US2431660A - Turbine blade - Google Patents

Turbine blade Download PDF

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Publication number
US2431660A
US2431660A US633196A US63319645A US2431660A US 2431660 A US2431660 A US 2431660A US 633196 A US633196 A US 633196A US 63319645 A US63319645 A US 63319645A US 2431660 A US2431660 A US 2431660A
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Prior art keywords
blade
metal
set forth
ceramic
turbine blade
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Expired - Lifetime
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US633196A
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Gaudenzi Arthur
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BBC Brown Boveri AG Germany
BBC Brown Boveri France SA
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BBC Brown Boveri France SA
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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01DNON-POSITIVE DISPLACEMENT MACHINES OR ENGINES, e.g. STEAM TURBINES
    • F01D5/00Blades; Blade-carrying members; Heating, heat-insulating, cooling or antivibration means on the blades or the members
    • F01D5/12Blades
    • F01D5/28Selecting particular materials; Particular measures relating thereto; Measures against erosion or corrosion
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S264/00Plastic and nonmetallic article shaping or treating: processes
    • Y10S264/36Processes of making metal-ceramics
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S60/00Power plants
    • Y10S60/909Reaction motor or component composed of specific material
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T29/00Metal working
    • Y10T29/49Method of mechanical manufacture
    • Y10T29/49316Impeller making
    • Y10T29/49336Blade making
    • Y10T29/49337Composite blade
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/12All metal or with adjacent metals
    • Y10T428/12014All metal or with adjacent metals having metal particles
    • Y10T428/12021All metal or with adjacent metals having metal particles having composition or density gradient or differential porosity
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/12All metal or with adjacent metals
    • Y10T428/12014All metal or with adjacent metals having metal particles
    • Y10T428/12028Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, etc.]
    • Y10T428/12063Nonparticulate metal component
    • Y10T428/12139Nonmetal particles in particulate component
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/12All metal or with adjacent metals
    • Y10T428/12486Laterally noncoextensive components [e.g., embedded, etc.]

Definitions

  • This invention relates generally to the construction of turbine blades or vanes and it has particular relation to blades for turbines which operate at extremely high temperatures.
  • a turbine blade for use with high temperature power-generating fluids should have the following properties: high tensile strength in the temperature range above 700 0., low specific weight, high heat conductivity and capability of enduring temperature changes, relatively great surface hardness, capability of simple and durable installation, and resistance to oxidation, 1, e. relatively free from slag formation.
  • the blade or vane has a metal foot or root portion to which is joined a top or working portion on which the high temperature fluid impinges and which is formed of, or provided with a covering or layer of, fritted metal and ceramic powder or ceramic-like powder, the metal content of the working portion decreasing with increasing distance from the foot portion of the blade.
  • a turbine blade thus stratified and having a steel foot portion can be installed on a turbine rotor in exactly the same manner and as easily as one made wholly of steel.
  • the steel foot portion may gradually merge into the interior of the composite top or working portion of the blade.
  • Figures 1 and 2 are side elevations, partly in section, of two different embodiments of the present invention.
  • the foot or root portion a of the blade is formed of a suitable steel and shaped to conform to the design of the stator and rotor mountings of the turbine, for example a de Laval turbine, in which it is to be incorporated.
  • the root portion a is tapered outwardly and located within the working portion b which pin e upon the turbine blade.
  • .metal powder may be of a corrosion-resistant steel that is not damaged by the high temperature gases that drive the turbine.
  • the root section a need not extend into the interior of the blade section but may be welded to the inner end of the working portion b of the turbine blade, As in the turbine blade of Fig. l, the composition of the fritted blade portion b changes gradually from a substantial all-metal section adjacent the steel root a to a substantially all-ceramic section or layer at the outer surface of the blade.
  • the metal powders of the fritted portion may be of a single metal or mixtures of metals such as iron, nickel, chromium, cobalt, tungsten, molybdenum or titanium; may be a steel including some of the recited refractory metals; or may be alloys of refractory metals, particularly steels or alloys of high tensile strength; metal powders of hard metal alloys such as tungsten carbide, either is composed of a fritted mixture of metal powder and ceramic or ceramic-like powder. The ratio of metal powder to ceramic powder decreases progressively with increasing distance from the steel root portion a of the blade.
  • the metal powder content adjacent the steel root portion a is so high as to result in a welding of the fritted working portion b to the root portion a.
  • the outer end of the working portion b of the blade, or at least the surface layer of the blade, is a fritted mass of ceramic or ceramic-like powder with little or no admixed metal powder.
  • the outer fritted layer of ceramic or ceramic-like material is sufilciently compact to be substantially impermeable to the high temperature gases that imwith or without additions of cobalt and/or nickel powders are also suitable.
  • the ceramic powder is selected from the refractory oxides of highly heat resistant materials and preferably from relatively stable oxides having relatively high heat conductivity; for example oxides of beryllium, aluminum, zirconium, magnesium and thorium. Mixtures of oxides are also suitable, such as spinel, zirconium silicate and others together with oxides having lower melting points such as quartz and titanium oxide; also porcelain comprising a mixture of kaolin, quartz and feldspar or the steatite group with talc or soapstone as the main component. Powdered glass may be used alone or in combination with the refractory oxides, the glass being of a hard or high temperature type such as the so-called oven glasses sold under the trade-marks Pyrex and Duran.
  • the weight of the fritted blade portion is substantially less than that of an all-metal blade, and the stresses due to centrifugal force are therefore substantially reduced.
  • Ceramic materials such as beryllium oxide or aluminum oxide are particularly useful as they have a heat conductivity similar to that of iron and steel. These oxides have meltin points above 2000 C. and, when vitrified, have a surface hardness greater than that of hardened steels.
  • a turbine blade or vane for use with high temperature pressure fluids said blade comprising a metal foot portion for attachment to a rotor or stator ring, and a working portion carried by and extending from said foot portion, the
  • the metal powder consists at least in part of working portion of the blade that is impinged upon by said fluids being a fritted mixture of metal and ceramic powders, the metal content of the blade decreasing as the distance from the foot portion increases.
  • the ceramic powder comprises oxides of highly fire-proof materials having high melting points.
  • the ceramic powder comprises oxides of highly fire-proof materials having high melting points and high heat conductivity.
  • the metal powder comprises an alloy of high .tensile strength.
  • the metal powder comprises hard metal alloys of high tensile strength.

Description

Nov. 25, 194.7. A. GAUDENZI TURBINE BLADE Filed Dec. 6, 1945 2 -Wu m a Patented Nov. 25, 1947 TURBINE BLADE Arthur Gaudenzi, Wettingen, Switzerland, as-
signor to Aktiengesellschaft Brown, Boveri & Ole, Baden, Switzerland, a joint-stock company Application December 6, 1945, Serial No. 633,196 In Switzerland December 1, 1944 Section 1, Public Law 690, August 8, 1946 19 Claims.
This invention relates generally to the construction of turbine blades or vanes and it has particular relation to blades for turbines which operate at extremely high temperatures.
A turbine blade for use with high temperature power-generating fluids, such as gas turbine blades, should have the following properties: high tensile strength in the temperature range above 700 0., low specific weight, high heat conductivity and capability of enduring temperature changes, relatively great surface hardness, capability of simple and durable installation, and resistance to oxidation, 1, e. relatively free from slag formation.
In accordance with this invention the blade or vane has a metal foot or root portion to which is joined a top or working portion on which the high temperature fluid impinges and which is formed of, or provided with a covering or layer of, fritted metal and ceramic powder or ceramic-like powder, the metal content of the working portion decreasing with increasing distance from the foot portion of the blade. A turbine blade thus stratified and having a steel foot portion can be installed on a turbine rotor in exactly the same manner and as easily as one made wholly of steel. The steel foot portion may gradually merge into the interior of the composite top or working portion of the blade.
In the drawing, Figures 1 and 2 are side elevations, partly in section, of two different embodiments of the present invention.
In both of the illustrated embodiments of the invention, the foot or root portion a of the blade is formed of a suitable steel and shaped to conform to the design of the stator and rotor mountings of the turbine, for example a de Laval turbine, in which it is to be incorporated. As shown in Fig. 1, the root portion a is tapered outwardly and located within the working portion b which pin e upon the turbine blade. Alternatively, the
.metal powder may be of a corrosion-resistant steel that is not damaged by the high temperature gases that drive the turbine.
As shown in Fig. 2. the root section a need not extend into the interior of the blade section but may be welded to the inner end of the working portion b of the turbine blade, As in the turbine blade of Fig. l, the composition of the fritted blade portion b changes gradually from a substantial all-metal section adjacent the steel root a to a substantially all-ceramic section or layer at the outer surface of the blade.
The metal powders of the fritted portion may be of a single metal or mixtures of metals such as iron, nickel, chromium, cobalt, tungsten, molybdenum or titanium; may be a steel including some of the recited refractory metals; or may be alloys of refractory metals, particularly steels or alloys of high tensile strength; metal powders of hard metal alloys such as tungsten carbide, either is composed of a fritted mixture of metal powder and ceramic or ceramic-like powder. The ratio of metal powder to ceramic powder decreases progressively with increasing distance from the steel root portion a of the blade. The metal powder content adjacent the steel root portion a is so high as to result in a welding of the fritted working portion b to the root portion a. The outer end of the working portion b of the blade, or at least the surface layer of the blade, is a fritted mass of ceramic or ceramic-like powder with little or no admixed metal powder. The outer fritted layer of ceramic or ceramic-like material is sufilciently compact to be substantially impermeable to the high temperature gases that imwith or without additions of cobalt and/or nickel powders are also suitable.
The ceramic powder is selected from the refractory oxides of highly heat resistant materials and preferably from relatively stable oxides having relatively high heat conductivity; for example oxides of beryllium, aluminum, zirconium, magnesium and thorium. Mixtures of oxides are also suitable, such as spinel, zirconium silicate and others together with oxides having lower melting points such as quartz and titanium oxide; also porcelain comprising a mixture of kaolin, quartz and feldspar or the steatite group with talc or soapstone as the main component. Powdered glass may be used alone or in combination with the refractory oxides, the glass being of a hard or high temperature type such as the so-called oven glasses sold under the trade-marks Pyrex and Duran.
The weight of the fritted blade portion is substantially less than that of an all-metal blade, and the stresses due to centrifugal force are therefore substantially reduced. Ceramic materials such as beryllium oxide or aluminum oxide are particularly useful as they have a heat conductivity similar to that of iron and steel. These oxides have meltin points above 2000 C. and, when vitrified, have a surface hardness greater than that of hardened steels.
I claim:
1. A turbine blade or vane for use with high temperature pressure fluids said blade comprising a metal foot portion for attachment to a rotor or stator ring, and a working portion carried by and extending from said foot portion, the
in the metal powder consists at least in part of working portion of the blade that is impinged upon by said fluids being a fritted mixture of metal and ceramic powders, the metal content of the blade decreasing as the distance from the foot portion increases.
2. The invention as set forth in claim 1, wherein the ceramic powder comprises oxides of highly fire-proof materials having high melting points.
3. The invention as set forth in claim 1, wherein the ceramic powder comprises oxides of highly fire-proof materials having high melting points and high heat conductivity. I
4. The invention as set forth in claim 1, wherein the ceramic powder consists at-least in part of beryllium oxide.
5. The invention as set forth in claim 1, wherein the ceramic powder consists at least in part of aluminum oxide.
6. The invention as set forth in claim 1, wherein the ceramic powder comprises a mixture of oxides.
7. The invention as set forth in claim 1, wherein the ceramic powder consists at least in part of porcelain.
8. The invention as set forth in claim 1, wherein the ceramic powder consists at least in part of steatites.
9. The invention as set forth in claim 1, wherein the ceramic powder consists at least in part of glass powder from hard glasses.
10. The invention as set forth in claim 1, wherein the metal powder consists at least in part of iron.
11. The invention as set forth in claim 1, wherein the metal powder consists at least in part of nickel.
12. The invention as set forth in claim 1, wherein the metal powder consists at least in part of chromium.
Y 4 1s. The invention as set forth in claim 1, where.-
molybdenum.
14. The invention as set forth in claim 1, wherein the metal powder comprises an alloy of high .tensile strength.
15. The invention as set forth in claim 1, wherein the metal powder comprises hard metal alloys of high tensile strength.
16. The invention'as set forth in claim 1, wherein the foot portion protrudes into the working portion and merges into the same in the interior thereof.
- 17. The invention. as set forth in claim'i, wherein the working portion is provided with a protective layer offritted metal and ceramic powder on all sides.
18. The invention, as set forth in claim 1, wherein the foot portion protrudes into the working portion and merges into the same in the in- REFERENCES CITED The following references are of record in the file of this patent:
FOREIGN PATENTS Country Date Italy 1940 OTHER REFERENCES Ser. No. 385,333, Schutte (A. P. C.) pub. May
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US633196A 1944-12-01 1945-12-06 Turbine blade Expired - Lifetime US2431660A (en)

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Cited By (58)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2653377A (en) * 1947-09-02 1953-09-29 American Electro Metal Corp Method for forming metal powder into a fluid guiding body
US2656596A (en) * 1949-05-17 1953-10-27 Union Carbide & Carbon Corp Tungsten-chromium-alumina metal ceramics
US2694646A (en) * 1949-07-19 1954-11-16 Zirconium Corp Of America Zirconia compositions
US2694851A (en) * 1948-04-28 1954-11-23 Daniel A Marra Method of forming torch tips
US2696652A (en) * 1951-07-25 1954-12-14 Raytheon Mfg Co Quartz article and method for fabricating it
US2698990A (en) * 1950-01-25 1955-01-11 Union Carbide & Carbon Corp Chromium-alumina metal ceramics
US2715011A (en) * 1949-07-19 1955-08-09 Maschf Augsburg Nuernberg Ag Ceramic blade for turbine engine
US2749029A (en) * 1948-11-26 1956-06-05 Sintercast Corp America Compressor blade
US2751293A (en) * 1951-07-31 1956-06-19 Allied Prod Corp Process of making perforated powdered metal article
US2751188A (en) * 1950-02-25 1956-06-19 Maschf Augsburg Nuernberg Ag Ceramic product
US2753612A (en) * 1956-07-10 Process of forming magnesia refractory
US2767463A (en) * 1951-04-19 1956-10-23 Onera (Off Nat Aerospatiale) Metallo-ceramic compositions and process of producing same
US2769611A (en) * 1951-08-15 1956-11-06 Schwarzkopf Dev Co Gas turbine rotors and their production
US2775426A (en) * 1951-12-20 1956-12-25 Westinghouse Electric Corp Blade structure
US2783966A (en) * 1948-10-22 1957-03-05 Maschf Augsburg Nuernberg Ag Parts for machinery
US2783967A (en) * 1952-01-03 1957-03-05 Maschf Augsburg Nuernberg Ag Ceramic machine parts
US2819515A (en) * 1951-06-26 1958-01-14 Thompson Prod Inc Method of making a blade
US2826512A (en) * 1953-08-14 1958-03-11 Jack F Govan Method of coating and resulting product
US2829427A (en) * 1948-10-13 1958-04-08 Onera (Off Nat Aerospatiale) Sintered refractory material
US2859163A (en) * 1957-12-30 1958-11-04 George L Ploetz Cadmium-rare earth borate glass as reactor control material
US2872724A (en) * 1953-07-31 1959-02-10 Union Carbide Corp Oxidized chromium-alumina metal ceramic protective tube
US2872726A (en) * 1955-01-04 1959-02-10 Gen Electric Sintered hard compositions
US2909834A (en) * 1955-10-14 1959-10-27 Union Carbide Corp Cermets with high impact strength
US2920830A (en) * 1956-12-26 1960-01-12 Niro Atomizer As Atomizer for the atomization of liquid dispersions in a reaction chamber
US2941281A (en) * 1953-12-04 1960-06-21 Int Nickel Co Hot workable, heat resistant metal bodies
US2954208A (en) * 1953-01-09 1960-09-27 Gen Motors Corp Air foil section
US2957238A (en) * 1953-11-18 1960-10-25 Rca Corp Method of forming a metallic surface layer on a ferrospinel body and bonding the same
US2961325A (en) * 1957-06-21 1960-11-22 American Lava Corp Cermet bodies
US2994124A (en) * 1955-10-03 1961-08-01 Gen Electric Clad cermet body
US3011761A (en) * 1954-11-25 1961-12-05 Power Jets Res & Dev Ltd Turbine blades
US3030071A (en) * 1959-09-22 1962-04-17 Gen Electric Erosion-resistant turbine blade
US3032316A (en) * 1958-10-09 1962-05-01 Bruce E Kramer Jet turbine buckets and method of making the same
US3047938A (en) * 1958-03-31 1962-08-07 Gen Motors Corp High temperature bond and method of forming same
US3052016A (en) * 1958-03-19 1962-09-04 Ind Fernand Courtoy Bureau Et Structure for joining by fusion-welding of ferritic steel with austenitic steel
US3066391A (en) * 1957-01-15 1962-12-04 Crucible Steel Co America Powder metallurgy processes and products
US3123447A (en) * 1964-03-03 Zirconium to stainless steel connection
US3123470A (en) * 1964-03-03 Bonding means and method
US3148981A (en) * 1961-04-21 1964-09-15 Nat Beryllia Corp Metal-oxide gradient ceramic bodies
US3175279A (en) * 1962-03-23 1965-03-30 Bendix Corp Ductile chromium composition
US3181947A (en) * 1957-01-15 1965-05-04 Crucible Steel Co America Powder metallurgy processes and products
US3188961A (en) * 1961-05-25 1965-06-15 Bendix Corp Means for cooling structures that are periodically heated to elevated temperatures
US3215511A (en) * 1962-03-30 1965-11-02 Union Carbide Corp Gas turbine nozzle vane and like articles
US3284194A (en) * 1962-03-23 1966-11-08 Bendix Corp Method of forming ductile metals
US3294496A (en) * 1963-11-29 1966-12-27 Union Carbide Corp Metal ceramic compositions
US3320036A (en) * 1964-10-26 1967-05-16 Bendix Corp Ductile molybdenum composition containing a spinel dispersion
US3320037A (en) * 1964-10-26 1967-05-16 Bendix Corp Ductile tungsten composition containing a spinel dispersed uniformly throughout
DE1751813B1 (en) * 1968-07-26 1971-04-29 Sulzer Ag GUIDE VANE FOR FLOW MACHINE
US3982854A (en) * 1971-12-20 1976-09-28 General Electric Company Friction welded metallic turbomachinery blade element
US4063939A (en) * 1975-06-27 1977-12-20 Special Metals Corporation Composite turbine wheel and process for making same
US4362471A (en) * 1974-11-29 1982-12-07 Volkswagenwerk Aktiengesellschaft Article, such as a turbine rotor and blade which comprises a first zone of a nonoxide ceramic material and a second zone of a softer material
US4512719A (en) * 1981-07-24 1985-04-23 Motoren-Un Turbinen-Union Munchen Gmbh Hot gas wetted turbine blade
EP0139396A1 (en) * 1983-08-29 1985-05-02 Westinghouse Electric Corporation Combustion turbine blade with varying coating
US4597926A (en) * 1981-11-30 1986-07-01 Tokyo Shibaura Denki Kabushiki Kaisha Method of manufacturing radial flow turbine rotor
DE4219470A1 (en) * 1992-06-13 1993-12-16 Asea Brown Boveri Component for high temperatures, in particular turbine blade, and method for producing this component
EP0574727A1 (en) * 1992-06-13 1993-12-22 Asea Brown Boveri Ag Method for the production of a high temperature-resistant element from two different materials
US5476723A (en) * 1992-05-27 1995-12-19 Societe Nationale D'etude Et De Construction De Motors D'aviation "S.N.E.C.M.A." Coated superalloy component
US20060204769A1 (en) * 2002-12-18 2006-09-14 Alessandro Coppola Manufacturing method for obtaining high-performance components for gas turbines and components thus obtained
US11261742B2 (en) 2013-11-19 2022-03-01 Raytheon Technologies Corporation Article having variable composition coating

Cited By (60)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3123447A (en) * 1964-03-03 Zirconium to stainless steel connection
US3123470A (en) * 1964-03-03 Bonding means and method
US2753612A (en) * 1956-07-10 Process of forming magnesia refractory
US2653377A (en) * 1947-09-02 1953-09-29 American Electro Metal Corp Method for forming metal powder into a fluid guiding body
US2694851A (en) * 1948-04-28 1954-11-23 Daniel A Marra Method of forming torch tips
US2829427A (en) * 1948-10-13 1958-04-08 Onera (Off Nat Aerospatiale) Sintered refractory material
US2783966A (en) * 1948-10-22 1957-03-05 Maschf Augsburg Nuernberg Ag Parts for machinery
US2749029A (en) * 1948-11-26 1956-06-05 Sintercast Corp America Compressor blade
US2656596A (en) * 1949-05-17 1953-10-27 Union Carbide & Carbon Corp Tungsten-chromium-alumina metal ceramics
US2694646A (en) * 1949-07-19 1954-11-16 Zirconium Corp Of America Zirconia compositions
US2715011A (en) * 1949-07-19 1955-08-09 Maschf Augsburg Nuernberg Ag Ceramic blade for turbine engine
US2698990A (en) * 1950-01-25 1955-01-11 Union Carbide & Carbon Corp Chromium-alumina metal ceramics
US2751188A (en) * 1950-02-25 1956-06-19 Maschf Augsburg Nuernberg Ag Ceramic product
US2767463A (en) * 1951-04-19 1956-10-23 Onera (Off Nat Aerospatiale) Metallo-ceramic compositions and process of producing same
US2819515A (en) * 1951-06-26 1958-01-14 Thompson Prod Inc Method of making a blade
US2696652A (en) * 1951-07-25 1954-12-14 Raytheon Mfg Co Quartz article and method for fabricating it
US2751293A (en) * 1951-07-31 1956-06-19 Allied Prod Corp Process of making perforated powdered metal article
US2769611A (en) * 1951-08-15 1956-11-06 Schwarzkopf Dev Co Gas turbine rotors and their production
US2775426A (en) * 1951-12-20 1956-12-25 Westinghouse Electric Corp Blade structure
US2783967A (en) * 1952-01-03 1957-03-05 Maschf Augsburg Nuernberg Ag Ceramic machine parts
US2954208A (en) * 1953-01-09 1960-09-27 Gen Motors Corp Air foil section
US2872724A (en) * 1953-07-31 1959-02-10 Union Carbide Corp Oxidized chromium-alumina metal ceramic protective tube
US2826512A (en) * 1953-08-14 1958-03-11 Jack F Govan Method of coating and resulting product
US2957238A (en) * 1953-11-18 1960-10-25 Rca Corp Method of forming a metallic surface layer on a ferrospinel body and bonding the same
US2941281A (en) * 1953-12-04 1960-06-21 Int Nickel Co Hot workable, heat resistant metal bodies
US3011761A (en) * 1954-11-25 1961-12-05 Power Jets Res & Dev Ltd Turbine blades
US2872726A (en) * 1955-01-04 1959-02-10 Gen Electric Sintered hard compositions
US2994124A (en) * 1955-10-03 1961-08-01 Gen Electric Clad cermet body
US2909834A (en) * 1955-10-14 1959-10-27 Union Carbide Corp Cermets with high impact strength
US2920830A (en) * 1956-12-26 1960-01-12 Niro Atomizer As Atomizer for the atomization of liquid dispersions in a reaction chamber
US3181947A (en) * 1957-01-15 1965-05-04 Crucible Steel Co America Powder metallurgy processes and products
US3066391A (en) * 1957-01-15 1962-12-04 Crucible Steel Co America Powder metallurgy processes and products
US2961325A (en) * 1957-06-21 1960-11-22 American Lava Corp Cermet bodies
US2859163A (en) * 1957-12-30 1958-11-04 George L Ploetz Cadmium-rare earth borate glass as reactor control material
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