Search Images Maps Play YouTube News Gmail Drive More »
Sign in
Screen reader users: click this link for accessible mode. Accessible mode has the same essential features but works better with your reader.


  1. Advanced Patent Search
Publication numberUS2793282 A
Publication typeGrant
Publication dateMay 21, 1957
Filing dateNov 28, 1951
Priority dateJan 31, 1951
Also published asDE903017C, US2793281
Publication numberUS 2793282 A, US 2793282A, US-A-2793282, US2793282 A, US2793282A
InventorsSteigerwald Karl Heinz
Original AssigneeZeiss Carl
Export CitationBiBTeX, EndNote, RefMan
External Links: USPTO, USPTO Assignment, Espacenet
Forming spherical bodies by electrons
US 2793282 A
Abstract  available in
Previous page
Next page
Claims  available in
Description  (OCR text may contain errors)

K. H. STEIGERWALD 2,793,282

FORMING SPHERICAL BODIES BY ELECTRONS" May 21, 1957 3 Sheets-Sheet 1 Filed Nov. 28, 1951 Jill/DING min/41 Irwin 5n" May 21, 1957 K. H. STEIGERWALD FORMING SPHERICAL BODIES BY ELECTRONS 3 SheetsSheet 2 Filed Nov. 28, 1951 I Q I I @000! may; 7

mm H mniumx. I. I; 144v: 522745040 my Fl- May 21, 1957 x K. H. STEIGERWALD 2,793,282

FORMING SPHERICAL scams BY ELECTRONS' Filed Nov. 28; 1951 United States Patent FORMING SPHERICAL BODIES BY ELECTRONS Karl Heinz Steigerwald, Mosbacli, Germany, assignor, by mesne assignments, to Carl Zeiss, Heidenheim (Brenz), Wurttemberg, Germany Application November 28, 1951, Serial No. 258,673 Claims priority, application Germany April 13, 1951 3 Claims. (Cl. 219-69) My invention relates to a novel apparatus for and methods of producing balls having a diameter of the order of millimeters to tenths of millimeters, and more par.- ticularly relates to apparatus for and methods of using the energy of an electron stream for this purpose.

In my copending application Serial No. 258,671, filed November 28, 1951, I have described in detail an arrangement for controlling an electron beam so as to produce a long distance to the focus plane. I have found as therein described that by a proper control of an electron stream, I can produce a suflicient current density thereof to heat objects to a temperature at'which the material becomes fluid and will flow.

In general my invention contemplates impinging such an electron beam on objects and transferring the kinetic energy of the electrons to the objects causing the object to soften sufficiently to flow into spherical forms without causing any rise in temperature in the adjacent region of the object.

In another form of my invention, I impinge electrons on the object with such force that the object, after being melted, explodes and forms a number of smaller objects of spherical shape.

Accordingly, an object of my invention is to provide apparatus for and methods of utilizing the energy of an electron beam to form spherical objects having diameters of the order of one millimeter to tenths of a millimeter.

A further object of my invention is to provide novel means for utilizing an electron beam to form minute particles from larger objects. I

Still another object of my invention is to provide a novel arrangement of an electron stream for transferring the energy therefrom to objects.

These and other objects of my invention willbe more clearly understood from the detailed description of my invention which is to follow in which:

Figure 1 is a cross sectional view of one embodiment of my invention.

Figure 2 is a cross section of a modified form of my invention in which a plurality of electron beams are impinged on an object; and

Figure 3 is a further modification of my invention in which a plurality of electron sources are employed for producing electron beams reacting on objects.

In the drawing, the electron gun 11' comprising a tubular housing made of any suitable metal is mounted on an insulator 12 with a suitable rubber ring washer 14. Mounted within the tubular housing 11 is a cathode 15 of any suitable electron emitting material'such'as tungs'ten. Leads 16 and 17 extending from the cathode are connected to any suitable source of direct current voltage supply such as battery 18 operating normally at a potential of four volts and supplying approximately four amperes.

Also mounted within the electron gun 11' in any suitable manner is a control electrode 19 having its upper portion 20 in the form of a cylinder and having an integral extension 21 of conical construction with an opening at its apex 22. A further integral extension 23 of the control electrode is cylindrical in shape.

The control electrode is connected over the conductor 24 to a potential source. The cathode is maintained at a potential of approximately 50,000 volts with respect to ground, and the control electrode is maintained over conductor 24 to a higher negative potential than the cathode by approximately to 300 volts. These voltages may be suitably regulated in any well known manner.

It will be noted that the electron emitter 15 protrudes through the apex opening 22 of the sonically shaped extension 21 of the control electrode 19. In practice, I have found that the cathode is preferably of hairpin shape having a wire diameter of 0.15 mm. For my purposes, I have found that the electron emitter should protrude beyond the opening 22 at the apex of the cone 21 by a distance substantially equal to the diameter of the wire for reasons which will be more clearly understood from the description which is to follow.

The cone section 21 of the control electrode may comprise a preferably six in number of conical sectors 25, insulated from each other. Each sector is maintained at suitable potential between each other and cathode of the order of 500 volts. 7

It will of course now be understood that the voltages of each of these sectors with respect to ground remain of the order of S0,000 volts.

To maintain these potential differences between the sectors, individual conductors corresponding to 24 are connected to each of the sectors 25 each having predetermined potentials applied thereto. Correspondingly, the cylindrical section 23 is also connected over its individual conductor corresponding to conductor 24 for applying a predetermined voltage thereto.

The cylindrical sections 23 may be also formed of a plurality of sectors, insulated from each other and each maintained at suitable potentials with respect to each other.

In the present illustrations however, the conical portions and the cylindrical portions are unitary members maintained at a common potential.

As will be seen, the cathode 15 protrudes beyond the conically shaped control electrode 21 by a distance equal to the diameter of the emitter wire. Adjacent to the electron emitter 15 there exists as is well known in the art, a space charge. The equipotential lines produced by the potential between the control electrode and anode assume the shapes shown by the lines 27, 27'.

It will be seen from Figure 1 that the equipotential lines follow the values of their adjacent electrodes.

The 50,000 volt equipotential line which is at the cathode or electron emitter potential follows generally the form of the cylindrical electrode 23 and the conical electrode 21. In Figure l, the line closest to the cathode has a slight hump 27" adjacent the space charge zone at the cathode tip. The negatively charged electrons in the space charge Zone are pulled out by this shape of the potential line. The equipotential lines thereafter rapidly straighten out this hump and assume complete convex forms as shown at 27*. The curvature of these lines further away from the cathode become straightas at 27 "and then concave as at 27.

Because these potential lines apply an accelerating force to the electrons in a direction normal to the potential, the electron beam is at first widened as at 32' and then accelerated inwardly slowly as at 32" by the potential lines 27 to produce a large distance to the focal plane.

It will of course be understood that the equipotential lines in Figure 1 necessarily are not shown in their true dimensions as this is not possible in illustrating the principal functions of these lines.

Preferably the cross section of the electron beam should be circular. This is determined by the shape of the cathode, the space charge adjacent thereto and the shape and potentials of the' various conical sectors 25. If because of an unsymmetrical shape of the electron emitter, the cross sectional area of the electron stream in the first instance is elliptical, I have found that by a proper distribution of potentials applied to the individual conical sectors, I can reconstruct the cross sectional shape of the electron stream to .restore it to a circle.

Thus for example, in the case .of an original elliptically shaped electron stream, I would increase the relative potential of those sectors opposite the long axis of the conical shaped electron stream causing the long axis to be reduced. I also decrease the potential of the sectors opposite the small axis of the sectors which enlarges the small axis and restores the cross sectional circular shape of the electron stream. By use of potential distributions between the sectors which are not chosen symmetrical to the optical axis, one can also secure deflections of the electron beams direction.

It will, of course, be understood that in referring to an increase or decrease of potentials at the conical sectors, I am here referring to the relative voltages with respect to each other.

The diameter of the electron stream at its widest point is between 0.5 to 1.5 mm. For the smaller diameter of electron stream, that is, 0.5 mm., the focal point of the electron stream will be approximately cm. from the electron emitter, whereas for the electron stream having a diameter of 1.5 mm. the focal point will be 30 cm. from the emitter.

As the potential between the electron emitter and the control electrode increases, the diameter of the cross section through the electron stream adjacent the cathode decreases and the length to the focusing plane of the electron stream correspondingly decreases. As a result the current density increases until a critical point is reached. A further increase in the potential difference between the electron emitter and the control electrode withdraws the hump 27" from the space charge region and the current density decreases.

I have given below a table in which such relative values are set forth. It Will be understood, however, that these values are not exactly reproduced but are given solely for purposes of illustration.

It will be noted that the anode 11 is grounded in any suitable manner as, for example, in the illustration here shown through the grounded base member 11'. The member 11 carries the entire electron gun. The entire mechanism including the base 11 and the electron gun construction hereinafter described is evacuated in any suitable manner.

The electron beam 32, as described hereinabove, has been provided with a long focal point located in the region 65. Mounted within the evacuated chamber is a rod 67 having a plurality of grooves 66. The rod 67 protrudes through the walls of the chamber and is connected to an operating handle 68 which permits the insertion and removal of the rod. In order to maintain vacuum within the chamber, gasket means 69 and 70 are provided of any well known construction such as rubber.

The rod 67 extends through a chamber 72 and gasket member 73. The chamber 72 is connected over the passageway 74 to an evacuating pump. In order to insert members to be treated, the rod 67 is drawn to the right until the grooves 66 are exposed on the outside of the chamber 72 and the material 75 to be treated is then in serted in the grooves.

It will of course be understoodthat the rod is sufiiciently long so that the stop 76 at the left end of the rod will hit the wall of the chamber only after all of the grooves have been exposed.

With this construction, it is now possible to slide the rod without disturbing the vacuum in the evacuated chamber. With the rod in the position shown, the article 76' is in the focal region of the electron beam.

The object or articles to be treated which may be of A1203 crystalline in construction, may have previously been broken up into small particles of millimeter size by any well known means and had assumed irregular shapes as shown at 75. When now the object in its groove is brought into the focal region of the electron stream, the material is brought to a fluid state in a matter of seconds. Due to the surface tension, the fluid material now flows into a ball or spherical form as shown at 76'.

Adherence to the walls of the container is prevented because the electron beam being concentrated on the object, it does not heat the surrounding regions so that they remain substantially cold. Before any substantial heat transfer can occur the ball-like structures which have been formed have cooled and resolidified.

The particular crystalline construction of the end product may be controlled by the rate of cooling. Where it is desired to provide a single crystal, the article is cooled at a relatively low speed by slowly decreasing the electron stream. This may be done either by changing the electron volts or by a diaphragm which regulates the electron stream. Such a diaphragm is illustrated at 81 and consists as described in connection with my aforesaid application, of a hollow U-shaped member 82, a disk 83, with an interposed diaphragm 84 having a central opening at 85 through which the electron beam moves.

The member 81 is adjustably moved to control the electron stream by means of the screw members 86 and 87. The diaphragm here shown is positioned in a position corresponding to the focus plane described in my aforesaid copending application which is hereby made a point of this application. Inasmuch as every electron ray in the focus plane is reproduced in the image plane, I may adjust merely one of the adjusting screws 86, for example, or 87.

By moving the diaphragm to the left, for example, whatever portion of the electron stream is left exposed will form an image in the image plane of uniform intensity.

In this illustration, the object 76 will be in the plane corresponding to the image plane of my copending application, although the focus plane may alternatively be used.

The electron chamber is evacuated in any well known manner, as by means of any standard pump. If desired, in order to further control the rate of cooling, I may heat the supporting members in which the slots are formed and in which the members to be treated have .mm. or less.

Where it is desired to form an amorphous construction, that is to say to reconstruct the crystals into a large number of individual crystals, a more rapid cooling is required. In such a case, the electron stream is instantly out 01f afterthe material has been sufficiently caused to flow. For balls having a diameter of 0.1 mm., the cooling may be achieved in 0.1 second the heat being dissipated mostly by radiation and by conduction to the surrounding regions. With such rapid cooling, I will form minute balls having a number of individual crystals formed therein.

To further decrease the speed of cooling, I may, if desired, provide a saucer or well 51 which is filled with a cooling fluid such as oils which have low vapor pressure and will remain in a fluid condition in an evacuated chamber. Immediately after the object has been formed into a ball construction, the handle 68 is rotated through 180 and the object will then fall into the fluid located directly underneath, the remaining objects are prevented from falling since the rod in these other regions is mounted within the tubular members 52 and 53.

If I desire to further reduce the object to smaller sizes I may first melt the object in the manner described above to a fluid. For the melting, I require fifty microamperes and this is obtained by the particular potential of the control electrode with respect to the electron emitter. By decreasing this negative potential of the control elec trode to 250 volts, I increase the current of the electron stream to 300 microamperes. At this value I have found that the object will explode, breaking up into a number (100 for example) of smaller particles of still smaller diameter. As they fall, these particles are cooled and when they reach the base, are sutficiently cold to retain their shape.

Any well known shape or construction of the base may be employed for collecting these balls as, for example, making the base of the evacuated vessel conical in shape.

In Figure 2 I have shown a modified form in which the electron stream from a common source is split into a number of electron beams for impinging on ditferent areas of the article. In this construction, the electron beam 121 which has been formed in the manner described in detail hereinabove is interposed by barrier 122 which has been grounded in any suitable manner.

The upper end 123 of the plate 122 is of increased thickness so as to keep the electron stream from touching the plate 122. On both sides of the plate 122 are deflecting electrodes 124 and 125 each maintained at a positive potential of the order of 100 to 1000 volts with respect to ground. Control of these electrodes is obtained through the rods 126 and 127 which protrude through the walls 128 of the evacuated vessel and are provided with gaskets and insulators 129 and 130 for preventing a loss of vacuum. The electron stream is thus divided into two electron streams 131 and 132 having predetermined angles of deflection and pass between the deflecting plates 134 and grounded plate 135 and between the deflecting plate 136 and grounded plate 137. Plates 134 and 136 are supported on adjustable rods 141 and 142 respectively extending through the wall 128 of the evacuated vessel and mounted in insulators and gaskets 143 and 144.

The deflecting plates 134 and 136 will redirect electron beams 131 and 132 to impinge upon adjacent or opposite walls of the object 145 mounted on the carriage 146 of a construction similar to that shown in Figure 1.

Although in this illustration I have shown the deflectors as plates, it will now be apparent that I may replace the plates 124 and 125 by a single flaring tubular member with a barrier rod extending through it. The deflecting plates 134 and 136 would then comprise a single deflecting plate which is a sector of a doughnut shaped member. The ground plates 135 and 137 would similarly form a single plate also of a sector of a doughnut shape. Between the single plate formed by 134 and 136, and the single plate formed by electrodes by 135 and 137, the electron beam now in the form of a paraboloid envelope would be deflected as a continuous beam impinging in a continuous ring over the upper surface of the object l45.

6 In the above construction, the plate 122 would be supported on a rod 147 extending to the wall 128 and which in turn may carry the grounding wire. The single construction formed by the plates and 137 could either be similarly supported or on the same rod.

In Figure 3 I have shown a still further modification in which I employed two separate electron streams 201 and 202 each formed by its own or individual electron source. Here as in the previous modification, the construction of the source including the electron emitter, the accelerators and anode are the same as previously described. The electron vessels 203 and 204 are arranged to meet in a common chamber 205 into which the rod 206 carrying the articles to be treated are seated. The construction and operation here are similar to that described in previous figures, the advantage residing in the impinging on the articles by independent electron streams at adjacent or opposite areas.

Although I have described the electron stream in simple form here, it will now be apparent that I may utilize an electron system with an optical system of the type described in my above referred to co-pending application.

In this construction I would use optical lenses or focusing means in the optical system for controlling the dimensions of the parameters of the electron stream and therefore the current densities that I may explain.

In some instances, depending upon the type of material, it may be desirable .to impinge the electron beam on the article in an intermittent fashion. In such a case I can control the electron beam at the source cutting it on and off at any desired rate. It is then possible to increase the current density of the electron stream and regulate the heat distribution to the object.

From the above description it will be apparent that I can, through a proper arrangement of the deflecting electrodes and the potentials applied thereto produce an electron beam which can be rotated as in an oscilloscope or can take any desired path. In this manner a number of objects can be successively treated.

A substantial deflection of the electron beam may also be achieved in the modification shown in Figure 2 by varying the potentials applied to the deflecting plates 134 and 136.

In this manner I may melt only a desired portion of the object to form any desired shape at that portion without aifecting the remaining portions. It is also possible by a predetermined control of the size of the electron beam and the manner of impingement on the objects not only to form spherical shapes but also other irregular shapes or alternatively thereto drill holes in the objects as described in my co-pending application.

As further described in my co-pending application referred to above, I may instead of using an evacuated vessel as herein described for illustrating my invention, employ a gas filled tube and utilize ions for performing my operation. In such a construction I would utilize the ions for treating the objects as the electrons are used in the present illustration. The ions would then be formed in a separate gaseous tube mounted within the electron tube.

The generation of the ions in such a case are made in a manner now well known in the art and are directed into the evacuated chamber through an opening just large enough to permit the passage of the ions and small enough to prevent any substantial escape of gas.

Provision must then be made to maintain vacuum in the evacuated section.

I claim:

1. An evacuated vessel having an electron emitter, means adjacent said electron emitter for focussing the electron beam from said electron emitter to increase the current density thereof, means for placing objects to be melted by said electron beam in the plane of maximum current density of said electron beam, said focusing means providing a density of the electron beam at the araaaaz 7 point of impingement of said objects so as to cause the objects to be split into a number vof smaller objectssaid second mentioned means being movable in a transverse direction with respect to saidelectron beam in said evacuated vessel with substantially no loss of vacuum.

2. An evacuated vessel comprising an electron emitter for generating an electron beam, means for energizing said electron beam to 50,000 electron volts and higher, means adjacent said electron emitter for focusing the electron beam from said electron emitter to increase the current density thereof, means for placing objects to be melted by said electron beam in the plane of maximum current density .of said electron beam, electrons from said emitter when focused and impinged on said objects by said focusing means having a density such that the object is split into a number of smaller objects, said second mentioned means being movable in a transverse direction with respect to, said electron beam in said evacuated vessel with substantially no loss oi vacuum.

3. In an electron tube, a source of electrons for gencrating .an electron beam, conductive plates positioned in the path of said electron beam and connected to ground to produce an electrical .field configuration to thereby split said electron beam into a plurality of beams, a carrier member for supporting articles to be treated by said electrons, means for energizing said electrons .to 50,000 electron volts and higher, and means for impinging said electron beams on a single article on said carrier member to melt and form said article into spherical form said electron tube being evacuated and said article carrier being movable in said .electron tube with no loss of vacuum.

References Cited in the file of this patent UNITED STATES PATENTS 2,128,58l Gardner Aug. 30, 1938 2,267,714 Borries Dec. 30, 1941 2,267,752 Ruska et al. Dec. 30, 1 941 2,345,080 Von Ardonne Mar. 28, 1944

Patent Citations
Cited PatentFiling datePublication dateApplicantTitle
US2128581 *May 18, 1936Aug 30, 1938Farnsworth Television IncFine beam electron gun
US2267714 *Apr 29, 1939Dec 30, 1941Fides GmbhDevice for producing filters
US2267752 *Jan 23, 1939Dec 30, 1941Fides GmbhArrangement for producing filters and ultra filters
US2345080 *Mar 24, 1941Mar 28, 1944Ardenne Manfred VonArrangement for producing filters
Referenced by
Citing PatentFiling datePublication dateApplicantTitle
US2911533 *Dec 24, 1957Nov 3, 1959Arthur C DamaskElectron irradiation of solids
US2968723 *Apr 11, 1957Jan 17, 1961Zeiss CarlMeans for controlling crystal structure of materials
US2981823 *May 5, 1958Apr 25, 1961Nat Res CorpProduction of metals
US2989633 *Feb 8, 1956Jun 20, 1961Standard Oil CoApparatus and process for radiation
US3005859 *Apr 24, 1958Oct 24, 1961Nat Res CorpProduction of metals
US3049618 *May 4, 1960Aug 14, 1962Commissariat Energie AtomiqueMethods and devices for performing spectrum analysis, in particular in the far ultraviolet region
US3068309 *Jun 22, 1960Dec 11, 1962Stauffer Chemical CoElectron beam furnace with multiple field guidance of electrons
US3082316 *Apr 12, 1960Mar 19, 1963Air ReductionElectron beam welding
US3101515 *Jun 3, 1960Aug 27, 1963Stauffer Chemical CoElectron beam furnace with magnetically guided axial and transverse beams
US3136883 *Apr 2, 1962Jun 9, 1964United Aircraft CorpSeal for moving electron beam column
US3157922 *Jun 7, 1961Nov 24, 1964Heraeus Gmbh W CMethod and apparatus for producing castings of metals having high melting points
US3198871 *Jun 26, 1961Aug 3, 1965CWesteren etal rotary furnace
US3206598 *Mar 19, 1962Sep 14, 1965Trub Tauber & Co A GEvacuated and cooled diffraction chamber for electron diffraction apparatus
US3219435 *Apr 8, 1960Nov 23, 1965Heraeus Gmbh W CMethod and apparatus for producing metal blocks by electron beams
US3237254 *Jun 26, 1962Mar 1, 1966Stauffer Chemical CoVacuum casting
US3242014 *Sep 24, 1963Mar 22, 1966Hitachi LtdMethod of producing semiconductor devices
US3258576 *Nov 30, 1964Jun 28, 1966United Aircraft CorpProcess for welding and soldering by means of a beam of charged particles
US3265801 *Aug 22, 1961Aug 9, 1966Ass Elect IndElectron beam furnaces
US3272661 *Jul 16, 1963Sep 13, 1966Hitachi LtdManufacturing method of a semi-conductor device by controlling the recombination velocity
US3329917 *Jul 26, 1965Jul 4, 1967Semel S P AResistor sensitive to temperature and process for manufacturing it
US3334213 *Dec 24, 1963Aug 1, 1967Commissariat Energie AtomiqueProcess for hot machining of metals
US3338988 *Mar 30, 1964Aug 29, 1967Commissariat Energie AtomiqueMethod of making bars of an uranium compound and in particular uranium carbide
US3351503 *Sep 10, 1965Nov 7, 1967Horizons IncProduction of p-nu junctions by diffusion
US3382114 *Jan 7, 1964May 7, 1968Philips CorpMethod of manufacturing semiconductor plate using molten zone on powder support
US3401249 *Jul 9, 1963Sep 10, 1968United Aircraft CorpApparatus for the machining of material by means of a beam of charge carriers
US3404255 *Jun 23, 1965Oct 1, 1968Bendix CorpSource of vaporizable material for bombardment thereof by an electron bombarding means
US3412196 *Jul 13, 1966Nov 19, 1968Sanders Associates IncElectron beam vacuum melting furnace
US3417224 *Aug 5, 1965Dec 17, 1968Steigerwald Gmbh K HMethod and device for working material by means of a corpuscular beam
US3420719 *May 27, 1965Jan 7, 1969IbmMethod of making semiconductors by laser induced diffusion
US3440390 *Apr 20, 1966Apr 22, 1969Little Inc AMethod and apparatus for treating continuous strip material under vacuum
US3452179 *Apr 12, 1967Jun 24, 1969Us Air ForceElectron optical system
US3472751 *Jun 16, 1965Oct 14, 1969Ion Physics CorpMethod and apparatus for forming deposits on a substrate by cathode sputtering using a focussed ion beam
US3869232 *Jun 13, 1973Mar 4, 1975Leybold Heraeus VerwaltungApparatus for preparing pellets by means of beams of charged particles
US3916202 *May 3, 1974Oct 28, 1975Gen ElectricLens-grid system for electron tubes
US4580619 *Oct 13, 1981Apr 8, 1986Derek AitkenComponents for evacuated equipment
US4762975 *Nov 12, 1987Aug 9, 1988Phrasor Scientific, IncorporatedMethod and apparatus for making submicrom powders
US4806150 *Jan 21, 1988Feb 21, 1989The United States Department Of EnergyDevice and technique for in-process sampling and analysis of molten metals and other liquids presenting harsh sampling conditions
US4874596 *Jun 28, 1984Oct 17, 1989Lemelson Jerome HProduction of crystalline structures
US5183481 *Jun 7, 1991Feb 2, 1993Aerochem Research Laboratories, Inc.Supersonic virtual impactor
US5462772 *May 13, 1993Oct 31, 1995Lemelson; Jerome H.Methods for forming artificial diamond
US5552675 *Mar 10, 1992Sep 3, 1996Lemelson; Jerome H.High temperature reaction apparatus
US5616372 *Jun 7, 1995Apr 1, 1997Syndia CorporationMethod of applying a wear-resistant diamond coating to a substrate
US5628881 *Jun 7, 1995May 13, 1997Lemelson; Jerome H.High temperature reaction method
US5688557 *Jun 7, 1995Nov 18, 1997Lemelson; Jerome H.Method of depositing synthetic diamond coatings with intermediates bonding layers
US5714202 *Jun 7, 1995Feb 3, 1998Lemelson; Jerome H.Synthetic diamond overlays for gas turbine engine parts having thermal barrier coatings
US5740941 *Jun 6, 1995Apr 21, 1998Lemelson; JeromeSheet material with coating
US5794801 *Jun 6, 1995Aug 18, 1998Lemelson; JeromeMaterial compositions
US5871805 *Apr 8, 1996Feb 16, 1999Lemelson; JeromeComputer controlled vapor deposition processes
US6083570 *Apr 16, 1997Jul 4, 2000Lemelson; Jerome H.Synthetic diamond coatings with intermediate amorphous metal bonding layers and methods of applying such coatings
US6904935Dec 18, 2002Jun 14, 2005Masco Corporation Of IndianaValve component with multiple surface layers
US6935618Dec 18, 2003Aug 30, 2005Masco Corporation Of IndianaValve component with multiple surface layers
US7216661Aug 10, 2005May 15, 2007Masco Corporation Of IndianaMethod of forming a wear resistant component
US7445026Apr 5, 2007Nov 4, 2008Masco Corporation Of IndianaValve component with improved wear resistance
US7866342Apr 9, 2007Jan 11, 2011Vapor Technologies, Inc.Valve component for faucet
US7866343Jun 18, 2008Jan 11, 2011Masco Corporation Of IndianaFaucet
US8118055Jun 15, 2010Feb 21, 2012Vapor Technologies Inc.Valve component for faucet
US8123967Jul 1, 2008Feb 28, 2012Vapor Technologies Inc.Method of producing an article having patterned decorative coating
US8220489Jul 17, 2012Vapor Technologies Inc.Faucet with wear-resistant valve component
US8555921Dec 17, 2009Oct 15, 2013Vapor Technologies Inc.Faucet component with coating
US9388910Sep 9, 2013Jul 12, 2016Delta Faucet CompanyFaucet component with coating
US20040118455 *Dec 18, 2002Jun 24, 2004Masco Corporation Of IndianaValve component with multiple surface layers
US20040129314 *Dec 18, 2003Jul 8, 2004Masco Corporation Of IndianaValve component with multiple surface layers
US20060038156 *Aug 10, 2005Feb 23, 2006Masco Corporation Of IndianaMethod of forming a wear resistant component
US20070278444 *Apr 9, 2007Dec 6, 2007Vapor Technologies, Inc.Valve component for faucet
DE1170092B *May 8, 1961May 14, 1964Stauffer Chemical CoElektronenstrahlofen mit einem evakuierbaren Raum
DE1615449B1 *Jan 10, 1967Nov 26, 1970Air ReductionVorrichtung zur Oberflaechenbehandlung eines Metallobjektes mittels Elektronenstrahlen
U.S. Classification219/69.1, 219/121.25, 315/382, 250/398, 373/10, 250/492.3, 219/121.65, 219/121.76, 968/713, 425/6, 264/485, 219/121.28, 264/15, 219/121.16, 164/DIG.400
International ClassificationG04D3/00, C23C14/30, H01J37/31, H01J37/301, H01J37/30, H01J37/305, H01J37/16, H01J37/063
Cooperative ClassificationH01J37/3007, G04D3/0071, H01J37/16, H01J37/063, H01J37/305, H01J37/30, Y10S29/026, H01J37/3053, H01J37/31, H01J37/301, Y10S164/04
European ClassificationH01J37/301, G04D3/00C1, H01J37/305, H01J37/063, H01J37/16, H01J37/30, H01J37/31, H01J37/305B, H01J37/30A4