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Publication numberUS3069760 A
Publication typeGrant
Publication dateDec 25, 1962
Filing dateJun 11, 1958
Priority dateJun 11, 1958
Publication numberUS 3069760 A, US 3069760A, US-A-3069760, US3069760 A, US3069760A
InventorsWilliam H Schultz
Original AssigneeUnited States Steel Corp
Export CitationBiBTeX, EndNote, RefMan
External Links: USPTO, USPTO Assignment, Espacenet
Ceramic coated tuyeres or the like
US 3069760 A
Abstract  available in
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Claims  available in
Description  (OCR text may contain errors)

Dec. 25, 1962 w. H. SCHULTZ CERAMIC COATED TUYERES OR THE LIKE 2 Sheets-Sheet 2 Filed June 11, 1958 //V VENTOR WILL 1AM H. SCHUL TZ Affarnev and (IER

William H This invention relates to a ceramic coated tuyere and is particularly directed to tuyeres or similar members which are inserte into a blast furnace. Such members include tuyere coolers, monkeys and monkey coolers. These members are normally made of copper and are subjected to extremely severe operating conditions because of the high temperatures in the furnace, abrasion from the moving furnace burden, and splashes of molten pig iron from the burden falling into the furnace bash. Because of these conditions, the tuyere and other members have a relatively short life.

It is therefore an object of my invention to provide a blast furnace tuyere or the like which has a longer than normal life.

This and other objects will be more apparent when referring to the following specification and attached drawings, in which:

FIGURE 1 is a longitudinal section of a tuyere and tuyere cooler as placed in a blast furnace wall;

FIGURE 2 is an enlarged sectional view of the tuyere of FIGURE 1;

FIGURE 3 is a sectional view taken on the line Ill-Ill of FIGURE 2; and

FIGURE 4 is a sectional view showing the monkey and monkey cooler in the furnace wall.

Referring more particularly to the drawings, the reference numeral 2 indicates the wall at the bottom of a blast furnace. A tuyere cooler 4 which supports a tuyere 6 is supported in the wall 2. The tuyere 6 is of usual construction having a body 8 with an air passage 10 therethrough for the admission of a blast of air to the furnace, this passage being connected at its inlet end with the source of air supply by means of a pipe 12. Surrounding the air passage 10 is a chamber 14 to which a cooling fluid is supplied by means of an inlet pipe 16. The fluid after passing through the chamber 14 is discharged through a pipe The tuyere and tuyere cooler are preferably made of copper but may be made of a copper alloy. The term copper as used in the claim is meant to include pure copper or an alloy which is predominantly of :1, the materials being those most commonly used in tuyeres. The surface of the tuyere exposed to the burden of the furnace is coated with a metallic layer with a ceramic coating 22. being applied over the metal coating. 1 have found that a metal coating having a coefiicicnt of expansion between that of the body of the tuyere and that of the ceramic coating 22 must be provided between the body of the tuyere and the ceramic coating to obtain the object of the invention. Metals suitable for the coating 20 include austenitic steels such as A131 types 301, 302, 30213, 303, 304, 308, 309, 310, 316, 321 and 347, chromium steels such as A151 types 403, 405, 406, 410, 414, 420, 430, 431, 440A, 4403, 440C, 442, 443, 446, 501 and 502, and pure nickel. The ceramic coating 22 may be of alumina, beryllium oxide, calcium oxide, cerium oxide, chromic oxide, chromite, magnesia, silica, strontium oxide, zirconia, and zirconia oxide silicate. In applying the coating, the surface of the tuyere to be coated is first roughened, as by grit blasting or knurling, to improve the adherence of the metal coating. The application of the coating 20 is preferably done by blowing the metal in powdered form through a flame which applies the metal in a semi-molten form to the tuyere, which is preferably rotated as the powder is applied. The fused ceramic coating is applied over the metal coating in a similar manner after the metal has solidified. A similar metal coating 24 may be applied over that portion of the tuyere cooler 4 exposed to the furnace burden with a similar ceramic coating 26 applied over the coating 24.

FIGURE 4 shows a cinder notch monkey 28 supported by a cinder notch monkey cooler 30, which in turn is sup ported by cinder notch cooler 32. The monkey 2d and monkey cooler 30 are made of the same material as the tuyere. A metal coating 34 and ceramic coating 36 are applied over that portion of the surface of the monkey 28 which is exposed to the furnace burden. A metal coating 33 and ceramic coating are applied over that portion of the surface of the monkey cooler 30 which is exposed to the furnace burden. The coatings 34 and 38 are applied in the same manner and are of the same material as coating 20 and coatings 36 and 40 are applied in the same manner and are made of the same material as coating 22.

A combination of coatings found to be unite successful is a coating of a metal containing 60 to 62% nickel, 12 to 15% chromium and the remainder iron, manganese and carbon with the ceramic coating being fused alumina (A1 0 The metal coating should be between 0.0005 and 0.02 inch thick and is preferably between 0.002 and 0.007 inch. The ceramic coating should be between 0.001 and 0.04 inch thick and is preferably between 0.005 and 0.015 inch.

While several embodiments of my invention are shown and described, it will be apparent that other adaptations and modifications may be made without departing from the scope of the following claim.

I claim:

A structure adapted to be inserted into a furnace or the like comprising a copper body, a metal coating bonded to and surrounding at least a portion of said body, said metal coating having a thickness between and 0.02 inch and a ceramic coating directly bonded to said metal coating, said ceramic coating having a thickness between 0.001 and 0.04 inch, said metal having a coeflicient of expansion intermediate the coefficient of expansion of said copper and said ceramic and being of the class consisting of austenitic steels, chromium steels and nickel, said ceramic being of the class consisting of alumina, beryllium oxide, calcium oxide, cerium oxide, chromic oxide, chromite, magnesia, silica, strontium oxide, zirconia, and zirconia oxide silicate.

References Cited in the file of this patent UNITED STATES EATENTS 185,339 Mackey Dec. 12, 1876 639,537 Dickey Dec. 19, 1899 1,161,944 Maddy Nov. 30, 1915 2,295,945 Fralish Sept. 15, 1942 2,310,002 Van Geel Feb. 2, 1943 2,340,362 Atlee Feb. 1, 1944 2,377,321 Brown June 5, 1945 2,470,753 Alban May 24, 1949 2,495,835 Comstock Ian. 31, 1950 2,515,337 Clark July 18, 1950 2,696,662 Les Sech Dec. 14, 1954 2,775,531 Montgomery Dec. 25, 1956 2,975,078 Rayfield Mar. 14, 1961

Patent Citations
Cited PatentFiling datePublication dateApplicantTitle
US185339 *Nov 16, 1876Dec 12, 1876 Improvement in plates for mending sheet-metal ware
US639537 *Aug 14, 1899Dec 19, 1899Wallace C DickeyManufacture of planished iron and steel.
US1161944 *Feb 2, 1915Nov 30, 1915Lohmann CompanyProcess of forming a protective metal coating upon metallic articles.
US2295945 *Jan 24, 1940Sep 15, 1942Western Electric CoManufacture of vitreous enameled articles
US2310002 *May 28, 1938Feb 2, 1943Hartford Nat Bank & Trust CoMethod of making blocking layer electrode systems
US2340362 *Feb 27, 1942Feb 1, 1944Gen Electric X Ray CorpWindow construction for chi-ray tubes
US2377321 *May 20, 1939Jun 5, 1945Western Electric CoEnamel coated article
US2470753 *Feb 18, 1946May 24, 1949Chace Co W MThermostatic laminated metal
US2495835 *Oct 15, 1945Jan 31, 1950George N HibbenLight-colored enameled steel article
US2515337 *Jun 24, 1947Jul 18, 1950Bell Telephone Labor IncMetal to glass seal and method of producing same
US2696662 *Oct 26, 1948Dec 14, 1954SnecmaMember to be used in thermic engines
US2775531 *May 10, 1949Dec 25, 1956Univ Ohio State Res FoundMethod of coating a metal surface
US2975078 *Oct 21, 1957Mar 14, 1961Cons Electrodynamics CorpCeramic coated wire
Referenced by
Citing PatentFiling datePublication dateApplicantTitle
US3175920 *May 8, 1961Mar 30, 1965North American Aviation IncCorrosion protection at intermediate temperatures
US3197291 *Jul 19, 1962Jul 27, 1965North American Aviation IncCeramic coated corrosion-resistant product
US3260579 *Feb 14, 1962Jul 12, 1966Hughes Tool CoHardfacing structure
US3831918 *Jun 13, 1973Aug 27, 1974Asahi Glass Co LtdHeat insulating durable tuyere
US3977660 *Feb 28, 1974Aug 31, 1976Toyo Calorizing Ind. Co., Ltd.Blast-furnace tuyere having excellent thermal shock resistance and high durability
US4189130 *Oct 19, 1978Feb 19, 1980Kawasaki Steel CorporationBlast-furnace tuyere
US4189331 *Jun 22, 1978Feb 19, 1980Canada Wire And Cable LimitedNickel oxide coating
US6446565 *Jul 26, 2001Sep 10, 2002Mannesmannröhren-Werke AgBlast tuyere for shaft furnaces, in particular blast furnaces or hot-blast cupola furnaces
DE2820699A1 *May 11, 1978Nov 16, 1978Kawasaki Steel CoHochofenwindform
DE102010007122A1 *Feb 5, 2010Aug 11, 2011SAB S.àr.l.Düsenstock
Classifications
U.S. Classification428/632, 428/677, 428/633, 428/675, 428/332, 110/182.5, 428/937, 428/926
International ClassificationC21B7/16
Cooperative ClassificationY10S428/937, Y10S428/926, C21B7/16
European ClassificationC21B7/16