|Publication number||US2695002 A|
|Publication date||Nov 23, 1954|
|Filing date||Jun 24, 1950|
|Priority date||Jun 24, 1950|
|Publication number||US 2695002 A, US 2695002A, US-A-2695002, US2695002 A, US2695002A|
|Inventors||Miller Merton R|
|Original Assignee||Ransburg Electro Coating Corp|
|Export Citation||BiBTeX, EndNote, RefMan|
|Patent Citations (5), Referenced by (46), Classifications (18)|
|External Links: USPTO, USPTO Assignment, Espacenet|
Nov. 23, 1954 M. R. MILLER ELECTROSTATIC ATOMIZER OF LIQUIDS l 2 Sheets-Sheet l Filed June 24. 1950 JNVENTOR. MEMO/v R M/LEH ATTORNEY Nov. 23, 1954 M. R. MILLER 2,695,002
ELECTROSTATIC ATOMIZER OF LIQUIDS Filed June 24, 1950 2 Sheets-Sheet 2 INVENTOR.
MERTO/V //HLLER United States Patent Gfce 2,695,002 Patented Nov. 23, 1954 11 anims. ici. 11s-s1) Ind., assgnor to Ransburg Indianapolis, Ind., a corpora- This invention relates generally to an electrostatic atomizer and more particularly to an atomizer capable of electrostatically atomizing liquids to produce a jet or spray having an elongated cross-section.
it has heretofore been proposed to produce a jet or spray of elongated cross-section by electrostatically atomizing liquid emerging from an elongated orifice or from a row of circular oriiices, but diliiculty has been encountered in maintaining a satisfactorily uniform disstribution along the extent of an elongated orifice or among the several orifices arranged in a row. Such difficulty arises at least in part from the fact that the low rate at which a liquid can be electrostaticaily atomized necessitates orifices of small cross-sectional area and low rates of flow through such orifices, and clogging of the orifices therefore occurs frequently.
It has likewise been proposed to atomize a liquid from the edge of a free-surfaced supportedl liquid film, but the uniform distribution of liquid required to maintain such a film involves difficulties of much the same type as those mentioned above. A single feed nozzle reciprocating along a film supporting surface parallel to the film-edge from which atomization takes place, may satisfactorily eliminate the danger of clogging; but in many instances it is difficult to move such a nozzle in a manner which will result in a uniform distribution of liquid in the film. The dwell of such a nozzle at the opposite ends of its reciprocating path causes eX- cess material to be delivered to those portions of the film-supporting surface opposite such ends. Further, the stopping of a reciprocating structure may jar the entire atomizer and thus cause ripples or concentrations of material in the film which results in non uniform atomization.
One object of the elongated spray formly dispersed.
A further object of the present invention is to provide novel electrostatic atomizing apparatus in which liquid is supplied uniformly without undesirable ripples and concentrations.
Another object of the present invention is to provide novel electrostatic atomizing apparatus which is simple in construction, the liquid passages of which may be maintained relatively free of obstructions and which combines the liquid distributing means and the liquid atomizing means in a unitary structure.
Other objects and advantages will become apparent in the following description and from the accompanying drawings in which:
Fig. l is an isometric view trating an electrostatic atomizer;
Fig. 2 is an isometric View partly in section illustrating another form of electrostatic atomizer;
Figs. 3, 4, 5 and 6 are schematic developments illustrating different types of ducts in both the discharge member and the distributing member and different arrangements of these ducts relative to each other;
Fig. 7 is an end elevation View and Fig. 8 is a side view partly in section illustrating different applications of the electrostatic atomizer.
In practicing my invention, there is provided a discharge member, a source of liquid and a distributing member for transferring the liquid from the liquid source to the discharge member for atomization therefrom.
The discharge member may include a duct 0r series of ducts and a discharge portion for receiving liqpresent invention is to produce an pattern in which the particles are unipartly in section illusa4 uid from the duct or ducts and presenting it to anatomizing electrostatic field. Desirably a liquid supporting surface is provided between the duct or ducts and the discharge portion so that the liquid will flow to the site of atomization as a supported free-surfaced film.
The distributing member is movably mounted adjacent the discharge member and, may be in the form of a rotor provided with a duct or series of ducts extending along a line preferably helical in form at the surface of the rotor. The duct or ducts in the rotor are operatively associated with the liquid source and upon the rotation of the rotor, the duct or ducts of the rotor are brought into registry with the duct or ducts of the discharge member to form a port or ports of liquid discharge whereby the liquid is transferred to the discharge portion where it is presented to an electrostatie field for atomization thereby.
Now referring to the drawings and more particularly to Fig. l, there is shown one embodiment of an electrostatic atomizer it), constructed in accordance with my invention. This atomizer 10 comprises a discharge member 12, a distributing member 14, a motor 16 and a high voltage source 18.
lne discharge member 12, as shown, is generally cylindrical in shape and is provided with an elongated internal cavity 2t), a duct 22 in the form of an elongated slot communicating with this cavity, and a liquid supporting surface 24 aligned with the lower wall of the slot 22 and extendingl out-wardly and terminating in an elongated discharge portion 26, which is shown as a narrow edge. The opposite ends of the discharge member 12 are closed by sealed bearing plates 28 and 3f). Discharge member 12 is adapted to be supported in any desired position by a suitable insulating structure which is not shown in Fig. l but one example of which is shown as '766 in Fig. 7. The discharge member 12 is connected to the ungrounded terminal of the high voltage source 13 by a conductor 32 for establisning a high gradient electrostatic field adjacent the edge 26.
'lhe distributing member 14, which in this embodiment is shown as an elongated rotor, is provided with an axial liquid passage 34, and one or more radial holes 36 of circular cross-section communicating with the passage 34 and opening into an elongated helical groove 3S on the outer surface of the rotor. At least adjacent the slot 22, the outer surface of the rotor and the inner surface of the cavity 2f) interengage in sealing relation, so that the liquid transfer to the discharge member 12 is limited only to the port of liquid discharge which is formed by the intersection of the slot 22 and the groove 3S. The rotor 14 is rotatably mounted in the bearing plates 23 and 3f? and is driven by an air motor 16 through worm 42 and worm wheel 44. The air motor is mounted on bracket 46 which is affixed to bearing plate 23 and is provided with compressed air from a suitable source through exible insulating pipe 48. Liquid is supplied to the atomizer 10 from a suitable source through a flexible insulated hose 5@ which feeds the liquid directly to the liquid passage 34 which extends through plate 30. Pressure for moving the liquid may be obtained by means of a pump, by means of air pressure within a liquid storage tank or by gravity.
In operation of the insulated atomizer 1b, the discharge member 12 is connected to the high voltage source 1S for establishing adjacent the discharge edge 26 a field of high potential gradient, the rotor 14 is rotated by the motor 16, and liquid is supplied to the rotor through the pipe 56. Assuming the rotor 14 is rotated in a clockwise direction when viewed from the left side of the drawing, the port of liquid discharge formed by the intersection of the slot 22 and the groove 38 moves at a uniform speed from right to left along,
the liquid supporting surface 24. By the time the port of liquid discharge has nished its sweep from right to left for transferring liquid to the liquid supporting surface 24 of the discharge member, the rotation of the rotor has brought the right end of the groove 38 into registry with the right end of slot 22 to form another port of 3 liquid discharge to sweep from right to left along the liquid supporting surface as the rotor continues to rotate. It will thus be seen that as the rotor is rotating, liquid will be transferred uniformly to the liquid supporting surface 24 of the discharge member progressively along its entire extent. The discharge member is arranged so that liquid supporting surface 24 is inclined downwardly toward the discharge edge 26 to permit the liquid to flow over it to the discharge edge 26 from where it is electrostatically atomized and dispersed into space by the high gradient field adjacent to the edge 26. The atomized liquid may be utilized for any desired purpose. Two such purposes are described in connection with Figs. 7 and 8 which illustrate coating apparatus and air treating apparatus, respectively.
The volume of liquid delivered by the atomizer per unit of time may be regulated by providing suitable mechanism for controlling the rate of liquid supply from the pipe to the atomizer. The constancy of the supply of the liquid to the discharge edge is effected by the repetition rate of traversal of the port of liquid discharge along the extent of the liquid supporting surface 24.
In general, the constancy of supply of liquid to the atomizing edge 26 of the discharge member 12 has a tendency of improving as the repetition rate of traversal of the port of liquid discharge is increased. Rates in the neighborhood of one or two traversals per second are considered adequate; however, these rates are not critical. The repetition rate of traversal of port of liquid discharge may be increased by increasing the speed of the rotor 14, by increasing the number of grooves 38 in the surface of the rotor, or by increasing both the speed of the rotor and the number of grooves 33 on the rotor. For optimum uniformity of liquid distribution with a rotor having a plurality of grooves, such grooves should be so arranged that upon completion of traversal of the port of liquid discharge formed by the registry of one groove with the slot 22, simultaneously another port of liquid discharge is formed by the registry of the immediately succeeding groove with the opposite end of the slot to make the next complete traversal. in most instances, it is not desirable to use rotors with a groove the pitch of which is such that it makes more than one revolution around the rotor from end to end. When a groove occupying more than one revolution is brought into registry with the slot in the discharge member, it forms simultaneously multiple, parallel ports of liquid discharge. It is diflicult to maintain equality'of liquid impedance in such parallel ports of liquid discharge, and without equal liquid impedance in each such port of liquid discharge it is diflcult to obtain an even distribution of liquid.
The electrostatic atomizer shown in Fig. 2 is another embodiment of an atomizer constructed in accordance with my invention. In this embodiment, atomizer 216 comprises discharge member 212 and distributing member 214 which is in the form of a rotor. The discharge member 212 is similar in construction to the discharge member 12 illustrated in Fig. l except that additionally it is provided with a liquid passage 221 which is supplied with liquid in any suitable manner from a source (not shown). This passage 221 extends along cavity 22@ of discharge member 212 and diametrically opposite to slot 222 of this discharge member. The rotor 214 is similar to rotor 14 illustrated in Fig. l except that the radial duct 36 and axial liquid passage 34 are omitted.
In the operation of the atomizer 210, liquid is fed to passage 221 from a suitable source. Upon the rotation of the rotor 214 in a clockwise direction as viewed from the left hand side of the drawing, one portion of the groove 232i is brought into registry with the liquid passage 221 and another portion of the same groove 238 is brought into registry with the slot 222 for transferring liquid from the passage 221 to the slot 222 from Where it is distributed on the liquid supporting surface 224 for liow in the forni of a thin lilm to the discharge edge 226, where it is electrostatically atomized. Reference is made to the application of Edwin M. Ransburg, et al. Serial No. 155,802, tiled April 14, 1950, which claims specific features of an atomizer which has some of the features of the atomizer illustrated in Fig. 2 and which has just been described. The broader aspects of that atomizer are within the scope of my invention and are being claimed herein.
The atomizers heretofore described may vary in the type of ducts formed in both the discharge member an liquid supply line.
4 the rotor and the relative arrangement of the ducts in the discharge member and the rotor. Referring to Figs. 3-6 inclusive, there are illustrated schematic developments embodying different types of ducts in both the discharge member and the rotor and different possible arrangements of these ducts relative to each other. ln these ligures, the duct or ducts of the discharge member are shown in full lines as extending horizontally and the duct or ducts of the rotor are shown in dotted lines, their oblique arrangements in the development reflecting their helical distribution in the rotor surface.
`Fig. 3 shows the duct arrangement previously described, the duct in the discharge member being au axially extending slot 322, and the duct in the rotor being the helical groove 338. The angle between groove 33S and slot 322 depends on the pitch of groove 33S. As the rotor surface is moved downwardly (which corresponds to clockwise movement) the point of registry (indicated by stippling) of the groove 33S with the slot 322 shifts transversely from right to left during the movement of the rotor.
Fig. 4 also shows the discharge member duct as an elongated slot 422, while the rotor is provided with a series of radial ducts 438 of circular cross-section distributed helically and appearing in the development in a line at an angle to the slot 422. As the rotor surface is moved downwardly, different successive ducts 438 from right to left are brought into registry with the slot 422 to iorm a shifting port of liquid discharge.
Fig. 5 shows the discharge member as provided with a series of ducts 522 of circular cross-section distributed in a horizontal line and the rotor as provided with an elongated groove 538 at an angle to the horizontally arranged ducts 522. As the rotor surface is moved downwardly, different portions of the groove 53S are brought into registry with different successive ducts 522 from right to left to form a shifting port of liquid discharge.
Fig. 6 shows the discharge member as provided with a series of ducts 622 of circular cross-section distributed in a horizontal line and the rotor as provided with a series of ducts 63S of circular cross-section of the same size as that of ducts 622 and distributed in a line at an angle to the horizontally distributed ducts 622. As the rotor surface is moved downwardly, different successive ducts 638 from right to left are brought into registery with corresponding successive ducts 622 from right to left to form a shifting port of liquid discharge with each registry of corresponding ducts 622 and 638.
Fig. 7 illustrates a manner in which the atomizers previously described may be utilized in coating apparatus. In this apparatus, the articles 76@ on supports 762 are moved by means of conveyor '764 over a predetermined path and in spaced relation to the atomizer l0 suitably supported on bracket 766 made of insulating material.
ln operation, liquid is distributed in the form of a iilm to the discharge edge 26. Under the influence of the high potential gradient which exists at the discharge edge the liquid is atomized to form a cloud of iinely divided charged particles in front of the atomizer. The articles to be coated being grounded as through the conveyor 764 or otherwise maintained at a potential different from that of the charged particles, will attract the particles to their surface where they will deposit it to form a protective or decorative coating.
Fig. 8 illustrates the utilization of the atomizer 21u for treating air. There is shown a conduit S60 through which air is forced in the direction of the arrows. The atomizer 21.6 is suitably mounted and electrically connected to the high voltage source to discharge into the conduit 863 an atomized spray of liquid, for example, a bactericide for treating air moving therethrough.
The liquid used in the atomizers may be either of an electrical insulating or an electrical conducting character. The degree of conductivity of the liquid material determines how great the electrical losses will be along the lf the liquid material has high conducting properties the entire liquid supply system must be insulated. If, however, liquid material has good insulating properties, it may be only necessary to insulate the atomizer itself. Y
Where the liquid has good insulating properties, the atomizer should be of conducting material. However, most liquids are sufliciently conductive that if the atomizer is made of insulating material the necessary potential gradient will still be established at the discharge edge by virtue of the conductivity -of the liquid.
While the present invention isof course, not restricted to the design of any particular atomizer or to any particular use of the atomizer, satisfactory results may be obtained in coating sheet steel plates 16 inches wide by apparatus illustrated in Fig. 7 and constructed-and arranged in accordance with the following conditions:
Cavity 20 1 Slot 22 Supporting surface 24 horizontal. Diameter of hole 36 1A; inch. l Groove 38 l inch deep, 1/s inch wide, l5
inch pitch', and one full turn. Spacing between edge 26 8 inches.
and article 760. Potential of discharge 100,000 volts (negative).
member 12. Rate of rotation of distrib- 2 revolutions per second.
uting member 14. Liquid coating material Synthetic enamel, modified urea formaldehyde 20 secs. viscosity Zahn No. 2 cup, 75 degrees F.
In coating, either the atomizer or the article can be grounded or both may be maintained at potentials different from ground; but, in most instances, it will be more convenient to ground the article. However, any arrangement which results in maintaining a potential difference between the article and the coating material and which attracts the coating material to the article will be satisfactory.
Any atomizer embodying my invention can be used otherwise than in the application of liquid coatings. In such other uses, atomizer may be supported spaced and insulated from grounded objects and connected to one terminal of a high-voltage source whose other terminal is grounded. In such use, it is unnecessary to provide any electrode (analogous to the articles in a coating process) in spaced relation to the atomizer and of opposite electrical polarity thereto. By providing such an opposed electrode, however, and raising it to a suicient potential, atomization can be effected even with the atomizer grounded.
From the foregoing, it will be evident that the present invention provides a novel means for distributing liquid uniformly and under controlled conditions for electrostatic atomization. The apparatus is simple in construction and may be easily cleaned and maintained in an operative condition.
What I claim is:
1. In an electrostatic atomizer, a discharge member, a distributing member, means for supplying liquid to said distributing member, said members having interengaging sealing surfaces, said distributing member being movable to cause its sealing surface to move over the sealing surface of the discharge member, means for so moving the distributing member, said distributing and discharge members respectively having inner and outer liquid-conveying ducts opening into the respective sealing surfaces for registry with each other, the openings of the inner and outer ducts being distributed in their respective surfaces along lines making different angles with the direction of relative motion of such surfaces, whereby the position at which the inner and outer ducts register will shift transversely to the direction of relative motion of said sealing surfaces as said distributing member moves, and means for creating an electrostatic field for electrostatically atomizing the liquid supplied to said discharge member.
2. The invention set forth in claim 1 with the addition that said discharge member being provided with a cylindrical cavity, said distributing member being cylindrical and received in such cavity.
Rounded at its edge to a radiusa discharge member supporting surface and toward said discharge portion,
a distributing member mounted adjacent to said discharge member in closing relation to said apertures and having at least one helical peripheral groove movable successively into' registry with each of said apertures, means for driving said distributing member, said groove being a conduit for conveying liquid to said apertures for distribution along said discharge portion and means including a high voltage source for establishing a field of sufficient potential gradient adjacent the liquid on said discharge portion to atomize liquid therefrom.
4.` In an electrostatic atomizer, a discharge member provided withl an elongated discharge portion,` a slot spaced from and extending longitudinally of said discharge portion and a liquid supporting surface between said discharge portion and said slot, a liquid distributing member mounted adjacent said discharge member in closing relation to said slot and having a helical groove along its peripheral' surface, different portions of which are adapted to move successively into registry with said slot, means for driving said liquid distributing member, said groove being a conduit for conveying liquid to said slot for distribution to said discharge portion, and means including a high voltage source for establishing a field of sufficient potential gradient adjacent the lfiquid on said discharge portion to atomize liquid thererom.
5. In an electrostatic atomizer, a discharge member provided with an elongated discharge portion, a slot spaced from and extending longitudinally of said discharge portion and a liquid supporting surface between said discharge portion and said slot, a liquid distributing member mounted adjacent said discharge member in closing relation to said slot, said distributing member having a plurality of apertures arranged longitudinally thereof and being adapted to be moved successively into registry with said slot, means for driving said distributing member, said apertures being conduits for conveying liquid to successive points along said slot for distribution to said discharge portion, and means including a high voltage source of establishing a eld of sufficient potential gradient adjacent the liquid on said discharge portion to atomize liquid therefrom.
6. In an electrostatic atomizer, an elongated discharge member, means for feeding liquid to said discharge member to maintain thereon a body of liquid extending continuously in the direction of elongation of said member, said feeding means including a cylindrical distributing member, means supporting said distributing member contiguous and parallel to the discharge member, means for rotating the distributing member, and means including a high voltage source for establishing a field of sufficient potential gradient adjacent the extended liquid body on said discharge member to atomize the liquid therefrom.
7. In an electrostatic atomizer, an elongated discharge member, a liquid distributing member rotatable about an axis extending longitudinally of said discharge member, means for supplying liquid to said distributing member, said two members having liquid conveying passages co-operating in the rotation of said distributing member to feed the liquid progressively to points distributed along said discharge member, and means including a high voltage source for establishing a field of sufficient potential gradient adjacent the liquid on said discharge member to atomize the liquid therefrom, said discharge member being provided with a liquid supporting surface extending outwardly from said distributing member and terminating in a discharge portion, said liquid supporting surface being arranged to permit the liquid received thereon to flow to said discharge portion in the form of a thin film.
8. In an electrostatic apparatus for atomizing liquid under the influence of a field of high potential gradient, an extended discharge member, a distributing member rotatable about an axis generally longitudinal of said discharge member, said members having inter-engaging sealing surfaces, means for supplying liquid to said distributing member, said distributing member being rotatable about its axis to move its sealing surface over surface, terminating..
the sealing surface of the discharge member, means for so rotating the distributing member, said distributing and discharge members having liquid-conveying ducts opening into their respective sealing surfaces for registry with each other, the openings of said ducts being distributed on their respective surfaces along intersecting lines for transferring liquid from the distributing member to the discharge member, whereby the point of intersection of said lines will shift axially of the distributing member as such member rotates, said discharge member having a blade-like liquid supporting element terminating in an extended discharge portion, said liquid supporting element being positioned and arranged to receive liquid discharged from the registering ducts and to spread such liquid into an extended thin ilm liowing to the discharge portion for atomization, and means including a high voltage source for maintaining said discharge portion as one terminus of an electrostatic field.
9. In an electrostatic apparatus for atomizing liquid material, an elongated lip-like discharge member, means for maintaining on said discharge member a thin film of liquid extending in the direction of elongation of said discharge member, said means including a cylindrical feed member mounted for rotation about its longitudinal axis lying parallel to the extent of said discharge member for supplying liquid to said elongated discharge member, and means including a high voltage source for 8 establishing the liquid on said discharge member as one terminus of an electrostatic iield of suiiicient potential gradient to electrostatically atomize and disperse the liquid into a spray.
10. The apparatus of claim 6 including means for conveying a plurality of articles past and in spaced relationship to said discharge member, and means connected to said conveying means to maintain an article carried by said conveying means at an electrical potential to attract and cause the deposition thereon of liquid atomized from said body.
11. The apparatus of claim 6 including a support position in spaced relationship to said discharge member, said support being adapted to support an article to be coated and means connected to said support to maintain an article on said support at an electrical potential to attract and cause the deposition thereon of liquid atomized from said body.
References Cited in the le of this patent UNITED STATES PATENTS Number Name Date 1,191,483 Thomas July 18, 1916 1,410,312 Huffman Mar. 21, 1922 2,109,333 Formhals Feb. 22, 1938 2,290,790 Yeomans July 2l, 1942 2,302,185 Campbell Nov. 17, 1942
|Cited Patent||Filing date||Publication date||Applicant||Title|
|US1191483 *||Aug 8, 1914||Jul 18, 1916||Carl C Thomas||Fluid-distributing device.|
|US1410312 *||Mar 16, 1920||Mar 21, 1922||Mike Huffman||Steam-boiler clean-out device|
|US2109333 *||Aug 15, 1936||Feb 22, 1938||Richard Schreiber Gastell||Artificial fiber construction|
|US2290790 *||Aug 31, 1938||Jul 21, 1942||Yeomans Lucien I||Method of distributing fluid in accurately measured quantities|
|US2302185 *||Jul 27, 1940||Nov 17, 1942||Union Oil Co||Electrified spray apparatus|
|Citing Patent||Filing date||Publication date||Applicant||Title|
|US2759763 *||Jul 22, 1952||Aug 21, 1956||Ransburg Electro Coating Corp||Spray coating apparatus and method|
|US2796146 *||Nov 13, 1952||Jun 18, 1957||Hersey||Scanning jet for filters|
|US2827394 *||May 9, 1955||Mar 18, 1958||Sherman Floyd A||Method and apparatus for electrostatically coating articles|
|US2860599 *||Aug 13, 1954||Nov 18, 1958||Binks Mfg Co||Electrostatic coating device with restricted fluid passageway opening adjacent sharpdischarge edge|
|US2869510 *||Jul 29, 1953||Jan 20, 1959||Licentia Gmbh||Electrostatic coating apparatus utilizing overflow means to facilitate constant level|
|US2961581 *||Feb 14, 1955||Nov 22, 1960||Schweitzer Electrostatic Compa||Electrostatic coating means and apparatus|
|US3024132 *||Aug 11, 1955||Mar 6, 1962||Gen Motors Corp||Method and apparatus for electrostatic spraying|
|US3136324 *||Feb 8, 1963||Jun 9, 1964||Thomas Hill Engineering Compan||Container rinsing apparatus|
|US3146953 *||Jun 4, 1963||Sep 1, 1964||Josef Komanns Heinrich||Spray spout for use in a dishwashing machine|
|US3398892 *||Oct 26, 1966||Aug 27, 1968||Ransburg Electro Coating Corp||Electrostatic coating apparatus|
|US3472165 *||Mar 28, 1963||Oct 14, 1969||Us Air Force||Warhead|
|US3486483 *||Aug 23, 1968||Dec 30, 1969||Mangnall Derek||Electrostatic spray coating apparatus|
|US3776181 *||Jul 28, 1972||Dec 4, 1973||Ransburg Electro Coating Corp||Deposition apparatus for an organometallic material|
|US3776187 *||May 3, 1972||Dec 4, 1973||Ransburg Electro Coating Corp||Electrostatic deposition apparatus|
|US3880357 *||May 23, 1974||Apr 29, 1975||Baisch Stephen J||Oscillating shower head|
|US4150512 *||Aug 29, 1977||Apr 24, 1979||Novak Walter M||Apparatus for cleaning moving abrasive members|
|US4475688 *||Sep 27, 1982||Oct 9, 1984||Hodges James L||Artificial snow making|
|US4830872 *||Aug 20, 1986||May 16, 1989||Sale Tilney Technology Plc||Electrostatic coating blade and method of applying a thin layer of liquid therewith onto an object|
|US4846407 *||Apr 21, 1987||Jul 11, 1989||Imperial Chemical Industries Plc||Electrostatic spraying apparatus|
|US5162193 *||Nov 19, 1990||Nov 10, 1992||Du Pont-Howson Limited||Radiation sensitive devices|
|US5326598 *||Oct 2, 1992||Jul 5, 1994||Minnesota Mining And Manufacturing Company||Electrospray coating apparatus and process utilizing precise control of filament and mist generation|
|US5582742 *||Sep 5, 1995||Dec 10, 1996||Ketema, Inc.||Rotary distribution pipe assembly|
|US5607110 *||Dec 14, 1994||Mar 4, 1997||Heidelberger Druckmaschinen Ag||Device for discharging blowing air|
|US6012657 *||Oct 3, 1997||Jan 11, 2000||Nordson Corporation||Powder spray head for fan-like patterns|
|US6579574||Apr 24, 2001||Jun 17, 2003||3M Innovative Properties Company||Variable electrostatic spray coating apparatus and method|
|US6645569||Jan 30, 2002||Nov 11, 2003||The Procter & Gamble Company||Method of applying nanoparticles|
|US6863933||Jan 30, 2002||Mar 8, 2005||The Procter And Gamble Company||Method of hydrophilizing materials|
|US6872444||Jan 30, 2002||Mar 29, 2005||The Procter & Gamble Company||Enhancement of color on surfaces|
|US6969540||Apr 1, 2004||Nov 29, 2005||3M Innovative Properties Company||Electrostatic spray coating apparatus and method|
|US7845307 *||Mar 31, 2005||Dec 7, 2010||Wladimir Janssen||Efficient and flexible multi spray electrostatic deposition system|
|US20020192360 *||Apr 24, 2001||Dec 19, 2002||3M Innovative Properties Company||Electrostatic spray coating apparatus and method|
|US20020192366 *||Jan 30, 2002||Dec 19, 2002||Cramer Ronald Dean||Method of hydrophilizing materials|
|US20040052957 *||Sep 16, 2003||Mar 18, 2004||Cramer Ronald Dean||Method of applying nanoparticles|
|US20040185180 *||Apr 1, 2004||Sep 23, 2004||3M Innovative Properties Company||Electrostatic spray coating apparatus and method|
|US20080067269 *||Mar 31, 2005||Mar 20, 2008||Wladimir Janssen||Efficient and Flexible Multi Spray Electrostatic System|
|DE1145967B *||Dec 5, 1956||Mar 21, 1963||Licentia Gmbh||Elektrostatische Sprueheinrichtung|
|DE1209026B *||Aug 10, 1956||Jan 13, 1966||Gen Motors Corp||Spritzkopf fuer Vorrichtungen zum elektrostatischen Farbspritzen|
|EP0216502A1 *||Aug 20, 1986||Apr 1, 1987||Sale Tilney Technology Plc||Electrostatic coating blade and method of electrostatic spraying|
|EP0250102A2 *||May 21, 1987||Dec 23, 1987||Imperial Chemical Industries Plc||Apparatus and process for spraying|
|EP0250102A3 *||May 21, 1987||Nov 30, 1988||Imperial Chemical Industries Plc||Apparatus and process for spraying|
|EP0250164A2 *||Jun 11, 1987||Dec 23, 1987||Imperial Chemical Industries Plc||Apparatus and process for producing powders and other granular materials|
|EP0250164A3 *||Jun 11, 1987||Nov 23, 1988||Imperial Chemical Industries Plc||Apparatus and process for producing powders and other granular materials|
|EP1059122A1||Jun 7, 1999||Dec 13, 2000||THE PROCTER & GAMBLE COMPANY||A spray device with flat fan nozzle|
|WO1984001524A1 *||Oct 21, 1983||Apr 26, 1984||Sale Tilney Technology Plc||Blades for electrostatic coating, apparatuses incorporating such blades and processes using such blades|
|WO1999051354A1||Apr 7, 1999||Oct 14, 1999||The Procter & Gamble Company||A packaged product|
|WO2005095001A1||Mar 31, 2005||Oct 13, 2005||Wladimir Janssen||Efficient and flexible multi spray electrostatic deposition system|
|U.S. Classification||118/626, 239/690, 239/263.1, 239/380, 239/597, 239/590.5, 361/228|
|International Classification||B05B3/14, B05B5/025, B05B5/08, B05B3/00, B05B5/057|
|Cooperative Classification||B05B5/08, B05B5/057, B05B3/14|
|European Classification||B05B5/057, B05B5/08, B05B3/14|