fluoborate electrolyte is not critical and will vary with the current density and the amount of brightening desired. A treatment of 5 to 15 minutes will generally give adequate results, but longer or shorter treatments may be used. When alternating current is used, the same operating conditions of voltages, temperature, and current density will produce satisfactory results. However, the concentration of the electrolyte should in general, be lower than that used with direct current, and the time of treatment required to obtain equivalent results is generally somewhat longer.

The fluoborate electrolytes referred to are formed by dissolving in water, compounds of the class composed of hydrofluoboric acid, and the compounds of that acid, such as, for instance, ammonium fluoborate, lead fluoborate, acetofluoboric acid, which class is generally herein and in the appended claim termed fluoborate. A convenient way of forming a suitable electrolyte for use in producing the article of my invention, particularly where fluoborates are not immediately available, is to mix hydrofluoric acid and boric acid. For the best results when the electrolyte is made in this way, the respective acids should be mixed in combining proportions, though either the boric acid or the hydrofluoric acid may be present in moderate excess in the electrolyte. If after mixing the acids the solution is allowed to stand for some time, the solution behaves more satisfactorily as an electrolyte. In forming the fluoborate electrolytes, compounds of relatively high purity are preferably used. The presence of some impurities in the electrolyte tends to reduce its useful life and impairs the quality of the results obtained. Sulfates, which are common impurities in commercial hydrofluoric acid, particularly show this property; and it is preferred that they be substantially removed when such acid is used in forming a fluoborate electrolyte. Certain components may also be added to the electrolyte in small amounts which do not deleterlously affect the action of the fluoborate in brightening the metal surface. For example, a small amount of a salt such as ammonium fluoride may be added to increase the conductivity of the electrolyte.

The concentation of the fluoborate in the electrolyte will vary with the particular fluoborate used and depending upon the type of current to be used. In general the concentration of the fluoborate solution for use in connection with alternating current is preferably considerably less than the concentration of a solution of the same fluoborate for use with direct current.

When an electrolyte containing hydrofluoboric acid is used in'connection with direct current, good results are obtained, for instance, with a concentration of 2.5 per cent of that acid, and an electrolytehaving a content of about 0.5 to 5.0 per cent of hydrofluoboric acid (HBF4) is particularly advantageous in the production of specularly reflecting aluminum surfaces. With alternating current a hydrofluoboric acid electrolyte containing about 0.8 per cent HBF4 gave good results in the production of specular reflecting surfaces.

The result of treating the aluminum reflecting surface in an electrolyte of fluoborate according to the process described in my copending application hereinabove referred to is to brighten and improve the reflecting power of the surface. The treatment appears to involve some solution of the aluminum surface. However, the attack of the surface by this electrochemical treatment is so regular that when a specular reflecting surface is treated the specular property of the surface is not appreciably impaired. The fluoborate solution is, however, capable of direct chemical attack on the aluminum surface if maintained in contact with it without the application of the electric current. In such case the attack is, however, not regular. Care should be taken, therefore, particularly where specular surfaces are treated, that the current is maintained throughout the period of the contact of the aluminum surface with the electrolyte. Furthermore, the bright reflecting surface obtained by my electrochemical treatment is coated with a transparent fllm which is quite thin and, as judged by commercial standards, is relatively soft, but which aifoids some protection for the bright metal surface.

By anodic oxidation of the surface thus obtained in suitable known electrolytes, such as oxalic acid or sulfuric acid, a hard, protective oxide coating of substantial thickness may be formed integral with the reflecting surface with only a slight reduction in reflectivity. For this purpose I prefer to carry out the anodic oxidation reaction in sulfuric acid electrolytes, since the coatings obtained are substantially colorless, clear and transparent, and this result is desirable in order that the reflectivity will be reduced as little as possible. But other oxide coat-forming electrolytes may be used, the main desideratum being to avoid the formation of a colored, cloudy or translucent oxide coating. Instead of the hard protective oxide coating, other forms of protective coatings may be applied to the bright surface obtained by treatment in fluoborate electrolytes, such as, for example, clear lacquer coatings. While in such case the reflectivity is somewhat reduced, the resulting coated surface, when the coating medium is itself clear, will generally have a high reflectivity and will be satisfactory for many purposes. 1

The provision of a hard, adherent, comparatively thick and dense oxide coating on the reflecting surface which has been treated in the fluoborate electrolyte is, however, the preferable procedure, particularly since it is possible in this manner to place upon the reflecting surface a coating which is thoroughly protective without decreasing substantially the reflectivity of the resulting surface, and a. coating which is substantially resistant to deterioration by handling and exposure, since it can be readily washed or otherwise cleaned to restore it to its original brilliance. The amount of reduction reflec tivity caused by placing upon the prepared reflecting surface the oxide coatings in question varies with the thickness of the coating and with the purity of the aluminum surface itself. 0xide coatings having thicknesses up to 0.4 mil. may be used in some cases without seriously impairing the reflectivity of the treated surfaces. With pure aluminum surfaces, for example, oxidation in a 7 per cent sulfuric acid electrolyte may be carried on for about 15 to 20 minutes at about 12 amperes per square foot current density without decreasing the reflectivity of the surface more than a few per cent. A less pure aluminum surface will have its reflectivity substantially decreased if the oxidation is allowed to proceed for longer than about 4 or 5 minutes, and in such case oxide coatings having thicknesses of the order of 0.1 mil. are most desirable. The degree of reflectivity obtained by the practice of the preferred method will vary somewhat, depending upon the exact treatment applied and upon the composition of the aluminum treated.

0n high purity aluminum I have obtained specularly reflecting surfaces having a light reflection factor as high as 87 per cent after anodically treating the polished surface in a fluoborate electrolyte, but; these surfaces are of course not as durable as desired for many types of service. However, when the surface is anodically treated in a fluoborate electrolyte, and. by subsequent treatment in an oxide coat-forming solution, a substantial oxide coating is placed upon the metal, I have obtained surfaces having a light reflection factor as high as per cent. Upon aluminum sheet of commercial purity, surfaces having lightreflection factors of about 80 per cent may be obtained. In general, aluminum alloys, when treated by the methods described, do not give reflection factors of this order. However, the method is applicable to many aluminum base alloys with advantage, and the term aluminum as used throughout this specification and in the appended claim is to be understood to include both aluminum and aluminum base alloys. In measuring the light reflection factor of the surface treated by my electrolytic brightening method I have used the Taylor reflectometer devised by A. H. Taylor of the National Bureau of Standards and described in the Scientific Papers of the Bureau of Standards Nos. S391 and 405.

The following speciflc examples clearly illustrate the advantageous characteristics of my new reflector when produced in accordance with the methods which have been described.

A solution of hydrofluoric acid was first prepared by adding 40 grams of boric acid to grams of concentrated hydrofluoric acid, containing about 48 per cent of HF, while the solution was kept cold. This amount of boric acid gives an excess of about 7.5 per cent over that required to combine with all of the hydrofluoric acid. The resulting solution contained about 37.7 per cent of hydrofluoboric acid and a slight excess of boric acid. The brightening electrolyte was then made up by diluting about 15 cc. of this hydrofluoboric acid solution to about 300 cc., thus producing an electrolyte containing about 2.5 per cent of hydrofluoboric acid and a trace of boric acid in excess. A sample of aluminum sheet of high purity (99.85 per cent aluminum) was polished and cleaned with acetone to remove surface grease. The reflection factor of the polished surface thus obtained was about 75 per cent. The aluminum sheet was then made the anode in an electrolytic cell, using as the electrolyte the above described 2.5 per cent solution of hydrofluoboric acid. A current density of about 20 amperes per square foot was employed at a potential of about 10 to 12 volts and with an electrolyte temperature of about 31 to 33 centigrade. After a treatment for 5 minutes in this manner the aluminum sheet was removed and the reflection factor of its surface again measured. The surface now had a reflection factor of 87 per cent. The sample was then subjected to anodic oxidation in an electrolyte containing 7 per cent sulfuric acid by weight, using a current density of 12 amperes per square foot at a potential of 20 volts and at a temperature of 25 to 26 centigrade. After treatment for 10 minutes the sample was removed and was boiled in pure water for 15 minutes. It was then polished with a mildly abrasive polishing cream and its reflection factor again measured. The flnal sample had a reflection factor of 85 per cent. The article could be handled without permanent marking or staining and could be readily washed or wiped without depreciation of its reflecting power.

A similar sample of aluminum sheet of high purity prepared as above was made an electrode in an electrolytic cell containing as electrolyte a hydrofluoboric acid solution containing 0.8 per cent HBF4. A GO-cycle alternating current was impressed upon this cell, using a current density of about 20 amperes per square foot at a potential of 8 toll volts and a temperature of 30 centigrade. After a treatment for 20 minutes in this manner the aluminum sheet was removed. The surface had a reflection factor of about 85 per cent. The sample was then subjected to anodic oxidation in an electrolyte containing 7 per cent sulfuric acid by weight, using a current density of 12 amperes per square foot at a potential of 20 volts and at a temperature of 22 centigrade. After treatment for about 10 minutes the sample was removed and was boiled in pure water for 15 minutes. It was then polished with a mildly abrasive polishing cream and its reflection factor. measured. The final sample had a reflection factor of 83 per cent.

To illustrate the beneflts obtained by the use in the above process of the step of anodically brightening the reflecting surface in a fluoborate electrolyte, there may be cited the case of a similar sample which was subjected to exactly the same treatment as above described in connec tion with the direct current, with the exception that the step of brightening the reflecting surface in the fluoborate electrolyte was omitted. In the case of this sample the flnal reflecting surface had a reflection factor of only 79 per cent.

I claim:

An aluminum light reflector having a bright metal surface from which the impurities normally present in aluminum have been substantially removed, said surface being provided with an adherent, clear, transparent, substantially colorless coating of a thickness of about 0.1 to about 0.4 mil. and consisting substantially of aluminum oxide integrally and artificially formed on said surface, said oxide-coated alumi-

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US2424282 *Nov 3, 1943Jul 22, 1947Bendix Aviat CorpBody and modified first porro type erecting system for telescopic instruments
US2464256 *Feb 5, 1944Mar 15, 1949Donald M PackerFront-surface reflector and method of making same
US2585128 *Mar 1, 1946Feb 12, 1952Bendix Aviat CorpAluminum optical mirror and method of making same
US2703781 *May 25, 1950Mar 8, 1955Kaiser Aluminium Chem CorpAnodic treatment of aluminum surfaces
US3372008 *May 10, 1962Mar 5, 1968Philips CorpMetal reflector and method of manufacturing such reflectors
US3380860 *Jan 27, 1964Apr 30, 1968Lord CorpTreatment of aluminum, compositions therefor and products thereof
US4257854 *Nov 19, 1979Mar 24, 1981U.S. Philips CorporationMethod of producing objects with a supersmooth aluminum surface
US5663001 *Mar 25, 1996Sep 2, 1997Alusuisse Technology & Management Ltd.Aluminum surfaces
US5828493 *Sep 17, 1996Oct 27, 1998Dielectric Coating IndustriesBase of unanodized aluminum; thick, nonporous oxide layer; opaque layer of vacuum deposited aluminum; quarter wavelength thick layers of low refractive index and of high refractive index vacuum deposited material; durability
US6005715 *May 14, 1998Dec 21, 1999Dielectric Coating IndustriesFormed on a polished aluminum base which is lightly anodized as a protective coating over which is vacuum deposited a thick layerof non-porus oxide underlying an aluminum reflectance layer which supports a pair of quarter wave length
U.S. Classification359/884, 205/116, 428/472.2, 428/336
International ClassificationC25F3/00, C25F3/20
Cooperative ClassificationC25F3/20
European ClassificationC25F3/20