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Publication numberUS2754225 A
Publication typeGrant
Publication dateJul 10, 1956
Filing dateNov 18, 1952
Priority dateNov 22, 1951
Publication numberUS 2754225 A, US 2754225A, US-A-2754225, US2754225 A, US2754225A
InventorsFritz Gfeller
Original AssigneeMartin Von Schulthess
Export CitationBiBTeX, EndNote, RefMan
External Links: USPTO, USPTO Assignment, Espacenet
Method of spray-coating with metals
US 2754225 A
Abstract  available in
Images(2)
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Claims  available in
Description  (OCR text may contain errors)

July 10, 1956 GFELLER 2,754,225

METHOD OF SPRAY-COATING WITH METALS Filed Nov. 18, 1952 2 Sheets-Sheet 1 Q grwmtcm July 10, 1956 F. GFELLER 2,754,225 METHOD OF SPRAY-COATING WITH METALS Filed Nov. 18, 1952 2 Sheets-Sheet 2 W01? MECE INVENTOR [6/72 GFfZ/E/Y BY 9 JW 7 914mg,

ATTORNEKF llnited States Patent Fritz Gfeller,

Zurich, Switzerland, assignor to Martin Von Schulthess, Zurich, Switzerland Application November 18, 1952, Serial No. 321,151

Claims priority, application Switzerland November 22, 1951 3 Claims. (Cl. 117-93) This invention relates to a method of spray-coating with metals and particularly to a simultaneous bonding of the sprayed metal particles with each other and with the surface to be sprayed, by the additional use of electrical energy.

The metal spray-coating methods known to the art have the disadvantage that the coating formed by these methods is composed of individual particles of varied magnitude which are bonded with each other and with the surface to be coated only by surface contact. Such a bonding of the particles results in insuflicient strength and density of the coating, which is spongy in texture and nonhomogeneous and can relatively easily be peeled from the surface. Furthermore, the output of these methods of metal spray-coating known to the art, which derive the energy for melting the metal wire exclusively from the exothermic reaction of the burning gases, is insuflicient and results in coatings which are unsatisfactory from the point of view of both quantity as well as quality, particularly in the case of metals having a high melting point.

The above-mentioned disadvantages are overcome by the method in accordance with the present invention by producing and discharging at least one electric field within the space between the point of the wire, which protrudes from the spray gun, and the surface of the body to be spray-coated. The electric field thus created acts in such a manner that by means of its discharge the protruding point of the wire, the surface to be spray-coated and the stream of atomized metal therebetween are furnished with substantial additional heat; the melting and the atomizing of the metal wire is thus increased and accelerated to a considerable degree, and the individual particles of metal against the surface to be coated are intimately bonded with each other and with the surface itself.

The method of spray-coating in accordance with the invention superimposes an electro-thermal action upon the known merino-chemical action of metal spray-coating with burning gases. The latter method serves to melt, atomize and spray a metal upon a surface, whereas the superimposed electric field serves to increase the melting energy and subsequently to bond intimately the metal particles sprayed upon the surface with each other and with the surface itself. The two actions supplement each other, are a mutual prerequisite for each other, and together fulfill the task intended by the invention.

The exothermic reaction of the burning gases effects a melting or at least a glowing of the point of the protruding metal wire as well as a liberation of electrons whose number is still further increased by the electric effects on the glowing wire point. Because of the presence of these free electrons, the burning gases become electrically conductive, so that through an increase of the potential of the electric field created in the region between the wire point and the surface to be coated up to the spark potential 21 self-discharge can be brought about. However, it is not essential to increase the potential of the electric circuit to the discharge point; it has proven to be more suitable to superimpose upon a main circuit of high current intensity and relatively low potential a second circuit Whose function is to cause and maintain a self-conductivity and self-discharge of the primary circuit and to furnish additional energy for ionization and for the increase of posi tive heat generation. For this secondary circuit a current of high potential and high frequency, but low amperage is suitable. The primary circuit as well as the secondary circuit can be connected on one hand to the metal wire point and on the other hand to the surface to be sprayed, both of which function as electrodes. However, the secondary circuit can also be connected at both poles with other electrodes in the space between the wire point and the surface to be sprayed. Depending upon the desired output or quality of the spray-coating to be produced, only the secondary circuit can be employed.

In addition to the two circuits mentioned above, it has proven suitable in some cases to provide sparks from a spark plug or similar luminous electrical discharges in the stream of gases or in the metal spray, which furnish additional energy on their part.

in addition to the electrons which, as indicated above, are liberated by the thermochemical reaction, additional free electrons are generated by the discharge of the abovementioned electrical circuits. These additional free electrons are generated through impact ionization. Through the electron bombardment of this impact ionization the protruding wire point, the surface to be spray-coated and the space therebetween are subjected to a very strong heating action over and above that furnished by the chemical combustion reaction of the gases. Only the sum of the heat energies furnished by the chemical and the electrical actions makes it possible to melt metal wires of all types, even those having a high melting point, and at the same time to obtain a high output capacity as well as a high atomizing effect and an intimate bonding of the metal particles with each other and with the surface to be coated.

The means for progressively advancing the metal wire is suitably coupled to the regulating means for the electric circuits so that they mutually adjust themselves automatically to the prevailing conditions. Thus, the driving by the circuits which create the electric fields. This mechanism controls the advance of the metal Wire depending upon the amount of current flowing in the electric field circuits.

The ionization of the gases can be additionally increased by admixing ionizing materials with the combustion gases, or by jacketing the metal wire with a material having an ionizing effect upon the gases, or by providing the ionizing material in the core of the metal wire. The ionizing material consists, for example, of alloys of alkali metals or alkali earth metals. However, certain elements may also be attached to the spray gun itself where they are caused to glow and emit electrons. For example, the point and the jacket of the jet nozzle through which the combustion gases are expelled are made of these ionizing elements, or these elements are coated with ionizing compounds which ionize when they are resistance heated to red heat, such as barium-oxide or thorium oxide.

Another method of further ionizing the gases ernergin from the spray gun consists of subjecting them to ionizin light, such as ultraviolet rays.

To summarize then, the method of spray-coating with metals in accordance with the invention consists of causing the chemical, electro-chemical and electric factors listed below to act together so that the respective amounts of energy created supplement each other, in order to elfect the melting and atomizing of the spray material in the most eflicient manner, and to cause to be intimately bonded with each the surface to be coated.

l. The exothermic reaction of the burning gases with its positive heat generation.

2. The ionization of the gases and the liberation of electrons by the chemical combustion process.

3. The thermo-electric effect of the glowing wire point and the additional emission of electrons thus created.

4. The impact ionization of the electric discharges of the superimposed circuits and the liberation of electrons caused by them through chain reaction.

5. The arrangement of electric ignition devices or electric arcs in the streamof gases or in the spray, such as ignition sparks from a spark plug or an electric arc between similar electrodes.

6. Additional ionization through:

a. Admixture ofionizing materials to gases.

b. The use of a jacket wire or an internal core within the wire, where the jacket or core material contains ionizing materials.

c. Heating of special elements to red heat, which elements are disposed within the spray gun for additional ionization at red heat.

d. Coating of such elements with ionizing materials.

e. subjecting the gas stream emerging from the spray gun to the rays of ionizing light for additional ionization.

7. The electricdischarge of the primary circuit at high amperage in the space between the point of the metal wire and the surface to be coated, which space is ionized by the above means and charged with free electrons.

In order to further facilitate the intimate bonding of the metal particles with each other and with the surface to be coated, and in order to impart special properties to the spray coating it has been found to be advantageous to admix alloy-forming substances with the metal spray by providing the metal wire, for instance, with a jacket or an internal core which contains such substances, for example, as metal carbonyls.

It has also been found that the intimate bonding of the metal particles with each other and with the surface to be coated is considerably improved by adding oxygenremoving substances. Such substances, for examplerferrotitanium-aluminum mixtures, are added to the jacket, or the internal core of the metal wire.

The attached drawing represents a preferred embodiment of the apparatus in accordance with the invention.

Fig. 1 is a longitudinal section through the spray gun and shows the necessary auxiliary attachments as well as the details of the spray gun as a whole.

Fig. 2 is a schematic representation of the manner in which a-second electric field is superimposed upon the metal spray.

Fig. 3 is a schematic diagram of a further variation of the present invention which shows how the secondary circuit is connected to electrodes other than the work piece and the spray gun. This figure shows in addition the arrangement of an ultraviolet light source, and the circuit connections for the automatic control means for the wire advancing mechanism, which are in turn connected and controlledbythe source which creates the electric field.

As an essential part of the apparatus the spray gun itself will be described first. it consists of a bell-shaped jacket 1 in theinterior of which the pear-shaped combustion chamher 2 is mounted. The combustion chamber 2 is made of steel and is mounted in jacket 1 so that between them three hollow spaces w, k and s are formed. The hollow space w is formed by a ring-shaped groove in spray nozzle 2c which forms a part of the combustion chamber 2. Space w is connected with space It through the spaces between the teeth of the toothed inner edge 21d of the ring-shaped groove. I However, the two hollow spaces]:

the sprayed particles other as well as with the combustion and s areseparated frorneach other by a ring-shapedsolid.

supporting rib 2 located on the outside of the combustion chamber. Immediately in front of the supporting rib 2f axial apertures 2g are provided in the wall of the combustion chamber which are evenly spaced about the circumference thereof and connect the space it with the combustion space T. Hollow space s and combustion space T are connected with one another by tangentially drilled apertures 2b in the shell of the combustion chamber; apertures 2b are also evenly spaced about the circumference of the chamber. Jacket ll also comprises two rearwardly directed sockets 1a and 112. Socket 1a allows spark plug 2 to be inserted therethrough and screwed into a threaded aperture in the wall of combustion chamber 2, as shown. Plug 14 renders the socket in gas tight and is made of insulating material. Contact screw 15 protrudes through plug 14 and serves to hold a spark plug lead-in wire C. Screw 15 is connected to the spark plug Z through spiral spring 13. Socket 1b, however, serves as a connecting socket for the fuel feed line B and comprises a bore 6 which leads into hollow space w. The fuel line 12 is connected to socket 1b by connecting stud 11. Cover 3, fastened to jacket 1 by bolts 3, forms an airtight closure of the mouth of the bell-shaped jacket. The cover 3 comprises a socket 30 with a conical seat for a guide tube 5, and an outside thread for flanged nut as well as a trumpet shaped funnel 3b with a spiral internal guide rib 3a. Funnel 3b protrudes forwardly into hollow space s and forms an additional hollow space 3. Guide tube 5, which serves to guide the wire electrode D therethrough is introduced from the rear through socket 3c in jacket cover 3, passes through the cylindrical portion 2e of combustion chamber 2, extends forwardly through space T, and its point protrudes into the opening at the exact'center of nozzle 2a. The guide tube 5, which is held by flanged nut 4 engaging flange 5b, and is pressed against the conical seat of guide socket 3c, comprises also radially disposed outlet apertures 5a which are located approximately equidistantfrom the front and rear ends of the guide tube. These outlet apertures connect hollow space m with hollow space 1. Guide tube 5 further comprises a smaller longitudinally arranged tube 6, whereby a hollow space it is formed. Central tube 7 is introduced from the rear through tube 6 and extends to the forward tip of guide tube 5 where it seals the'forward open end of guide tube 5 and forms an extension thereof, so that the wire electrode D, when introduced and pushed through central tube 7, passes through the longitudinal axis of the spray gun. At the rear of guide tube Sthere is a lateral bore 6:: with a conical fitting, which bore passes through guide tube 5 and tube 6 and leads into hollow space n. A compressed air line A is connected to thisrbore by suitable means, so as to render the connection airtight.

Behind the spray gun is the wire electrode advancing mechanism M which is attached to the spray gun rigidly or flexibly, as desired. This mechanism is here only schematically shown, and the arrow merely indicates the direction of rotationof the lower roller.

. The mechanism Q which furnishes the additional electrical energy for bonding the particles with each other and with the surface to be coated is connected to an alternating current line N and is shown here schematically as a direct current source. its negative terminal P is connected to connection it? of compressed air line A in such a manner that the point Di of wire electrode D acts as a cathodev The positive terminal R is connected to the schematically represented work piece Y, which in the present case is a cpnductive substance. The spray X of metallic, electricity/bearing particles emanating from metal pointDi and the electric field E are superimposed upon each other. .The metalcoating deposited upon the work piece Y is designated by L. v V

In operation, the spray gun functions as follows: .Compressed air enters through fitting it passes through annular space it longitudinally toward the tip of guide tube 5,. thence throu gli annular space m rearwardly to exhaust is ignited by spark plug Z. energy necessary to bond the metal particles deposited on work piece Y with each other as well as with the surface of the work piece is supplemented by the field created between the spray gun and the work piece. As the point atomized, the wire advancing mechanism M will automatically advance wire D through central tube 7 so as to maintain a constant fresh supply of metal.

In Fig. 2 the primary circuit of high frequency, low potential and high current intensity creates the primary field between the nozzle and the work piece, each of which act as an electrode. Superimposed upon this primary field is a secondary field which is generated by a high potential, high frequency, but low current circuit. The function of the secondary field is to cause and maintain the self-conductivity and self-discharge of the primary field, as well as to furnish additional heat energy.

In Fig. 3, the secondary field is created by two separate electrodes, While the primary field has as its elec trodes the spray gun and the work piece, Depending upon the desired output or the quality of the spray emerging from the nozzle of the spray gun and thus increase the effectiveness of the superimposed electric fields. The wire advancing mechanism is connected to the mechanism which creates the electric fields and field intensity.

It is to be understood that I do not wish to be bound by the particular structure of the spray gun disclosed herein. Any other type of spray gun functioning in substantially the same manner is equally suitable to carry out my invention.

Having now described my invention, what I claim is:

1. The method of spray-coating a surface with metal,

rent and low potential, and said secondary electric field generated by a circuit of high frequency, low cur rent and high potential.

2. The method of spray-coating a surface with metal,

a metal selected from the group consisting of barium and thorium.

3. A method of spray-coating a surface with metal, which comprises igniting a gaseous fuel in a combustion chamber, atomizing a heated metal wire with said gaseous References Cited in the file of this patent UNITED STATES PATENTS 1,139,291 Jenkins May 11, 1915 1,615,995 Muller Feb. 1, 1927 2,231,247 Bleakley Feb. 11, 1941 FOREIGN PATENTS 28,001 Great Britain of 1912 28,132 Great Britain of 1913 196,695 Great Britain of 1923 553,099 Great Britain of 1943

Patent Citations
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US1139291 *Dec 16, 1914May 11, 1915Charles Francis JenkinsCoating with fusible material.
US1615995 *Jan 24, 1924Feb 1, 1927Electroiuimica De Flix SocElectric arc for melting and pulverizing metals
US2231247 *Feb 12, 1936Feb 11, 1941Bleakley CorpMethod of forming composite metal structures
GB196695A * Title not available
GB553099A * Title not available
GB191228001A * Title not available
GB191328132A * Title not available
Referenced by
Citing PatentFiling datePublication dateApplicantTitle
US2939943 *Jun 23, 1955Jun 7, 1960Vac AnstaltProcess and device for vaporizing electrically conductive substances, preferably metals, in vacuo
US2953472 *Jan 15, 1958Sep 20, 1960Johan BjorkstenMethod of coating metallic articles with metal
US2990293 *Jan 13, 1956Jun 27, 1961Ohio Commw Eng CoMethod of impregnating and rustproofing metal articles
US3010009 *Sep 29, 1958Nov 21, 1961Plasmadyne CorpMethod and apparatus for uniting materials in a controlled medium
US3048498 *Jan 8, 1959Aug 7, 1962Ransburg Electro Coating CorpElectrostatic spray coating system
US3049301 *Dec 9, 1960Aug 14, 1962Escher Wyss GmbhElectrostatic spraying of atomized material
US3057046 *Nov 12, 1957Oct 9, 1962Maarschalk Handelscie N VMethod for the manufacture of metal bearings or bearing surfaces
US3064114 *Sep 8, 1960Nov 13, 1962British Oxygen Co LtdApparatus and process for spraying molten metal
US3075066 *Dec 3, 1957Jan 22, 1963Union Carbide CorpArticle of manufacture and method of making same
US3082516 *Dec 3, 1957Mar 26, 1963Union Carbide CorpFabrication of metal shapes
US3119707 *Mar 31, 1960Jan 28, 1964Space Technology Lab IncMethod for the deposition of thin films by electron deposition
US3131091 *Mar 8, 1960Apr 28, 1964Jones Harry SSpray gun having means to control heat concentration in metal substrate
US3140380 *Sep 8, 1961Jul 7, 1964Avco CorpDevice for coating substrates
US3317138 *Feb 24, 1964May 2, 1967Sames Sa De Machines ElectrostElectrostatic spraying apparatus
US3680779 *Oct 5, 1970Aug 1, 1972Oxy Dry Sprayer CorpMethod and apparatus for electrostatic spraying
US4004735 *Jun 3, 1975Jan 25, 1977Zverev AnatolyApparatus for detonating application of coatings
US4264641 *May 10, 1978Apr 28, 1981Phrasor Technology Inc.Electrohydrodynamic spraying to produce ultrafine particles
US4579282 *Jul 20, 1983Apr 1, 1986Stani Vyzkumny Ustav Ochrany Materialu G.V. AkimovaGas burner for wire fed metal-spraying pistol
US4954682 *May 1, 1989Sep 4, 1990Maneely-Illinois, Inc.Internal weld bead metallizing system and method
US4961973 *Mar 8, 1989Oct 9, 1990W. S. Molnar Co.Thermally applying a metallic spray coat from materials in a hollow wire filled with iron and alloys
US5136609 *Jul 27, 1990Aug 4, 1992Nippon Steel CorporationMethod of producing finely divided particles or powder, vapor or fine droplets, and apparatus therefor
Classifications
U.S. Classification427/449, 427/455, 239/13, 427/576, 219/76.1, 239/690, 427/422, 239/81, 239/3, 427/474, 118/726, 239/84, 219/76.17
International ClassificationB05B7/20, B05B5/025, B05B7/16, B05B5/03, C23C4/12, B05B7/22, B05B7/18
Cooperative ClassificationB05B5/032, B05B7/18, C23C4/124, B05B7/22, B05B7/203
European ClassificationB05B7/22, B05B7/20A1, B05B5/03A, C23C4/12D, B05B7/18