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Publication numberUS2816066 A
Publication typeGrant
Publication dateDec 10, 1957
Filing dateMay 14, 1956
Priority dateMay 14, 1956
Publication numberUS 2816066 A, US 2816066A, US-A-2816066, US2816066 A, US2816066A
InventorsAlexander G Russell
Original AssigneeWestern Electric Co
Export CitationBiBTeX, EndNote, RefMan
External Links: USPTO, USPTO Assignment, Espacenet
Methods of plating articles
US 2816066 A
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Description  (OCR text may contain errors)

A. G. RUSSELL METHODS oF PLATING ARTICLES Filed May 14, 1956 n' vez /4 "t/f1? ff ,ff/5.4 f-/'-fg /71/1217'06 A? caff/Sra 5y (ifs.-

United States Patent O lVIETHODS F PLATING ARTICLES Alexander G. Russell, Arden Hills, St. Paul, Minn, as-

sgnor to Western Electric Company, Incorporated, New York, N. Y., a corporation of New York Application May 14, 1956, Serial No. 584,549

1 Claim. (Cl. 204-37) This invention relates to methods of plating articles and more particularly to methods yof electroplating articles made of metals which are normally diicult to electroplate.

An object of this invention is to provide methods of plating articles.

Another object of this invention is to provide methods of electroplating articles made of metals which are normally dicult to electroplate.

In a method illustrating features of the invention, a thin strike layer of metal is electroplated onto a metallic article and the article is then heat treated in a protective atmosphere to alloy the strike layer with the metallic article. A final layer of desirable metal is then electroplated onto the article to a desired thickness.

A complete understanding of the invention may be obtained from the following detailed description of a method forming a specific embodiment thereof, when read in conjunction with the appended drawing, in which Fig. 1 is a cross-sectional view of a tank containing an electrolytic solution in which a metallic electrode and the article to be plated are submerged;

Fig. 2 is an enlarged cross-sectional View of an article to be plated;

Fig. 3 is the disclosure of Fig. 2 after a thin strike layer has been plated on the article;

Fig. 4 is the disclosure of Fig. 3 after the article has been heat treated to alloy the strike layer with the surface of the article; and

Fig. 5 is the disclosure of Fig. 4 after another layer of metal has been electroplated onto the article.

Referring now in detail to the drawing, a tank 11 is shown containing an electrolytic solution 12 in which an article 14 made of molybdenum and a gold electrode 15 are suspended in submerged positions. A suitable electrolytic solution may contain 3-3.5 ounces of potassium gold cyanide per gallon; 7-7.5 ounces of potassium cyanide per gallon; and 0.5-0.75 ounce of potassium hydroxide per gallon of solution. Current from a power source 17 connected t-o the article 14 and the gold electrode 15 ows therethrough to plate a thin strike layer 19 of gold on the article 14, the cathode current density being lamperes per square foot. When this layer 19 is approximately 000001-00001 inch thick the article 14 is removed from the electrolytic solution 12.

The plated article 14 is then placed in a heat treating furnace (not shown) of a well-known type utilizing a vacuum or other neutral or reducing atmosphere for the protection of the article during the heat treating operation. A suitable protective atmosphere may consist of thermally cracked ammonia which has the composition of approximately 75% hydrogen and 25% nitrogen by volume. 'Ihe article 14 is heat treated at 2000-2500 F. for approximately tive minutes to cause the strike layer ICC 19 of gold to become alloyed or diffused with the surface of the article 14 whereby the strike layer adheres firmly to the article, this alloyed or diffused zone being represented in the drawing by the numeral 20. The strike layer 19 is thin enough that it will not blister when heated, and is thick enough that it will not dissolve and disappear into the article 14 during the heat treating operation.

After the heat treating operation, the article 14 is removed from the furnace and replaced in the electrolytic solution 12. The power source 17 is then connected to the article 14 and a final layer 22 of gold, or any other metal which can be electroplated onto gold, is electroplated on the article. This final layer 22 may be of any desirable thickness, and will be firmly bonded to the article 14.

In the above-described example of a method illustrating features of the invention, a strike layer of either copper or nickel may be substituted for the gold strike layer 19, and the final layer 22 may be of any metal or alloy which can be electroplatcd on copper or nickel. If a copper strike layer is used, the article is heat treated at approximately 1700-2000" F. for approximately lfive minutes. If a nickel strike layer is used, the article is heat treated at 20002300 F. for approximately five minutes.

The abovedescribed method can be also used to electroplate other ditiicult-to-plate metals and alloys such as tungsten, cobalt and nickel alloys. Another example of a method illustrating features of the invention may be as follows: a strike layer of nickel is electroplated to a depth of 0.00001"-0.000l, on an article made 4of an alloy consisting of cobalt, 9.5% iron and 0.5% manganese, and the article is heat treated at approximately 20002300 F. for approximately five minutes whereby the strike layer becomes alloyed with or partly diffused into the article and is thus firmly bonded to it. A final layer of a desirable metal is then electroplated on the nickel-plated article. This final layer may be of any desirable thickness, and will adhere firmly to the article.

It is to be understood that the above-described arrangements are simply illustrative of the application of the principles of this invention. Numerous other arrangements may be readily devised by those skilled in the art which will embody the principles of the invention and fall within the spirit and scope thereof.

What is claimed is:

The method of plating articles made -of metal of the group consisting of molybdenum, tungsten, cobalt, molybdenum-base alloys, tungsten-base alloys and cobalt-base alloys, comprising electroplating such an article with a strike layer of gold, said strike layer having a thickness within the range 0.00001" to 0.0001, heat treating the article to a temperature within the range of 2000J to 2500 F. for 3 to l0 minutes, and electroplating the heat treated article with another layer of gold.

References Cited in the tile of this patent UNITED STATES PATENTS 2,116,927 Germer May l0, 1938 2,195,499 Schofield Apr. 2, 1940 2,683,835 Freedman July 13, 1954 FOREIGN PATENTS 283,288 Great Britain Ian. 9, 1928 473,479 Great Britain Oct. 11, 1937

Patent Citations
Cited PatentFiling datePublication dateApplicantTitle
US2116927 *Apr 13, 1937May 10, 1938Germer EdmundElectrical discharge device
US2195499 *May 25, 1937Apr 2, 1940Schofield Joseph KProcess of metal coating
US2683835 *Feb 19, 1949Jul 13, 1954Rca CorpElectron tube structure
GB283288A * Title not available
GB473479A * Title not available
Referenced by
Citing PatentFiling datePublication dateApplicantTitle
US2886499 *Jan 7, 1957May 12, 1959Glenn R SchaerProtective metal coatings for molybdenum
US3123543 *Nov 24, 1961Mar 3, 1964 Method and apparatus for feeding articles
US3147547 *Mar 10, 1960Sep 8, 1964Gen ElectricCoating refractory metals
US3159462 *Sep 24, 1962Dec 1, 1964Int Rectifier CorpSemiconductor and secured metal base and method of making the same
US3223599 *Apr 15, 1963Dec 14, 1965Beckman Instruments IncHolding plate for electroplating a detonator plug
US3238025 *Dec 31, 1962Mar 1, 1966Anaconda Wire & Cable CoHigh-temperature conductor
US3281264 *Jan 31, 1963Oct 25, 1966Coast Metals IncMethod of gold-plating aluminum
US3342564 *Jan 22, 1965Sep 19, 1967Martin Metals CompanyComposite castings
US3386896 *Nov 5, 1964Jun 4, 1968Bell Telephone Labor IncElectroplasting onto molybdenum surfaces
US3499740 *Oct 24, 1966Mar 10, 1970Int Nickel CoOxidation resistant coated article containing iridium,ruthenium,molybdenum or tungsten
US3753665 *Nov 12, 1970Aug 21, 1973Gen ElectricMagnetic film plated wire
US3963455 *Feb 26, 1975Jun 15, 1976Lea-Ronal, Inc.Electrodeposited gold plating
US4397086 *Jan 26, 1981Aug 9, 1983The Bendix CorporationMethod of fabricating a socket type electrical contact
US4551184 *Nov 13, 1984Nov 5, 1985Inco LimitedGold-nickel coins
US20110256759 *Jun 28, 2010Oct 20, 2011Astrium LimitedConnector
Classifications
U.S. Classification205/170, 428/935, 205/224, 205/266, 428/663, 428/668, 428/926, 428/665
International ClassificationC25D5/50, C25D5/28
Cooperative ClassificationC25D5/38, Y10S428/935, Y10S428/926, C25D5/50
European ClassificationC25D5/38, C25D5/50