|Publication number||US2989798 A|
|Publication date||Jun 27, 1961|
|Filing date||Jun 30, 1955|
|Priority date||Jun 30, 1955|
|Publication number||US 2989798 A, US 2989798A, US-A-2989798, US2989798 A, US2989798A|
|Inventors||Douglas G Bannerman|
|Original Assignee||Du Pont|
|Export Citation||BiBTeX, EndNote, RefMan|
|Patent Citations (16), Referenced by (55), Classifications (21)|
|External Links: USPTO, USPTO Assignment, Espacenet|
June 27, 1961 D. G. BANNERMAN 2,989,798
' FILAMENTS OF IMPROVED DYE-RECEPTIVITY Filed June 30, 1955 F g 4 INVENTOR DOUGLAS G. BANNERMAN BY M A. yacz ATTORNEY 2,989,798 Ice Patented June 27, 19
2,989,798 FILAMENTS F IMPROVED DYE-RE'CEPTIVITY Douglas G. Bannerman, Wilmington, Del., assignor to E. I. du Pont de Nemours and Company, Wilmington, Del., a corporation of Delaware Filed June 30, 1955, Ser. No. 519,033 2 Claims. (CI. 28-82) This invention relates to extrusion of fiber-forming compositions, concerning especially formation of readily dyeable nylon filaments.
Many synthetic fiber-forming polymers are known, among which the polyamides have achieved considerable commercial importance. Unfortunately, textile materials constituted of polyamides generally are difiicult to dye to deep fast colors. Furthermore, modification of polyamide compositions to improve their dyeability has proved a handicap to filament formation, and after-treatment of unmodified polyamide filaments for better dyeing has presented problems of control and economy.
A primary object of the present invention is provision of nylon filaments of improved dyeability. An object is provision of multicomponent filaments containing readily dyeable polyamide composition. Other objects, together with means and methods for attaining the various objects, will be apparent from the following description and the accompanying diagrams.
FIGURE 1 is an axial longitudinal section of a spinneret assembly designed according to this invention for extrusion of multicomponent filaments. FIGURE 2 is a transverse cross section of the apparatus of FIGURE 1 taken at 22 thereof and showing the plan of the front or bottom spinneret plate. FIGURE 3 is a transverse cross section taken at 3--3 of FIGURE 1 to show the plan of the top or back plate thereof. FIGURE 4 is a transverse cross section of a filamentary product of the apparatus of FIGURE 1.
In general, the objects of the present invention are accomplished by simultaneous extrusion of more than one polymeric substance, including one that is characterized by amine end-groups, as a core, and one that is essentially free of amine end-groups, as a surrounding sheath. This is done by extruding the polymers, of which at least one has fiber-forming characteristics, simultaneously, after having surrounded a stream of the polymer having amine end-groups with a fluid layer of the polymer relatively free of amine end-groups. The invention comprehends particularly a polyamide filamentary structure characterized by dyeability with acid dyes. and formed by simultaneous extrusion of a first polyamide having acid-receptive amine end-groups and constituting the core of the structure and a second polyamide essentially lacking such amine end-groups and constituting a surrounding sheath.
Polyamides having an intrinsic viscosity of at least about 0.4 can be converted into self-supporting filaments by extrusion of the molten polymer through fine orifices (melt-spinning), tenacity and other properties of the product being enhanced subsequently by cold-drawing it to increased length. Sometimes an excess of one or the other of the polymerizing reactants is employed in the polymerization of diamines and dicarboxylic acids or their amide-forming derivatives, or some other viscosity stabilizer is used with these reactants or in the polymerization of aminocarboxylic acids, with the objective of terminating growth of the polymer molecules. .Residual unreacted amine and carboxyl end-groups are determinable by microtitration methods, as described by Waltz and Taylor in Analytical Chemistry 19, 448' (1947); neutral (e.g., alkyl) and end-group content can be calculated from the amount of stabilizer (e.g., acetic acid) reacted with the polymer or its polymerizable components. According to G. B. Taylor, who discusses relationships of end-groups,
relative viscosity, intrinsic viscosity, and number-average molecular weight of polyhexamethylene adipamide in J. Am. Chem. Soc. 69, 635 (1947), use of equal amounts of diamine and dicarboxylic acid (as their salt) and an acidic viscosity stabilizer always produces polymer with a finite quantity of amine end-groups (e.g., from 14 to 40 equivalents, per 10 grams for polymer having relative viscosity of from 12 to 46). For the present purpose, polymer having fewer than about 50 amine equivalents per 10 grams of polymer is considered essentially free of amine end-groups because at that content melt-spinning of the polymer is commercially feasible, despite degradation (attributable to amine content) that occurs upon exposure of the polymer to the atmosphere. Spinning of polymer containing more than this amount has not been commercial, and a content of 10 equivalents of amine end-groups per 10 grams of polymer is termed high in degradable amine. Although the usual terminal amine group is primary, secondary and tertiary amine groups are included also. Filaments of high average amine endgroup content are dyeable to deep fast colors with acid dyes.
Devices for making sheath-core filaments are known; a recently developed preferred form of apparatus for use in practicing this invention is illustrated in the diagrams. FIGURE 1 shows in axial section a spinneret assembly useful for this purpose. Front or bottom plate 1 with orifices 2 is recessed at the back about plateau-like protrusions 4. Back or top plate 7 is sealed against and spaced from the front plate by gasket 6 and shim 16, the former being ring-shaped and located near the periphery of the opposing faces of the two plates and the latter being disc-shaped and located concentric with the two plates. Relatively unconstricted region 12 between the two plates is interrupted at intervals by constricted regions 15 between the opposing face of the back plate and plateaus 5 of the protrusions from the front plate. The back plate is partitioned on top by outer wall 19 and inner wall 29 into annular chamber 8 and central chamber 9. The annular chamber communicates with the constricted regions between the two plates through counterbored apertures 10, and the central chamber communicates with the intervening relatively unconstricted region through holes 11. The two plates are retained in place by cap 18 threaded onto the end of the back plate. The upper part of the housing (not shown) receives suitable piping or other supply means for separate connection to the two chambers, which may constitute distribution or filtering spaces as desired. Pin 14 through cylindrical openings (opening 25 in the front plate and opening 26 in the back plate) near one edge of the plates ensures concentricity of the two plates.
FIGURE 2 shows the plan of the front plate. Appearing in this view are eight plateaus, each concentric with an extrusion orifice and uniformly spaced about a circle inside the outer gasket. As shown in this view and in FIGURE 1, each orifice consists of capillary 21 at the exit end and larger counterbore 22 extending to the capillary from the plateau. Also visible, supported in a shallow annular groove, is gasket 6, the opposing face of the back plate being similarly grooved to ensure a good seal between the two plates. The apertures in the top plate opposite the orifices of the bottom plate are similarly constructed, each being composed of terminal capillary 23 and introductory counterbore 24. FIGURE 3 shows the appearance of the back plate sectioned as indicated on FIGURE 1. Visible are the concentric outer and inner walls, the capillaries and counterbores of eight apertures spaced uniformly on a circle between the two walls, and four openings located within the central chamber defined by the inner wall.
Operation of the described apparatus in the practice of this invention is readily understood. Separate polymers characterized by relative freedom from amine end-groups and high content of degradable amine end-groups are supplied to the inner and outer chambers, respectively, of
the back plate; the former flows through the openings into the relatively unconstricted space between back and front plates, through the relatively constricted regions between the plateaus and the opposing plate face, and through the extrusion orificeswhile the latter passes first through the apertures in the back plate and directly into and through the aligned orifices in the front plate. Upon emerging from the spinneret orifices, the core-forming component is protected from the atmosphere by a uniform cover of the sheath-forming component. For practical purposes this eliminates troublesome bending, flicking, and dripping of the extruded filamentary stream normally encountered in 'the spinning of filaments composed of polymers having EXAMPLE I A polyamide is formed by reacting 10,523 grams of hexarnethylenediammonium adipate (40.1 moles), 93.7 grams of hexamethylene diamine (0.808 mole), and gram of acetic acid (0 mole), under the conditions taught by Carothers in Patent 2,130,948, September 20, 1938. A solution of 5.5 grams of the polymer in 50 ml. of 90% formic acid has a relative viscosity of 31.4 at 25 C. and contains 26 and 135 equivalents of carboxyl and amine end-groups, respectively per grams of polymer. This polymer is spun as the core of a two-component fiber simultaneously with a polyhexamethylene adipamide of 41 relative viscosity having 43 and 74 equivalents of amine and carboxyl end-groups, respectively, per 10 grams of polymer as the sheath component. The pump speeds for the two components are adjusted to give a sheath-core weight ratio of 30/70. The polymers are spun at 285 C. and the resultant yarn wound up at 1206 yards per minute. Good spinning ensues for a period of five hours, at which time the spin is discontinued. with no spinneret drips having occurred. (When the high-amine component polyamide was spun as a single-component fiber under similar conditions, spinneret drips occurred at an average frequency of one in 3.5 hours.) The yarn is drawn 3.22X over a cold pin to give a final yarn with a total denier of 95. The yarn has a tenacity of 4.7 grams per denier and an elongation at break of 24.3%. The yarn is of uniform denier and shows uniform concentric sheath/ core relationships from filament to filament.
Tubings knit from the two-component yarn prepared as above and from a single-component yarn prepared under similar conditions but using only the low-amine polyhexamethylene adipamide used for the sheath above were dyed separately at the boil for one hour (ratio of bath: tubing of of 50:1) in an acid dye bath having the following composition: 0.5% 1-amino-4-anilino-2-anthraquinone sodium sulfonate, 3% acetic acid, and 2% sodium lauryl sulfate. From saturation dyeings the high-amine two-component tubing picked up 3.4 weight percent of dye as contrasted with 1.8 percent dye takeup by the tubing made of the one-component, low-amine yarn. When both tubings were dyed to the same shade and then submitted to repeated launderings, the tubing made of the two-component yarn retained 91% of the dye in contrast to the low-amine yarn tubing which retained only 78% of the dye.
EXAMPLE II Polyhexamethylene adipamide with a relative viscosity of 31 and containing 43 and 70 equivalents each of amine and carboxyl end-groups, respectively, per 10 grams of polymer is mixed with 1.9% of its weight of titanium dioxide and melt-spun into yarn at 800 yards per minute, a spinning speed previously known to give minimum frequency of spinneret drips. The observed spinneret drip frequency averages only one in twenty hours. The yarn is cold-drawn to give a final delustered yarn (hereinafter designated as control 1) with total denier of 70.
A polyhexamethylene adipamide is made by reacting hexamethylenediammonium adipate with hexamethylene diamine equivalent to 1.14 mol percent of the salt and with acetic acid equivalent to 0.182 mol percent of the salt as above. The final polyamide has a relative viscosity of 36 and contains and 44 equivalents of amine and carboxyl end-groups, respectively, per 10 grams of polymer. This polymer is mixed with 1.9% of its weight of titanium dioxide and 0.56% of its weight of the sodium salt of phenyl phosphinic acid (as disclosed by Gray in Patent 2,510,777), in order to reduce the atmospheric degradation of the polymers at the spinning temperature and spun at 800 yards per minute. The frequency of spinneret drips is one per six hours in spite of the added stabilizer. The yarn is cold-drawn to give a delustered yarn (hereinafter designated as control 2) with a total denier of 72.
Another high-amine polyamide is made by reacting hexamethylenediamrnonium adipate with 1.94 mol percent of hexamethylene diamine under conditions as given above. The resulting polymer has a relative viscosity of 41 and contains 146 and 22 equivalents of amine and carboxyl end-groups, respectively, per 10 grams of polymer. This polymer is mixed with 2.4% of its weight of titanium dioxide and spun as the core of a two-component yarn; and a polymer as used for control 1, but without titanium oxide is used for the sheath of the yarn. The spinning pumps for the two-component melts are adjusted to give a ratio of sheath/ core of 15/85. The polymers spin well and no spinneret drips occur in 44 hours, at which time the run is stopped. The filaments are drawn over a cold pin to give a delustered yarn with a total denier of 71, total TiO content of 1.9%, and an over-all amine content of 12x10 equivalents per gram. Representative transverse cross sections of these filaments appear in FIGURE 4, the dyeing of the core being represented by stippling.
It is surprising not only that the sheath-core yarn exemplified here spun much better than the single-component high-amine yarn (more than 44 hours versus 6 hours for the same drip frequency) even though it contained more amine groups but also that the two-component yarns with a bright sheath, i.e., with no delusterant present, spun much better than control 1, which contained pigment but less than 0.3 as many amine groups as the core of the two-component fiber (more than 44 hours per drip as compared to 20 hours).
The three yarns had physical properties given in Table I below.
Table I Yarn Tenacity Elongation (g.p.d.) (percent) The abrasive qualities of the three yarns were measured by the time required by the yarn to cut through a small standard copper wire under controlled conditions of tension and speedwith results as shown in Table II.
Table II Yarn: Cutting time in seconds Control 1 385 Control 2 500 Sheath-core 67,000
Knit tubings were made of the three yarns and dyed competitively in the dye bath of Example I. Control 1 gave the lightest shades, control 2 gave an intermediate shade and the sheath-core yarn gave the darkest blue shades. Similar results were obtained for 2, 5, and 15- minute dyeing. Fabrics were also woven of the three yarns and dyed separately under equivalent conditions in the dye bath of Example I to similar shades. The fabric woven of the sheath-core yarn with the high-amine core showed the greatest wash-fastness, with control 2 being intermediate between it and control 1. Similarly, the dyed fabric Woven of the sheath-core yarn showed the greatest light-fastness as determined by 20' hours exposure in a fadeometer instrument, with control 2 being intermediate. Similar dyeing results were obtained with the acid dye Cl. 430. Three fabrics woven to the same specifications were considered to be equivalent in covering power, as determined by ultraviolet light-transmission measurements. This is surprising because the sheath-core yarn had an undelustered sheath. Thus, by use of a sheathcore structure a delustered yarn was made that had the relatively non-abrasive characteristics of a lustrous yarn.
Although this invention has been illustrated with polyhexamethylene adipamide because of its recognized commercial importance, it is applicable also to other polyamides, including copolymers, whether prepared by the reaction of diarnines and dibasic acids, and their derivatives, amino acids, or other compounds (e.g., caprolactam, which yields a polyamide under proper reaction conditions). The invention is applicable similarly to other fiber-forming polymers that may contain amine groups, including polyureas derived, for example, from a diisocyanate and a diamine, as shown by Rinke et al. in Patent 2,511,544; polyurethanes; polythioureas; polythioamides; polysulfonamides, as taught by Jones et al. in Patent 2,667,468; polyimides; and poly-4-arnino-1-2-4-triazoles as taught by Fisher et al. in Patent 2,512,629. Copolyesteramides also can be used. The amine content of the core polymer may arise from a blend of a polymer containing amine groups and another polymer with few or no amine groups as, for example, a blend of a polyamide and a polyester, such as polyethyleneterephthalate.
Although this invention has its greatest application to polymers containing primary amine groups, it is of value with polymers containing secondary and tertiary amine groups. Thus, an N-amino-alkyl morpholine can be used as a viscosity stabilizer in the preparation of polyamides, as taught by Watson in Patent 2,585,199, in order to obtain polymers with tertiary amine end-groups having increased dyeability with 'acid dyes. Other means of forming amine end-groups by polymerization or after-treatment of a polymer will be obvious to those skilled in the art.
In general, this invention is of value when spinning polyamides containing from about 4 to 400 equivalents of amine group per grams of polymer. The invention affords a process for the commercial spinning of any polymers containing any finite concentration of amine groups. In order to obtain a satisfactory deep-dyeing (with acid dyes) product, the over-all amine concentration in the two-component filament should be between and 400 equivalents per 10 grams of polymer and preferably between and 200. This can be obtained by balancing the amine content of the core and sheath and their relative thickness. The products of this invention can be dyed with that class of dyes containing acid groups known as acid or direct dyes, including those with the following color index numbers: 176, 161, 1088, 365, 589, 594, and 5 83.
Although this invention has been illustrated by the cospinnin of two difierent polyarnides, the sheath and core of a filament need not be composed of the same type of polymer. For example, a polyester sheath can be spun over polyamide core having a high content of amine endgroups. In this manner the acid-dyeing characteristics of one polymer can be combined with the surface properties of a second polymer.
This invention is of value in that it provides two-component filaments that can be dyed to deep, uniform shades that are washand light-fast. Although this invention has been illustrated with filaments containing the sheath and core components in a concentric relation, any eccentric arrangement can be used and, furthermore, the shape can be as desired, e.g., cruciform, ribbon, Y-shape, as well as circular. Regardless of shape, the dyed products display greater fastness to laundering and light than single-component filaments dyed to the same shade. The products are eminently suitable for all manner of textile applications.
The claimed invention:
1. A filament of improved dye receptivity and retention comprising a sheath-core filament having comprising as a core a polymeric substance containing at least 10 equivalents of amine end-groups per 10 grams of polymer and as a sheath a polymeric substance having fewer than about 50 amine equivalents per 10 grams of polymer.
2. A filament of improved dye receptivity and retention comprising a sheath-core filament having as a core a fiber-forming polyamide containing at least 10 equivalents of amine end groups per 10 grams of polymer, and as a sheath a fiber-forming polyamide having fewer than about 50 amine equivalents per 10 grams of polymer.
References Cited in the file of this patent UNITED STATES PATENTS 2,238,694 Graves Apr. 15, 1941 2,265,559 Watkins Dec. 9, 1941 2,340,377 Graumann et a1 Feb. 1, 1944 2,417,453 Wade Mar. 18, 1947 2,439,814 Sisson Apr. 20, 1948 2,440,761 Sisson May 4, 1948 2,458,397 MacGregor Jan. 4, 1949 2,612,679 Ladisch Oct. 7, 1952 2,636,873 Graham Apr. 28, 1953 2,674,025 Ladisch Apr. 6, 1954 2,705,184 Drisch Mar. 29, 1955 2,732,279 Tachikawa Jan. 24, 1956 2,736,946 Stanton et al Mar, 6, 1956 2,798,281 Herzog July 9, 1957 FOREIGN PATENTS 744,112 Germany Ian. 10, 1944 776,961 France Feb. 8, 1935 UNITED STATES- PATENT. OFFICE CERTIFICATE OF CORRECTION Patent N09 2,-989,798- June 27,1961
9 Douglas G, Bannerman It is hereby certified that error appears in the above numbered petent requiring correction and that the said Letters Patent should read as corrected below.
Column 6, line 33, strike out comprising, second occurrence,
Signed and sealed this 16th day of January 1962,.
ERNEST W, SWIDER Attesting Officer DAVID L. LADD Commissioner of Patents
|Cited Patent||Filing date||Publication date||Applicant||Title|
|US2238694 *||May 15, 1939||Apr 15, 1941||Du Pont||Polymeric materials|
|US2265559 *||Mar 9, 1939||Dec 9, 1941||Du Pont||Dyed regenerated cellulose containing a polyamide|
|US2340377 *||Jan 4, 1941||Feb 1, 1944||Erich Graumann||Process of making artificial fibers|
|US2417453 *||Dec 8, 1943||Mar 18, 1947||American Viscose Corp||Process of producing a textile product|
|US2439814 *||May 13, 1943||Apr 20, 1948||American Viscose Corp||Crimped artificial filament|
|US2440761 *||Jul 1, 1946||May 4, 1948||American Viscose Corp||Apparatus for producing artificial filaments|
|US2458397 *||Oct 12, 1944||Jan 4, 1949||Courtaulds Ltd||Dyeing of nylon fibers by treating with nitrogenous condensation products|
|US2612679 *||Aug 21, 1951||Oct 7, 1952||Ladisch Rolf Karl||Filaments containing fillers|
|US2636873 *||Aug 13, 1949||Apr 28, 1953||Du Pont||Blends of polyamides and polymeric polyamines|
|US2674025 *||Aug 15, 1949||Apr 6, 1954||Texiclon Corp||Polymeric filaments|
|US2705184 *||Jul 3, 1952||Mar 29, 1955||Textile & Chemical Res Company||Process for the production of rayon products|
|US2732279 *||Dec 29, 1951||Jan 24, 1956||Shozo tachikawa|
|US2736946 *||Jul 3, 1952||Mar 6, 1956||Dow Chemical Co||Polyacrylonitrile fibers having a scaly integument|
|US2798281 *||Jul 15, 1954||Jul 9, 1957||American Enka Corp||Stocking and method of making the same|
|DE744112C *||Jul 28, 1939||Jan 10, 1944||Ig Farbenindustrie Ag||Vorrichtung zur Ausfuehrung des Verfahrens zur Herstellung von Kunstfaeden beliebiger Feinheit|
|FR776961A *||Title not available|
|Citing Patent||Filing date||Publication date||Applicant||Title|
|US3117906 *||Jun 20, 1961||Jan 14, 1964||Du Pont||Composite filament|
|US3251913 *||Jun 1, 1961||May 17, 1966||Ici Ltd||Production of a sheath-core polyester filament of enhanced dyeability|
|US3386967 *||Jan 19, 1965||Jun 4, 1968||Allied Chem||Polycaproamide having excess number of carboxyl end groups over amino end groups|
|US3477899 *||May 18, 1965||Nov 11, 1969||Bayer Ag||Bifilar polyamide yarns and filaments|
|US3505165 *||Oct 28, 1968||Apr 7, 1970||Bayer Ag||Bifilar polyamide yarns and filaments|
|US3511815 *||May 8, 1968||May 12, 1970||Sayin Ahmet Nuri||Deep dyeing polycarbonamide filament|
|US3541198 *||Mar 19, 1969||Nov 17, 1970||Ueda Keizo||Process for manufacturing composite filaments|
|US3687904 *||Dec 4, 1970||Aug 29, 1972||Ici Ltd||Polyamides|
|US3933963 *||Dec 13, 1974||Jan 20, 1976||E. I. Du Pont De Nemours And Company||Spinning process|
|US3943095 *||Sep 26, 1974||Mar 9, 1976||E. I. Du Pont De Nemours And Company||Acid dyeable yarn from polyamide having N,N'-di (3-aminopropyl)piperazine moiety units|
|US3983201 *||Jun 9, 1972||Sep 28, 1976||Fmc Corporation||Method of preparing a lacquer coated regenerated cellulose film with an intermediate layer of hydroxyalkyl cellulose|
|US4017255 *||May 20, 1974||Apr 12, 1977||Imperial Chemical Industries||Dyed textile materials|
|US4075378 *||Sep 12, 1975||Feb 21, 1978||E. I. Du Pont De Nemours And Company||Polyamide filaments with a basic-dyeable sheath and an acid-dyeable core and dyeing process therefor|
|US4251200 *||Nov 23, 1979||Feb 17, 1981||Imperial Chemical Industries Limited||Apparatus for spinning bicomponent filaments|
|US4293516 *||Jun 24, 1980||Oct 6, 1981||Imperial Chemical Industries, Limited||Process for spinning bicomponent filaments|
|US4309476 *||Apr 14, 1980||Jan 5, 1982||Teijin Limited||Core-in-sheath type aromatic polyamide fiber and process for producing the same|
|US4350006 *||Jul 15, 1981||Sep 21, 1982||Toray Industries, Inc.||Synthetic filaments and the like|
|US4612150 *||Nov 28, 1983||Sep 16, 1986||E. I. Du Pont De Nemours And Company||Process for combining and codrawing antistatic filaments with undrawn nylon filaments|
|US4680156 *||Oct 11, 1985||Jul 14, 1987||Ohio University||Sheath core composite extrusion and a method of making it by melt transformation coextrusion|
|US5009954 *||Apr 4, 1990||Apr 23, 1991||Ohio University||Sheath core fiber and its method of manufacture|
|US5162074 *||Aug 7, 1989||Nov 10, 1992||Basf Corporation||Method of making plural component fibers|
|US5219508 *||Feb 6, 1991||Jun 15, 1993||Ohio University||Method of manufacturing sheath core fiber|
|US5256050 *||Jun 5, 1992||Oct 26, 1993||Hoechst Celanese Corporation||Method and apparatus for spinning bicomponent filaments and products produced therefrom|
|US5344297 *||Jun 4, 1992||Sep 6, 1994||Basf Corporation||Apparatus for making profiled multi-component yarns|
|US5447794 *||Sep 7, 1994||Sep 5, 1995||E. I. Du Pont De Nemours And Company||Polyamide sheath-core filaments with reduced staining by acid dyes and textile articles made therefrom|
|US5466410 *||May 11, 1994||Nov 14, 1995||Basf Corporation||Process of making multiple mono-component fiber|
|US5505889 *||Jul 14, 1993||Apr 9, 1996||Hoechst Celanese Corporation||Method of spinning bicomponent filaments|
|US5551588 *||Jun 6, 1995||Sep 3, 1996||Basf Corporation||Profiled multi-component fiber flow plate method|
|US5562930 *||Jun 6, 1995||Oct 8, 1996||Hills; William H.||Distribution plate for spin pack assembly|
|US5888651 *||Aug 25, 1997||Mar 30, 1999||Basf Corporation||Colored bicomponent fibers|
|US5922462 *||Jan 20, 1998||Jul 13, 1999||Basf Corporation||Multiple domain fibers having surface roughened or mechanically modified inter-domain boundary and methods of making the same|
|US5932346 *||Jan 7, 1998||Aug 3, 1999||Basf Corporation||Multiple domain fibers having inter-domain boundary compatibilizing layer and methods of making the same|
|US6162382 *||Nov 20, 1998||Dec 19, 2000||Basf Corporation||Process of making multicomponent fiber|
|US6531218||Apr 30, 2001||Mar 11, 2003||Basf Corporation||Dyed sheath/core fibers and methods of making same|
|US7033669||Feb 7, 2003||Apr 25, 2006||Honeywell Int Inc||Cationically dyed fibers and articles containing the same|
|US7618704||Sep 28, 2004||Nov 17, 2009||E.I. Du Pont De Nemours And Company||Spin-printing of electronic and display components|
|US7919419||Nov 5, 2008||Apr 5, 2011||Buckeye Technologies Inc.||High strength and high elongation wipe|
|US8143326||Mar 27, 2012||E.I. Du Pont De Nemours And Company||Spin-printing of electronic and display components|
|US8252385||Mar 23, 2006||Aug 28, 2012||E I Du Pont De Nemours And Company||Spin-printing of electronic and display components|
|US8501647||Feb 4, 2011||Aug 6, 2013||Buckeye Technologies Inc.||High strength and high elongation wipes|
|US20020098356 *||Jan 16, 2002||Jul 25, 2002||Basf Corporation||Dyed sheath/core fibers and methods of making same|
|US20020110688 *||Jan 31, 2002||Aug 15, 2002||Basf Corporation||Dyed sheath/core fibers and methods of making same|
|US20030104163 *||Jun 20, 2002||Jun 5, 2003||Basf Corporation, Inc.||Colored fibers having resistance to ozone fading|
|US20040132375 *||Nov 7, 2003||Jul 8, 2004||Toyotaka Fukuhara||Thermal insulating material for housing use and method of using the same|
|US20050089679 *||Sep 28, 2004||Apr 28, 2005||Ittel Steven D.||Spin-printing of electronic and display components|
|US20070054104 *||Mar 23, 2006||Mar 8, 2007||Ittel Steven D||Spin-printing of electronic and display components|
|US20080153973 *||Mar 11, 2008||Jun 26, 2008||Steven Dale Ittel||Spin-Printing of Electronic and Display Components|
|US20090092809 *||Nov 5, 2008||Apr 9, 2009||Buckeye Technologies Inc.||High Strength And High Elongation Wipe|
|US20110159265 *||Jun 30, 2011||Buckeye Technologies Inc||High Strength and High Elongation Wipes|
|USRE29382 *||Mar 1, 1972||Sep 6, 1977||Akzona Incorporated||Multifilament yarns for reinforcing articles|
|DE3036931A1 *||Sep 30, 1980||Apr 23, 1981||Schweizerische Viscose||Antistatischer zweikomponenten-faden und verfahren sowie vorrichtung zu seiner herstellung|
|EP2256550A1||Sep 29, 2004||Dec 1, 2010||E. I. du Pont de Nemours and Company||Spin-printing of electronic and display components|
|EP2463425A1||Dec 8, 2011||Jun 13, 2012||Buckeye Technologies Inc.||Dispersible nonwoven wipe material|
|WO2012078860A1||Dec 8, 2011||Jun 14, 2012||Buckeye Technologies Inc.||Dispersible nonwoven wipe material|
|WO2015073917A1||Nov 14, 2014||May 21, 2015||Buckeye Technologies Inc.||Dispersible nonwoven wipe material|
|U.S. Classification||428/373, 264/172.15, 264/DIG.260, 264/78, 428/394, 264/172.18|
|International Classification||D01F6/60, D01D5/34, D01F8/04, D01D5/08, B29C47/06|
|Cooperative Classification||B29C47/128, Y10S264/26, D01D5/08, D01D5/34, D01F8/12|
|European Classification||D01F6/60, B29C47/12E, D01D5/08, D01D5/34, D01F8/04|