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Publication numberUS2901722 A
Publication typeGrant
Publication dateAug 25, 1959
Filing dateApr 21, 1953
Priority dateApr 21, 1953
Publication numberUS 2901722 A, US 2901722A, US-A-2901722, US2901722 A, US2901722A
InventorsJr William Arnott
Original AssigneeBurndy Corp
Export CitationBiBTeX, EndNote, RefMan
External Links: USPTO, USPTO Assignment, Espacenet
Coating for metal to reduce electrical contact resistance
US 2901722 A
Abstract  available in
Images(1)
Previous page
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Claims  available in
Description  (OCR text may contain errors)

Aus- 25, 1959 w. ARNQTT, JR 2,901,722

COATING FOR METAL TO REDUCE ELECTRICAL CONTACT RESISTANCE VFiled April 21. 1953 United States Patent() COATING FOR METAL TO REDUCE ELECTRICAL CONTACT RESISTANCE WilliamvArnott, Jr., New Canaan, Conn., assignor to Burndy Corporation, a corporation of New York Application April 21, 1953, Serial No. 350,251

1 Claim. (Cl. 339-114) My invention relates to Ithe art of protecting metals from corrosion and oxidation. For example, aluminum to aluminum, and aluminum to copper electrical connections are subject to corrosion and oxidation. This causes the electrical resistance of the joint to increase rendering the connection unsatisfactory.

Hitherto the problem was resolved by the use of tapes, petroleum grease, or putty-like compounds which were applied manually over the joint. These methods were laborious and time consuming to insure complete coverage of the joint; moreover, they involved solid or semisolid materials which are incapable of penetrating completely into cracks and interstices. Another disadvantage is the relatively high contact resistance when applied to an aluminum contacting face. Further, these prior coverings age and change their physical properties. A further objection is found in the disruption in the covering when the connection is subjected to mechanical motion causing a slight separation of the parts.

Non-oxidizing metal particles are sometimes placed in petroleum compounds. The theory is that the petroleum prevents oxidation and the metal particles mechanically break the aluminum oxide iilm and provide current paths through the film and across any voids between metal surfaces.

Accordingly, the various objects of my invention are to provide a new type of metal protection against corrosion and oxidation, a metal protection which is especially useful in electrical conductors, and particularly when used on aluminum to aluminum and aluminum to copper connections; to provide a metal protection which may be easily, quickly and conveniently applied to the connection, and which will possess other physical characteristics advantageous for solving the particular problems here involved.

These and other objects are accomplished and my new Aresults obtained, as will be apparent from the device and methods described in the following specification and shown in the accompanying drawing, in which:

Fig. 1 is an exploded view of a connector shown in longitudinal cross-section, prepared in accordance with my invention, and a conductor ready for insertion therein.

Fig. 2 is an assembled View of the same.

Referring more in detail to the drawing, reference numeral designates a terminal connector comprising a barrel 12 and a terminal tongue 14 containing a perforation 16 for bolted attachment to a supporting structure. Within the hollow portion of the barrel is shown a mixture prepared in accordance with my invention.

The exposed end 18 of the conductor, insulated as at 20, is forced into the hollow barrel as is shown in Fig. 2, forcing the mixture 15 into intimate contact with all the interstices and crevices of the conductor and connector. An indentation 22 is then applied to the connection to secure the connector to the conductor. The mixture 15 may be applied to the finished connection, as is shown in Fig. 2.

I have found that zinc, tin, cadmium and the like rela- ICC 2 tively non-oxidizing metal particles, when mixed with--a low molecular weight polymer, such as a form ofpolybutene, satisfactorily accomplishes the various objects of my invention. This material is supplied as Vistac No. l by Advance Solvents & Chemicals Corp., New York, N .Y. Various tests established that this material, when used'on electrical connections, was superior to other types of covering used for the same purpose. Joints covered with this material have a lower initial electrical resistance;r l they show smaller increases in electrical resistance after-exposure in a salt spray corrosion chamber; andthe material resists oven aging better than other types.

I also found that the material does not affect rubber insulation materials which are adversely hardened, swelled and deteriorated by some other joint covering materials; that when used on oil-filled electric cables it will not adversely affect the power factor of the cable oil; and that it makes no difference in dielectric breakdown strength when applied to joints on paper-insulated cables. l further found that the material will prevent oxidation on aluminum after the oxide is removed mechanically. The material is hydrophobic and water-repellent. Whereas other covering materials will dry and crack to expose the metal when the dimensions are changed, my material is non-drying and permanently wet. It will creep into crevices and interstices and exclude air and moisture therefrom.

In application the polybutene is mixed with the metal particles in any suitable proportion. I have tested satisfactorily one part of polybutene to four parts of zinc dust, by weight, as well as one to one ratio. The connectors may be supplied lled with the mixture and corked; or in cans, bottles or collapsible tubes.

Some specific properties of polybutene are:

The material does not change its physical nature with age. Excess material will drip off a connection leaving a thin iilm.

Another tacky polybutene which will cling to metallic surfaces is polyisobutylene having the trade name Vistanex, supplied by Enjay Co., Inc.

I have thus described my invention, but I desire it understood that it is not confined to the particular forms or uses shown and described, the same being merely illustrative, and that the invention may be carried out in other ways without departing from the spirit of my invention, and, therefore, I claim broadly the right to employ all equivalent instrumentalities coming within the scope of the appended claim, and by means of which objects of my invention are attained and new results accomplished, as it is obvious that the particular embodiments here shown and described are only some of the many that can be employed to attain these objects and accomplish these results.

I claim:

An electrical connection comprising an electrical conductor, a connector for connecting said conductor to another conductor, said connector and conductor provided with contacting faces covered with a mixture of nondrying, permanently wet polymer of polybutene and zinc metal particles.

(References on following page) D Y c Reference'sCitd in the 'tile of this patent UNITED STATES PATENTS 1,863,429 Willmore June 14, 1932 `2,409,356 Young v1 1.-. o ct. 15, `1946 5 @1,423,290 Bonwitt ;Iuly 1, 1947 V2,437,220 Bonwitt aahaagceAa-a- A Mar. 2, 1948 FOREIGN PATENTS l225,877 Great Britain 1.. Apr. '9, 1925 10 OTHER REFERENCES ,'Pubi'ipafi/qn alecuical wond, ,'Juiy i4, 1952 pages 1295135. and139=1f41. McGraw-Hill lpublication. Copy in Div. 69, Class 174-494.

Publication II-Catalogue of the Advance Solvents and Chemical Corp., 245 5th Avenue, New York, N.Y., entitled Vistanex, a product of Standard Oil Development Co. Received January 25, 1939. In Div. 50.

Publication III-Polybutene etc. (Thomas et 211.), published in Industrial and Engineering Chemistry, March 1940 (page 301 relied on).v Copy in Scientific Library and Div. 69. Class 174-110 (4.2). y

Publication IVA-,Vistanex published by the Enjay Company, Inc., 15 West 51st Street, New York 19, N.Y. Copyright 1948. Copy in the Scientific Library and Div. 50.

Patent Citations
Cited PatentFiling datePublication dateApplicantTitle
US247220 *May 17, 1881Sep 20, 1881 Bag-holder
US1863429 *Nov 18, 1929Jun 14, 1932Aluminum Co Of AmericaBus bar joint
US2409336 *Sep 20, 1941Oct 15, 1946Jasco IncChemical-resistant coating material
US2423290 *May 3, 1945Jul 1, 1947Burndy Engineering Co IncAluminum conducting surface treatment
GB225877A * Title not available
Referenced by
Citing PatentFiling datePublication dateApplicantTitle
US3073785 *Jul 2, 1959Jan 15, 1963 Electrically conductive polymeric
US3156763 *Jun 19, 1961Nov 10, 1964Aluminum Co Of AmericaElectrical conductor joining practices
US3252215 *Dec 6, 1961May 24, 1966Dow Chemical CoMethod of coating a magnesium metal article
US3699275 *Nov 18, 1970Oct 17, 1972Insul 8 CorpComposite electrical conductor
US3730310 *Sep 30, 1971May 1, 1973Hk Porter CoCurrent conductor rail
US4214121 *Mar 3, 1978Jul 22, 1980Charneski Mitchell DElectrical joint compound
US4241490 *May 12, 1977Dec 30, 1980CCL Systems, LimitedMethod of applying metal sleeve to concrete reinforcing bar, metal sleeve and swaged connection
US4312793 *Mar 3, 1980Jan 26, 1982Charneski Mitchell DElectrical joint compound
US4386354 *Dec 15, 1980May 31, 1983Plessey Overseas LimitedElectromagnetic noise suppression
US5090923 *Sep 28, 1990Feb 25, 1992Burndy CorporationDedicated contact aid for connectors utilizing high speed installations
US5362250 *Nov 25, 1992Nov 8, 1994Raychem CorporationCoaxial cable connection method and device using oxide inhibiting sealant
US5490803 *Nov 8, 1993Feb 13, 1996Raychem CorporationCoaxial cable connection method and device using oxide inhibiting sealant
US5532433 *May 19, 1994Jul 2, 1996Yazaki CorporationWaterproof-type terminal connection structure and method of producing same
US5567174 *Jun 2, 1994Oct 22, 1996The Ericson Manufacturing Co.Water tight grease filled connector with strain relief
US6334798 *Apr 6, 2000Jan 1, 2002Yazaki CorporationMethod of and structure for connecting electric wire and connecting terminal
US7896712 *Dec 20, 2006Mar 1, 2011Tensolite, LlcIntegral bonding attachment
US7906046Apr 4, 2008Mar 15, 2011Panduit Corp.Antioxidant joint compound and method for forming an electrical connection
US7954235 *Oct 20, 2009Jun 7, 2011Delphi Technologies, Inc.Method of making a seal about a copper-based terminal
US8246390Feb 28, 2011Aug 21, 2012Tensolite, LlcIntegral bonding attachment
US8268196Jan 13, 2011Sep 18, 2012Panduit Corp.Antioxidant joint compound and method for forming an electrical connection
US20120318576 *Jun 19, 2012Dec 20, 2012Yazaki CorporationConnecting structure and connecting method for electric cables
CN102025090B *Sep 17, 2010Jan 7, 2015德尔菲技术公司用保形涂层制作密封电缆芯和端子的改进电连接的方法
CN102025091B *Sep 17, 2010Jan 7, 2015德尔菲技术公司使密封电缆芯和端子改进的电连接的方法
DE19727314B4 *Jun 27, 1997Jan 12, 2012Bayerische Motoren Werke AktiengesellschaftCrimpverbindung
EP2107643A2 *Mar 24, 2009Oct 7, 2009Panduit Corp.Antioxidant joint compound and method for forming an electrical connection
Classifications
U.S. Classification439/203, 403/285, 439/877, 174/94.00R, 403/269, 403/267, 439/936, 252/512, 403/268
International ClassificationH01R4/62, H01B1/22, C09D5/25
Cooperative ClassificationH01B1/22, Y10S439/936, H01R4/62
European ClassificationH01B1/22, H01R4/62