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Publication numberUS3293104 A
Publication typeGrant
Publication dateDec 20, 1966
Filing dateNov 23, 1962
Priority dateNov 23, 1962
Publication numberUS 3293104 A, US 3293104A, US-A-3293104, US3293104 A, US3293104A
InventorsRobert Hull Donald
Original AssigneeDu Pont
Export CitationBiBTeX, EndNote, RefMan
External Links: USPTO, USPTO Assignment, Espacenet
Styled pile fabrics and method of making the same
US 3293104 A
Abstract  available in
Previous page
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Claims  available in
Description  (OCR text may contain errors)

11R. HULL 33,293,194

5 mm mamas AND mmnon ormxme THE SAME Filed Nov. 25; 1962 comma mm fl 5mm PARTICLES SLITS PENETRATE EETIRE TNIGKHESS 0F BLOCK 10 moms imam sur ovsmcs BACKING ADHESIVE am INVENTOR DONALD ROBERT HULL United States Patent 3,293,104 STYLED FILE FABRICS AND METHOD OF MAKING THE SAME Donald Robert Hull, Wilmington, Del., assignor to E. I.

du Pont de Nernours and Company, Wilmington, DeL,

a corporation of Delaware Filed Nov. 23, 1962, Ser. No. 239,716 11 Claims. (Cl. 16167) This invention relates to the styling of textile articles and more particularly to improved methods of styling and unique products resulting therefrom.

Many methods are currently known for styling of pile fabrics such as carpets by conventional techniques of embossing, cutting, printing, sculpturing, and the like. However, most of the current mechanical methods for creating, patterning or texturing designs in such textiles as carpets are carried out by hand, which makes them an expensive element in the final cost of the carpet.

One of the objects of this invention is to provide an improved process for styling textile articles. Another object is to provide such a styling rocess which can be performed .as a high-speed, easily controlled and mechanized continuous process. A further object is to provide a process particularly adapted to styling fiber-on-end textiles. Another object is to provide a group of novel pile fabrics, the surface of which exhibit a wide variety of patterned and textured effects. Other objects will be aparent from a further description of the invention given below.

The process of the invention relates to the manfacture of a styled pile fabric by the series of steps including the adherence of a backing to a layer of porous, sel-f supporting material comprising a plurality of contorted filamentary structures. These structures are 80 arranged to be overlapping, aligned in generally the same direction, and interconnected throughout the three dimension of the layer. The layer is further characterized as having a fiber density below 25 lbs/ft. and having at least one substantially planar surfaces defined by filament ends which will be adhered to the backing. According to this process, before adhering the layer to the backing, the layer is provided with a predetermined pattern of non-intersecting, substantialy parallel slits extending throughout a single dimension of the layer to intersect the mentioned planar surface, i.e. that to ultimately be adjacent the backing, at an angle no less than about 50. The resulting patterned material is then stretched in a direction substantially perpendicular to the plane of the slits to provide openings of lower fiber density than the remainder of the structure. In such a stretched condition, the layer is then adhered to the backing to form a unique styled pile fabric. If desired the points of interconnection within the material, where such points are formed by a soluble binder, can be thereafter removed to leave simply points of contact. In any event the resulting product will comprise the hacking and filamentary structures but will be unque because of the non-uniform distortion of the layer. Visually, areas of the layer having slits before the stretching action become a pattern of isolated voluminal sections or openings having an average fiber density less than 50% of the average fiber density of the remaining layer. Moreover the geometrical configuration of the sections will extend throughout a single dimension of the layer to intersect the planar surface adjacent the backing in the manner as did the original slits. Normally these isolated sections will appear substantially in the form of cylinders wherein each of the bases thereof are in the planes of opposite faces of the layer.

The invention is further illustrated in the accompanying drawings in which FIGURE 1 represents a photo- 3 ,293,104 Patented Dec. 20, 1966 ice graph of the pile surface or top view of a typical carpet made in accordance with this invention. represents a schematic diagram of a bonded filamentary block in which a series of slits have been out in the same general direction as the lengths of the filaments. It will be apparent that a corresponding filamentary sheet sliced from such a block and provided with slits would only differ in thickness. FIGURE 3 represents a schematic diagram of the bonded block of FIGURE 2 after one face of the block has been attached to a backing. FIGURE 4 represents an expanded sheet material attached to a backing; such product embracing the case where an expanded sheet has been attached to the backing and also where the material of FIGURE 4 has been sliced transverse to the direction of the filaments.

A suitable method for carrying out the present invention follows. A bonded block of filaments is first prepared by arranging a group of continuous filaments each having a three-dimensional crimp, so that the filaments are aligned generally in the .same direction and are overlapping when they are placed in a mold. A suitable binder is applied to the assembly of filaments while held together in the mold, and the excess binder is then allowed to drain from the mold so that adjacent filaments are bonded together discontinuously by point bonds along their lengths. After setting of the binder and removal of the body from the mold there results a porous selfsuppo-rting block which is composed of an interconnected network of highly crirnped filaments bonded together at isolated points along their lengths. The thickness direction of the block is defined as the direction in which the filaments are aligned. Next the block is sliced transversely to the direction of the filaments to provide a face of cut filament ends. Thereafter a series of small isolated slits are made in the block by inserting a sharp knife at several places in one face of the block and cutting slits, preferably uniplanar, that run the full thickness of the block in generally the same direction as that of the filaments. These slits are made such that the planes thereof are approximately parallel to one another in direction and, in a preferred embodiment, will be substantially at right angles to the two opposite faces of the block. Merely cutting the slits does not, of course affect the fiber density throughout the material. The dimensions of each slit are such that it extends the full thickness of the block in the thickness direction of the slit, but the other two dimensions of the slit are much less than the width and length dimensions of the block. For example, in a block of bonded filaments measuring 24 inches x 24 inches x 24 inches, each slit may be 24 inches in thickness, 2 inches long and Ms inch wide. Next a stretching force is applied to the block in a direction perpendicular to the direction of the filaments and at the same time perpendicular to the plane of the slits. This stretching force enlarges the size of each rectangular slit to an es- .sentialy elliptic cylindrical opening having a major axis 1% inches long and a minor axis inch wide. The stretching force causes the filaments to separate at the openings and provide a larger opening free from filaments than before stretching. A backing layer such as burlap is then coated on one face with a suitable permanent adhesive and the coated face is pressed flat against the bottom face of the block containing the cut filament ends in the face. A cutting blade is then used to make a transverse slice through the block at a distance of /2 inch or so, depending upon the desired pile thickness, from the plane of attachment of one face of the block to the backing to provide a hacked article having a pile layer. Preferably, the binder composition is then removed from the pile layer by washing with a solvent in which the binder is soluble. This results in a pile fabric having a textured or patterned appearance on the FIGURE 2 pile surface. The areas of the stretched openings in the pile layer become areas where virtually no filaments are attached to the backing. After removal of the binder, the free ends of the filaments in the pile layer adjacent to the openings tend to expand into the voids created by the openings which results in areas on the surface of the pile which exhibit lower pile height and reduced fiber density in comparison with the volume of the pile. Desi-r-ably the stretching is effected to such as extent that the elongated dimension is increased in length by at leart 5%. The fiber density of sections defined by the opening may be from 0 to 50% of the remaining fiber density.

7 The pile fiber density or simply fiber density reported in pounds per cubic foot is a measure of the density of the fibers in the pile layer of the backed carpet or other specimen from which layer the binder has been removed, or in other words the density of the shearable fiber above the adhesive line. This pile fiber density is calculated by dividing the effective pile weight of the fibers in the pile layer by the volume of these fibers occupy when the specimen is under a load of 0.1 p.s.i. This volume is determined by multiplying the average width by the average length of the conditioned carpet specimen by the efiective pile height, and then applying suitable conversion factors to obtain the volume in units of cubic feet.

A full description of the filamentary materials employed in accordance with this invention for the production of styled pile fabrics is set forth in C. R. Koller U.S. application Serial No. 787,662, filed January 19, 1959, now U.S. Patent No. 3,085,922. These materials are of a porous character and have a plurality of contorted, e.-g. crimped, filamentary structures which overlap, are aligned generally in the same direction, are interconnected throughout the three dimensions of the material and the material has a fiber density below 25 lbs/ftfi. Although a description of these materials, including definitions of the terms used on connection therewith, is fully set forth in the above Koller application, the disclosure of which is specifically incorporated herein by reference, they will be briefly mentioned herein. By contorted it is meant that the profile (i.e. side elevation) of an individual filament .is irregular (i.e. not straight) when the filament is viewed from at least one side. In addition to being contorted, it is necessary that such filamentary structures overlap adjacent structures throughout the three dimensions of the article. By the term overlap is meant that in at least one view, a filamentary structure crosses over, with or without touching or attachments, an adjacent fila menta-ry structure. Furthermore it is critical to such structures that the contortion and overlapping of the filamentary structures do coact or are allowed to coact with one another. By coact is meant that the contortion and relative placement of the filamentary structures are such that they assist one another in producing and maintaining the claimed structures \both with respect to the general alignment of the filamentary structures and their spacing with respect to each other to achieve the desirable densities contemplated.

The initial filamentary material may be in any of a variety of forms, for example, carded webs of substantially aligned staple fibers or bodies of substantially aligned filamentary structures prepared from a warp of sliver, top, roping, roving, tow, stutter box crimped tow, steam bulked tow, steam crimped continuous filament yarn, gear crimped continuous filament yarn, twist setback twisted continuous filament yarn, knife edge crimped continuous filament yarn, two-component bulky continuous filament yarn, spun yarns, and many others. Any of the above procedures may then be followed to prepare the layer of material tor use in this invention.

In preparaing a block or sheet material of contorted fibers a wide variety of polymeric compositions may be employed. Typical of the fibers and filaments which may be employed are those made of polyamides, such as poly(hexamet-hylene adipamide), poly(meta-phenylene isop'hthalamide), poly(hexamethylene sebacamide, polycaproamide, copolyamide and irradiation grafted polyamides, polyesters and copolyesters such as condensation products of ethylene glycol with terephthalic acid, ethylene glycol with a 90/10 mixture of terephthalic/isophthalic acids, ethylene glycol with a 98/ 2 mixture of terephthalic/S (sodium sulfo) isophthalic acids, and trans-p-hexahydroxylylene glycol with terephthalic acid, self-elongating ethyleneterephthalate polymers, polyacrylonitrile, copolymers of acrylonitrile with other monomers such as vinyl acetate, vinyl chloride, methyl ac-rylate, vinyl pyridine, sodium styrene sulfonate, terpolymers of acrylonitrile/rnethylacrylate/ sodium styrene made in accordance with U.S. Patent 2,837,501, vinyl and vinylidene polymers and copolymers, polycarbonates, polyacetals, polyethers, polyurethanes such as segmented polymers described in U.S. Patents 2,957,852 and 2,929,- 804, p-olyesteramides, polysul-fonarnides, polyethylenes, polypropylenes, fiuorinated and/or chlorinated ethylene polymers and copolymers (e.g., polytetrafiuoroethylene, polytrifiuorochloroethylenes), cellulose derivatives, such as cellulose acetate, cellulose triacetate, composite filaments such as, for example, a sheath of pclyamide around a core of polyester as described in U.S. Patent 3,038,236, and selt-crimped composite filaments, such as two acrylonit-rile polymers differing in ionizable group content cos-pun side by side as described in U.S. Patent 3,038,237, regenerated cellulose, cotton, wool, glass, metal, ceramic and the like- Blends of two or more synthetic or natural fibers may be used, as Well as blends of synthetic and natural. Other fibers such as silk, animal fibers such as mohair, angora, vicuna, are also suitable.

The self-supporting sheet material may be prepared from a wide variety of forms of fibers and filaments, having any of the above mentioned compositions, such as, for example, continuous monofilaments, continuous multifilaments, carded webs, warp, sliver, top, roping, roving, tow, bulked tow, bulked continuous filament yarn, spun yarn, batts, felts, papers and other non-Woven webs, and the like. The fibers and filaments used as raw material may be either crimped or uncrimped, bulked, or onbulked, drawn or undrawn or twisted or untwisted. The denier of the filaments is not critical and may vary from about 0.5 to about 50 denier or even higher.

The use of a binder is preferred to interconnect the filamentary structures at a plurality of points along their length. Depending upon the use desired these may be either soluble or insoluble, and may be either thermoplastic in nature of may be thermosetting for subsequent reaction with a curing agent to form a cured polymer. By binder is meant the additional material used to attach the filaments to each other. Normally these materials will be used in an amount of at least about 0.5% by weight based on the filamentary structures. If it is desired to remove the binder a soluble binder will be employed which may be either organic-soluble or watersoluble. Suitable organic-soluble binders include natural rubber or synthetic elastomers (e.g., chloroprene, butadienestyrene copolymers, butadiene-acrylon-itrile copolymers), which may be used in the form of a latex dispersion or emulsion or in the form of a solution, vinyl acetate polymers and copolymers, acrylic polymers and copolymers such as ethyl acrylate, methyl acrylate, butyl acrylate, methyl methacrylate, acrylic acid/ acrylic and methacrylic ester copolymers, cellulose nitrate, cellulose acetate, cellulose triacetate, polyester resins such as ethylene terephthalate/et hylene isophthalate coplyrners, polyurethanes such as the polymer from pipe-razine and ethylene bis-chloroformate, po'lyamide polymers, and copolymers, methoxy-methyl polyam-ides, vinyl chloride polymers and copolymers such as vinyl chloride/vinylidene chloride c0- polymer lattices. Alcohol soluble polyamide resins are also suitable organic-soluble binders. Suitable watersoluble binders include materials such as polyvinyl alco sulfonate Chol, sodium a'lginate, acrylic acid polymers and copolymers such as polyacrylic acid, carboxyme-thyl cellulose, hydroxyethyl cellulose, dextrins, animal glue, soybean glue and sodium silicate. Suitable binders which are in soluble in organic solvents include polytetrafiuoroet hylene and ureaformaldehyde resin lattices.

Additional suitable binder compositions include chlorosulfonated polyethylene; butyl rubbers, such as isobutylene/isoprene copolymers; polyhydrocarbons, such as polyethylene, polypropylene and the like and copolymers thereof; high molecular weight polyethylene glycols sold under the trade name of Polyox; epoxide resins, such as the diepoxide of bisphenols and glycols; polystyrene, alkyd resins, such as polyesters of glycerol with phthalic or maleic acid; polyester resins such as frompropylene glycol-maleic anhydridestyrene; phenol-formaldehyde resins; resorcinol-formaldehyde resins; polyvinyl acetals, such as polyvinyl butyral and polyvinyl formal; polyvinyl others, such as polyvinyl isobutyl ether; starch, zein, casein, gelatine, methyl cellulose, ethyl cellulose, polyvinyl fluoride, natural gums, polyisobutylene, shellac, terpene resins and rosin soaps. Segmented polymers, such as spandex polymers, polyether amides, poyether urethanes (e.g. those in US. 2,929,800) and polyester urethanes are also suitable.

The adhesives which may be used when applying the backing are varied. By adhesive or glue is meant the material used to cause the filamentary structures and sheet materials to adhere to the backing or is meant the material used to constitute the backing. Illustrative adhesives are: chloroprene rubber, elastomeric foams and sponges, butadiene-styrene rubber, polyvinyl chloride resin (e.g. those in combination with either a polymeric plasticizer or a monomeric plasticizer curable after application of the adhesive), polyurethane resins, polyamide copolyme-r of hexamethylene diamine and adipic and sebacic acids, casein resin, and epoxy resins such as the diepoxide of 2,2-bis(parahydroxyphenyl)propane. Illustrative backings are: woven fabrics such as burlap, canvas, and nylon scrim fabrics, knit fabrics such as nylon tricot, nonwoven fabrics such as polyethylene or polypropylene fiber webs, resin bonded polyethylene terephthalate fiber vwebs, papers of cellulosic and/or synthetic fibers, paper felts such as asphalt impregnated cellulose, elastomeric foams and sponges, plastic films such as from polyethylene terephthalate, polypropylene and polyvinyl chloride polymers, metal, foils and rigid sheets such as fiber glass reinforced polyester resins, metals, ceramics and wood, elastic, stretchable or shrinkable fabrics and films, and the like.

The slits made in the porous self-supporting body of bonded filaments may be accomplished by any suitable means such as a sharp knife or other cutting blade for making a planar cut in the thickness or filament direction of the body without removing an appreciable quantity of filaments from the body. The slits must be isolated in the sense each cannot be connected to the outside face or edge of the body and so that each slit does not intersect another slit in the volume of the body. A plurality of the isolated slits should penetrate the volume thickness of the body in the direction of the filaments from one face to the other. The planes defined by the slits should intersect at an angle no less than about 50 the face which will be attached to the backing. Angles less than 50 would be unsatisfactory for the reason that excessive quantities of filamentary structures would be removed. In addition to the essential isolated slits in the body, there may also be a few small slits made from any of the faces of the body provided that they do not run the full dimension of the body from where they start, but only penetrate into the volume a short distance. The thickness direction of each slit should be at least half the thickness of the body although a plurality of the slits must run the full thickness dimension of the body. The other two dimensions of each slit must be shorter than the width and length of the block, that is, such that the slit does not extend throughout their length. Each slit may be of essentially identical cross-sectional shape or may be of somewhat different dimensions or at slightly different angles. A slit will normally be cut in the thickness direction of the body substantially parallel to the average direction of the filaments running through this thickness dimension, but for some uses it may be made in the thickness direction of the body at a small transverse angle to the average direction of the filaments, for example, up to 40 either side of the average direction of the filaments.

For purposes of practicing the invention, the porous self-supporting body of bonded filaments may be any convenient size depending upon the nature of the final textile article desired. Reference is made herein to the terms body, block and sheet. The term block is usually applied to a body having a relatively large thickness in the direction of the filament length, whereas the term sheet is usually applied to a body having a relatively small thickness in the direction of the filament length. Thin sheets may be sliced from thicker blocks of bonded filaments either before or after the slits are made in the body of bonded filaments. After the body containing enlarged openings has been attached to a backing, the resulting backed textile articles may be employed as such for certain end uses, or it may be desirable to remove a portion or all of the binder from the pile layer. If the binder is removed from the pile layer in the backed article, other materials may be applied to the backed textile article to additionally modify the properties thereof.

The primary advantage of this invention is that it provides a versatile styling technique for making backed textile articles which is uniquely applicable for making pile fabrics by a high-speed, easily controlled, mechanized continuous process. This method of styling provides an economic advantage in styling carpets, since in the present process none of the costly pile fiber need be lost in the process. This feature, it Will be apparent, would not be realized by cutting large openings in a block or sheet material followed by simply removing the severed sections and then adhering to a backing. Another advantage is that the present process provides greater flexibility in styling carpets than former methods available for styling tufted and woven carpets. Hence a wider variety of textured and patterned pile surfaces are made available. In addition, the process provides a method of producing pile fabrics having lower fiber density in the pile, while at the same time retaining the important aesthetics and mechanical properties in the pile fabrics. The invention also provides a method for changing the compressional characteristics of textile articles such as cushions by means of introducing volumes of lower fiber density in the cushion products.

The present invention is useful for preparing a wide variety of textile articles in the form of floor coverings such as carpets and tiles, upholstery fabrics, furs and fleeces, garment interliners. blankets, cushions, mattresses, fibrous laminated structures, sponges, insulating materials, filters for gases, liquids, and solids, and the like.

The following example illustrates a specific embodiment of this invention but is not intended to limit the scope of the invention.

Example The filaments used are a warp of 120 ends of continuous filament polyhexamethylene adipamide yarns (l0l20 denier, 68 filaments, Z twist, having a trilobal cross section). The Wanp is bulked with steam under the conditions disclosed in Example 2 in Table III of Belgian Patent 573,230 and subsequently aligned in the same direction and assembled in a mold 30" x 30" x 12" thick with the fiber ends all directed toward the top and bottom (30" x 30" faces) of the mold. Thereafter the assembly is impregnated with an excess of a 6% solution in an ethanol/Water (/20 by volume) solvent of a soluble terpolymeric binder formed by condensing together capr-olacta-m, hexamethylene diamine, adipic acid and sebaic acid so as to provide substantially equal pro-portions therein of polycaproamide, polyhexamethylene adijamide and polyhexa-methylene sebacam-ide. The excess of the binder solution is drained from the fiber assembly and the assembly is heated to remove the solvent and solidify the binder. The bonded fiber block is removed from the mold and found to hEUVE a fiber density of 4.1 lbs/cu. ft. and a binder content of 4% based on the weight of the fiber. The bonded block is sliced transversely to the filaments in a plane parallel with the top of the block (30" x 30" face) to (give thick porous self-supporting sheets of bonded fibers with the direction of the fibers running from one cut face to the opposite cut face.

One of these thick bonded fiber sheets is cut with a sharp knife at intermittently spaced intervals perpendicular to the cut face of the sheet and parallel to the fiber direction so as to give slits that penetrate the entire thickness of the sheet. The planes of the slits are generally parallel to each other and vary in length from about A" .to 3". The slits are spaced from /2" to 2" apart and in a nonregular pattern. The slit sheet is stretched about in a direction perpendicular to the length of the slits so as to expand the width of the slits and, while in this expanded state, one of the faces of the sheet consisting of cut fiber ends is embedded in a layer of rubber adhesive coated onto one face of burlap fabric. The adhesive is allowed to set by drying and there is obtained a hacked pile fiber article with the fibers strongly bonded to the backing.

The pile fiber surface of this backed article is washed with ethanol/Water (80/20 by vol.) to remove the terpolymer binder. There is obtained a soft a soft pile fabric suitable for use as :a canpct. The areas corresponding to the slits in the sheet had no pile fiber attached to the backing. Pile fiber from adjacent areas partially expanded into the areas of the slits, which resulted in a low pile density and a low pile height in these regions. This gave an attractive pile-textured carpet having a high-low pile effect.

What is claimed is:

1. In a process for the manufacture of a pile fabric whereby a backing is adhered to a layer of a porous, selfswpporting material comprising a plurality of contorted filamentary structures which are overlapping and are aligned in generally the same direction, said filamentary structures being interconnected throughout the three dimensions of said material, said material having a fiber density below lbs/ft. and having adjacent the backing a substantially planar surface defined by filament ends, the improvement wherein said layer before adherence to said backing is provided with a predetermined pattern of non-intersecting, substantially parallel slits extending throughout a single dimension of said layer to intersect said planar surface at an angle no less than about 50,

and subsequently stretching the resulting patterned material in a direction substantially perpendicular to the plane of said slits to provide openings of lower fiber density.

2. The process of claim 1 wherein said slits are substantially parallel to the direction of fiber alignment and both are at approximate right angles to the said planar surface.

3. The process of claim 1 wherein said filamentary structures are interconnected by means of a binder composition.

4. The process of claim 3 wherein the binder composition is at least about 0.5% based on the weight of filamentary structures.

5. The process of claim 3 wherein the binder composition is removed after adherence of the layer to the backmg.

6. The process of claim 1 wherein the said layer adhered to said backing is subsequently sliced transverse to the direction of filament alignment to provide a backed pile of desired height.

7. The method of claim 1 where-in the slits are uni planar and act to sever the filamentary structures intersected thereby without their removal.

8. A styled pile fabric comprising a non-slit backing having attached to at least one surface thereof a face of a porous self-supporting layer having at least two faces, each being defined by the ends of a plurality of random contorted filamentary structures, said filamentary structures overlapping and being aligned generally in the same direction, the said filamentary structures forming a pile having a fiber density below 25 lbs./ft. said pile constituting a network wherein at least a major proportion of the filamentary structures con-tact each other throughout the three dimensions of the pile, said layer having a predetermined pattern of isolated v-oluminal sections having an average fiber density less than 50% of said layer, the geometrical configuration of said sections extending throughout a single dimension of said layer and intersecting said planar surface.

9. The styled pile fabric of claim 8 wherein said isolated sections are substantially in the form of eliptic cylinders wherein each of the bases thereof are in the .planes of opposite faces of the said layer.

10. The styled pile fabric of claim 8 wherein said filamentary structures are interconnected by means of a binder composition.

11. The styled pile [fabric of claim 10 wherein the binder composition is at least about 0.5% based on the weight of the filamentary structures.

References Cited by the Examiner UNITED STATES PATENTS 7/1933 Mickelson l56-163 X 4/1960 Mcsscrli l6 l62

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Referenced by
Citing PatentFiling datePublication dateApplicantTitle
US3632466 *Oct 19, 1966Jan 4, 1972Uniroyal IncStabilized latex coating composition containing an alkyl sulfide terminated oligomer
US3655501 *Mar 26, 1969Apr 11, 1972Guenther Horst TeschFlexible materials
US4279954 *Dec 6, 1979Jul 21, 1981Forbo Betriebs AgWeb with relief-structured surface and method of making the same
US4412877 *Apr 21, 1982Nov 1, 1983E. I. Du Pont De Nemours & Co.Embossing secondary backings of carpets
US4608292 *Oct 17, 1983Aug 26, 1986Kimberly-Clark CorporationWeb with enhanced fluid transfer properties and method of making same
US4701237 *Jun 5, 1986Oct 20, 1987Kimberly-Clark CorporationWeb with enhanced fluid transfer properties and method of making same
US4837066 *May 29, 1986Jun 6, 1989Gates Formed-Fibre Products, Inc.Foldable rigidified textile panels
US5403640 *Aug 27, 1993Apr 4, 1995Reichhold Chemicals, Inc.Textile coating and method of using the same
US6420625Sep 12, 1997Jul 16, 2002Kimberly-Clark Worldwide, Inc.Breathable, liquid-impermeable, apertured film/nonwoven laminate and process for making same
US7964049Jul 26, 2007Jun 21, 2011E. I. Du Pont De Nemours And CompanyProcesses for making fiber-on-end materials
US20080023015 *Jul 26, 2007Jan 31, 2008E. I. Dupont De Nemours And CompanyProcesses for making fiber-on-end materials
US20080023125 *Jul 26, 2007Jan 31, 2008E. I. Dupont De Nemours And CompanyProcesses for making fiber-on-end materials
US20080268309 *Apr 16, 2008Oct 30, 2008Toyota Jidosha Kabushiki KaishaReformer and fuel cell system incorporating the same
DE19581616B4 *May 18, 1995Feb 22, 2007Kimberly-Clark Worldwide, Inc., NeenahPerforierte, gebundene Vliesbahn, sowie Verfahren zur Herstellung einer perforierten, gebundenen Vliesbahn
U.S. Classification428/95, 428/138, 428/155, 156/257, 156/229, 428/97, 156/163, 428/136
International ClassificationD04H11/00
Cooperative ClassificationD04H11/00
European ClassificationD04H11/00