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Publication numberUS2374674 A
Publication typeGrant
Publication dateMay 1, 1945
Filing dateOct 28, 1944
Priority dateOct 28, 1944
Publication numberUS 2374674 A, US 2374674A, US-A-2374674, US2374674 A, US2374674A
InventorsFox Abraham L, Julius Chindgren Carl
Original AssigneeFox Abraham L, Julius Chindgren Carl
Export CitationBiBTeX, EndNote, RefMan
External Links: USPTO, USPTO Assignment, Espacenet
Method for thermal decomposition of metallic nitrates
US 2374674 A
Abstract  available in
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Description  (OCR text may contain errors)

Patented May 1, 1945 METHOD FOR THERMAL DECOMPOSITION OF METALLIC NITItATES Abraham L. Fox and Carl Julius Chindgren, Salt Lake City, Utah, assignors to the Government of the United States, as represented by the Secretary of the Interior No Drawing. Application October 28, 1944, Serial No. 560,830

(Granted under the act of March 3, 1883, as

' amended April 30, 1928; 370 0. G. 757) 3 Claims.

The invention described herein may be manufactured and used by or for the Government of p the United States for governmental purposes without, the payment to us of any royalty thereon in accordance with the provisions of the act of April 30, 1928 (Ch. 460, 45 Stat. L. 467).

This invention relates to the production of metallic oxides, and more particularly to the production of such oxides by the thermal decom position of metallic nitrates. In the production of metallic oxides by the thermal decomposition of metallic nitrates, such as manganese nitrate, the customary way of accomplishing the decomposition is to heat a body of the metallic nitrate until it is fused and thereupon to continue the heating until nitrogen oxides are liberated and the metallic oxide remains as a residue. However, the heating of'metallic nitrates by direct com- .bustion gases is impractical for large scale commercial operations since the uccess of such operations depends economically upon the recovery of the nitrogen oxides evolved. Obviously, dilution of the evolved nitrogen oxides with large .quantities of flue gases renders their recovery impractical. Furthermore, if a body of metallic nitrate, such as manganese nitrate, is heated indirectly by means of steam coils or application of heat; to the container in which the body of nitrates is held, the liberated metallic oxide forms a hard, impervious coating upon the interior of the container which soon insulates the main body of molten nitrate from the heat source, and the deposit is also very difiicult to remove.

It is accordingly the object of this invention to provide a method of heating metallic nitrates to decompose them so that the thermal decomposition of such nitrates can be carried out without forming scaling or dilution of the evolved gases. Other objects will be apparent or will appear hereinafter as the description proceeds.

In accordance with this invention, metallic nitrates, such as manganese nitrate, are thermally decomposed by heating such nitrates with a portion of the gases liberated'from a previous decomposition, said gases having been heated at an intermediate stage of the process. During operation, the evolved gases from the decomposition of the manganese nitrate or other metallic nitrate are collected, a portion of such gases are heated to a temperature at least as high as decomposition temperature of the nitrate being treated, and then the heated gases are passed over additional metallic nitrate undergoing decomposition.

In the foregoingfashion, the decomposition of suitable metallic nitrates is carried outin a simple fashion without diluting the evolved gases and without a formation of scaly deposits and excessive foam.

Suitable metallic nitrates for decomposition 1n accordance with this invention include the nitrates of manganese, cobalt, aluminum, and many others too numerous to mention. Manganese nitrate, either in the hydrated or anhydrous form, constitutes a preferred metallic nitrate for decomposition in-accordance with this invention The thermal decomposition of manganese nitrate, suitably in the form of its hexahydrate, liberates manganese dioxidegnitric oxides, and water. Manganese nitrate hexahydrate melts or fuses at 25 C. and i completely decomposed at C. i

The liberated reaction gases and vapors, herein called gases, are'withdrawn from the reaction zone and a portion of them is heated to a temperature at least as high as the decomposi-' tion temperature of the nitrate being treated. For example, in the case of manganese nitrate, the withdrawn portion of the evolved gases is heated to a temperature of at least 160 C., and preferably to about 400 C. to 500 C. After heating, the gases are brought into contact with additional quantities of metallic nitrate being decomposed. Thus, the process lends itself particularly well to operation in a cyclic continuous manner. k

In operation, we have found that a desirable rate of decomposition is achieved when the reheated or superheated gaseous products of de-' composition are passed over a shallow pool of molten manganese or other metallic nitrate. In

this case the liberated manganese or other oxide forms a fine suspension in the pool of molten material, and no foaming or frothing has been observed. It will be apparent from the foregoing that there has been provided a desirable and efiicient' method for decomposing molten metallic nitrates. Various changes may be made in the invention by those skilled in the art without departing from the spirit and scope of the invention.

What we claim is: 1. In a process for the production of manganese dioxide by the thermal decomposition of manganese nitrate, the improvement which comprises collecting the evolved gases from such a decomposition, heating a portion of such gases to a temperature at least as high as the decomposition temperature of manganese nitrate, and passing said heated gases into contact with adposition.

nese dioxide bythe thermal decomposition of manganese nitrate, the improvement which comprises collecting the evolved gases from such a decomposition, heating a portion of such gases to a temperature of about 400 C. to 500 C., and passing said heated gases into contact with additional manganese nitrate undergoing decom- ABRAHAM L. FOX,


Referenced by
Citing PatentFiling datePublication dateApplicantTitle
US2681268 *May 7, 1949Jun 15, 1954Nossen Ernest SamuelProcess for the manufacture of manganese dioxide and depolarizers for electric cells
US2737441 *Dec 5, 1950Mar 6, 1956Nossen Ernest SamuelSeparation of manganese from iron and other undesirable ore components
US2779659 *Oct 23, 1953Jan 29, 1957Vitro Corp Of AmericaDecomposition of manganese nitrate solutions
US4141963 *May 16, 1977Feb 27, 1979Ciba-Geigy CorporationThermal decomposition of metal nitrates
US4175116 *Apr 20, 1978Nov 20, 1979Ciba-Geigy CorporationNon-electrolytic production of chlorine utilizing HC1 derived from a cyanogen chloride process
US4250149 *May 15, 1979Feb 10, 1981Chemetals CorporationManganese nitrate decomposition
US4276268 *Oct 9, 1979Jun 30, 1981Chemetals CorporationProcess for preparing manganese nitrate solution
US4310494 *Dec 16, 1980Jan 12, 1982Chemetals CorporationManganese nitrate spray decomposition
EP0065608A1 *May 26, 1981Dec 1, 1982Chemetals CorporationProcess for preparing manganese nitrate solution
WO1980002555A1 *May 15, 1980Nov 27, 1980Chemetals CorpManganese nitrate splash/spray decomposition
U.S. Classification423/605
International ClassificationC01G45/00, C01G45/02
Cooperative ClassificationC01G45/02
European ClassificationC01G45/02