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Publication numberUS3118750 A
Publication typeGrant
Publication dateJan 21, 1964
Filing dateJul 22, 1958
Priority dateJul 22, 1958
Publication numberUS 3118750 A, US 3118750A, US-A-3118750, US3118750 A, US3118750A
InventorsDonald T Dunlap, Herbert W Coates
Original AssigneeCelanese Corp
Export CitationBiBTeX, EndNote, RefMan
External Links: USPTO, USPTO Assignment, Espacenet
Low density non-woven web
US 3118750 A
Abstract  available in
Previous page
Next page
Claims  available in
Description  (OCR text may contain errors)

D. T. DUNLAP ETAL LOW DENSITY NON-WOVEN WEB Filed July 22, 1958 Jan. 21, 1964 OVEN United States Patent 3,118,750 LGW DENSlTY NUNAVGVEN WEB Donald T. Dunlap and Herbert W. Coates, harlotte, N.C., assignors to Celaneee Corporation of America, New York, N.Y., a corporation of Delaware Filed July 22, 1953, Ser. No. 75%,223 16 Claims. (Ci. 55-524) The present invention relates to the formation of fibrous non-woven webs or batts characterized by low density, high loft and resilience.

An irnportant feature of the invention is the provision of air filters of suificient rigidity to permit them to be used without frames, if desired, which filters achieve efiicient filtration of dust with minimum resistance to the fiow of air. The invention is particularly directed to the provision of rigid or semi-rigid disposable filter media for use in air conditioning units as well as for similar air filtering purposes. The invention includes the method of producing such webs or batts.

Filters suitable for use in air conditioners are generally formed by applying an adhesive or binder to a non-woven batt formed by carding or air-blowing staple fibers. Batts exhibiting desirable physical properties and yet low in cost can be produced using synthetic thermoplastic staple fibers. Such fibers are formed by extrusion of a solution or melt of filament-forming material through orifices to form continuous filaments to which an anti-static lubricant is applied, -i.e. one which will prevent build up of static electricity, so as to permit the filaments to be held closely together as m aid in further processing. The filaments are gathered into a large bundle or tow, they are usually crimped and they are subsequently cut into short lengths, i.e. staple fibers, to be incorporated into non-woven batts as described.

In accordance with one aspect of the present invention it has been found that control of the composition of each fiber and of the mix permits production of nonwoven batts and of filters characterized by greater loft, i.e. lower density, higher filtering efficiency and lower pressure drop than heretofore attained with generally similar filter constructions. The fiber mix to achieve these results is composed of some fibers which will not build up a static charge (or will dissipate the charge rapidly if built up), referred to hereinafter as low static fibers, and some fibers which will readily build up and retain an electrostatic charge, referred to hereinafter as high static fibers. The high static fibers build up and retain electrical charges so as to repel each other and produce a more lofty or bulky structure. Advantageously, at least 16% and preferably at least by weight of the fibers are high static fibers to realize the desired advantages. Greater proportions of high static fibers increase the amount of repulsion but advantageously no more than 50% and preferably no more than by weight are high static fibers. Greater amounts produce so much static repulsion that there is insufiicient interlocking to form a coherent structure and in addition complicate processing since the fibers tends to stick to the processing machines due to their high static charges.

The high static fibers of the composition can be formed from synthetic thermoplastic filamentary material by a procedure identical with conventional practice except that application of an anti-static lubricant is omitted. Alternatively, an anti-static lubricant such as sulfonated and/ or sulfated hydrocarbons, salts of a long chain fatty acids, alkyl phosphates, ethylene oxide derivatives of sorbitol, or the like, dissolved or emulsified in a liquid such as mineral oil or other hydrocarbon, can be applied so as to facilitate crimping and processing, for example, and the fibers can be scoured as in hot soap solution to remove the lubricant after which they are dried ice and mixed with low static fibers, e.g. fibers which are inherently low static fibers such as cotton or rayon, or fibers carrying an antistatic finish or lubricant.

The denier of the component fibers may vary widely, e.g. from 0.5 to 35.0 :or more, although lower denier fibers will provide more surface and finer spaces so as to improve filtration. The length of the fibers can also be varied within wide limits, e.g. to 3 inches or more. Generally the fiber length will range from about 1.5 to 2.5 inches to produce sufiicient interlocking while also perrnitting easy processing on conventional equipment for forming non-w0ven batts.

The use of a mixture of different denier and different length fibers is advantageous because high denier per filament fibers provide structural strength as well as openness to the web whereas low denier per filament fibers provide greater surface area for high titration.

As noted, the fibers are preferably crimped, containing from about 1 to 20 and preferably 6 to 12 chimps per inch of tensioned filament, i.e. in a length of filament which when tensioned just sufiiciently to cause the crimps to disappear is one inch lon This crimp can be inserted either chemically (by immersion in a swelling agent followed by dryin in relaxed condition) or mecham'cally or may inherently be present in the filaments as produced. The crimp incre es the bulk and in addition aids in interlocking so as to form a stronger and more rigid structure. The use of fibers of non-circular cross-section further increases the bulk and rigidity.

The composition of the high static fibers may vary widely, representative fibers being thermoplastic and composed of polyamicles such as nylon, polyesters such as polyethylene terephthalate, acrylonitrile polymers and copolymers, ethers of cellulose, organic acid esters of cellulose, and the like. Preferably they are composed of lower alk-anoic esters of cellulose such as cellulose propionate, cellulose butyrate, cellulose acetate-butyrate, and the like, and especially cellulose acetate. The cellulose acetate may be conventional cellulose acetate having an acetyl value of about 55% by weight calculated as acetic acid or it may constitute cellulose triacetate having an acetyl value in excess of about 59%. The other organic acid esters of cellulose may have corresponding variations in their acyl and free hydroxyl contents. The low static fibers can comprise an inherently hydrophilic material such as cellulose, e.g. cotton, rayon (regenerated cellulose) or the like, or may comprise normally hydrophobic materials of the same composition as the high static fibers but treated with an anti-static finish.

Following formation of the batt using an air-blowing apparatus or a cotton card and camel-back cross-laying apparatus, a bonding agent is applied to bond the fibers. Suitable bonding agents include solutions or dispersions in organic solvents or water, i.e. latexes of binders such as natural or synthetic rubber, polyvinyl acetate, copolymers of vinyl acetate and chloride, commercial modified urea or melamine formaldehydes, phenolics, acrylic or epoxy resins, insolubilized starches and the like. Where there are desired filters of sufiicicnt rigidity to be self-sustaining without a frame, fiexible but comparatively still bonders such as polyvinyl acetate and the commercial modified urea formaldehydes give particularly good re sults. Conventional anti-oxidants, pigments, filters, and the like may be present as well as vulcanizing agents and/or accelerants when required. The bonding agent can be applied by immersing the non-woven in the bonding agent, by spraying the bonding agent on the nonwoven possibly with the aid of suction to draw the bonding agent through the non-woven, by depositing the bonding agent in the form of a foam on the non-woven, or the like. The impregnated non-woven is then dried to remove liquid and other volatiles and is cured or vulcanized it necessary. The ratio of binder solids to fibers generally ranges from about to 40%, and preferably to by weight.

To increase the "mensional stability of the filter it may be backed win an open mesh scrim, cg. cotton woven with an open Leno weave with successive warps and fillings spaced about 0.25 inch from each r. The may ap d after the filter is com ctely formed ,y be po ned on one or both s ces of the ROQJWOVH batt waile the bonding agent is app so as to be joined thereto simultaneously with bonding. if desired, the scrim aay be sandwiched between two baits.

fiubsequcntly, filters are desirably fireproofed as by sprayg or impregnating the bonded nber web or batt v ith a rlicproofing agent. A particularly preferred fireproo ing agent is a l:1 mixture of borax nd boric acid which may be applied the form of a 44% by weight solution in water. This 1:1 mixture of borax and boric acid is outstai g be aus it provides elfective fire retardency combined ab .y to cling to the bonded filter. If the scrim is not already present during this treatment it may be si larly treated separately.

1 a flow sheet illustrating a continuous manner carrying out the process of the invention; and FIG. 2 is a perspective view or" a filter produced there- Referring to i lubricant is supp' lub icant-coatccl fibers is scoured as indicated at 11 with the two types of fibers then being supplied to a mixer 12 and to an air blot g device 13 to produce a batt i l of mixed randomly arranged fibers. The batt 14 is sprayed with a bonding agent at 15 and bonding agent is cured in the oven is. T

G. l fiber coated with an anti-static 3 f om a source In and part of the *he bonded bait is then sprayed with a fire retardant as indi ated at 17 and the fireproof-ed batt is dried in the oven In the preferred form of the invention which illustrated, a scrim 19 is saturated with a fireproofing agent in the saturator and then dried in the oven 21, after which the scrim is sprayed with adhesive as indicated at 22 and then contacted with the batt and. bonded thereto the oven 23. The finished product emerging from the oven 23 is indicated by the numeral 24.

If desire-., the process can be effected discontinuously with b s of predetermined size.

As seen in FIG. 2, the filter comprises a coherent mass of fibers 25 bonded to each other with scrim 19 bonded to the upper surface. The scrim 19 comprises warp threads as each held in no on by an entwined pair of filling 27,

Filters duced in accordanc with the present invention are sufficiently rigid and possess suificient integrity to wi istand substantial air velocity without the use of a frame. They are capable of efiective dust removal, such effective dust removal being ind ted by an efiiciency rating of about 50% or better as determined by the Department of Commerce Recommended Standard Testing Procedure, TS5315, dated May 21, 1956. They possess a minimum resistance to the passage of air therethrough. Thus, wah a filter richness of /2% inch, the maximum 1 I restriction is less than 0.09 inch of water at a face air velocity of 350 feet per minute. Moreover, the structure of the filter is such that af r 199 grams of standard test dust is supp ed to a 6 x 6 inch sample batt, the restriction to air passing through tire batt at a face velocity of 350 feet per minute still does exceed 0.18 inch of water. The st ndard test dust is composed of 72% by weight of standardized air cleaner test dust fine, 25% by weight of Kl carbon black 3% by Weight of No. 7 cotton linters ground Wiley Mill with 4 minimeter screen.

While the non-woven batts have been described with respect to tneir use as filters, either with or without Example I A non-Woven batt is inch thick was produced by airblowing cellulose acetate fibers, acetyl value 54%, comprising the following weight composition:

75% of 2 inch fibers, denier per fiber, lubrica cd 10% of 2 inch fibers, l7 denier per fiber, lubricant-free 15% of 1.6 inch fibers, 5.5 denier per fiber, lubricantfree All the fibers were crimped to the extent of about 8 crimps per tensioned inch. The anti-static lubricant was pre ent on the 35 denier fibers to the extent of 3% by T lit and comnrised mineral oil plus sulfonated hydrocarbon. The lubricant-free fibers were Y-shaped in crosssection to impart increased bulk. The batt was sprayed with a 20% dispersion of polyvinyl acetate in water in an amount sufficient to deposit on the fibers of their weight of polyvinyl acetate. The sprayed batt was heated for 2 minutes in an oven at 350 F. and weighed 6 ounces per square yard. its thickness was only slightly less than inch. Its filtration characteristics as an air conditioning filter were excellent, giving high filtration efficiency at low pressure drop.

Example 11 By the same process outlined in Example I a filter was formed of a fiber m made up as follows:

most 7% inch thick, with almost the same filtration charteristic:

75% of 3 inch fibers, 35 denier per fiber, lubricated 25% of 1.6 inch fibers, 5.5 denier per fiber, lubricant- .1 tree.

Example IV The fibers or" Example Ill when mixed in equal proportions and processed as in Example I produced a filter almost thick, weighing 5.1 ounces per square yard and of approximately the same filtration characteristic as in Example lil.

it is to be understood that the roregoing detailed description is given merely by way of illustration and that many variations may be made therein without departing from the spirit of our invention.

Having described our invention what We desire to secure by Letters Patent is:

l. A non-woven batt comprising high static thermoplastic resinous fi ers and low static thermoplastic resinous fibers carrying an antistatic lubricant, about 10 to of the total fiber weight comprising high static fibers.

2. A batt as recited in claim 1 in which said batt includes a resilient binder securing the fibers thereof to one another.

3. A batt as recited in claim 2 including an open mesh scrim adhesively secured thereto.

4. A batt as recited in claim 1 in which said high static fibers comprise an organic acid ester of cellulose free of antistatic lubricants.

5. A batt as recited in clai 1 in which said high static fibers comprise cellulose acetate.

6. A batt recited in claim 1 in which said high static fibers comprise about 15 to 25 of the total weight of said fibers.

7. A non-woven batt comprising antistatic lubricantcarrying low static thermoplastic resinous fibers and high static crirnped thermoplastic resinous fibers, the fiber mixture including fibers of difierent deniers and fibers of different lengths, about to 50% of the total Weight of said fibers comprising high static fibers, the fibers of said batt being secured together by a resilient binder.

8. A non-Woven batt as recited in claim 7 in which said binder is present in about to 30% by weight of the fibers.

9. A non-woven batt as recited in claim 7 impregnated with a fireproofing agent.

10. A non-woven batt as recited in claim 7 including an open mesh scrim adhesively secured thereto.

11. A non-woven batt comprising antistatic lubricantcarrying low static thermoplastic resinous fibers and crimped cellulose acetate fibers free of antistatic lubricant, the length and denier of the lubricant-free cellulose acetate fibers being different from those of at least some of the lubricant-carrying fibers, the denier of said fibers ranging from about 0.5 to 35.

12. A non-woven batt comprising antistatic lubricantcarrying 10w static crimped cellulose acetate fibers and crimped cellulose acetate fibers, free of antistatic lubricants, ranging in denier from about 0.5 to 35, and about 15 to of the total fi er Weight comprising lubricantfree fibers, and a resilient binder adhesively securing said fibers to each other.

13. A non-woven batt as recited in claim 12 wherein said binder comprises polyvinyl acetate present in about 15 to 30% by Weight of the fibers.

14. A fiber mixture adapted for the formation of non- Woven batts comprising high static thermoplastic resinous fibers and low static thermoplastic resinous fibers carrying an antistatic lubricant, about 10 to of the total fiber weight comprising high static fibers.

15. In the production of a highly *orous non-Woven filter wherein fibers are formed into a non-Woven batt and a binder is applied to said batt to secure said fibers to each other, the improvement which comprises employing as said fibers a mixture of low static thermoplastic resinous fibers carrying an antistatic lubricant and high static thermoplastic resinous fibers, about 10 to 50% of the total fiber Weight comprising high static fibers.

16. The process recited in claim 15 in which said high static fibers comprise cellulose acetate, free of antistatic lubricants.

References Cited in the file of this patent UNITED STAT ES PATENTS 1,645,858 Hayes Oct. 18, 1927 1,821,317 Offord et al. Sept. 1, 1931 1,978,125 Bennett Oct. 23, 1934 2,483,406 Francis Oct. 4, 1949 2,543,101 Francis Feb. 27, 1951 2,580,202 Talalay et a1. Dec. 25, 1951 2,810,426 Till et al. Oct. 22, 1957 2,825,199 Hicks Mar. 4, 1958 3,008,215 Pitts Nov. 14, 1961

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US1978125 *Aug 19, 1929Oct 23, 1934Sprayo Flake CompanyArt of insulation and fireproofing
US2483406 *Dec 16, 1947Oct 4, 1949American Viscose CorpProcess and apparatus for producing fibrous materials
US2543101 *Jul 20, 1944Feb 27, 1951American Viscose CorpComposite fibrous products and method of making them
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Referenced by
Citing PatentFiling datePublication dateApplicantTitle
US3429104 *May 26, 1965Feb 25, 1969Monsanto CoExtraction process and product
US3535191 *May 6, 1968Oct 20, 1970Appleton Wire Works CorpSewn fabric and method of manufacture
US4099943 *Oct 18, 1976Jul 11, 1978Tenneco Chemicals, Inc.Composite fluid filtering medium and method of making
US4118531 *Nov 4, 1977Oct 3, 1978Minnesota Mining And Manufacturing CompanyWeb of blended microfibers and crimped bulking fibers
US4281042 *Aug 30, 1979Jul 28, 1981E. I. Du Pont De Nemours And CompanyPolyester fiberfill blends
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US4413391 *Aug 2, 1982Nov 8, 1983Albany International Corp.Resin containing textiles
US7226877Dec 27, 2004Jun 5, 2007E. I. Du Pont De Nemours And CompanyLiquid water impermeable reinforced nonwoven fire blocking fabric, method for making such fabric, and articles fire blocked therewith
US7229937Mar 23, 2004Jun 12, 2007E. I. Du Pont De Nemours And CompanyReinforced nonwoven fire blocking fabric, method for making such fabric, and articles fire blocked therewith
US7247585Nov 23, 2004Jul 24, 2007E.I. Du Pont De Nemours And CompanyReinforced nonwoven fire blocking fabric having ridges and grooves and articles fire blocked therewith
US7819994Oct 26, 2010E. I. Du Pont De Nemours And CompanyReinforced nonwoven fire blocking fabric, method for making such fabric, and articles fire blocked therewith
US20050026528 *Jul 29, 2003Feb 3, 2005Forsten Herman HansFire resistant fabric composite, process for fire-blocking a mattress and mattress set, and a mattress and mattress set fire-blocked thereby
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US20050215142 *Mar 23, 2004Sep 29, 2005Bascom Laurence NReinforced nonwoven fire blocking fabric, method for making such fabric, and articles fire blocked therewith
US20060042058 *Oct 21, 2005Mar 2, 2006Knoff Warren FMultilayer spunlaced nonwoven fire blocking composite
US20060048302 *Nov 4, 2005Mar 9, 2006Forsten Herman HFire resistant fabric composite, process for fire-blocking a mattress and mattress set, and a mattress and mattress set fire-blocked thereby
US20060111000 *Nov 23, 2004May 25, 2006Bascom Laurence NReinforced nonwoven fire blocking fabric having ridges and grooves and articles fire blocked therewith
US20060141880 *Dec 27, 2004Jun 29, 2006Bascom Laurence NLiquid water impermeable reinforced nonwoven fire blocking fabric, method for making such fabric, and articles fire blocked therewith
US20070224405 *May 23, 2007Sep 27, 2007Bascom Laurence NReinforced nonwoven fire blocking fabric, method for making such fabric, and articles fire blocked therewith
U.S. Classification55/524, 442/60, 442/110, 428/369, 57/901, 19/145, 428/921
International ClassificationD04H1/64
Cooperative ClassificationY10S428/921, Y10S57/901, D04H1/643
European ClassificationD04H1/64C