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Publication numberUS2794239 A
Publication typeGrant
Publication dateJun 4, 1957
Filing dateDec 5, 1952
Priority dateDec 5, 1952
Also published asCA639824A, CA639825A, DE1407402B, US2900988, US2953837, US2953838
Publication numberUS 2794239 A, US 2794239A, US-A-2794239, US2794239 A, US2794239A
InventorsRobert T Crawford, Joel B Stevens
Original AssigneeEastman Kodak Co
Export CitationBiBTeX, EndNote, RefMan
External Links: USPTO, USPTO Assignment, Espacenet
Tow for use in the production of tobacco smoke filters
US 2794239 A
Abstract  available in
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Claims  available in
Description  (OCR text may contain errors)

June 4, 1957 R. T. CRAWFORD ETIAL 2,794,239

TOW FOR USE IN THE PRODUCTION OF TOBACCO SMOKE FILTERS 2 Sheets-Sheet 1 Filed Dec. 5, 1952 Mas \mmm w m 0 M Y B .R P E T H 0 w M Z m G '27 B Z 0 0 mm R c mm m mm H u FILTER PA PER ATTORNEYS June 4, 1957 R. T. CRAWFORD ETAL 2,794,239

TQN FOR USE IN THE PRODUCTION OF TOBACCO SMOKE FILTERS 2 Sheets-Sheet 2 Filed Dec. 5, 1952 INVENTORY RobertT. Crawford Y Joel B.Slevens M Q OHNEYS United States Patent TOW FOR USE IN THE PRODUCTION OF TOBACCO SMOKE FILTERS Robert T. Crawford, Greenville, S. C., and Joel B. Stevens, Kingsport, Tenn., assignors to Eastman Kodak Company, Rochester, N. Y., a corporation of New Jersey Application December 5, 1952, Serial No. 324,342 3 Claims. (Cl. 28-81) relates to tobacco smoke filtering elements comprising fibrous cellulose esters, particularly cellulose acetate of the yarn-type. More par-ticularly the invention is concerned with a method for the preparation of structurally unitary elongated rod-like masses of cellulose acetate fibers contained Within an outer surrounding wrapper of paper and suitable in appropriate lengths for use as cigarette filter tips and as filter elements for pipes and for cigar and cigarette holders.

The present application relates to a modified procedure for making filters of a type similar to those disclosed in copending patent :application of Cobb and Hargrave, Serial No. 324,284 filed December 5, 1952. As disclosed in said copending application, the excellent adaptability of fibers of cellulose acetate, e. g., cellulose triacetate, cellulose acetate butyrate, and cellulose acetate propiw mate as well as ordinary yarn-type cellulose acetate having an acetyl value in the range 38-41%, to purposes of tobacco smoke filtering have been known for some time. The Cobb and Hargrave application teaches that superior filter elements of improved filtering ability and designed for employment in the mass production methods and machinery of the cigarette industry may be severed in suitable lengths from a continuous running length of rod comprising a shaped and formed bundle of cellulose acetate fibers primarily longitudinally oriented and surrounded by a continuous peripheral retaining shell. The fiber bundles are made from continuous fiber masses, e. g., tows of continuous filaments or slivers of carded cut staple fibers.

The problems associated with production of a filtering element acceptable to the cigarette manufacturing industry have been numerous. Requirements for a satisfactory cigarette filter tip are stringent in that the tip must be of proper density, weight, body, resiliency, rigidity, etc., for use in manufacturing and packaging machinery commonly employed in cigarette factories. Furthermore, the industry has high standards as regards uniformity of composition and structure in filter tip elements and demands that draw-backs such as result, for example, from occasional loss of one or more fibers or filaments from the filtering elements be entirely eliminated. It is a particularly difficult problem to produce a satisfactory filter element of cellulose acetate fibers which will conform to the above-stated requirements and yet meet the other demands in structural uniformity of its transverse section and particularly uniformity as regards air pressure drop from one end to the other of the element. It is also a difiicult problem to provide :a fibrous filter of the general type disclosed by Cobb and Hargrave wherein optimum density and body for manufacturing and packaging purposes and optimum air pressure drop for smoking purposes are both simultaneously maintained, especially where these goals must be achieved in the absence of any tendency exhibited in the filter element toward formation of passages which would lead to channeling of the smoke. A filter .element must be rejected if it contains passages which lead to channeling of the smoke The present invention fibers will not accidentally Patented June 4, 1957 since in such case inadequate filtering will resul, On the other hand, where compaction of the fibers transversely is increased to avoid the possibility of channels, either the drawing properties of the cigarette are so affected that the filter element again is considered not serviceable or the density, weight or body become intolerable to the manufacturing procedures.

We have discovered a method leading to the preparation of filter elements composed of yarn-type cellulose acetate fibers wherein the filter produced is of superior quality as regards all of the above-identified requirements. The novel elements of the invention utilize all of the known capabilities of cellulose acetate tobacco filters and yet are uniform and adequate as respects the other requirements of the cigarette manufacturing industry.

Accordingly, it is an object of the invention to overcome in toto the problems enumerated above and to meet all the requirements outlined in respect to tobacco smoke filter-ing elements, especially cigarette filter tips and pro a filter element in 'which the fibers have been dechannel-v ized, so to speak, wherein there are present within the larger fiber mass no smaller distinct fiber bundles which will result in channeling of the smoke through the filter because of improper cross-sectional distribution of the fibers. Still another object is to provide'an elongated paper-wrapped cellulose acetate fiber rod in which the fibers :are randomly oriented primarily in a longitudinal direction to produce a fiber rod of uniform cross-sectional fiber distribution, and thus uniform cross-sectional air pressure drop. A further object of the invention is to provide a method for the preparation of elements of the described character. A still further object is the preparation of structurally unitary fibrous filters in which substantially each and every fiber is positively bound to the structural unit and from which, therefore, the removal of occur when the filter element is in use. Other objects will be apparent from the present specification and claims.

In the foregoing, the expression randomly oriented primarily in a longitudinal direction is intended to describe the condition of the fibers within the filters of the present invention in which the fibers are as a whole longitudinally aligned and are in the aggregate in a parallel orientation, but in which distinct short portions of individual fibers may run more or less at random in nonparallel diverging and converging directions.

The term strand as employed in the present specification and claims is intended to mean an elongate continuous relatively loose and uncompacted mass of fibers substantially oriented in a longitudinal direction and the term is generic to both continuous filament tows and continuous slivers of carded staple fiber. By continuous filament tow we mean the material which results when filaments spun from a plurality of spinnerets holes are brought together and combined, preferably with filaments from other spinnerets to form a tow of parallel filaments. By

carded sliver we refer to the untwisted continuous strand or rope comprised of cut fibers which results from the passage of said fibers through a conventional carding machine e. g. a cotton, woolen or worsted card. In the ber of conditioning treatments during which the strand is opened and dechannelized. During the strand treating period the strand more or less loses its identity as such in that it is converted into a quite open and loose form with the filaments in indeterminate relationship, subsequently assuming web-like and ribbon conformations. Therefore the fiber mass is more aptly identified during the treating period as a fiber bundle rather than a strand. The treated dechannelized strand or fiber bundle finally is run through a tapered condensing tube and becomes thereby reformed and condensed as a compacted dechannelized strand. The structurally unitary product resulting from shaping and heat treatment of the condensed strand will be referred to as a rod.

While the preparation of tobacco filter rods from yarntype spun cellulose acetate filaments in either tow or sliver form heator solventor plasticizer-treated to produce structurally unitary aligned fiber masses of various types is taught in the aforementioned Cobb and Hargrave application, we propose to take advantage of one species best adapted to standard paper-wrapped cigarette filter and cigarette production methods and'further to take advantage of the continuous and uniform properties of spun cellulose acetate at its stage of manufacture when it is in the form of a strand of carded sliver or more advantageously a crimped continuous filament tow. In a method generally similarto that disclosed in the aforementioned application, but differing in a specific and critical procedure for pretreatment of the strand, we form the strand into a structurally unitary rod-like condition only after the special novel pretreatment thereof. The treated and formed strand is shaped to the transverse section of a cigarette body and paper is subsequently closed around the compacted strand and sealed in place as an outer retaining skin, the paper-covered fiber rod thus produced subsequently being cut to appropriate lengths. The special objects of the present invention are accomplished particularly by the intervening treatment of the strand. As will be observed from the following description, the invention is designed primarily for use with a strand consisting of a continuous filament tow of cellulose acetate fibers.

In accordance with our invention which seeks especially to achieve a structurally unitary elongated rod-like element comprising an opened and dechannelized mass of fibers uniformly distributed throughout the transverse section of the rod and randomly oriented primarily in a longitudinal direction, the strand is brought to an open relaxed form whereby the extent of fiber orientation is reduced and in its opened, relaxed form the strand is subjected to a treatment with a fluid chemical which subsequently results in bonding of the fibers at random points of contact. A lofting or second opening operation follows the chemical treatment. We have found that such procedure results in uniform cross-sectional distribution of fibers and in a fiber bonding which insures that fibers will be positively retained in place within the body of the filter elements. We have further found that the proper degree of strand opening and treatment may be controlled more precisely by a series of steps comprising in sequence variable drafting, relaxation, web opening, chemical treatment, air lofting and finally dwell period relaxation. In brief, a preferred embodiment of the invention resides in a method comprising carrying out the above-listed sequential steps upon a crimped continuous filament tow from which the slack has been removed and subsequently condensing and forming the moving treated strand into desired size and shape by means of a condensing tube, laying the condensed strand into a moving ribbon of paper which then is closed about the periphery of the condensed strand and serves as a retaining shell for the latter, and finally heat treating the paper covered compacted strand and thereby forming a structurally unitary rod-like article.-

The invention is illustrated in ings in which:

Figure 1 is a schematic diagram of the various phases of treatment required to convert the initial strand into final rod-like filter elements in accordance with a preferred method;

Figure 2 is a vertical longitudinal section through the tip end of a portion of a cigarette provided with a filter element of the invention;

Figure 3 is an enlarged view of a portion of crimped tow shown in Figure 1; and

Figure 4 is an illustration of tow of the type shown in Figure 3 packaged in a conventional ball Warp.

With reference to Figure 1, a strand, most advantageously a previously preferably mechanically crimped tow, 1 is passed through a series of tension fingers 2 to remove slack. The tow from which the slack has been removed is passed to a variable drafting arrangement comprising a pair of positively driven rolls 3 and a pair of rolls 4 which either are positively driven at a slower rate than the rolls 3 or are held from free turning by a braking or friction action so that they are resistingly turned by the action of rolls 3 in positively pulling through the tow 1. In the drafting device the strand is subjected to suflicient tension to produce a restriction of the strand which results, upon emergence of the strand from the nip of the positively driven rolls into a zone of relaxation, in a more random distribution of the filaments. The restriction is a result of inherent elastic forces within the filaments of the strand. The strand, which as a result of the drafting and relaxation has become somewhat webbed, next is sent through an opening device 5 provided with a plurality of air jets which move the filaments apart and produce a ribbon-like fiber mass or bundle from which smaller individual bundles are eliminated and which has a stillmore web-like nature. From the air opening device the bundle passes then to chemical treating apparatus 6 which preferably is composed of a multiplicity of atomizing sprays directed at the ribbon-like bundle from all points around the latter. Here a plasticizer or the like which serves to partially dissolve or soften the fiber which it reaches and which will produce in the fibers a sticky attitude sufiicient to subsequently produce fiber bonding is injected into and throughout the fiber bundle. From the chemical treating apparatus the moistened fiber moves next to a lofting device 7 which serves further to fluff up and improve the loftiness of the fiber mass. From the outlet end of the lofting device the lofted moving bundle is led onto an apron or scray plate 8 where it collects and dwells for a short period of time in a relaxed condition. Subsequently the bundle is withdrawn from the scray plate and passed into a suitable funnel-like horn 9 which serves as a condenser. Within the horn 9 the strand is reformed as a condensed dechannelized mass, i. e. the bundle is shaped into a partially compacted mass of approximately desired transverse section which normally will be circular.

In regular cigarette manufacture, shredded tobacco is metered from a hopper onto a moving paper ribbon carried by a flax tape. The tobacco and the paper then go through several dies thus forming the tobacco into a cylinder and lapping the paper over itself. The glue on the paper is heat sealed forming a continuous cigarette. A cutter knife cuts the tube into desired lengths. With very minor modifications the partially compressed dechannelized strand of a continuous nature is substituted for the stream of tobacco fed onto the paper in the remainder of the process of the present invention to form the cigarette filter which we propose as new and novel. Thus, the compacted dechannelized strand from the condenser, is passed onto a moving ribbon 10 of cigarette paper fed from a supply roll 11 and carried by an endless conveyor belt 12. From this point the condensed reformed strand and the paper with which it is associated the accompanying drawpaste along the edge of t e paper, next to a final forming die 15 which completes positioning of the paper.

around its associated strand, thence to a sealing device such as an electric heating shoe 16 which serves to seal closed the pasted paper. Finally the paper enclosed strand may be subjected to a treatment with a heated die 17 which insures satisfactory fusion and welding of the fibers at random points of contact and thereby results in rod formation. The rod thence is passed to a cutting device 18 which is adjusted to sever the paper covered rod into filter elements of desired length. An alternate method is to cut the rod before complete bonding action occurs and complete the process by storing the severed elements in an oven.

Normally the strand should be treated with a lubricant prior to being subjected to the various phases of the process. Thus it may be stated that the process of the invention employs as a starting material a crimped lubricated strand of synthetic filaments or fibers. The lubricant may be any one of a number of neutral, nontoxic materials. It has been found advantageous to employ on the fiber approximately 0.5% by weight of pharmaceutical grade mineral oil. I

The so-called yarn-type cellulose acetate is a preferred material for use as an acetate having an acetyl value in the range of 38-41%, most advantageously 38.8-39.2%. However, the term cellulose acetate is used generically herein to include, not only cellulose acetate having an acetyl value of 38-41%, but also cellulose triacetate, acetate-propionate and acetate-butyrate.

While it is not necessary to use plasticized fibers it is pos-' sible to practice the invention with a strand which constitutes a fiber mixture having some plasticized fibers. If plasticized fibers are to be employed, it will be possible under suitable conditions to use 100% plasticized fiber if a low percentage of plasticizer has been put in the fiber. With a blend of plasticized and unplasticized fibers, plasticized fibers containing 33% of a suitable plasticizer such as triethyl citrate havebeen found best. It is to be remembered, however, that even totally unplasticized acetate fibers will fuse with proper heat control and that in accordance with advantageous procedure of the invention, plasticizer is applied to all the fibers. The fibers employed might perhaps satisfactorily be in the form of a strand comprising 100% yarn-type unplasticized cellulose acetate such spinning of a cellulose acetate acetone dope. The strand is suitably crimped and contains in accordance with the invention 4-15 crimps per inch, most advantageously -15 crimps per inch. A crimped tow proves most advantageous in that it offers continuously uniform properties. The tow employed may be in the form of a ball warp, i. e., a continuous crimped tow as taken from crimping machines and wrapped on a core.

The acetate filaments should have a weight within the range of 3 to 16 denier per filament and a total denier of the tow within the range of 80,000 to 160,000 denier. An advantageous starting material is a yarn-type dull cellulose acetate continuous filament tow of 5 denier per filament with 90,000 total denier. Where plasticized fibers are to be used in mixture with unplasticized fibers a continuous filament tow may be made up with one or more filaments of plasticized yarn which plasticized yarn may have a maximum total denier of 80,000. If a carded sliver is to be employed rather than a continuous filament tow, the sliver may have a weight of 100 to 300 grains per yard.

similar to that which results as results from the dry from which there has As an example, good filters were made from a 5 denier per filament, 160,000 denier tow of spun cellulose acetate with crimps varying from 5 to 7 per inch. This tow was subjected to the special opening and liquid treatment and the resulting bundle was presented to a regu-- lar Molins cigarette making machine where it was compressed, wrapped withpaper and severed into suitable lengths.

The tensioning step which is accomplished for the purpose of slack removal provides an evened-out strand and requires merely that suflicient tension be applied to the tow to remove the slack in any of the filaments. Such a procedure is well known to those familiar with the textile art and may be accomplished with any suitable arrangement of a series of tensioning bars or spools.

The drafting step employing a double set of rolls to produce variable draft serves to enhance the bloom or loftiness of the tow. As the tow relaxes upon emerging from the nip of the front rolls the elastic forces inherent in the fibers cause reactions in all planes and result in a more opened tow. The actual degree of initial crimp and the following controlled drafting, relaxing, etc. is subject to variation over a wide range depending upon the various deniers per filament, total deniers, lubricant, and such changes as may be developed from time to time.

The air opening procedure, which might more properly be termed bundle breaking uses high velocity air or other gas and should be provided with variable air pressure. The expressions dechannelizing and dechannelized, etc., as employed in the present specification have reference respectively to the procedure of strand opening and the character for the resulting fiber mass as explained in the instant paragraph. In accordance with the defined terminology, a dechannelized fiber strand is one been removed the tendency for smaller groups of adjacent fibers or filaments to become associated as distinct compacted smaller bundles within the larger mass or bundle of filaments. Such a tendency of course inherently includes a tendency toward formation of channels. The multitude of orifices in the air-jet strand opener or dechannelizer produces a high degree of separation and the filament strand is well opened resulting in a large percentage of the fibers being directly exposed to the spray in the subsequent chemical treatment. The bundle breaking operation reduces interior filament marriage resulting from the crimping operations. It is necessary to'remove and break up such grouping in order that there be no small fiber bundles present in the final product. The air jet breaking procedure preferably is accomplished with jets provided by approximately 600 holes of 0.3 mm. diameter and air pressure at 15 to 20 pounds gauge. Obviously these conditions can be varied within relatively wide limits as can the spacing and positioning of the air jets.

The chemical treatment of the air opened ribbon-like bundle utilizes a battery of air atomizers to produce intimate spraying among and onto the fibers throughout the bundle body whereupon the fiber mass becomes more or less saturated with the treating liquid. Theoretically, all or substantially all of the individual fibers are wet at a plurality of points along any given length corresponding to the extent of a single filter element. Most advantageously a plasticizing agent such as methyl phthalyl ethyl glycollate (Monsanto Santicizer M-l7) is employed although varying situations may make it equally feasible to use semi-solvents, oils, etc., which will serve to bond the fibers together and produce subsequent consolidation of the strand. Other suitable nontoxic plasticizers which have nontoxic decomposition products and do not adversely affect the taste of tobacco smoke filtered through elements of the invention are dibutyl phthalate, tripropionin and acetyl triethyl citrate. The plasticizing agent preferably is sprayed on until the fibers contain 5 to 30% by weight of plasticizer, more preferably 10 to 15%. If

7 V desired, the temperature at which the chemical treatment takes place may be controlled.

The lofting procedure is necessary to restore the fiber mass into a springy, resilient condition and to prevent group bundling and matting of the Wetted fibers. For lofting, one may use an elongated tube into the leading end of which is directed an annular controlled blast of air of varying turbulence under a pressure of to 100 lbs. gauge, preferably 45 to 50 pounds gauge. The annular blast creates an aspirating effect to move the tow and additional air through the annulus and the remaining portion of the tube. All of the entering air, and of course the tow, pass out of the tube at the opposite end. Since the fiber bundle entering the lofting tube advantageously is in the form of a ribbon-like web, we prefer to employ an air blast in the form of two flat jets disposed respectively above and below the web. Sufficient turbulence is thereby produced to restore the bundle to its previously existing Well opened state and the loftiness of the fiber strand in its subsequently applied paper wrapper. The lofting operation increases the filtering efficiency of the fiber rod and adds body to the final filter assembly.

The step in which the treated fiber mass is permitted to dwell upon the scray plate permits relaxing and eases the strains produced by the straight-line tension to which the fiber previously has been subjected and prevents extension of the fiber to the point where decrimping or breaking occur from excessive tensile forces. In addition, the scray serves as a bin or reservoir.

At this stage of the procedure the opened, sprayed and lofted relaxed fiber bundle is passed into the funnellike condensing nozzle and thence into the shaping end thereof wherein the lands consolidate the mass, reforming the dechannelized strand in a compacted condition and shaping it to suitable size and transverse section for laying into the advancing cupped paper ribbon. Normally the transverse section will be circular, but it may be oval, triangular, square, or any special shape as desired. For most standard brands of cigarettes made in the United States, a final circular section of 0.32" diameter is desired in the filter elements. It should be noted in this connection, however, that variation in circumference or diameter ordinarily ismore critical than Variation in weight of elements prepared for use as cigarette filter tips as regards problems encountered in using the tips in standard cigarette manufacturing and packing procedures.

The remaining steps of the process are generally old in the art of cigarette manufacture and may be suitbe known to those familiar with the art. Essentially the process is carried out as if the paper carried a charge of tobacco rather than fibrous filtering material. A possible distinction is that a heat treating station may be inserted into the path of movement of the fiber strand subsequent to the point at which the paper wrapper has been sealed. Such an after treatment of the continuous rod in its paper wrapper may be conducted in a heated die in order to accomplish final bonding and welding of the fibers sufiicient to insure against their displacement.

We have found it satisfactory to subject the finally wrapped rods to a temperature of 160 F. for four hours although the treating time may be varied from /2 to 24 hours depending on the particular plasticizing agent employed. Any temperature Within the range of 125 F. to 300 F. may be found satisfactory. It sometimes may be preferable to forego a final heat treatment and merely to allow the paper-wrapped rod to age for a period of, for instance, 24 hours to allow the plasticizer to penetrate and the bonding to become thorough and complete.

After the paper-covered rod has b en severed by the cutting apparatus into elements of appropriate length, these may be employed as the final product for use in pipes and cigarettes and cigar holders. If the filter material is to be used as a tip for cigarettes, known procedures for manufacturing filter tip cigarettes may be used. That is to say, elements of appropriate length may be fed to a joiner or other machine which serves to position the filter elements adjacent to tobacco bodies, join the two and sever the joined pieces at the proper points.

The product produced in accordance with the present invention is an elongated rod, normally cylindrical in form and customarily substantially the size of a cigarette in circumference and diameter, the rod being a strucurally unitary element composed of a dechannelized mass of randomly but primarily longitudinally oriented and transversely uniformly distributed crimped yarntype cellulose acetate fibers severed from a condensed reformed treated strand prepared from a continuous filament tow, or carded sliver, and a cylindrical paper retaining shell surrounding said mass at the periphery thereof, substantially all of the fibers of the mass being positively bonded Within said structurally unitary rod. In other words, the filter elements comprise paper encased rods of cellulose acetate fibers having the individual fibers thereof tack welded to each other, the rods being pervious to air along their longitudinal axes. That is to say, the bonding is not sufiiciently complete to give anything approaching a solid material with longitudinal passages but is rather a matter of spot bonding each filament at various points so as to give a material which has approximately the same physical characteristics as a plain, wrapped strand, but is yet suificiently unitary to prevent individual filaments being pulled out.

The invention is further illustrated in the following examples:

Example 1 Filter elements of various materials of approximately length and normal cigarette diameter were compared by passing through them tobacco smoke containing tars, nicotine, etc., distilled off from burning tobacco at normal burning temperatures. Analysis of the products retained by each filter indicated that a cellulose acetate element made in accordance with the invention gave superior results.

Example 2 A continuous filament tow of yarn-type unplasticized dull cellulose acetate containing 0.5% mineral oil lubricant and having 12 crimps per inch produced by a crimping machine, 5 denier per filament and 90,000 total denier was passed through a tension device and slack was removed from the tow. The tensioned tow next was passed through two pairs of controlled drafting rolls as illustrated in the drawings and was thence directed to an air jet bundle breaker of a type such as that illustrated in the drawing. Air jets from above and below the tow operating at a pressure of 15 to 20 pounds gauge and having a total of 600, 0.3 mm. holes were directed against the tow and succeeded in breaking the individually formed bundles therein and opening the tow to provide a fiber mass or bundle of Web-like form. Thence the opened fiber mass was sent to a chemical conditioning station where it was continuously sprayed with 10 to 15% of Monsanto Santicizer M17. The sprayed, webbed fiber bundle next was passed to a lofting tube in which it was subjected to a blast of air at 45 to 50 pounds gauge and ejected onto a scray plate. From the scray plate the lofted fiber bundle was passed through a guide horn Which tapered to an orifice of diameter and the fiber bundle was pulled therefrom as a shaped, organically wetted strand cylindrical in shape. The strand was passed onto amoving paper tape with which it subsequently was sized, covered and sealed in a fashion as described above. The product was severed into short lengths as cylindrically shaped rod-like filter elements of desired body, size, draw, resiliency, rigidity, weight, and transverse fiber distribution. By aftertreatment in an oven for approximately four hours at F. the bonding action of the plasticizer was completed. The elements contained no individual fiber bundles and no perceptible channels. The elements did not lose fibers inadvertently. An element prepared as described was formed into a filter-tipped cigarette on a conventional cigarette making machine and the cigarette produced gave a highly satisfactory filtered smoke. It was particularly noticeable that no fibers from the filter were plucked out by the tongue of the smoker in trials under normal conditions.

It should be borne in mind that among the special reasons why the instant process is ably adapted to the manufacture of improved cigarette filter tips are the advantages obtained in the use of continuous fiber strand, e. g., tow without sacrifice of filter quality or standardization. The invention thereby achieves not only an adequate filter of a character acceptable in all respects to the tobacco industry, but also a method adapted to the established manufacturing and packaging procedures of the industry.

The condition and relative arrangement of the fibers which results from various treatments to which the fiber strand and bundle are subjected is variously described in the present specification and the following claims as one in which, so to speak, a regular irregularity has been produced. Thus the rod may be described as consisting of randomly but primarily longitudinally oriented fibers. The various expressions employed obviously are intended to define that condition which exists when a tow in which all fibers are substantially longitudinally aligned and therefore mostly parallel are subjected to the various opening and dechannelizing treatments. In other words, the rods produced in accordance with the invention are composed of fibers which in the aggregate are parallel and longitudinally aligned but which have short portions divergent from the main fiber axis. Thus a strand which has been treated in accordance with the invention will consist of a fiber mass in which the fibers may be said to lie randomly but primarily in longitudinal orientation. The nature of a product made in accordance with the foregoing disclosure is illustrated in Figure 2.

As indicated in the foregoing description, tobacco smoke filtering elements may be produced in accordance with our invention from a wide variety of thermoplastic filamentary material. While a preferred material is cellulose acetate of the so-called yarn type, many other cellulose derivatives may be employed such as cellulose acetates of varying degrees of acetylation, cellulose propionates, cellulose butyrate, cellulose acetate butyrate and other organic acid esters of cellulose. Likewise, filamentary or fibrous material composed of synthetic thermoplastic material such as the various polyamids, polyacrylic and polyester materials typified by materials sold under trade names such as Nylon, Orlon, Acrilan, Dacron, and similar materials may be employed. In fact, any non-inflammable or slow burning synthetic thermoplastic material which is susceptible of surface or partial solvation may be used.

By the term solvation as employed in the present specification and claims is meant the formation, by the action of a solvent or plasticizer and/ or heat, of an adhesive condition in surface portions of fibers whereby there is produced a welding and adhesion between adjacent fibers contacting at such portions.

Certain subject matter disclosed in this application but not herein claimed is claimed in our copending continuation-in-part U. S. patent application Serial No. 374,168 filed August 14, 1953.

We claim:

1. An article of manufacture comprising an intermediate product for use in the manufacture of fibrous cigarette filter tip elements of which all fibers are coextensive, said packaged, substantially un' filament tow of which the intermediate product being a twisted, elongate, continuous filaments in the aggregate are substantially parallel, said tow having filaments of an unplasticized but plasticizable, dry-spun, cellulose acetate having an acetyl content of about 38-41%, said filaments being of about 3 to about 16 denier per filament and the total denier of the tow being within a range corresponding to about 80,000 to about 160,000, the individual filaments containing a high degree of crimp, of the order of about 10 to 15 crimps per inch, the tow having a low degree of lubrication pr vided by a small amount, of the order of about 0.5% by weight, of a non-toxic lubricant comprising a pharmaceutical grade mineral oil, the high order of crimp and low order of lubrication providing the tow with good blooming qualities.

2. An article of manufacture comprising an intermediate product for use in the manufacture of fibrous cigarette filter tip elements of which the fibers are parallelized and coextensive, said intermediate product being a packaged, substantially untwisted, elongate, crimped, continuous filament tow of which the filaments in the aggregate are substantially parallel, said tow having filaments of an unplasticized but plasticizable, dry-spun, cellulose acetate having an acetyl content of about 38-41%, said filaments being of about 3 to about 16 denier per filament and the total denier of the tow being within a range corresponding to about 80,000 to about 160,000, the tow having at least 4 crirnps per inch and a lowdcgree of lubrication provided by a small amount, of the order of about 0.5 by weight, of a non-toxic lubricant comprising a pharmaceutical grade mineral oil, the crimp and low order of lubrication providing the tow with good blooming qualities.

3. A packaged article of manufacture comprising an intermediate product as defined in claim 2 wherein the tow is made up of about 18,000 filaments of about 5 denier per filament.

References Cited in the file of this patent UNITED STATES PATENTS 964,489 Campo July 19, 1910 1,237,026 Fonseca Aug. 14, 1917 1,520,252 Linklater Dec. 23, 1924 1,572,342 Wiltsey Feb. 9, 1926 1,725,829 Ryley et a1 Aug. 27, 1929 1,967,585 Minton July 24, 1934 2,089,238 Whitehead Aug. 10, 1937 2,159,121 Alley May 23, 1939 2,172,946 Sutter Sept. 12, 1939 2,174,573 Finlayson Oct. 3, 1939 2,216,810 Dreyfus et al Oct. 8, 1940 2,228,383 Berl Ian. 14, 1941 2,259,150 Childs et al Oct. 14, 1941 2,271,184 Dreyfus I an. 27, 1942 2,324,838 Harz et a1 July 20, 1943 2,369,395 Heymann Jan. 13, 1945 2,411,660 Manning Nov. 26, 1946 2,433,531 Ryan Dec. 30, 1947 2,465,996 Bloch Apr. 5, 1949 2,476,582 Browne et al July 19, 1949 2,502,129 Brabander Mar. 28, 1950 2,688,380 MacHenry Sept. 7, 1954 FOREIGN PATENTS 665,278 Great Britain Ian. 23, 1952 OTHER REFERENCES American Handbook of Synthetic Textiles, first edition, published by Textile Book Publishers, Inc., 1952.

Patent Citations
Cited PatentFiling datePublication dateApplicantTitle
US964489 *Aug 14, 1908Jul 19, 1910Luigi CampoSmoking-filter for the removal of the impurities from tobacco-smoke.
US1237026 *Jan 31, 1917Aug 14, 1917Francisco E FonsecaSmoke-filter for cigars and cigarettes.
US1520252 *Aug 29, 1921Dec 23, 1924Linklater John TNicotine absorber
US1572342 *Mar 22, 1921Feb 9, 1926Charles E WiltseyMethod for making pipe filters
US1725829 *Jan 2, 1924Aug 27, 1929Celanese CorpManufacture or treatment of threads of artificial filaments
US1967585 *Apr 12, 1933Jul 24, 1934Minton Paul HAbsorbent filter cartridge for smoking appliances
US2089238 *Feb 2, 1934Aug 10, 1937Celanese CorpCrepe fabric and method of preparing same
US2159121 *May 14, 1937May 23, 1939American Mach & FoundryFilter tip for cigarettes
US2172946 *Sep 4, 1935Sep 12, 1939Sutter Roser BTobacco smoke purifier
US2174573 *Apr 7, 1937Oct 3, 1939Celanese CorpProduction of crimped cellulose derivative yarns
US2216810 *Jun 3, 1936Oct 8, 1940Celanese CorpManufacture of artificial yarns
US2228383 *Nov 22, 1939Jan 14, 1941Ernst BerlTobacco smoke filtering
US2259150 *Feb 29, 1940Oct 14, 1941Eastman Kodak CoProduction of crimped cellulose derivative staple fibers
US2271184 *Dec 31, 1940Jan 27, 1942Camille DreyfusStaple fiber and yarn
US2324838 *Jan 5, 1938Jul 20, 1943Harz WalterFilter material
US2369395 *Jan 21, 1942Feb 13, 1945American Viscose CorpYarnlike structure
US2411660 *May 22, 1943Nov 26, 1946Fred W ManningMethod of making filter cartridges, abrasive sheets, scouring pads, and the like
US2433531 *Jul 30, 1940Dec 30, 1947Kendall & CoMilk filter
US2465996 *Oct 4, 1946Apr 5, 1949Godfrey BlochYarn and fabric
US2476582 *Jun 11, 1945Jul 19, 1949Houdaille Hershey CorpMethod of making filter units
US2502129 *Jul 29, 1944Mar 28, 1950American Viscose CorpMethod of treating filamentary materials
US2688380 *Jul 13, 1951Sep 7, 1954American Viscose CorpFilter cartridge
GB665278A * Title not available
Referenced by
Citing PatentFiling datePublication dateApplicantTitle
US2908045 *Oct 20, 1955Oct 13, 1959Eastman Kodak CoMethod for removing false twist and longitudinal folds from continuous filament crimped tow
US2909182 *Dec 9, 1954Oct 20, 1959Pluess Staufer North AmericanTobacco smoke filters
US2953837 *Aug 28, 1958Sep 27, 1960Eastman Kodak CoFilter tow made from fine filaments and low total denier
US2953838 *Nov 27, 1957Sep 27, 1960Eastman Kodak CoTow for use in the production of tobacco smoke filters
US2974101 *May 22, 1957Mar 7, 1961Rohm & HaasIon-exchange assemblies and methods of treating liquids
US3016581 *Nov 7, 1957Jan 16, 1962Eastman Kodak CoApparatus for opening continuous multifilament crimped tow
US3016945 *Sep 17, 1958Jan 16, 1962Eastman Kodak CoMethod and apparatus for forming tobacco smoke filters
US3021242 *Dec 16, 1957Feb 13, 1962Eastman Kodak CoBonding additives onto filament filters
US3026226 *Dec 9, 1957Mar 20, 1962Eastman Kodak CoProcess of manufacturing filters
US3038478 *May 23, 1960Jun 12, 1962Eastman Kodak CoMethod for producing rigid tobacco smoke filters
US3043736 *Mar 2, 1959Jul 10, 1962Eastman Kodak CoMethod for making additive filters
US3050430 *Nov 12, 1959Aug 21, 1962Eastman Kodak CoJet and method of filter manufacture
US3065519 *Feb 26, 1958Nov 27, 1962English Rose LtdMethod of producing crimped thermoplastic yarns
US3079663 *May 21, 1958Mar 5, 1963Eastman Kodak CoMethod and apparatus for producing tobacco smoke filters
US3080611 *Nov 8, 1960Mar 12, 1963Eastman Kodak CoMethod for the production of cigarette filters
US3093583 *Oct 14, 1958Jun 11, 1963Robert Bosch G M B H FaFilters and processes for manufacturing the same
US3095632 *Jul 14, 1961Jul 2, 1963Eastman Kodak CoMethod for continuously opening crimped tow
US3099594 *May 5, 1960Jul 30, 1963Eastman Kodak CoMethod for blooming filter tow
US3103220 *Jun 12, 1959Sep 10, 1963Celanese CorpFilter cigarettes
US3126095 *Jan 9, 1961Mar 24, 1964 Debundlized tow
US3173188 *Nov 3, 1961Mar 16, 1965Eastman Kodak CoTobacco smoke filter formation
US3177872 *Nov 23, 1962Apr 13, 1965Eastman Kodak CoVaginal tampon and applicator
US3194002 *Jul 25, 1962Jul 13, 1965Eastman Kodak CoMultifilament yarn of non-regular cross section
US3202155 *Jun 5, 1964Aug 24, 1965Eastman Kodak CoLight weight cigarette filter
US3205107 *Dec 2, 1959Sep 7, 1965Eastman Kodak CoProcess for making filament tobacco smoke filters
US3226795 *May 23, 1962Jan 4, 1966Celanese CorpMethod for producing a high bulk filamentary material
US3227791 *Aug 8, 1962Jan 4, 1966Eastman Kodak CoProcess for producing tobacco smoke filter elements from cellulose ester filaments containing polyethylene glycol
US3232268 *May 15, 1962Feb 1, 1966Celanese CorpApparatus for lubricating cigarette-filter-forming filamentary material
US3255580 *May 22, 1959Jun 14, 1966Spunize Co Of America IncMethod of blending or combining fibers and product
US3346682 *Mar 16, 1962Oct 10, 1967Du PontMethod for making a filtering medium from plexifilamentary material
US3366521 *Jan 30, 1967Jan 30, 1968Celanese CorpMethod for the production of cellulose acetate cigarette filter tips
US3393120 *Sep 22, 1965Jul 16, 1968Eastman Kodak CoPolyolefin tow for cigarette filters
US3396073 *May 5, 1966Aug 6, 1968Eastman Kodak CoFilter tow of crimped continuous polyolefin filaments
US3402096 *Apr 13, 1967Sep 17, 1968Monsanto CoVariable bulk continuous filament yarn
US3438806 *Nov 18, 1966Apr 15, 1969American Cyanamid CoProcess for the manufacture of cigarette containing cyanamide-cellulose acetate filter elements
US3640742 *Jul 3, 1967Feb 8, 1972Eastman Kodak CoPlasticizer blend for cellulose esters
US4243053 *Feb 5, 1979Jan 6, 1981Gulf & Western CompanyFilter cigar
US4369117 *May 12, 1980Jan 18, 1983American Hospital Supply CorporationSerum separating method and apparatus
US5225277 *Nov 16, 1990Jul 6, 1993Daicel Chemical Industries, Ltd.Acetate tow having high crimp modulus and manufacturing method thereof
US5618620 *May 18, 1995Apr 8, 1997Daicel Chemical Industries, Ltd.Filter rod for filtering the smoke of a cigarette
US5947126 *May 29, 1997Sep 7, 1999Eastman Chemical Co.Environmentally disintegratable tobacco smoke filter rod
US5970988 *Sep 25, 1995Oct 26, 1999Eastman Kodak CompanyEnvironmentally non-persistant cellulose ester fibers
US6133439 *May 14, 1999Oct 17, 2000Eastman Chemical CompanyEnvironmentally non-persistant cellulose ester fibers
US6983520 *Sep 26, 2003Jan 10, 2006Celanese Acetate, LlcMethod and apparatus for making an absorbent composite
US7152288 *Jul 7, 2005Dec 26, 2006Celanese Acetate LlcStuffer box crimper and a method for crimping
US7896011Jul 31, 2007Mar 1, 2011Philip Morris Usa, Inc.Method of forming a filter component
US8434498Aug 11, 2009May 7, 2013R. J. Reynolds Tobacco CompanyDegradable filter element
US8671652Apr 29, 2011Mar 18, 2014Eastman Chemical CompanyPackages, packaging systems, methods for packaging and apparatus for packaging
US8720450Jul 30, 2010May 13, 2014R.J. Reynolds Tobacco CompanyFilter element comprising multifunctional fibrous smoke-altering material
US8973588Jul 29, 2011Mar 10, 2015R.J. Reynolds Tobacco CompanyPlasticizer composition for degradable polyester filter tow
DE1182571B *Aug 8, 1958Nov 26, 1964Mueller Paul AVorrichtung zum Herstellen von Tabakwarenfiltern
DE1275428B *Feb 19, 1965Aug 14, 1968Eastman Kodak CoVerfahren zur Herstellung von Tabakrauchfilterelementen
EP0880907A2May 25, 1998Dec 2, 1998Eastman Chemical CompanyEnvironmentally disintegratable tobacco smoke filter rod and method for producing same
WO2008017958A2 *Aug 8, 2007Feb 14, 2008Philip Morris ProdRapidly degradable filters by electron ionization
WO2011019646A1Aug 9, 2010Feb 17, 2011R.J. Reynolds Tobacco CompanyDegradable filter element
WO2012003092A1Jun 15, 2011Jan 5, 2012R.J. Reynolds Tobacco CompanyDegradable filter element for smoking article
WO2012012053A1Jun 16, 2011Jan 26, 2012R.J. Reynolds Tobacco CompanyBiodegradable cigarette filter
WO2012016051A2Jul 28, 2011Feb 2, 2012R. J. Reynolds Tobacco CompanyFilter element comprising multifunctional fibrous smoke-altering material
WO2012166302A2May 8, 2012Dec 6, 2012R.J. Reynolds Tobacco CompanyCoated paper filter
WO2012177482A1Jun 14, 2012Dec 27, 2012Eastman Chemical CompanyFilters having improved degradation and methods of making them
WO2012177483A1Jun 14, 2012Dec 27, 2012Eastman Chemical CompanyCellulose esters having mixed-phase titanium dioxide particles for improved degradation
WO2013009410A1Jun 5, 2012Jan 17, 2013R. J. Reynolds Tobacco CompanySegmented cigarette filter for selective smoke filtration
WO2013019413A2Jul 18, 2012Feb 7, 2013R.J. Reynolds Tobacco CompanyDegradable cigarette filter
WO2013019616A2Jul 27, 2012Feb 7, 2013R. J. Reynolds Tobacco CompanyPlasticizer composition for degradable polyester filter tow
Classifications
U.S. Classification206/417, 428/401, 210/508, 28/283, 428/369, 131/343
International ClassificationA24D3/02, B01D39/18, A24D3/10, D02G1/00, A24C5/24, D02G1/12, D06M13/144, A24D3/14, D06M13/224
Cooperative ClassificationA24D3/022, A24D3/14, B01D39/18, D06M13/144, A24D3/0237, D06M7/00, D06M13/224, D06M2200/40, D02G1/12
European ClassificationD06M7/00, A24D3/02D3L, D06M13/144, A24D3/14, A24D3/02F3, B01D39/18, D02G1/12, D06M13/224