US 3117014 A
Description (OCR text may contain errors)
United States Patent 3,117,614 AMYLACEOUS COMPGSlTl-QNS FOR SHAPED ARTECLES AND PROCESS Eugene D. King, Wilmin ton, Delt, assignor to Hercules Powder Company, Wilmington, Del, a corporation of Delaware No Drawing. Filed Apr. 13, 1960, Ser- No. 21,334 17 Claims. (Cl. 105-213) This invention relates to compositions which flow under heat and pressure and which are water soluble, and more particularly to such compositions comprising a derivative of an amylaceous material, a plasticizer therefor and Water. One aspect of the invention relates to making shaped articles from said compositions.
By amylaceous material as usedherein is meant any of the forms of starch, e.g. wheat, corn, sorghum, potato, tapioca, waxy maize, or amylose or amylopectln alone or any combination of amylose and amylopectin.
In defining the compositions of this invention the amount of plasticizer is expressed herein as percent by weight of the derivative of the amylaceous material as the derivative is normally dried L1 preparation; such dried derivatives contain about l%% water. The percent water is expressed herein as percent by weight of the derivative of the amylaceous material on a bone dry basis.
An object of the present invention is to provide a composition which fiows under heat and pressure and which is water soluble. A further object is to provide such a cornposition containing a derivative of an amylaceous material. a plasticizer therefor and water, the amount of water being 1%20% by weight of said derivative on a bone dry basis. A still further object is to provide such a composition which can be worked from a hot melt. Another object is a process of making shaped articles from such a composition comprising subjecting said composition to heat and pressure While maintaining said moisture content.
The above and other objects will become apparent from the description of this invention given hereinafter.
The above and other objects are accomplished according to the present invention by providing a composition which flows under heat and pressure and which is water soluble comprising (1) a derivative of an amylaceous material, (2) a plasticizer for said derivative, and (3) water, the amount of water being 1%Z0% by weight of said derivative on a bone dry basis.
The following examples illustrate various embodiments of the present invention, but it is not intended to limit the invention thereto except as defined in the claims of this application. MS is used herein-to mean the moles of etherifying agent (e.g., alkylene oxide) combined per anhydroglucose unit of the starch molecule and is determined by the familiar Zeisel-Morgan method.
The following examples show a large number of comlllfiid Patented Jan. 7, 1964:
positions within the scope of this invention. In order to determine how various such compositions perform, the amount of plastic flow of the composition was determined under the application of heat and pressure in an Olsen Bakelite flow tester. This is a standard testing device widely used in the plastics industry. It is described in ASTM method D569-46A (ASTM Standards, 1958, Part 9, page 393). This device is perhaps more often referred to in the art as the Tinius Olsen flow tester.
For these plastic flow tests, very uniform mechanical mixtures of the derivative and plasticizer were made. By heat and pressure, the material was fused into a plastic mass. This mass was ground to a fine powder and conditioned generally at C. and RH. for about 24 hours. Cylindrical pellets x /3" were formed from this powder in a pelleting machine. The pellet was placed in the Tinius ()lsen flow tester and the plastic flow thereof measured under the conditions shown in the examples.
The water content of the molding powders was determined by modification of the method described in Mitchell and Snell, Aquametry, pages 178479 (1958), Interscience Publishers, New York City. Thus a 2.5 gram sample of the molding powder was mixed with enough methanol to fill a ml. volumetric flask. This was allowed to stand at about 25C. for 45 minutes. Then an aliquot was analyzed by the .lohansson modification of the Karl Fischer method (see the above Mitchell and Snell reference).
In the following tables various abbreviations are used as a matter of convenience:
HiS is hydroxypropyl starch EPA is hydroxypropyl amylose EPA]? is hydroxypropyl amylopectin CMS is carboxymethyl starch CMA is carboxymethyl amylose CMAP is carboxymethyl amylopectin AS is acetyl starch AA is acetyl amylose AA? is acetyl amylopectin Methyl S is methyl starch MA is methyl amylose MAP is methyl amylopectin CMHPS is carboxymethyl hydroxypropyl starch MHPS is methyl hydroxypropyl starch AHPS is acetyl hydroxypropyl starch The amylopectin derivatives were prepared from a commercial grade of waxy maize starch. The amylose derivatives were prepared from a commercial grade of amylose obtained by fractionation of potato starch. All derivatives prepared from starch, is. the HPS, HES, CMS, AS, Methyl S, CMHPS, MHPS, and AHPS were prepared from a commercial grade of wheat starch containing about 25% amylose and 75% amylopectin.
TABLE 1 Exampl fiecz of MS Plasticizer Extrusion Example Derivative H2O, Flow, N Type MS percent 1 inches! Type Amt, Temp, Pressure, 2 mins.
' percent C. psi.
Propylene glycol 10 540 0, 49 d0 10 100 540 1,1 d0- 10 100 540 1. 4 d0 10 100 540 1. 8 d0. 10 540 0. 56 (l0 10 150 540 0. 92 do 10 100 340 0. 66 d0 10 100 340 1.02
1 Plasticized derivatives conditioned at 50% RH. and 25 O. for 24 hours and flow tested immediately.
TABLE 2 Examples 913.Eflect of Water Plastieizer Extrusion Example Derivative H1O, Flow,
No. Type MS percent inches/2 Type Amt, Temp, Pressure, mins.
percent G. psi.
0. 58 Propylene glyeol 20 1. 4 100 540 1. 5 O. 58 s do 20 3. 6 100 540 5. 5 0. 44 20 2. 7 100 540 1. 0. 44 20 6. 3 100 540 5. 9 0. 44 20 7. l 100 540 5.
TABLE 3 Examples 1422.Use of VGTZOZIS Plastzczzers Plasticizer Extrusion Example Derivative H2O, Flow,
N 0. Type MS percent 1 inches/2 Type Amt, Temp, Pressure, ruins. percent G. p.s.i.
. 44 Propylene glycol. 10 100 540 1.4 44 Diethylene glycoL 10 100 540 1. 7 44 Dipropylene glycol. 10 100 5-10 0. 50 44 i o noaeetyl glycerol 10 110 540 0. 72 44 Diaeetyl glyeerol l0 110 540 0. 70 44 Hydroxypropyl l0 110 540 O. 52
glycerol. .44 Aminoethyl 10 110 540 0.77
ethanolamine, .44 Motlryl diet-honol- 10 110 540 0. 73
amine. 4-1 Glycerol 10 100 540 2. 1
1 Plastiei'ted derivatives conditioned at 50% R11. and 25 C. for 2/4 hours and flow tested immediately. In each example the HPS had a viscosity of 210 cps. measured at 5% solids concentration in aqueous solution at 25 C. with a. Brookfield viscometer.
TABLE 4 Examples 2333.-Various Amounts of Plasticizer Plasticizer Extrusion Example Derivative H2O, Flow,
N 0. Type MS percent inches/2 Type Amt, Temp, Pressure, rnius.
percent O. p.s.i.
0. l3 Propylene glycol 10 120 540 0. 49 O. 13 do 2O 120 540 3. 0 0,13 Dipropylene glyeol 10 120 540 0. 16 0.13 do 2O 120 540 0. 67 0. 58 Propylene glyeol. 20 100 540 5. 5 0.28 Dipropylene glycol 10 100 540 0. 14 0. 28 .d0 20 100 540 0. 47 O. 28 Diethylene glycol- 10 100 540 0. 37 0.28 do 20 100 540 1. 5 0. 28 10 100 540 0. 28 0. 28 2O 100 540 Too soft I Plastieized derivatives conditioned at 50% R11. and C. for 24 hours and flow tested immediately. 1 Plastieized derivatives conditioned at 20% RH. and 25 0. for 24 hours and flow tested immediately.
TABLE 5 Examples 3438.-Eflect of Viscosity Plasticizcr Extrusion Example Deriva- Viscosity, H20, Flow,
0. tive ops. MS percent 2 inches] Type Type Amt, Temp., Pressure, 2 mins.
percent 0. psi.
150 O. Propylene 10 100 540 1. 08
glycol. 125 0. 5 doe 100 540 1. 28 50 O. 50 do 100 540 1. 49 16. 5 0.50 (10 100 540 1. 7. 0 O. 50 d0 5-40 5. 3
1 Measured at 5% solids concentration in aqueous solution at 25 0. with a Brookfield viscometer, i.e.,
viscosity of 5% aqueous solution of tho 2 Plastieized derivatives eondrtione derivative.
(1 at 50% RH. and 25 C. for 2 1 hours and flow tested immediately.
TABLE 6 Examples 39-5 4 .--Use of Various Derivatives of Amylaceous Materials Plasticizer Extrusion Example Derivative Flow, No. Type MS 1 inches/ Type Amt., Temp, Pressure, 2 mms.
percent C. p.s.i.
100 540 1. 13 10 150 540 0. 56 10 100 340 07 66 100 540 3. 8 20 150 540 0.21 20 100 540 1.8 10 100 540 2.0 10 150 540 0.83 10 100 540 1. 7 O 10 100 540 1. 6 10 150 540 2. 6 Methyl AP 10 100 540 2.1 HES 20 100 540 11.0
1 For the irixod derivatives the MS of each substituent is given in the order in which the derivative is named cg. the MS for the CMHPS means a cnrboxymothyl MS of 0.10 and a hydroxypropyl MS of 0.19.
2 Hydroxyethyl starch (see page 3 for meaning of other derivative abbreviations).
The above examples show the effect of a number of variables on this invention. Examples 1-8 (Table 1) show that the plastic flow increases with increase in the MS of the derivative used in the composition. Examples 9-13 (Table 2) show that the plastic flow increases with increase in the water content of the composition. I have found that water is a necessary ingredient of the composition. While I may use about 1%-20% water by weight of the starch derivative on a bone dry basis, I prefer to use about 3%-8% of water. It is necessary to retain the moisture content within the 1%-20% range (preferably 3%-8%) during extrusion or other means of making useful articles from the composition. For example, I have found that it is necessary that the extruder be unventer. For example, as contrasted with this I have found that the use of hot two-roll mills, as commonly used in the art for processing other thermoplastic materials, is not satisfactory and forms a very brittle product because the water flashes oif during processing.
Although a plasticizer is a necessary ingredient in my compositions in order for the compositions to be commercially attractive, the amount of plasticizer may vary widely and I have successfully used various amounts and numerous types of plasticizers. In general, while better results were obtained with the plasticizers in Examples 14-22 and 23-33 (Tables 3 and 4 above), I have also successfully used as plasticizers according to this invention hydroxyethyl morpholine, butyl carbitol and polyoxyethylene. As to amount of plasticizer, I have obtained excellent results with compositions containing 10%-20% plasticizer by weight of the derivative of the amylaceous material. Amounts outside this range of plasticizer may be used. For instance, for some commercial operations where very rapid fiow rates are economically desirable, one may use amounts of plasticizer considerably greater than 20%. (See Examples 55-57 hereinafter.)
Examples 34-38 (Table 5) show that plastic flow increases with decrease in viscosity of the derivative. However, the outstanding advantage of this invention is realized irrespective of the viscosity of the derivative. That is, whether the viscosity of the derivative is low or high, in making the shaped articles of this invention I employ the compositions of my invention as a hot melt instead of an aqueous solution. In fact, aqueous solutions cannot be efiiciently made into the shaped articles of this invention. Large amounts of water would have to be evaporated when using a solution. This would be commercially unacceptable not only from the standpoint of cost of removing the tremendous amount of water but also from the standpoint of drastically limiting the rate of making shaped articles from aqueous solutions.
The prior art has provided the derivatives used in this invention in various degrees of degradation. The prior art has used various means of degradation, including acid hydrolysis, oxidation, heat, light, high energy radiation, and enzymes. The means used to degrade the derivatives is immaterial insofar as the nature of the degraded product is involved, and all such means are applicable in my invention. The hydroxypropyl starch derivatives in Table 5 above were degraded by oxidation to the viscosities shown.
Some variation in flow may be obtained by varying the amount and type of plasticizer. However, I prefer to control with plasticizcr the shaped article properties of flexibility, and resistance to curl, blocking and cracking, and to control with temperature and pressure the flow of the composition in making the shaped articles. Variation of the MS-of the derivative may be used to control flow and also the above-mentioned properties of the shaped articles.
Examples 39-54 (Table 6) show the use of a large number of derivatives of amylaceous materials in accordance with this invention. However, my invention is app icable to derivatives of amylaceous materials broadly as defined hereinbefore. These include, e.g., the following water-soluble derivatives of amylaceous materials.
(1) Saturated alkyl, including, e.g., methyl, ethyl, propyl (2) Unsaturated alkyl, e.g., vinyl, aliyl (3) Hydroxyalkyl e.g., hydroxyethyl, hydroxypropyl (4) Carboxylalkyl, e.g., carboxymethyl, carboxyethyl,
carboxypropyl (5) Cyanoalkyl, e.g.,
(1) Saturated fatty acid, e.g., acetyl, propionyl (2) Unsaturated fatty acid, e.g., acrylyl cyanoethyl IiI. Mixed derivatives comprising two or more of the others and/ or esters in I and H above. Typical mixed derivatives are the carboxymethyl hydroxypropyl, methyl hydroxypropyl, ethyl hydroxyethyl, acetyl hydroxypropyl derivatives.
Table 7 hereinafter gives the broad and preferred MS ran es applicable to this invention. As one exceeds the preferred maximum MS the benefits realized from increased MS begin to level off, especially the hydroxyalkyl and carboxyalkyl derivatives. In the case of the alkyl and acetyl derivatives, one should not exceed an MS of about 1.5 because the product becomes less water soluble and more organosoluble such that at an MS of about 2 they are water insoluble and organosoluble and this would eliminate one of the chief advantages of the present in- Although all of the compositions of this invention are useful in making all of the shaped articles of this inventron, for making shaped articles in which one desires vention. high tensile strength and flexibility, I prefer to use corn- TABLE 7 Broad and Preferred ZMS Ranges Amylopectin Amylose-Amylopectin Amylose Mixture Derivative Broad MS Preferred Broad MS Preferred Broad MS Preferred his 1V1 MS Hydroxyalkyl At least 0.1.." 0.2-0.6 0.2416 0.5-1.0 Oarboxyalk'yl- At least 0.5 0.8-1.5 0.84.5 1. 2-1.8 Alkyl 0.3-1.5 0.5-1.2 0.5-0.8 0.8-1.2 .Acetyl 0.3-1.5 0.5-1.2 0.5-0.8 0.8-1.2
This invention has a large number of applications wherein it excels. it may be used wherever there is a 2 need for shaped articles, e.g., filaments, films, sheets, rods, tubes, capsules and containers in general or other such articles.
A very desirable property for many applications, which I have found that the articles made from the compositions of this invention have, is that of heat scalability. That is, by the application of slight pressure and heat, the material permanently heat seals or adheres to itself and various other materials. The following Examples 5559 are specific applications of these.
Examples 5557.-Films, Rods and Filaments in order to prepare shaped articles in the form of films, a sample of h'ydroxypropyl amylosc of 0.50 MS was intimately mixed with 50% propylene glycol by weight of the hydroxyp'ropyl amylose. This was allowed to condition for 18 hours at 25 C. and 50% RH. The resulting rubbery mass, which contained about 8% water, was extruded through a one-inch United States Rubber Machine extruder fitted with a 2-inch long slit 10 mils wide to form films. The films were extruded at a tem- .perature of 300 F. and 52 rpm. screw speed. The films were smooth, colorless, tough, flexible and transparent. The thickness of the films. varied from 6 to 2 mils depending on how much tension the films were subjected to during extrusion.
In order to prepare shaped articles in the form of rods, some of the extruded films were recycled through the extruder using a diameter circular orifice at 250 F.
and 32 rpm. screw speed. The rods had excellent fiexi bility and strength.
By applying tension to the rods during extrusion, which was done by winding the rods around a spindle, the size of the rods were drawn down to very fine filaments.
These filaments had excellent flexibility and strength.
Example 58.Sheets In order to prepare shaped articles in the form of sheets a sample of hydroxyethyl starch of 0.89 MS was intimately mixed with 3% propylene glycol by weight of the hydroxypropyl starch. This was allowed to condition for 24 hours at 25 C. and RH. The resulting powdery mass, which contained about 8% water, 'was compression molded for three minutes between polished metal plates at 220 F. and 300 psi. After cooling the molds to about 110 F. the molded sheets 'were removed. The molded sheets were about 10 mils :thick, clear, smooth and transparent.
Example 59.Sheets Sheets were prepared as in Example 58 above using hydroxycthyl amylose of 0.50 MS and a molding temperature of 300 F. The sheets had substantially the same properties as the sheets of Example 58 but were significantly tougher.
positions wherein the amylaceous material from which the derivative is made contains about 50%-90% amylose. The amylose-rich starches may be obtained by any of the standard methods of fractionation whereby the amylose and amylopectin in starches are separated,
F such as for example the fractionation method disclosed 20 in P. G. Schoch, Advances in Carbohydrate Chemistry edited by W. W. Pigman and M. L. Wolfrom, page 247 (1945), Academic Press, New York City. I have obtained excellent results with a commercial product which contains approximately amylose and 10% amylopectin and was obtained by fractionating potato starch. Also equally applicable are several other high amylose content starches which have recently become available.
As those skilled in this art will appreciate, various additional materials may be used with the compositions of this invention. These additional materials include, e.g., clay, pigments, fillers in general, dyes.
Likewise, the artisan will know that the'various con ventional techniques of preparing shaped articles are applicable in my invention; these techniques include, e.g., compression molding, injection molding, and extrusion.
As many apparent and widely diiferent embodiments of this invention may be made without departing from the spirit and scope thereof, it is to be understood that the invention is not limited to the specific embodiments thereof except as defined in the appended claims.
What I claim and desire to protect by Letters Patent is:
1. A composition consisting essentially of (1) a derivative of an amylaceous material selected from the group consisting of amylaceous (at) others, (b) esters, (c) mixed ether-esters, (d) mixed ethers and (e) any combination of (a), (b), (0), and (d), (2) a plasticizer for said derivative, and (3) water, the amount of water being 1%20% by weight of said derivative on a bonedry basis, the amount of plasticizer being at least about 3% by weight of said derivative, said plasticizer being selected from the group consisting of water-soluble and water-miscible plasticizers, said composition being further characterized by being water-soluble and by flowing under heat and pressure to form articles which are heat-scalable.
2. The composition of claim 1 wherein said derivative is the hydroxyalkyl derivative.
3. The composition of claim 1 wherein said derivative is the hydroxypropyl derivative.
4. The composition of claim 1 wherein said derivative is the hydroxyethyl derivative.
5. The composition of claim 1 wherein said derivative is the carboxyalkyl derivative.
6. The composition of claim 1 wherein said derivative is the carboxymethyl derivative.
7. The composition of claim 1 wherein said derivative is the alkyl derivative.
8. The composition of claim 1 wherein said derivative is the methyl derivative.
9. The composition of claim 1 wherein said derivative is the carboxyalkyl hydroxyalkyl derivative.
10. The composition of claim 1 wherein said derivative is the carboxymethyl hydroxpropyl derivative.
11. The composition of claim 1 wherein said derivative is the carboxymethyl hydroxypropyl derivative.
12. The composition of claim 1 wherein said derivative is the methyl hydroxypropyl derivative.
13. The composition of claim 1 wherein the amount of Water is 3%8%.
14. The composition of claim 1 wherein said plasticizer is propylene glycol.
15. The composition of claim 1 wherein said plasticizer is diethylene glycol.
16. The composition of claim 1 wherein said plasticizer is glycerol.
17. Process of making shaped articles from the com- References Cited in the file of this patent UNITED STATES PATENTS 2,530,439 Molteni Nov. 21, 1950 2,883,300 Rickert Apr. 21, 1959 2,973,243 Kudera Feb 28, 1961 OTHER REFERENCES Kerr: Chemistry and Industry of Starch, 2nd Edition, Academic Press Inc., N.Y., '1950, page 298. (Copy in Scientific Library.)
UNITED STATES PATENT OFFICE CERTIFICATE OF CORRECTION Patent No, 3 111 014 January 7 1964 Eugene DO Klug It is hereby certified that error appears in the above numbered patent requiring correction and that the said Letters Patent should read as corrected below.
Column 5 line 39 for "unventer read unvented column 9 line 6 for "carboxymethyl hydroxypropyl derivative" read alkyl hydroxyalkyl derivative -o Signed and sealed this 16th day of June 1964 (SEAL) Attest:
ERNEST W. SWIDER EDWARD J. BRENNER Attesting Officer Commissioner of Patents