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Publication numberUS3210168 A
Publication typeGrant
Publication dateOct 5, 1965
Filing dateMay 22, 1962
Priority dateMay 22, 1962
Publication numberUS 3210168 A, US 3210168A, US-A-3210168, US3210168 A, US3210168A
InventorsArnold J Morway
Original AssigneeExxon Research Engineering Co
Export CitationBiBTeX, EndNote, RefMan
External Links: USPTO, USPTO Assignment, Espacenet
Stabilized oiled coal slurry in water
US 3210168 A
Abstract  available in
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Claims  available in
Description  (OCR text may contain errors)

No Drawing. Filed May 22, 1962, Ser. No. 196,611 2 Claims. (Cl. 44'-51) This invention relates to a stabilized slurry of pulverized coal coated with a liquid hydrocarbon fuel in water to make the slurry suitable for pumping through a pipeline. In particular, this invention is concerned with stabilizing the pulverized coal coated with hydrocarbon oil using an imidazoline surfactant which stabilizes the dispersion of the oil-coated pulverized coal in a relatively small amount of water.

Tests have been carried out to demonstrate that an aqueous coal slurry containing at least 30 to 40 wt. percent water can be pumped through pipelines for transportation to where the coal is to be burned. However, there are disadvantages in using only water as the liquid medium in that the water of such proportions, above 20%, makes combustion of the slurry in the furnace less eflicient. Difliculties also arise in the transporting of an aqueous slurry or oil slurry of coal in the tendency of the powdered coal to settle out.

The present invention has been found to provide a more suitably powdered coal slurry in a composition with petroleum oil and a more limited amount of water, particularly when the mixture is stabilized by the use of a relatively small amount of imidazoline which serves to stabilize the slurry.

The imidazoline agent has the general formula:

wherein R is an aliphatic hydrocarbon chain radical containing 10 to 23 carbon atoms. The aliphatic radical may be an alkyl group such as present in high molecular weight fatty acids, e.g., lauric, myristic, palmitic, stearic, archidic and carnaubic. The aliphatic radical may be alkenyl radical or an alkdienyl radical, or in other words, an unsaturated aliphatic radical such as present in the following unsaturated acids, e.g., oleic, linoleic, linolinic and eurcic.

These imidazolines and methods for their preparation are described in U.S. Patent 2,361,488 of Louis A. Mikeska.

The stable coal slurry compositions made in accordance with the present invention using pulverized coal coated with hydrocarbon oil dispersed in water should contain about 15 to 20 Wt. percent of water. Larger amounts than this proportion give unsatisfactory combustion and difliculties in maintaining a stable slurry. The proportion of hydrocarbon oil, e.g., crude petroleum oil or a petroleum fuel oil, used in coating the coal particles is in the range of about 25 to 35 wt. percent. The amount of pulverized coal used in the slurry is in the range of 45 to 55 wt. percent. The amount of the surfactant agent in the slurry formulation is about 0.3 to 2 wt. percent. The pulverized coal is preferably of a particle size to make substantially all the pulverized coal pass through an 8 mesh sieve, and with about 90% which would be retained on a 200 mesh sieve. In these slurries, the hydrocarbon oil, with the aid of the imidazoline surfactant in small amount, coats the coal particles and replaces the amount of water that cannot be tolerated for stable suspension and satisfactory combustion.

In preparing a composition containing the maximum amount of water, 20 wt. percent water, the pulverized United States Patent dered coal suspension to obtain the following slurry formulation:

Percent Pulverized coal 50.0 Water 20.0 Fuel oil 28.0 Imidazoline surfactant 2.0

Petroleum fuel oils found suitable for use in the formulations are residual oils of the following types:

Inspection of heavy fuel oils from various crudes Venezuelan U.S.A.

Middle East 1 2 East West Coast Coast Specific Gravity 60 FL... 0.962 0.980 1.008 0.971 0.983 Closed Flash Point, F. 192 162 210 180 200 Viseoslty Redwood, Sec.

F 3, 570 3, 745 4, 050 1, 850 3, 347 Sulfur Content, percent..... 2. 17 2. 65 l. 7 1. 24 4. 5 Gross Oalorifie Value,

B.t.u./lb 18, 540 18, 440 18,200 18, 490 18, 290

In general, the more suitable residual fuel oils for use in the slurries have specific gravities of about 0.9 to 1 (at 60 F.) and viscosities about 40 to 300 Saybolt furol seconds at 122 F.

The pulverized coal may be of various types of coal, e.g. bituminous, anthracite, or semi-bituminous. Other finely-divided solid carbonaceous materials may be used, e.g. coke either from coal or petroleum.

The following example describes a slurry formulation which was considered closer to the optimum in stability.

Slurry formulation 1 Residual type oils for burner installation equipped with preheating facilities.

This slurry formulation showed no appreciable tendency to settle out after standing for over 24 hours. It has suitable fluidity under pressure for pumping through a pipeline, being equivalent in this respect to a slurry of 60 wt. percent pulverized coal in 40 wt. percent water.

The invention described is claimed as follows:

1. A stabilized aqueous slurry of powdered coal and residual petroleum fuel oil which comprises 8 to 200 mesh particle coal in a proportion of 45 to 50 wt. percent, 25 to 35 wt. percent of petroleum residual oil having a 3 4- specific gravity of 0.9 to 1 at 60 F. and a Saybolt furol viscosity of 40 to 300 seconds at 122 F., 15 to 20 wt. 1% E percent water and about 0.3 to 2.0 wt. percent of an imidazoline surfactant of the formula:

Hg-CHr-NH;

wherein R represents a C to C aliphatic hydrocarbon NCH1 radical, the powdered coal being coated by the hydro- R(".|; 43H, carbon oil containing the imidazoline and the thus-coated powdered coal being suspended in the water. N 10 I 1 References Cited by the Examiner UNITED STATES PATENTS wherein R represents heptadecenyl and heptadecadienyl g &2; chains, the powdered coal being coated with the oil con- 2622018 12/52 32 44 63 taining the surfactant. i 1 e e a 2. A stabilized aqueous slurry of powdered coal and FOREIGN PATENTS oil which comprises about 45 to 50 wt. percent of pow- 408 951 4/34 Great Britain dered coal, about to wt. percent of hydrocarbon 454:796 10/36 Great Britain fuel oil, 15 to 20 wt. percent water, and about 0.3 to 2.0 wt. percent of an irnidazoline having the formula:

DANIEL E. WYMAN, Primary Examiner.

Patent Citations
Cited PatentFiling datePublication dateApplicantTitle
US2128913 *Feb 3, 1936Sep 6, 1938Standard Oil CoCoal handling
US2553183 *Jul 3, 1948May 15, 1951Shell DevFuel oil composition
US2622018 *Oct 19, 1949Dec 16, 1952Socony Vacuum Oil Co IncMotor fuel
GB408951A * Title not available
GB454796A * Title not available
Referenced by
Citing PatentFiling datePublication dateApplicantTitle
US4030894 *Jun 30, 1975Jun 21, 1977Interlake, Inc.Stabilized fuel slurry
US4094810 *Jun 1, 1976Jun 13, 1978Kerr-Mcgee CorporationAqueous slurry of ash concentrate composition and process for producing same
US4147519 *Jun 27, 1977Apr 3, 1979International Telephone & Telegraph Corp.Coal suspensions in organic liquids
US4153421 *May 17, 1976May 8, 1979Interlake, Inc.Stabilized fuel slurry
US4203729 *Jun 26, 1978May 20, 1980Nippon Oil & Fats Co. Ltd.Method for producing coal dispersing oil compositions
US4251230 *Oct 26, 1978Feb 17, 1981International Telephone And Telegraph CorporationCoal suspensions in organic liquids
US4288232 *Dec 19, 1979Sep 8, 1981Basf Wyandotte CorporationEster containing fuel composition
US4335684 *Sep 22, 1980Jun 22, 1982Thermo Electron CorporationMicronized coal-water fuel slurry for reciprocating internal-combustion engines
US4358293 *Jan 29, 1981Nov 9, 1982Gulf & Western Manufacturing Co.Coal-aqueous mixtures
US4364741 *Mar 26, 1981Dec 21, 1982Diamond Shamrock CorporationOil slurries of carbonaceous materials
US4364742 *Apr 1, 1981Dec 21, 1982Diamond Shamrock CorporationCarbonaceous materials in oil slurries
US4441889 *Sep 10, 1982Apr 10, 1984Gulf & Western Industries, Inc.Coal-aqueous mixtures
US4453947 *Mar 18, 1982Jun 12, 1984University Of FloridaLow viscosity stable mixtures of coal and fuel oil containing alcohol
US4511365 *Apr 10, 1984Apr 16, 1985Sohio Alternate Energy Development CompanyCoal-aqueous mixtures
US4551179 *Oct 11, 1983Nov 5, 1985The Standard Oil CompanyCoal-aqueous mixtures
US4637822 *Nov 2, 1981Jan 20, 1987Basf CorporationCoal-oil slurries containing a surfactant
US4705533 *Apr 4, 1986Nov 10, 1987Simmons John JUtilization of low rank coal and peat
US4713086 *Mar 2, 1984Dec 15, 1987Amax Inc.Oil-compatible coal/water mixtures
US5096461 *Aug 22, 1990Mar 17, 1992Union Oil Company Of CaliforniaSeparable coal-oil slurries having controlled sedimentation properties suitable for transport by pipeline
DE2717796A1 *Apr 19, 1977Oct 26, 1978Interlake IncStabilised fuel slurry prepn. - in the form of thixotropic oil-in-water emulsions, esp. for use in blast furnaces
DE2933760A1 *Aug 21, 1979Mar 12, 1981Bojak KurtQuasi-fluessiger brennstoff auf kohlenstaub-basis
DE2947788A1 *Nov 28, 1979Jul 23, 1981Bojak KurtFuels comprising aq. coal slurries - with aq. phase contg. salts, sugar and/or soap
EP0290699A1 *May 12, 1987Nov 17, 1988Cadet InternationalFluid combustible mixture based on coal and process for its preparation
WO1980000449A1 *Aug 14, 1978Mar 20, 1980E CottellFuels and methods for their production
WO1987005891A1 *Mar 25, 1987Oct 8, 1987Simmons John JUtilization of low rank coal and peat
Classifications
U.S. Classification44/281, 516/43, 516/DIG.700, 516/68
International ClassificationC10L1/32
Cooperative ClassificationY10S516/07, C10L1/324
European ClassificationC10L1/32B