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Publication numberUS2291865 A
Publication typeGrant
Publication dateAug 4, 1942
Filing dateMay 1, 1940
Priority dateMay 17, 1939
Publication numberUS 2291865 A, US 2291865A, US-A-2291865, US2291865 A, US2291865A
InventorsAlbert Allendorfer, Hans Bernstorff
Original AssigneeChemical Marketing Company Inc
Export CitationBiBTeX, EndNote, RefMan
External Links: USPTO, USPTO Assignment, Espacenet
Process for the production of metal alloys
US 2291865 A
Abstract  available in
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Claims  available in
Description  (OCR text may contain errors)

Patented Aug. 4, 1942 Hans Bernstorfl, Franki'ort-on-thc-Main, and Albert Allendiirter,

Bad Homburg vor der Hohe,

Germany, assignors to Chemical Marketing Company, Inc., New York, N. Y., a corporation No Drawing. Application May 1, 1940, Serial No.

i 332,842. InGermany May 1-1, 1939 2 Claims. (01. 75-122).

Our invention relates to the production 'of alloys from metals with great aflin'ity to gases such as oxygen or nitrogen, for instance, beryllium, titanium, zirconium, thorium or tungsten with other metals.

To alloy these metals with other metals such as copper, iron, nickel, molybdenum or their alloys, especially steels made therefrom is extremely diflicult. During the addition of these highly oxydizable metals to a copper melt tor the production of an alloy, the reactive metals oxidise so quickly that only a relatively small percentage alloys-with the copper. The loss by burning of the valuable reactive metalis rather heavy. Moreover, the oxides of these metals cannot or can only partly be separated from the melt, thereby tending to decrease the mechanical propertiesand the workability of the alloys. Finally, it is thereby nearly impossible to control the ratio of the amounts of the alloy components.

It was therefore suggested to carry out the melting process either in vacuo or in a protecting gas atmosphere whereby, however, considerable technical and apparatus difilculties occurred which made the production of these alloys nearly impossible.

According to our invention we have found that metal alloys from metals with great afllnity to gases-such as oxygen or nitrogen-as, for instance, beryllium, titanium, zirconium, thorium, tungsten with other metals, for instance, copper, iron, nickel, molybdenum or their alloys may be produced in such manner that in the first step the metals are difiused together at temperatures below their fusion points, if desired under pressure, thereby producing a preliminary alloy and finally alloying these alloys with less reactive metals. Surprisingly, these reactive metals rather lose their aflinity to, for instance, oxygen, so that they may be remelted without any danger to be oxidized.

In carrying out our invention we proceed in such manner that the reactive metals are embedded in less reactive metals or their alloys. Thus, for instance, a finely divided strongly oxidizable metal is filled into a copper tube, closed The diffusion maybe enhanced by utilization of a light pressure, for instance, hydraulic pressure. Another way of carrying out our invention,

especially for the production of alloys with a higher content of reactivemetals, consists in an alternate filling. of a form of .less reactive metal, for instance, a copper tube with the susceptible and non-susceptible metal in form of b'riquets, for instance, lamellae oi zirconium and copper layers. This copper ingot is now heated, for instance, for one hour at a temperature farv below the fusion point of the metals, i. e. at about on one end, sealed with a copper layer and heated to temperatures below the fusion point of both metals. It is advantageous to choose the perature in such manner that it lies only slightly above the eutecticum which may be formed of the two alloy components or, in case of absolute solubility in a solid state, just above the solidus line. Hereby the metals diffuse with each other.

940-9'70 C. and that in contact with the open air. The pressure is hereby preferably chosen in such manner that already below the working temperature the copper tube is subjected to a certain deformation which causes an airtight occlusion of the metal lying therein and an intimate contact of it with the copper. This intimate contact accelerates the difi'usion at the working temperature. v

The so formed preliminary alloys may bemelted in the open air before the production orthe final alloys without any loss by burning, thereby causing an absolutely homogeneous structure. They may also be directly alloyed with the less reactive metals, as usual.

Our invention shows several advantages. It enables the production of alloys of metals reactive to oxygen, nitrogen or the like without the utilization of vacuum or a protecting gas. Nev? ertheless, a" loss by burning with the formation of oxides and contamination of the formed alloys is absolutely prevented. Furthermore, by the production of a preliminary alloy in a solid state the danger of liquation or segregation in the remelting process of the preliminary alloy 01' in the melting operation of the final alloy will be considerably lessened. This is of extraordinary importance with alloys resulting from components with very difierent density. Finally, it is possible according to our invention, to produce final alloys with definite composition through the formation of a preliminary alloy.

What we claim is: t

l. A- process for the production of a metal alloy from at least one reactive metal having a great aflinity to gases selected from the group con sistingof beryllium, titanium, zirconium, thorium and tungsten and at least one less reactive metal selected from the group consisting of copper, iron, molybdenum and nickel, which comprises mixing the reactive metal in finely divided form with the less reactive metal, inclosing such mixture in a casing of the less reactive metal and heating the combination to a temperature below the melting point of the respective metals to cause diffusion of the metals to form a preliminary alloy and employing this alloy to introduce the desired quantity of the reactive metal in further quanti ties of the less reactive metal.

2. A process for the production of a metal alloy from at least one reactive metal having a great afflnity to gases selected from the group consisting of beryllium, titanium, zirconium, thorium and tungsten and at least one less reactive metal selected from the group consisting of copper, iron, molybdenum and nickel, which comprises forming briquets of the reactive and the less reactive metals, introducing such briquets alternately into a. casing of a less reactive metal, heating the filled casing to temperatures below the melting points of the metals to cause diffusion of the metals to form a preliminary alloy.


Referenced by
Citing PatentFiling datePublication dateApplicantTitle
US2938784 *Jan 9, 1946May 31, 1960Frank H SpeddingNuclear fuel composition
US3529958 *Nov 4, 1966Sep 22, 1970Buehler William JMethod for the formation of an alloy composed of metals reactive in their elemental form with a melting container
US4564396 *Jan 31, 1983Jan 14, 1986California Institute Of TechnologyFormation of amorphous materials
WO1984002926A1 *Jan 9, 1984Aug 2, 1984California Inst Of TechnFormation of amorphous materials
U.S. Classification420/1, 420/441, 419/31, 419/32, 420/494, 420/590, 420/469
International ClassificationC22C1/03
Cooperative ClassificationC22C1/03
European ClassificationC22C1/03