Search Images Maps Play YouTube News Gmail Drive More »
Sign in
Screen reader users: click this link for accessible mode. Accessible mode has the same essential features but works better with your reader.


  1. Advanced Patent Search
Publication numberUS2778743 A
Publication typeGrant
Publication dateJan 22, 1957
Filing dateNov 16, 1954
Priority dateNov 16, 1954
Publication numberUS 2778743 A, US 2778743A, US-A-2778743, US2778743 A, US2778743A
InventorsBrice M Bowman
Original AssigneeBell Telephone Labor Inc
Export CitationBiBTeX, EndNote, RefMan
External Links: USPTO, USPTO Assignment, Espacenet
Method of making electrical carbonfilm resistors
US 2778743 A
Abstract  available in
Previous page
Next page
Claims  available in
Description  (OCR text may contain errors)


NIT/P06 50,

N/ TRO GEN 5 A I! III III! 1! 3 v r. I

w m E NITROGEN mm, 5/ c/ HEL/UM NI/TROGEN FL USH United States Patent ME'I'HUD OF MAKING ELECTRICAL CARBON- FILM RESISTORS Brice M. Bowman, Erie, Pa., assignor to Bell Telephone Laboratories, Incorporated, New York, N. Y., a corporation of New York Application November 16, 1954, Serial No. 469,111

Claims. (Cl. 117-46) This invention relates to methods of depositing carbon films containing materials codeposited with carbon, and particularly to improvements in the method of making carbon-film resistors.

Because the inductive eflects and skin effects associated with wire-windings become increasingly troublesome in circuits carrying high-frequency currents, wire-wound resistors are often undesirable for use in such circuits. Although carbon-coated resistors are relatively free of these disadvantages of wire-wound resistors and may thus be preferred for high-frequency currents, they themselves often show larger temperature coefi'lcients of resistance than do metal windings. These thermal variations in resistance value may limit the carbon-film resistor to uses in which resistance fluctuation with temperature can be tolerated.

Resistors having boron codeposited with carbon in the film and the method of making such resistors are taught in United States Patent 2,671,735 issued March 9, 1954 to R. O. Grisdale, A. C. Pfister and G. K. Teal. The inclusion of boron in carbon films, as taught by the patent, greatly improves the temperature coefiicient of resistance of such films as compared with unmodified films of carbon alone.

The present invention, relating to the production of films in which silicon is codeposited with boron and carbon, renders carbon-film resistors even more useful and facilitates their production. While retaining or even decreasing the low thermal coefficients of resistance characteristic of the borocarbon films, the new films show increased adherence and coherence of the deposit, making them more stable to the adverse influences of heat, moisture and abrasion.

In the new method, vapors of volatile silicon and boron compounds are admixed with a carbonaceous gas and passed over a non-conducting base heated to a temperature sufficient to decompose the gaseous compounds. Upon decomposition, boron, carbon and silicon are left in a thin film on the non-conducting core, which can then be subsequently fashioned into a resistor.

In the accompanying drawings:

Fig. l is a front view, partly in section, of a suitable type of apparatus in which deposition may be accomplished; and

Fig. 2 is a front view, in section, of a portion of Fig. 1'

enlarged to show the detailed construction of the apparatus of Fig. l in the region of the reaction zone; and

Fig. 3 is a front view, partly in section, of a resistor made according to the present invention.

The apparatus shown in Fig. 1 is of a design which has given especially satisfactory film deposits. Substantially continuous lengths of the non-conducting core on which a film of silicon and borocarbon is to be deposited are fed downward through the upper aperture 11, descend through the apparatus through the guide tubes 12 and emerge covered with a film at the lower aperture 13. Mechanical means (not shown) are provided for moving the continuous core piece through the guide tubes 12 by.

Patented Jan. 22, 1957 pushing and pulling, with, generally, a rate of travel of the core through the apparatus between 6 inches per minute and 1 /2 inches per minute being maintained. The guide tubes 12 are mounted such that one end of each tube opposes, on a common vertical axis which is the longitudinal tube axis, an end of the other of the two tubes, a separation 18 of approximately 2 inches, measured along the common axis, being maintained between the open opposing ends of the tubes. Cross streams of an inert gas, conveniently nitrogen, are passed through the seal-fittings 14 at the extreme ends of the guide tubes. The gas flush and flexible rubber diaphragms, seated at the apertures 11 and 13 and punctured to permit the passage of the core piece through the apparatus, act to keep air from entering the guide tubes 12.

Other streams of inert gas, conveniently helium, are fed into the upper and lower guide tubes 12 at the points 15 and 16, respectively, in the diagram. These oppositely directed gas streams keep the coating. gases from entering the guide tubes 12, and escape at the break 18 in the guide tubes, merging there with the film-coating gases. It is at this axial break 18' that the core piece is exposed to the coating atmosphere and in this region deposition of the film takes place.

Water is led through cooling chambers 17 in the upper and lower portions of the apparatus. The chambers serve to confine heat to the portion of the apparatus between them; the lower chamber, in addition, functions to. cool the inert gas entering the inlet 16, which gas in turn then lowers the temperature of the filmed cores before they emerge at the aperture 13.

immediately beneath the reaction zone 18, and beginning at the upper end of the lower guide tube 12, a second tube 19 concentrically surrounds the lower of the two guide tubes. This second tube, conveniently 1 /4 inches in diameter, is connected to a gas line 20 through which carrier gas, preferably nitrogen, saturated with vapors of a boron compound and a silicon compound, preferably boron trichloride and silicon tetrachloride, is eventually led to the reaction zone 18.

Concentric with both the guide tubes 12 and the second duct 19 for reactants, there is a larger cylindrical jacket 21, conveniently having an outside diameter of 2 inches. The jacket 21 shields the reaction zone 18, and is sealed above and below the reaction zone around the tubes passing through it, but has an inlet 22 for the admission of a carbonaceous gas, preferably methane, and an outlet 23 for removing all excess and unreacted active components, inert carrier, diluent, and the gaseous decomposition products formed in the Zone 13.

Immediately surrounding the jacket 21 is a refractory furnace core 24 on which is wound electrical resistance wire 25. The furnace core 24 has, conveniently, an inside diameter of 2 inches, so that it fits snugly over the jacket 21. The surface of the furnace core 24 may be corrugated to hold the wire windings 25 in position. Current passed through the windings 25, which are preferably of a platinum-rhodium alloy, furnishes the heat required to bring the apparatus to a desired temperature.

The entire core 24 and windings 25 are embedded in a thermal insulating material 26, conveniently a granular refractory material, the Whole being then protected by a metal casing 27.

' In Fig. 2 is given a detailed view of that portion of the apparatus of Fig. 1 surrounding the deposition chamber 18. In Fig. 2 are shown the guide tubes 12, the concentric tube 19 for reactants and the inlet tube 20, the cylindrical jacket 21 and its corresponding inlet 22, the furnace core 24, resistance winding 25, the insulating sheath 26 and metal casing 27, and a portion of the lower cooling" chamber 17.

The guide tubes 12, reactant tube 19, and cylindrical awa ts jacket 21 are preferably made of a heat-resistant ceramic such 'as McDanel high-temperature combustion-tube porcelain. The furnace core is, similarly, composed of heat resistant ceramic, and an alundum material, such as Norton No. 8707 RA98, has proved convenient.

The resistor of Fig. 3 is made up of a non-conducting base 31, generally a ceramic composition, at the surface of which is deposited a layer 32 of carbon, boron, and silicon, as indicated. Metal terminals 33 are fastened to the end of the resistor to make electrical contact with the carbon layer. A thin metal film covering the portion of the carbon layer at which the metal terminals are applied may facilitate making electrical contact. In the resistor shown a helical groove 34 has been cut through the surface into the ceramic base to increase the length of the current path through the carbon layer.

In a preferred example, nitrogen has been used as a carrier gas, functioning to transport the vapors of volatile boron and silicon compounds to the reaction zone where they are decomposed and deposition occurs. Nitrogen does not interfere chemically in the proper thermal decomposition of the compounds which it carries, and other gases preferably having a similar property, such as argon, helium, carbon monoxide or hydrogen, can be used. If unreactive with the boron and silicon containing materials at ordinary temperatures, the carbonaceous gas needed in the deposition can also be employed as a carrier. As the presence of water vapor and oxidizing impurities such as oxygen may be detrimental to the formation of a suitable deposit, the carrier is preferably dried and oxygen removed. Admixture of small amounts of hydrogen and passage over a palladinized alumina catalyst has, for example, been used to convert oxygen as an impurity to water vapor. Water vapor itself may be removed by contact of the gas with a drying agent, and passage of the gas over calcium hydride, for example, has been successfully used as a drying step. Because nitrogen is readily available dry and with a high degree of purity, it is often used as a gaseous vehicle in the deposition process.

Any of the volatile boron compounds suggested in United States Patent 2,671,735, mentioned previously, may be used as the source of the boron ultimately deposited in the resistor film. Diborane, borane halides, boron trihalides, alkyl, aryl, and mixed alkyl-aryl borines, and borines in which one or more alkyl or aryl groups has been replaced by a halogen are suitable, as there suggested. Any boron compound capable of being introduced into the furnace may be employed, though r preferably the boron compound chosen should be volatile at temperatures low enough to render its vaporization a convenient process. Practical considerations dictate the use of a material which is non-corrosive to the apparatus or the base on which the deposit is to be laid.

The carbonaceous gases amenable to use in the deposition are usually gaseous or readily-volatizable paraffinic and aromatic hydrocarbons, such as methane, ethane, propane, butane, benzene, toluene and xylene, or partially halogenated hydrocarbons, as taught in the aforementioned United States Patent 2,671,735 issued to Grisdale, Pfister and Teal.

Those compounds chosen to furnish silicon for deposition are also, generally, those with high vapor pressures'at conveniently low temperatures. Silanes, halogen substituted silanes, silicanes and halogenated silicanes are in this category. Thus, silane, and di-, tri-, and

tetrasilane, S1'H4, SizHs, SisHa, SlHlO, all have normal boiling points below 85 C. Halogen substituted silanes, such as SiI-IsBr, SiI-IaCl, SiHzBrz, SiHzClz, SiHBrs, SiHCla, Sil-IFa, SiCli, SiF4, SizCls, SizFs can be employed, as all are relatively volatile. Again, practical consideration favors those compounds most easily handled or those readily available at low cost. If fluorosilanes are used,ffor example, special materials resistant'to fluorine struction of the apparatus.

Compounds which are both carbonaceous and siliconcontaining can be employed in the deposition technique. Examples of such compounds are relatively volatile members of the class 1'1. where R1, R2, R3, R4 are hydrogen, aryl or alkyl radicals, or halogens Typical compounds are methyl silicane, SiH3(CH3), diand tetramethyl silicanes, SiH2(CH3)2 and Si(CHs)4, methyltriphenyl silicane, Si(CHz) (CsHs)s, tetraethyl silicane, Si(C2H5)4, tetrabenzyl silicane, EKCeHsCHzM, chloromethyl silicane, Sil-IzClCHa, and dichlorodimethyl silicane, SiCl2(CHa)z. Hexamethyl disilicane, Si2(CHs)s, is an example of volatile higher silicane homologues which are adaptable to the deposition technique.

Although, in a preferred technique which has been particularly successful in forming good siliconborocarbon films, boron trichloride, silicon tetrachloride, and methane are chosen, so that each of the materials in the final. deposit originally enters the gas stream as a compound containing only that material and non-deposited constituents, modification of the procedure to use those volatile substances containing both carbon and boron, or carbon and silicon, is possible. Any desired ratio of carbon to silicon and carbon to boron in the final gas mixture is obtainable by proper dilution of the pure compounds containing both carbon and a second depositable constituent, the dilution being made with appropriate carbonaceous gases which are silicon or boron free, or with silicon or boron compounds containing no carbon.

Although it is possible to stream mixtures of some of these pure gases directly to the heated surface at which deposition is to take place, considerations of flow rates and the rate of deposition preferably call for a dilution of the mixture of gaseous pure compounds with an inert gas. As with the carrier gas discussed above, a waterfree substance chemically inert or reducing in character best serves the purpose. Again, argon, helium, hydrogen, or nitrogen are examples of satisfactory diluents. Some diluent gas is most easily introduced with the mixed stream of boron and silicon components, the balance of desired diluent being added with the carbonaceous component, but mixture with any or all of the reacting gases suifices, and the dilution may occur at any point in the system including the area immediately surrounding the heated base on which deposition is to occur.

The flow of gases about the heated base should be such that a turbulence suflicient to get a homogeneous, uniform coating of deposit on all portions of the base results. The flow rate is largely determined by the geometry of the deposition apparatus. Once a rate suitable for giving a uniform deposit is reached, it is generally more convenient to vary the composition of the gas mixture or the time for which contact between the heated base and the mixture is maintained as the variables controlling the thickness and chemical make-up of the deposit, rather than altering the rate of flow of the depositing gas mixture.

The temperatures at which the most satisfactory depositions occur lie within the approximate limits 1000" C. to 1400 C. and preferably between 1100 C. and 1300 C. Lower temperatures do not generally give good deposits, and at higher temperatures some materials from Which the resistor bases are manufactured may become unstable. Further, the design of apparatus to withstand such higher temperatures becomes difficult. Deposition temperatures of 1125 C. to 1200 C. are found best. An optimum operating temperature is 1150 C.

A temperature sufliciently high to decompose the boron, silicon or carbon-donating gases to form a deposit is required. If suitable substances having low decomposition.

temperatures are chosen, a film can be deposited at temperatures as low as 600 C., though the characteristics of the films which are most sought often diminish in the films at deposition temperatures of 900 C. to 950 C. and lower.

The resistor bases on which the deposit is laid are generally of a ceramic composition, though any non-conducting material stable at an elevated deposition temperature would sufiice. A number of suitable ceramic materials is suggested in the previously-mentioned patent of Grisdale, Pfister and Teal, United States 2,671,735. The ceramics may be either vitreous or porcelain'like in nature and a particularly suitable ceramic composition is described in United States Patent 2,386,633, issued October 9, 1945 to M. D. Rigterink. Bodies shaped of this material a're fired at approximately 1250 C. after being shaped from a paste of parts flint ground to 325 mesh, 50 parts of kaolin, sufiicient water to give a proper consistency, and parts of a fired mixture of 60 parts kaolin, 10 parts magnesium carbonate, 10 parts calcium carbonate, 10 parts strontium carbonate and 10 parts barium carbonate, said mixture being previously calcined at 1200 C. and ground thereafter to 325 mesh.

in a deposition technique employing the apparatus schematized in Fig. 2, boron trichloride, silicon tetrachloride and methane, as mentioned previously, were the compounds chosen to furnish the film constituents upon decomposition. Nitrogen was used as a carrier and diluent, and helium was the gas employed as a flush. All methane, helium and nitrogen used in this specific deposition technique were dried by passage over calcium hydride before introduction into the system. Since oxygen-free methane, and nitrogen and helium both having low oxygen analyses were used directly, no further purification to remove oxygen was found to be necessary.

In the preferred example, liquid boron trichloride, used as the boron-contributor, was kept in a glass bubbler apparatus through which nitrogen could be passed. The bubbler was surrounded by a mechanically agitated bath of trichloro ethylene at the normal freezing point of trichloroethylene, -36 C. A cooling medium of Dry Ice and acetone in a suitable flask was immersed in the vessel containing trichloroethylene.

The silicon containing compound chosen in the preferred example was liquid silicon tetrachloride, kept in a second bubbler similar to that used for boron trichloride. A temperature of 0 C. was maintained by immersion of the bubbler in a water-ice bath.

For both substances, dried nitrogen was passed through the liquid using a tube having an outlet beneath the liquid level, the outlet being fitted with a fritted glass disk to cause the release of small gas bubbles into the liquid. A given volume of carrier gas, essentially saturated with either boron trichloride or silicon tetrachloride at a fixed temperature, had, then, a content of either of the two noninert vapors which could be calculated from knowledge of the vapor pressure of boron trichloride or silicon tetrachloride in the carrier nitrogen at that temperature. Subsequent dilution with nitrogen to give a desired composition of the final gas mixture could then be accomplished.

In an apparatus of the construction shown, a total rate of flow of gases between 600 cubic centimeters per minute and 1200 cubic centimeters per minute has proved efiicacious for the particular existing geometry. A total rate of flow of 800 cubic centimeters per minute has been found as most desirable, and the depositions are generally done with this amount of gas passing. Any deposition apparatus, of which the one described is an example, may have an almost unique geometry which may affect the optimum flow-rate value in that apparatus.

Suitable borocarbon films containing codeposited silicon can be conveniently produced from gas mixtures in which the ratio of the number of boron atoms to the number of carbon atoms in the mixture lies between the limits 1.00 and 0.01. For the preferred example in which methane,

boron trichloride and silicon tetrachloride compose the active ingredients in the gaseous deposition mixture, the composition range set forth above corresponds to mixtures in which the percent by volume of boron trichloride in the combined boron trichloride and methane lies between 50 percent and one percent. Though increased amounts of boron may be used in the depositing gas, the resultant films may have higher surface resistances in-ohms per square, than are of interest at present. More commonly used resistance values are obtained when the boron content of the depositing gas is reduced so that the aforementioned atomic ratio lies between the values 0.33 and 0.01 corresponding to a value of the ratio lying between 25 volume percent and one volume percent. Deposits having specially favorable thermal coetficients of resistance are obtained when the boron-carbon atomic ratio lies between the values 0.25 and 0.026 with an optimum value for the ratio, giving the films with least resistance change with temperature, appearing at 0.18. In volume percent, these figures correspond to 20 volume percent, two and one-half percent and an optimum of 15 percent boron trichloride by volume, respectively, in the quantity BCls BCls CH4 Similarly, the ratio of the number of silicon atoms to the number of carbon atoms in the depositing gas mixture is best kept between the limiting values 3.00 and 0.01. When silicon tetrachloride and methane are used in the deposition, as in the preferred example, this range of the silicon to carbon ratio corresponds to a percent by volume of silicon tetrachloride in the gaseous mixture of silicon tetrachloride and methane lying between 75 volume percent and one volume percent.

The lower limit on the silicon-carbon ratio may be conveniently raised to 0.053 or five volume percent of silicon tetrachloride in the silicon tetrachloride-methane mixture.

Better films are deposited with the ratio of the number of silicon atoms to the number of carbon atoms in the mixture having values between 0.67 and 0.11 and particularly good films are obtained with an optimum ratio of 0.43. Measured by the quantity SiCls SiCl4+CH4 these ratios take the values 40 volume percent, ten volume percent and an optimum of 30 volume percent, respectively.

The geometry of the furnace may be influential in determining which gas compositions are most efiective in producing good deposits. The limits on composition ratios and the optimum values of those ratios recited above have been determined using a furnace of the type shown in Fig. 1. Variations in furnace geometry may also afiect the optimum gas composition values listed, but suitable resistance films are produced by keeping within the limits set on the boron-to-carbon and siliconto-carbon ratios mentioned earlier.

The final film thickness is usually kept at the same order of magnitude as for boron-carbon films, between 10- aud 10* centimeters. By increasing or decreasing the time in which a portion of the ceramic base remains in the reaction zone, the film thickness can be increased or decreased. Thicker films with resistance values of ohms per square, and films thin enough to give a resistance of 2500 ohms per square have been produced, as well as those with intermediary resistance values. A film with resistance as high as 10 ohms per square can be obtained.

It is not known how the silicon borocarbon film differs structurally from the borocarbon film, or whether silicon 7 is present as silicon carbide or in elemental form in solid solution with carbon. The silicon borocarbon films show striking improvement, however, in some characteristics considered particularly desirable in a resistor film.

The silicon borocarbon films show a decreased susceptibility to oxidative changes in the film upon exposure to high temperatures. Where resistors may overheat, such an increased chemical stability and resistance to oxidation is of particular importance.

Increased adherence of the silicon borocarbon films is shown by rub-up tests in which the change in film resistance caused by abrasion under controlled conditions is measured. Whereas borocarbon films usually show a 10 to 15 percent increase in resistance from mechanical loss of film material, the more adherent films containing silicon showed resistance changes less than five percent.

In a check of resistance stability, test resistors were separately encased in glass and heated to 400 C. for one hour while the containers enclosing them were evacuated. During the sealing, pumping, and baking operations, borocarbon films generally showed six to eight percent changes in resistance values. The more stable and more densely compacted silicon-borocarbon films showed an average change of as little as 1.5 percent in resistance value, as measured on films for which the boron-carbon atom ratio was 0.33 and the silicon-carbon atom ratio was 3.00 in the depositing gas. Increased coherence and adherence of the films can also be correlated with a greater tendency of the films to retain their fixed resistance values in humid atmospheres. Penetration of less coherent films by moisture appears to be the cause of resistance value fluctuations in plain borocarbon films.

In addition to increased adherence and better behavior of the fiims in heat and moisture, the thermal coeificients of resistance of the silicon borocarbon films retain the small negative values which originally made plain borocarbon films desirable. The films with silicon can be made such that their thermal resistance coefficients fall within the envelope surrounding the curves representing the best behavior of the thermal coefiicients of borocarcon films. The silicon borocarbon films can thus be made at least as good as borocarbon films, with respect to their thermal resistance variation, and in many cases the silicon films may better the borocarbon films by a factor of 50 percent in their reduced thermal resistance coefficients.

Although specific embodiments of this invention have been shown and described, it will be understood that they are but illustrative and that various modifications may be made therein without departing from the scope and spirit of the invention.

What is claimed is:

1. The method of making borocarbon-film electrical resistors with increased stability against heat, moisture, and abrasion due to increased adherence and coherence of the film, which method comprises contacting at an elevated temperature a non-conducting core with. a gaseous mixture comprising chemically-bound carbon, chemically-bound boron, and chemically-bound silicon, in which mixture the ratio of the number of bound boron atoms to the number of bound carbon atoms lies between 1.00 and 0.01 and the ratio of the number of bound silicon atoms to the number of bound carbon atoms lies between 3.00 and 0.01.

2. The method of making borocarbon-film electrical resistors as described in claim 1 wherein the chemicallybound carbon is present as a compound selected from the group consisting of hydrocarbons and halogenated hydrocarbons, the chemically-bound boron is present as a compound selected from the group consisting of borane halides and boron trihalides, and the chemically-bound silicon is present as a halogen substituted silane.

3. The method of making borocarbon-film electrical resistors as described in claim 1 wherein the chemicallybound carbon is present as methane, the chemicallybound boron is present as boron trichloride, and the chemically-bound silicon is present as silicon tetrachloride.

4. The method of making borocarbon-film electrical resistors with increased stability against heat, moisture, and abrasion due to increased adherence and coherence of the film, which method comprises contacting at an elevated temperature a non-conducting core with a gaseous mixture comprising chemically-bound carbon, chemically-bound boron, and chemically-bound silicon, in which mixture the ratio of the number of bound boron atoms to the number of bound carbon atoms lies between 0.33 and 0.01 and the ratio of the number of bound silicon atoms to the number of bound carbon atoms lies between 0.67 and 0.11.

5. The method of making borocarbon-film electrical resistors as described in claim 4 for which the chemicallybound carbon is present as methane, the chemicallybound boron is present as boron trichloride, and the chemically-bound silicon is present as silicon tetrachloride.

References fited in the file of this patent UNITED STATES PATENTS 1,742,259 Kelleher Jan. 7, 1930 2,057,431 Hobruck Oct. 13, 1936 2,313,410 Walther Mar. 9, 1943 2,328,422 Christensen Aug. 31, 1943 2,544,320 Hurd Mar. 6, 1951 2,671,735 Grisdale Mar. 9, 1954 LCM m

Patent Citations
Cited PatentFiling datePublication dateApplicantTitle
US1742259 *Jul 17, 1925Jan 7, 1930Harper Electric Furnace CorpElectrical resistor, conductor, and the like
US2057431 *Mar 29, 1933Oct 13, 1936Raymond H HobrockMethod of making resistance elements
US2313410 *Mar 31, 1939Mar 9, 1943Bell Telephone Labor IncPreparation of boron compositions
US2328422 *Oct 9, 1940Aug 31, 1943Bell Telephone Labor IncMethod for coating bodies with carbon
US2544320 *Oct 24, 1946Mar 6, 1951Gen ElectricFabricated article
US2671735 *Jul 7, 1950Mar 9, 1954Bell Telephone Labor IncElectrical resistors and methods of making them
Referenced by
Citing PatentFiling datePublication dateApplicantTitle
US2893895 *May 4, 1956Jul 7, 1959Corning Glass WorksMethod of vapor coating
US3015587 *Sep 5, 1958Jan 2, 1962Technology Instr Corp Of ActonRhodium germanium film resistor
US3057325 *Apr 1, 1959Oct 9, 1962Western Electric CoCarbon deposition apparatus
US3074817 *Apr 26, 1957Jan 22, 1963Int Resistance CoPyrolytically decomposed resistor consisting of the elements carbon, oxygen and silicon
US3098763 *May 29, 1961Jul 23, 1963Raytheon CoChemical reactor
US3101280 *Apr 5, 1961Aug 20, 1963IbmMethod of preparing indium antimonide films
US3107337 *Dec 28, 1959Oct 15, 1963Wilbur M KohringElectrical element having a conductive film
US3171871 *Jul 19, 1960Mar 2, 1965Norton CoMethod of making electrical heater bars
US3244559 *Mar 7, 1961Apr 5, 1966Texas Instruments IncModified carbon film resistor and method of making
US3292130 *Jul 28, 1961Dec 13, 1966Texas Instruments IncResistor
US3369920 *Nov 24, 1964Feb 20, 1968Union Carbide CorpProcess for producing coatings on carbon and graphite filaments
US3475211 *Oct 27, 1969Oct 28, 1969Matsushita Electric Ind Co LtdDurable resistive element of glass and a process for preparing the same
US3891828 *Oct 18, 1973Jun 24, 1975Westinghouse Electric CorpGraphite-lined inert gas arc heater
US3949106 *Feb 19, 1974Apr 6, 1976Toyo Boseki Kabushiki KaishaMethod for producing isotropic pyrolisis carbon coatings
US4783369 *Mar 20, 1986Nov 8, 1988Canon Kabushiki KaishaHeat-generating resistor and heat-generating resistance element using same
US20090061646 *Sep 5, 2008Mar 5, 2009Chiang Tony PVapor based combinatorial processing
U.S. Classification427/101, 264/DIG.360, 252/502, 427/122, 427/249.5, 338/300, 118/715, 264/81, 252/516, 338/308, 427/102
International ClassificationH01C17/20
Cooperative ClassificationY10S264/36, H01C17/20
European ClassificationH01C17/20