|Publication number||US3047434 A|
|Publication date||Jul 31, 1962|
|Filing date||Mar 28, 1958|
|Priority date||Mar 28, 1958|
|Publication number||US 3047434 A, US 3047434A, US-A-3047434, US3047434 A, US3047434A|
|Inventors||Bulat Thomas J|
|Original Assignee||Bendix Corp|
|Export Citation||BiBTeX, EndNote, RefMan|
|Patent Citations (10), Referenced by (17), Classifications (8)|
|External Links: USPTO, USPTO Assignment, Espacenet|
This invention relates to solutions and methods for radioactive decontamination.
Radioactive contaminants occur as unstable forms of the elements which in practical situations may be found in pure form but are usually found mixed in any of a wide variety of soils. Effective decontamination involves both stabilization and physical removal of the radioactive contaminant. An object of the invention is to provide improved solutions and methods for achieving this result.
Previous decontamination methods have been based on an attempt to remove the soil from articles to be cleaned in the hope that its radioactive ingredients would be removed in the process. The process is practiced in the specific form required for the removal of the soil. On the other hand, this invention provides a decontamination solution capable of direct action on the radioactive contaminant although in practice it will remove most of the soils as well.
Another object is to provide highly effective solutions for decontamination when the radioactive contaminant is specifically identified; but the provision of solutions which are very effective evenvwhen the radioactive contaminant is not known, is also an object.
Another object of the invention is to provide a solution, for general application to the problem of decontamination, sufiiciently effective to warrant its use for average cases, for those cases in which a variety of radioactive substances are present, and for first decontamination in preparation for specific contamination in special cases.
Another important object is to provide a solution which is sufliciently inexpensive to make practical the decontamination of inexpensive hand tools such as pliers, screwdrivers, and the like which now must be disposed of, often after only a single usage.
These andother objects and advantages of the invention which will hereinafter be apparent, are realized by the provision of a radioactive contaminant comprising a mixture of a detergent liquid, an ion exchange agent soluble in said liquid to form ions charged oppositely of the radioactive contaminant, and adsorbent solids distributed in the liquid. Each of these ingredients has a specific individual function in the decontamination process, the effectiveness of each of which depends upon the function of the other whereby the invention contemplates solutions simultaneously containing all of these substances. The article to be decontaminated is immersed in the solution which advantageously is subjected to forces producing cavitation. 1
In addition to their functional interdependence there is a mechanical cooperation between the substances. The detergent serves as the vehicle by which the exchange agent and adsorbent may move into association with one another and the surface to be cleaned, while the forces exerted by the substances accounts for that movement. Provision for cavitation action aids the movement and intermixing of the constituents of the solvent in addition to providing mechanical force for dislodging contaminants and soil from the article being cleaned and from one another.
The individual functions of the detergent, ion exchange agent, and adsorbent, taken one at a time, are the functions associated with those names by chemists although the action by which the function is provided may not yet have been defined. The detergent, through the applicaa 3,047,434 C3 Patented July e1, 1962 2 tion of hydrophilic, hydrophobic, lipophilic, or lipophobic forces or chelating action, overcomes the mechanical forces and affinities which bind the soil and contaminants to the articlebeing cleaned.
The ion exchange agent, having polarity opposed to the polarity of the charge associated with the instability or radioactivity of the contaminant, has an afinity for the contaminant and joins it to form a discreet particle. The integrity of the union of the exchange agent and contaminant is preserved by their adherence in combination to the adherent which in turn is prevented by the detergent from adherence to the article being cleaned.
When the contaminant is identified, the ion exchange agent is selected in accordance with principles well known in the chemical art so that chemists having at least ordinary skill can select a proper agent. When the contaminants or some of them are not identified, sulfides, carbonates, hydroxides and sulfates can be utilized. The sodium salts of these radicals are preferred in accordance with the invention and a positive ion from this group should be included if there exists a possibility that one of the contaminants is negative.
To augment the action of the exchange agent, the detergent advantageously includes a chelating agent. In the interest of cost reduction as well as for its eflectiveness as a wetting agent in connection with most soils, it is preferred that the detergent consist primarily of water. Advantageously the detergent may comprise a mixture of water and ethylene diam-inc tetra acetic acid.
A wide variety of adsorbents have been used with good results including silicates such as a colloidal cl-ay, talc, and fullers earth, chalk; sulfides of arsenic and antimony; diatomaceous earth; carbon black; and metallic oxides such as alumina, magnesia, iron oxide, and titanium and manganese dioxide.
Of course, the action of solutions made according to the invention may be augmented and hastened by mechanical agitation to insure that fresh solution reaches the surface to be decontaminated and by mechanical actions on the soil itself.
A superior kind of such mechanical action is ultrasonic cavitation of the decontamination solution and the solution found to be most advantageous for general decontamination is entirely compatible with this kind of action. That solution comprises water, ethylene diamine tetra acetic acid, sodium sulfate, sodium hydroxide, manganese dioxide, and carbon black.
By way of example and not of limitation, since other solutions are possible and the relative quantities in this solution may be modified within the scope of the invention and the appended claims, a particularly effective solution for decontamination was made by the mixing of ingredients in the following proportions:
milliliters of water, 1 gram ethylene diamine tetra acetic acid, 0.2 gram sodium sulfate, 0.2 gram sodium hydroxide, 0.1 gram manganese dioxide and 0.1 gram carbon black. A soiled article having radioactive contaminants, especially radioactive cesium 134, was immersed in this solution.
Also, a similarly contaminated article was immersed in a like solution and the latter was activated to produce cavitation bythe action of ultrasonic energy with improved result.
I claim: I
1. A solution for radioactive decontamination comprising a mixture of water, ethylene diamine tetra acetic acid, sodium sulfate, sodium hydroxide, manganese dioxide, and carbon black.
2. The decontamination method which comprises immersing a radioactively contaminated article in a solution comprised of water, ethylene diamine tetra acetic acid, sodium sulfate, sodium hydroxide, manganese dioxide,
3 4 and carbon black, and subjecting said solution to ultra- 2,401,484 Jackson June 4, 1946 sonic vibration forces sufiicient to produce cavitation 2,607,738 Hardy Aug. 19, 1952 therein. 2,672,449 Snell Mar. 16, 1954 2,678,303 Bonewitz May 11, 1954 References Cried 1n the file of th1s patent 5 2,736,640 McGraW Feb- 28 1956 UNITED STATES PATENTS 2,739,882 Ellis Mar. 27, 1956 2,016,265 Doherty Oct. 1, 1935 2,802,758 Kearney Aug. 13, 1957 2,241,984 Cooper May 13, 1941 2,814,575 Lange NOV. 26, 1957
|Cited Patent||Filing date||Publication date||Applicant||Title|
|US2016265 *||Apr 9, 1932||Oct 1, 1935||Standard Oil Dev Co||Cleaning composition|
|US2241984 *||Jan 5, 1940||May 13, 1941||Glass washing composition|
|US2401484 *||Aug 3, 1940||Jun 4, 1946||Mine Safety Appliances Co||Composition for purification of air and a process of making same|
|US2607738 *||Jun 25, 1948||Aug 19, 1952||Monsanto Chemicals||Bleaching, sterilizing, disinfecting, and deterging compositions|
|US2672449 *||Sep 15, 1949||Mar 16, 1954||Foster D Snell Inc||Composition for cleaning metal|
|US2678303 *||Sep 7, 1950||May 11, 1954||Bonewitz Paul W||Water treating and cleaning composition|
|US2736640 *||Dec 1, 1954||Feb 28, 1956||Fmc Corp||Chemical polishing bath|
|US2739882 *||Feb 25, 1954||Mar 27, 1956||Raytheon Mfg Co||Surface treatment of germanium|
|US2802758 *||Mar 15, 1955||Aug 13, 1957||Detrex Corp||Method of cleaning|
|US2814575 *||Aug 13, 1954||Nov 26, 1957||Hodes Lange Corp||Method and apparatus for cleaning ampoules with the aid of ultrasonic vibration|
|Citing Patent||Filing date||Publication date||Applicant||Title|
|US3437521 *||Jan 21, 1964||Apr 8, 1969||Purex Corp Ltd||Radioactive decontamination|
|US3487916 *||May 31, 1966||Jan 6, 1970||Collo Rheincollodium Cologne G||Method and means for removal of radioactive contaminants|
|US3488219 *||Mar 23, 1965||Jan 6, 1970||Collo Rhelncollodium Koln Gmbh||Method and means for removal of radioactive contaminants|
|US4056112 *||May 2, 1974||Nov 1, 1977||Calvin Calmon||Containment and removal of radioactive spills by depositing a crosslinked ion exchange composition in a dry form over region of spill|
|US4659512 *||Dec 21, 1983||Apr 21, 1987||Pedro B. Macedo||Fixation of dissolved metal species with a complexing agent|
|US4681705 *||Oct 15, 1985||Jul 21, 1987||Carolina Power & Light Company||Decontamination of radioactively contaminated liquids|
|US4850380 *||May 21, 1985||Jul 25, 1989||Pall Corporation||Entry/exit decontamination system using adsorbent powder|
|US5292456 *||Mar 20, 1992||Mar 8, 1994||Associated Universities, Inc.||Waste site reclamation with recovery of radionuclides and metals|
|US5322644 *||Jan 3, 1992||Jun 21, 1994||Bradtec-Us, Inc.||Process for decontamination of radioactive materials|
|US5332532 *||Dec 9, 1992||Jul 26, 1994||Waste Reduction By Waste Reduction, Inc.||Method for disposing of radioactively labeled animal carcasses|
|US5434331 *||Nov 17, 1992||Jul 18, 1995||The Catholic University Of America||Removal of radioactive or heavy metal contaminants by means of non-persistent complexing agents|
|US6446277 *||Jun 8, 2000||Sep 10, 2002||Prevor International||High-capacity method and system of chemical and/or radiological decontamination|
|US7568523||Feb 8, 2007||Aug 4, 2009||Total Separation Solutions, Llc||Treatment of cesium-containing fluids|
|US7799143 *||Nov 30, 2009||Sep 21, 2010||George Mason Intellectual Properties, Inc.||Method for removing radionuclides from a radioactive material|
|US7910788||Jul 13, 2006||Mar 22, 2011||Digestor, Llc||System for treating infectious waste matter|
|US7915472||Feb 7, 2006||Mar 29, 2011||Battelle Energy Alliance, Llc||Surface decontamination compositions and methods|
|WO2006088826A2 *||Feb 13, 2006||Aug 24, 2006||Total Separation Solutions Llc||Conserving components of fluids|
|U.S. Classification||134/1, 976/DIG.376, 376/309, 134/7, 510/110|