|Publication number||US2393778 A|
|Publication date||Jan 29, 1946|
|Filing date||Sep 29, 1943|
|Priority date||Sep 29, 1943|
|Publication number||US 2393778 A, US 2393778A, US-A-2393778, US2393778 A, US2393778A|
|Inventors||Hull David C|
|Original Assignee||Tennessce Eastman Corp|
|Export Citation||BiBTeX, EndNote, RefMan|
|Referenced by (14), Classifications (12)|
|External Links: USPTO, USPTO Assignment, Espacenet|
D. C. HULL jan, 299 E946*s Filed Sept. 29, 1945 L S Y w m E a m. m
D m A mT\. Q ma ko Bnmm 2@ a ZEE Al Emzmnzou N z ramadan, ze, 194s' UNITED srA-'rEs PATENT OFFICE :saam
raocass nonrsxs AND mmros l'olt 'ma rror oaoamc oouronnns nana c. nim. that?? muismat: 'l'cnncneelastman alims. Cmatimlhmcrtrmamtim anmsasepamsezamasumuamm z calm. (ci. 20e-ssn) tures of the order ofv 1000 C. or higher. Fifth, the material must be of such a nature that it will have no adverse catalytic eect when in contact with the materials being processed. Finally, the
. material must not change in composition or physical characteristics such as by internal grain growth-with accompanying development of brittleness after being in use for some time.
In the pyrolysis of acetone, acetic acid and other vketenizable compounds to produce ketene and other products, it has heretofore been the practice in carrying out the pyrolysis operation to employ pyrolysis chambers or apparatus constructed of carbon, copper, silver, brass, bronze, clay, silica and various other materials. Such materials have numerous disadvantages which render their use wholly impractical or impossible when carrying out the pyrolysis reaction at temperatures of the order of or in excess of 1000 C., particularly when low vacuum conditions in the apparatus are employed. For example, when it.v
-pyrolysis chamber had become so severely deteriorated as to be completely unuseable for further operation. Silver coils are likewise so easily burned up under high temperature conditions as to be totally unuseable. Coils or pyrolysis chambers constructed of clay and silica, while able under certain circumstances to resist the relatively high temperatures employed, are nevertheless wholly unfeasible for use in pyrolysis operations because of the fact that they have such poor heat transfer and because they are so porous.
It will thus be readily understood that the pyrolysis of ketenizable organic compounds, such as the production of ketene by the pyrolysis of acetic acid presents a multiplicity of problems, the solution of which is exceedingly dimcult. First, the pyrolysis reaction must be carried out in a reaction vessel constructed of a non-porous material. Second, the material lmust be able to withstand heat shock and not burn up under the high temperature conditions of the reaction. Third, the material must have sumcient strength to withstand high pressure, either from the outside or from the inside of th'e vessel. Fourth, it must be able to stand up under the severe oxidizing and reducing action of the heating llame at tempera- To the bestof my knowledge and belief, in spite of the vast accumulation of knowledge and experience on the part of those skilled in the art and the prophetic statements in the patent and technical literature, no one, until the advent of the present invention. has ever provided a process for pyrolyzing ketenizable organic compounds wherein the pyrolysis reaction could be carried out at maximum eillciency and without shutdowns, severe material losses and other undesirable results directly traceable to failure of the material employed in the pyrolysis vessel. In fact, s o vital is the matter of carrying out the pyrolysis reaction in contact with a material which will withstand the extremely severe conditions met with, that thereon depends the success or failure, or, in other words, the operability or inoperability, of the process.
This invention has for an object to provide an improved process of and apparatus for the pyrolysis of ketenizable organic compounds such as acetone, acetic acid and the like. A further object is to provide a process for the production of lsetenev by the pyrolysis of ketenizable organic compounds under extremely severe temperature and oxidationl conditions.v A still further object is to provide a process for the pyrolysis of organic compounds at temperatures of the order of, or in excess of, `1000 C. which may be operated continuously for long periods of time without burning out or other deterioration of the equipment and with a minimum decomposition of the reactants through catalytic or other action. Other objects will appear hereinafter.
These objects are accomplished by the following invention which, in its broader aspects, comprises pyrolyzing ketenizable organic compounds such as acetone, acetic acid, and other ketenizable compounds at high temperature ina heat-resistant yand oxidation-resistant pyrolysis vessel composed of a catalytically inactive high chromium steel alloy containing nitrogen and small fractions of manganese, nickel and carbon, such as known to skilled metallurglsts, small fractions of a percent of other elements, such as sulfur and silicon, may be present as impurities.
In extensive research carried out for many years on large scale commercial operations, I have found that pyrolysis of ketenizable organic compounds to produce ketene and other desired products athigh temperatures of the order of 1000 C. can be successfully carried out only in pyrolysis vessels oi arelatively extremely limited chemical constitution. These materials are steel alloys containing a relatively high chromium content and a relatively low content of other materials, as indicated. I have found that the alloy manufactured and sold by the Babcock and Wilcox Tube Company of Beaver Falls, Pa., under the trade name Croloy 27" is a particularly valuable material for this purpose. This is a high chrome steel alloy containing 27% chromium. a maximum of 0.2% carbon, 1% nickel, about..2% nitrogen (.12 to .25%) and the balance iron. Other alloys having components within the limits designated in the previous paragraph are obtainable upon the open market, such for instance as the alloy manufactured and sold by National Tube Co., Pittsburgh, Pa... containing 24-26% chromium, .6% manganese, 1.5% silicon, .2% carbon and .3% nitrogen, 'each of the last-four-mentioned ingredients being a maximum, and the balance being iron..
In the following examples and description I have set forth several of the preferred embodments of my invention but they are included merely for purposes of illustration and not as a limitation thereof. v l
'I'he single figure of the accompanying drawing is a diatic elevational view, in partial section, and in the nature of a flow sheet l1- lustrating a typical method of pyrolizing ketenizable organic compounds in accordance with the instant invention.
A clearer understanding of my invention will shown. The preheated vapors thus pass through conduit 8 into the pyrolysis chamber ink which they are heated to a temperature of 600 to 900 or less circuitous path before reaching the pybe obtained from consideration of a typical procv ess and the apparatus employed cordance with my invention.
. The numeral I designates Ya. suitable pipe therein in acv through which may be led a ketenizable organic compolmd, such as acetic acid, now of the compound to the vaporizer 2 being controlled byvalve 3.
In the vaporizer 2, which may take the form of a coil, still pot, or other vessel equipped with a suitable source of heat such as a heating jacket,
.electrical resistance coils or other means, the
acetic acid is vaporized and then conducted through conduit 4 to preheating vessel l5, which may likewise take the form of a heating coil, metal still pot or other appropriate device, and is there heated to a temperature of approximately 600 to 800 C. v
In order to facilitate the ketene reaction' a suitable catalyst, such as a phosphate compound` may be admixed in small quantities with the acetic acid vapors passing through` conduit l, the catalyst being conveniently supplied to the acetic vapors through conduit 4 through conduit 6 controlled by valve 1.
The numeral 8 designates apyrolysis vessel which may take theformof a heating coil similar to that of coil 5. This vessel is constructed of the high chrome-nitrogen steel alloy described above. 'Pyrolysis vessel 8 is connected with lthe preheating vessel l by means of a conduit 9. as
. that it burns out almost immediately under the divides the preheating chamber from the pyroly-v sis chamber, but leaves an opening for the passage of the heating medium from the pyrolysis chamber to the preheating chamber. Under the inuence of the extremely high temperature prevailing within the pyrolysis vessel the acetic acid or other ketenizable organic compoundlis cracked to ketene which passes, together with any other products of reaction from the pyrolysis chamber, by means of conduit H to condenser I2 where the ketene gas is separated from condensible components, including by-products and unchanged raw materials, which latter are removed by suitable draw-oli means as shown. If desired, and as shown, a suitable catalyst neutralizer may be introduced into the vapors passing through conduit H before they lreach the con-V denser I2. The ketene gas produced may then be conducted to any other desired reaction zone for conversion to other valuableproducts suchV as acetic anhydride by reaction withacetic acid.
In operating the process as above described, Y
trate the very marked and unpredictable increase in eiiiciency of the process for pyrolyzing ketenizable organic compounds, by carrying out the reaction in a pyrolysis vessel composed of the particular high chrome-nitrogen-steel alloy described above, -a further discussion of the wide discrepancy between the results obtained in pyrolysis processes carried out in vessels composed of other alloys and the results to be obtained'by carrying out the process in accordance with my invention, is desirable.
Reference has been made to the fact that if the pyrolysis chamber is constructed of copper, 1t is substantially worthless because of the fact temperatures encountered and the severe oxidizing conditions met with during the reaction. For example, I have found that after a very short period'vof useage under such conditions a copper vessel loses all its strength and completely disintegrates. In addition even for such short period, it is necessary to protect the outer side of the pyrolysis vessel from attack bythe flamesl 'ordinarily used to heat such vessels. Even when the procprotected the .pyrolysis vessels fail and ess is brought to a standstill. l
It might be supposed that otherv alloys such as Nichromeor other alloys having high chromium and nickel content might be employed. However, I have found that although such alloys will resist fairly well the atmosphere encountered. as well as the high temperatures prevailing on the outside of the vessels.- these alloys are absolutely worthless when employed in pyroly. sis vessels for the production of ketene because their catalytic activities are so great that even at moderate temperatures almost complete carbonization of the ketenizable substances fed through the apparatus takes place.
Other steel alloys have' been found t0 be almost equally deficient for use in the pyrolysis reaction for one reason or another. For example, a well' known stainless steel such as Type-316, when employed in the pyrolysis vessel has approximately ten times the adverse catalytic activity o! the high chrome, nitrogen steel described above. This can readily be determined by measuring the amount of carbon formed by passing a known amount of acetic acid over the metal at an elevated temperature and measuring the quantities of the decomposition gases given up when a known amount of the acid is passed over. Furthermore, the heat resistance of stainless steel -alioys auch as Type-316 or Type-304 is such that they are entirely unsuitable for any continued use above an outside temperature ot about '100 C., which is a temperature entirely unsuited for successful large-scale operation.
In addition to deflclenciea o! such alloys from the catalytic standpoint, they present the drawback that. even under the most favorable circumstances, they result in the production of very poor yields. For example, whereas yields of the order of only 20 or 30% are obtainable when Nlchrome steels are employed. by the use or the hish chrome, nitrogen steels described above. yields of the order of ilo-95% can be readily obtained. Thus. I have provided a process and apparatus which will accomplish to an unusual decree ot eillciency, avery important chemical reaction with much lower cost of operation than possible with alloys usually employed for such Purposes.
What I claim is:
l. The process of pyrolyxing ketenizable organic compounds such as acetic acid to produce ketene and other products which comprises pyrolyzing the ketenizable compound in the vapor phase at a temperature of the order o! 1000 C. in a pyrolysis vessel constructed ot a non-catalytic high chrome, nitrogen steel alloy containing 1840?, chromium. about .2 to about 1.5% nitrogen and, small amounts of manganese, nickel, and carbon, the balance beins iron.
2. An apparatus for thermally decomposing ketenizable organic compounds to produce ketene and other products which comprises a pyrolysis vessel constructed essentially of a non-catalytic, high chrome-nitrogen steel alloy containing 18-40% chromium, about .24.5% nitrogen and, small amounts of mansanese, nickel and carbon, and the balance iron, means for introducing ketenizable organic compounds into the pyrolysis vessel and means for heating the vessel to pyrolysls temperatures.
DAVID C. HULL.
|Citing Patent||Filing date||Publication date||Applicant||Title|
|US2526651 *||Aug 2, 1945||Oct 24, 1950||Hydrocarbon Research Inc||Separating powdered catalysts from exothermically reactive gases|
|US2537079 *||Jun 4, 1948||Jan 9, 1951||Standard Oil Dev Co||Prevention of coke formation in pyrolysis of acetone|
|US2537687 *||Jan 13, 1948||Jan 9, 1951||Standard Oil Dev Co||Preventing coke formation in pyrolysis of ketones|
|US2541471 *||Jul 11, 1947||Feb 13, 1951||Eastman Kodak Co||Furnace for pyrolyzing ketenizable organic compounds|
|US2776192 *||Dec 10, 1952||Jan 1, 1957||Eastman Kodak Co||Acetic acid cracking furnace|
|US2820058 *||Jun 15, 1953||Jan 14, 1958||Celanese Corp||Production of ketene|
|US2863922 *||Oct 2, 1956||Dec 9, 1958||Hoffmann La Roche||Preparation of ketene|
|US3161683 *||Feb 9, 1960||Dec 15, 1964||Acidos Grasos Limitada||Process for partial oxidation of acetylene|
|US3450506 *||Jul 23, 1964||Jun 17, 1969||Lummus Co||Apparatus for the production of hydrogen|
|US3475131 *||Sep 9, 1965||Oct 28, 1969||Perkin Elmer Ltd||Pyrolysis apparatus|
|US3969109 *||Aug 12, 1974||Jul 13, 1976||Armco Steel Corporation||Oxidation and sulfidation resistant austenitic stainless steel|
|US4532109 *||Jan 30, 1984||Jul 30, 1985||Jgc Corporation||Process for providing an apparatus for treating hydrocarbons or the like at high temperatures substantially without carbon deposition|
|US5475144 *||Jun 8, 1994||Dec 12, 1995||The University Of Delaware||Catalyst and process for synthesis of ketenes from carboxylic acids|
|DE1101403B *||Aug 4, 1958||Mar 9, 1961||Hoffmann La Roche||Verfahren zur Herstellung von Keten|
|U.S. Classification||568/302, 420/34, 422/198, 420/65, 422/240|
|International Classification||C07C45/89, C07C45/88, C07C45/00|
|Cooperative Classification||C07C45/88, C07C45/89|
|European Classification||C07C45/88, C07C45/89|