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Publication numberUS2801213 A
Publication typeGrant
Publication dateJul 30, 1957
Filing dateAug 31, 1955
Priority dateAug 31, 1955
Publication numberUS 2801213 A, US 2801213A, US-A-2801213, US2801213 A, US2801213A
InventorsFrank O Beuckman, William M Tucker
Original AssigneeEastman Kodak Co
Export CitationBiBTeX, EndNote, RefMan
External Links: USPTO, USPTO Assignment, Espacenet
Method of electroplating on titanium
US 2801213 A
Abstract  available in
Previous page
Next page
Claims  available in
Description  (OCR text may contain errors)

United States Patent 2,801,213 METHOD or ELECTROPLATING N TITANIUM Frank O. Beuckman and William M. Tucker, Rochester,

N. Y., assignors to Eastman Kodak Company, Rochester, N. Y., a corporation of New Jersey No Drawing. Application August 31,1955, Serial No. 531,812

1 Claim. (Cl. 204-32) This invention relates to electroplating and more particularly to electroplating adherent electrodeposits of metals on titanium such as on very thin vacuum coated deposits of titanium.

Heretofore to obtain adherent deposits on titanium, strong pickling solutions and reagents have been employed. These solutions not only remove the oxide layer from the titanium but etch it as well. We have found in the case of very thin layers of vacuum coated titanium that these previous methods of effecting adherence of metals to titanium are entirely unsuited because the vacuum coated titanium layers are destructively attacked.

An object of the present invention is, therefore, to provide an improved electroplating process for plating metals onto articles which have been coated with a relatively thin titanium layer by vacuum coating methods.

Another object of this invention is to provide an improved electroplating plating process whereby metals such as copper and nickel may be plated onto thin titanium coatings without attacking or etching the titanium.

Other objects will appear hereinafter.

In accordance with the invention these and other objects are attained by cathodically cleaning the titanium surface to be plated, activating the surface in a stannous chloride activating solution, coating the titanium surface by immersion in a copper reducing solution or gold chloride dip, electroplating copper thereon from a special copper solution and copper striking the surface in a copper cyanide solution. The work is preferably rinsed between each of the above steps.

The invention is presented in more detail in the following examples:

Example 1 A surface having a vacuum coated layer of titanium thereon is cleaned by being made the cathode in an aqueous alkaline cleaner solution containing 8 ounces per gallon of sodium orthosilicate and 2% by dry weight of orthosilicate of a non-ionic surfactant. The temperature of the solution was maintained at 160 F. Three volts were applied for 5 minutes. The cleaned titanium surface was then rinsed and given a two minute dip in an aqueous stannous chloride activating solution. The activating solution contained 1% stannous chloride and 1% hydrochloric acid. After rinsing, a reduced copper mirror was placed on the titanium surface by dipping it into a copper reducing solution containing:

Copper sulfate grams 2 After rinsing, the surface was electroplated in a special copper solution containing:

Copper sulfate grams 25 Rochelle salts do Triethanolamine milliliters 25 Water ter..- 1

A current of 28 amperes per square foot was employed for 15 minutes. The solution was held at about 20 C. The plated surface was rinsed and copper plated in a copper cyanide solution comprising:

with a bath temperature of F.

Example 2 A surface having a vacuum coated layer of titanium thereon is cleaned by being made the cathode in the cleaner solution described in Example 1, the temperature of which was maintained at a temperature of F. The cleaned titanium surface was then rinsed and given a two minute dip in an aqueous stannous chloride activating solution containing 1% stannous chloride and 1% hydrochloric acid. After rinsing the titanium surface was coated with a layer of gold by chemical displacement in a 1% gold chloride solution at room temperature. A good film forms in approximately l2 minutes. The gold layer promotes the formation of a better and thicker copper mirror. The surface was rinsed and a reduced copper mirror was placed thereon by dipping it into the copper reducing solution shown in Example 1. The plated surface was then rinsed and further plated in the copper cyanide solution shown in Example 1 while employing a current of 15 amperes per square foot with an electrolyte temperature of 140 F.

Further examples of this technique would involve the formation of silver or gold mirrors by chemical reduction over the sensitized titanium surface and their subsequent plating with copper.

The mirrors may alternatively be plated with nickel in lieu of copper provided the nickel deposit has little internal stress.

On massive objects of titanium the process may be further modified by coating the copper mirror or gold immersion coating directly with nickel phosphorous al- 10y as deposited from the catalytic chemical reduction processes as disclosed in Brenner et al. Patent No. 2,532,283 of December 5, 1950.

Palladous chloride may be substituted for the gold chloride to form a palladium layer followed by nickelphosphorous alloy coating by catalytic chemical reduction.

Our process for plating metals onto thin layers of titanium more particularly titanium coated by vacuum methods gives excellent adhesion without removing a measurable amount of vacuum coated titanium.

We claim:

A method of electroplating a firmly adhering metal coating onto a thin titanium layer which comprises cathodically cleaning the titanium surface in an alkaline solution containing sodium orthosilicate, activating the cleaned surface in an aqueous stannous chloride solution, adding a relatively thin copper coating thereover by dipping into an aqueous copper reducing solution containing copper sulfate, sodium hydroxide, Rochelle salts, potassium sulfate and formalin, electroplating a copper layer thereover from an electrolyte comprising copper sulfate, Rochelle salts, triethanolamine and water While employing a current of 28 amperes per square foot and further electroplating the surface in a copper cyanide electrolyte comprising copper cyanide and free sodium cyanide while holding the pH of the solution at approximately 10.

(References on following page) Patented July 30, 1957 References Cited in the file of this patent UNITED STATES PATENTS Roux June 22, 1915 Merritt Aug, 9, 1921 De Trairup Oct. 13, 1931 Bergstrom Feb. 15, 1955 FOREIGN PATENTS Great Britain May 13, 1948 OTHER REFERENCES Handbook of Titanium Metal, Titanium Metals Corporation of America, 7th Edition, Aug. 1, 1953, page 92. Principles of Electroplating and Electra-Forming, Blum 5 and Hogaboon, 3rd Edition, pages 226-227, McGraw-Hill Book Co., Inc. (1949).

Patent Citations
Cited PatentFiling datePublication dateApplicantTitle
US1144000 *Jan 19, 1914Jun 22, 1915Aluminum Francais Soc DTreament of surfaces of aluminum or alloys of aluminum in order to prepare them for receiving a metallic deposit.
US1387426 *Oct 13, 1919Aug 9, 1921Merritt Metals CompanyMethod of soldering aluminum
US1827142 *Dec 4, 1929Oct 13, 1931De Trairup Martin KristensenProcess for the treatment of aluminum
US2702253 *Nov 1, 1950Feb 15, 1955Gasaccumulator Svenska AbSurface metallizing method
GB601825A * Title not available
Referenced by
Citing PatentFiling datePublication dateApplicantTitle
US2900715 *May 28, 1956Aug 25, 1959Steel Improvement & Forge CoProtection of titanium
US2938841 *Apr 13, 1956May 31, 1960Olin MathiesonPreparation of zirconium for cold working
US3291714 *Jan 8, 1962Dec 13, 1966Ici Australia LtdElectrodes
US4153742 *Jul 8, 1977May 8, 1979Basf AktiengesellschaftManufacture of electrodes
US4294670 *Oct 29, 1979Oct 13, 1981Raymond Louis WPrecision electroplating of metal objects
US5009966 *Sep 19, 1989Apr 23, 1991Diwakar GargHard outer coatings deposited on titanium or titanium alloys
US5456819 *Oct 1, 1993Oct 10, 1995The United States Of America As Represented By The Secretary Of CommerceProcess for electrodepositing metal and metal alloys on tungsten, molybdenum and other difficult to plate metals
US6656606Aug 17, 2000Dec 2, 2003The Westaim CorporationElectroplated aluminum parts and process of production
US6692630Aug 9, 2001Feb 17, 2004The Westaim CorporationElectroplated aluminum parts and process for production
U.S. Classification205/182, 205/116, 428/674, 427/328, 205/212, 428/935, 428/660, 205/187
International ClassificationC25D5/38
Cooperative ClassificationC25D5/38, Y10S428/935
European ClassificationC25D5/38