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Publication numberUS2157933 A
Publication typeGrant
Publication dateMay 9, 1939
Filing dateAug 6, 1938
Priority dateAug 6, 1938
Publication numberUS 2157933 A, US 2157933A, US-A-2157933, US2157933 A, US2157933A
InventorsFrans R Hensel, Kenneth L Emmert
Original AssigneeMallory & Co Inc P R
Export CitationBiBTeX, EndNote, RefMan
External Links: USPTO, USPTO Assignment, Espacenet
Silver-indium contact
US 2157933 A
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Description  (OCR text may contain errors)

Patented May 9, 1939 UNETE s'rArss' PATENT OFFICE SHNER-INDIIM CONTACT No wing.

Application August 6, 1938,

Serial No. 223,507

This invention relates to electric contacts.

An object of the invention is to improve the characteristics of electric contact elements containing silver.

5 Another object of the invention is to provide a silver base contact material which is highly resistant to tarnishing and therefore will not form a layer of high contact resistance.

A still further object is to provide a new con- 1 tact material which can be used under severe electrical conditions, without welding.

It is a further object of the invention to provide a contact capable of operating on high frequency at heavy current values, without objec- 15 tionable contact metal transfer.

Other objects of the invention will be apparent from the following description taken in connection with the appended claims.

The present invention relates to an electric contact and the combination of elements therefor, methods of manufacture and the product thereof, brought out and exemplified in the disclosure hereinafter set forth, the scope of the invention being indicated in the appended claims.

35 While a preferred embodiment of the invention is described herein, it is contemplated that considerable variation may be made in the method of procedure, and the combination of elements, without departing from the spirit of the m invention.

The present invention comprises an improvement in silver electric contact elements, and especially in contact elements formed of at least 70% of silver. According to the invention, the

;;.-, contacts are improved by the addition of indium.

The contacts may be composed of silver and indium, accordingly. The ingredients may bepresent in approximately the following proportions:

Indium 0.1 to 21% Silver Balance It is likewise possible to improve the characteristics of silver alloys containing additional in- 5 gradients, by the addition of indium; thus silver alloys containing beryllium, magnesium, zinc.

cadmium, copper, gold, nickel, manganese, palladium group elements, platinum group elements,

silicon, titanium and zirconium can be improved 50 by the addition of indium in substantially the proportions indicated above.

We have found that silver and indium, up to 21% indium, alloy very readily and the cast ingots have an extremely clean surface. The alloys 55 can be readily swaged and drawn to wires from which contacts may be prepared by a screw machine operation or by cold heading. Silver-indium alloys may also be rolled in the form of sheet, and contacts may be punched from sheets. Silver-indium alloys lend themselves very readily to be prepared in the form of contact bimetals, in which one side consists of a base metal, such as an alloy of iron, nickel or a copper base material, and silver-indium material on the other side. The nature of the alloy is such as 1 to lend itself readily to the formation of electrical contacts by beading or fusing the alloy directly to the surface of a base metal blank, such as a rivet, screw or disc, etc. The ease with which these materials can be rolled has reduced greatly scrap losses and produced smooth surfaces which are ideally suitable for the manufacture of electric contacts.

In a number of contact applications, silver is mixed with refractory materials, taken from the group of tungsten and molybdenum, or their compounds. These materials are prepared either by mixing the powders together, pressing same and hot and cold working same into suitable forms from which contacts can be prepared. We 5 have found that the addition of indium to the silver base used in such contact combination, is extremely beneficial for several reasons. Indium improves the fluidity of molten silver, and when such contact materials are produced by an impregnating process the presence of indium in percentages up to 21%, will improve the "alloying or impregnating action of the liquid silver base. Therefore, a structure is obtained which is much more uniform and homogeneous, and 5 at the same time it is possible to produce pieces of much larger cross section by substituting a silver-indium alloy for fine slver. Indium has the definite advantage, furthermore, of having a very low melting point of 155 degrees C., but a very high boiling point of 1450 degrees C. It, therefore, mixtures are being prepared by using powders of the elements incorporated into the final mixture, sintering temperatures can be used which are comparatively high, without fearing the loss of any indium, due to vaporization.

It is possible also to produce a much stronger mixture that way, because the materials can be prepared by having a liquid phase present, which will cement not only the silver particles, but also the refractory particles, much better.

We have limited ourselves in the indium content to 21%, because we have found that the most desirable contacts can be prepared from an alpha solid solution of indium in silver. The solid solubility of indium in silver at room temperatures, is approximately 20.4%, while at 693 degrees 0., it is 21%.

When operated on voltage regulators, such as used in regulation of automotive generators, the material of the present invention, operating against a high silver alloy of a different composition, such as a-silver-palladium alloy, maintained perfect regulation. This operation at frequencies between 50 and 400 cycles, for periods of in excess of 500 hours, gave contact resistance values of extremely low order, 0.4 to 0.5 mllliohms. After continuous operation exceeding 750 hours, our resistance value is in the order of M of that normally encountered on alloys previously adopted for this type of service.

On applications for standard relay equipment, operating on a direct current, it has been found that the use of alloys of the type covered by the present combination, will increase the critical current value or value of failure current, between 80 and 100% over other commercial alloys at present available. The material does-not transfer as readily, which reduces the tendency to failure by sticking, because by relatively high increases in current density, due to reduction in area.

tact. At the same time, definite "seating" of the contacts is effected with extremely small dimensional displacements, so that it is possible to accurately maintain the shape'and placing of the contacts where such factors materially aflect the operation of the equipment on which the contacts are a part.

While the present invention, as to its objects and advantages has been described herein, as carried out in specific embodiments thereof, it is not desired to be limited thereby, but it is intended to cover the invention broadly, within the spirit and scope of the appended claims.

What is claimed is:

1. An electric contact member containing as an essential ingredient, silver to which has been added indium, in quantities ranging from 0.1 to 21%.

2. An electric contact, consisting of an alloy of 0.1 to 21% indium, balance substantially all silver.

3. An electric contact member composed of a refractory metal base and a silver alloy containing 0.1 to 21% indium.

4. An electric contact member formed oi a bonded mass of refractory metal powders selected from the group consisting of tungsten and molybdenum together with a silver alloy containing 0.1 to 21% indium.

FRANZ R. HENSEL. KENNETH L, EMMERT.

Referenced by
Citing PatentFiling datePublication dateApplicantTitle
US2456593 *Mar 22, 1945Dec 14, 1948Monroe ShermanSilver brazing alloy containing indium
US2464821 *Aug 3, 1942Mar 22, 1949Indium Corp AmericaMethod of preparing a surface for soldering by coating with indium
US2530413 *Oct 29, 1945Nov 21, 1950Crown Cork & Seal CoContainer
US2572662 *Jul 12, 1945Oct 23, 1951Cutler Hammer IncElectrical contact
US2623273 *May 5, 1945Dec 30, 1952Indium Corp AmericaSoldered joint and method of making same
US2771499 *Dec 9, 1952Nov 20, 1956Nickel Cadmium Battery CorpElectric battery plate and method of producing the same
US2894890 *Jul 20, 1949Jul 14, 1959John R KeelerJacketing uranium
US2935401 *Dec 10, 1957May 3, 1960William K AndersonControl rod alloy containing noble metal additions
US2949592 *Apr 19, 1951Aug 16, 1960Gen Radio CoAdjustable transformer with stabilized contact track
US3765880 *Nov 18, 1971Oct 16, 1973Texas Instruments IncOhmic contacts for gallium arsenide semiconductors
US4370164 *Jan 2, 1981Jan 25, 1983Jostens Inc.Yellow metal alloy
US4804517 *Apr 22, 1987Feb 14, 1989Williams Dental Company, Inc.Gold colored palladium - indium alloys
US5023144 *Mar 23, 1990Jun 11, 1991Mitsubishi Metal CorporationSilver alloy foil for interconnector for solar cell
US5242658 *Jul 7, 1992Sep 7, 1993The Indium Corporation Of AmericaSolders
US5256370 *May 4, 1992Oct 26, 1993The Indium Corporation Of AmericaLead-free alloy containing tin, silver and indium
US5435857 *Jan 6, 1994Jul 25, 1995Qualitek International, Inc.Tin, indium, antimony, silver and bismuth
US5558833 *Jun 9, 1995Sep 24, 1996Zamojski; Marek R.Indium, molybdenum, copper, reduced surface porosity
US5580520 *Nov 4, 1994Dec 3, 1996The Indium Corporation Of AmericaLead-free alloy containing tin, silver and indium
US7189292Oct 31, 2003Mar 13, 2007International Business Machines CorporationElectronic with an alloy of silver and beryllium, and a surface layer of beryllium oxide made by oxidizing the surface of said alloy that acts as a barrier layer; useful for back end of the line (BEOL) metallic conductors in microelectronics devices such as memory or logic devices
US7527188Jan 5, 2007May 5, 2009International Business Machines CorporationElectronic with an alloy of silver and beryllium, and a surface layer of beryllium oxide made by oxidizing the surface of said alloy that acts as a barrier layer; useful for back end of the line (BEOL) metallic conductors in microelectronics devices such as memory or logic devices
US7694871May 4, 2009Apr 13, 2010International Business Machines Corporationformed by selectively oxidizing alloying element by annealing at temperature of about 250 degrees to about 500 degrees C. in an oxidizing atmosphere containing an oxidizing agent having a partial pressure of about 10-8 to about 1 Torr, forming a layer of alloying element oxide on the alloy
WO2010005382A1 *Jul 3, 2009Jan 14, 2010Sandvik Intellectual Property AbAnti- tarnish silver alloy
WO2012107524A1 *Feb 9, 2012Aug 16, 2012Impact Coatings AbMaterial for providing an electrically conducting contact layer, a contact element with such layer, method for providing the contact element, and uses of the material
Classifications
U.S. Classification75/245, 428/567, 428/929, 75/247, 29/602.1, 420/501
International ClassificationH01H1/023
Cooperative ClassificationY10S428/929, H01H1/023
European ClassificationH01H1/023