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Publication numberUS3400762 A
Publication typeGrant
Publication dateSep 10, 1968
Filing dateJul 8, 1966
Priority dateJul 8, 1966
Publication numberUS 3400762 A, US 3400762A, US-A-3400762, US3400762 A, US3400762A
InventorsNeedham Riley B, Peacock Dixon W
Original AssigneePhillips Petroleum Co
Export CitationBiBTeX, EndNote, RefMan
External Links: USPTO, USPTO Assignment, Espacenet
In situ thermal recovery of oil from an oil shale
US 3400762 A
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Description  (OCR text may contain errors)

Sw 1 1958 D.w. PEACOCK ETAL; 7 3,400,762 I SITU THERMAL RECOVERY OF OIL FROM AN OIL SHALE FRACTUR'NG filed July 8 l 6 FRACTURING V PRESSRE PRESSURE /L '6' OVERBURDEN 2m FRACTURES PRoPPEo/fl J AM I PRODUCTION E TO CONDENSER PROPPED FRACTURES/7 q Kf q M PYROLYSIS ZONE 'SATURATED kSTEAM STEAM ZONE PLUS H2O H "FRACIURES on. FLOW THROUGH eobodo ooaooo J INVENTORS PYROLYSIS DUE TO BUgNlgGa DML PEACQCK i v as. NEEDHAM I f ATTORNEYS as 42 FIG. 2 Y Y a I l.

3 7 NR PRODUCTION 4o 44 L I ABSTRACT OF THE DISCLOSURE An oil shale formation penetrated by an injection well and a production well is fractured from one well to the other. A portion of the fractured formation extending part of the way between the wells is subjected to superheated steam, and oil is recovered through the production well. The steamed portion of the formation is then subjected to in situ combustion to produce additional oil in the production well. The. steaming and. combustion of steamed portions are alternately continued until the combustion front reaches the production well.

This invention relates to a process for producing oil from an oil shale.

- Large deposits of oil in the form of oil shale are found in various sections of the United States and, particularly.

in Colorado and surrounding states. Various methods of recovery'of'oil from these shale deposits have been proposed andthe principal ditiiculty with these methods is ihe high cost which renders the recovered oil too expen sive to compete with petroleum crudes recovered by more conventional methods. The in situ retorting of oil shale to recover the oil contained therein is made diificult because of the nonpermeable nature of the oil shale and the difficulty of applying heat thereto without extensive mining or drilling operations. The mining and removal of the oil shale for retorting of the shale in furnaces outside the formation is commercially uneconomical in most cases.= I I This invention is concerned with a process for the therma! recovery of oil from shale in situ which avoids mining and removal of the oil shale for retorting.

Accordingly, it is an object of the invention to provide a process for the thermal in situ production of oil from an immrmeable oil shale. Another object is to provide a iijiliifiil rates Fatent G Patented Sept. 10, 1968 jection steps either by injecting a propping agent into the process for'the production of oil from oil shale by in situ I heating which avoids mining of the shale and retorting of same above ground. Other objects of the invention will become apparent to one skilled in the art upon consideration of the accompanying disclosure.

. A broad aspect of the invention comprises fracturing an oil shale by conventional fracturing techniques between an injection well and a production well penetrating the shale stratum, preferably, at several different levels therein and holding the fracture(s) open; injecting superheated steam into the fractures of the stratum thru the injection well so as to heat the stratum and establish a thermal front therein; after a substantial sectionof the stratum has been heated and oil driven therefrom thru the fractures into the production well, terminating steam injection and injecting combustion-supporting, (Il -containing gas into the stratum (fractures) thru the injection well so as to initiate a direct drive in situ combustion operation thru the section of stratum heated by the steam;

and repeating the stream injection and gas injection steps sequentially, the produced oil and gas from the steam and fractures during or after the fracturing operation or by maintaining suflicient gas pressure in the stratum during the injection steps to hold the fractures open.

In order to efficiently heat the stratum during steam injection, it is preferred to operate with steam at a temperature of at least 800 F., and more desirably, 1000 F. The steam injection phase or step of the operation heats and fluidizes the kerogen or solid oil in the oil shale, rendering the same readily flowable as liquid and vapor. Steam injection is continued for a period ranging from" several weeks to several months so as to heat a substantial section of the oil shale extending in the range of 5 to 25 feet or more into the stratum from the injection well and the oil thermally produced from the shale is driven thru the fractures into the production well from which it is readily produced by pumping or in other conventional manner.

Air is the preferred combustion-supporting gas because of its ready availability and low cost but oxygen-enriched air may be utilized. Upon contacting the hot oil shale with air, combustion is initiated which adds additional.

pyrolysis zone formed during the steam injectionstep,

air injection. is terminated and steam injection isfagain resumed. After another substantial steam injection period, this step is terminated and air is again injected thru the injection well into the expanded pyrolysis zone for further combustion of residual coke and hydrocarbon material therein. The alternate movement of the pyrolysis zone by steam and combustion greatly increases the recovery of shale oil compared to either method alone and more rapidly opens up the entire shale stratum to gas flow, rendering the stratum more permeable.

A more complete understanding of the invention may be had by reference to the accompanying schematic draw ing of which FIGURE 1 is an elevation thru a stratum penetrated by an injection well and a production well, illustrating the fracturing and propping phase of the operation; FIGURE 2 is a similar view illustratingthe conditions in the stratum after a substantial steam injection period; and FIGURE 3 is a similar view illustrating the combustion phase of the operation.

Referring to FIGURE 1, an oil stratum 10 is penetrated by an injection well 12 and a production well 14. Tubing string 16 in injection well 12 extends to a lower section of stratum l0 and forms an annulus 18 with the wall of the well or casing 20. A packer 22 packs off the annulus at the approximate top level of the shale stratum. A similar arrangement in well 14 includes a tubing 24, a casing 26, and a packer 28. Fracturing fluid is applied thru tubing 16 and tubing 24, if desired, so as to build up sufficient fracturing pressure to produce fractures at selected levels, such as 30, 32, 34, and 36. If the fracturcs are to be propped, the propping agent in the form of hard, rugged, particulate material is injected with either the fracturing fluid near the end of the fracturing operation or after fracturing has been effected. The fracturing and propping operation is a conventional operation that needs no further discussion.

Casing strings 20 and 26 may be cemented in at the top of the stratum or they may extend to the bottom, in which case they are perforated at selected levels therein coinciding with the fracturing levels (and at intermediate levels, if desired). I

Referring lu FHlURH 2, a steam generator 38 provides steam from a source of water not shown and the steam passes thru line 40 to a steam supcrheutcr 42 for healing to the desired temperature. The superheated steam is injected thru line linlo tubing 16 from which it passes to the well below packer 22 tmdcnters fractures 30, 32,

34, and 36, which are either held open by propping material or by steam injection pressure by regulating the back pressure on well 14. After an extended steam injection period, a saturated steam zone exists between dotted line 46 and 48 with a steam plus condensate (H O) occupying a substantial zone between lines 48 and 5t The pyrolysis zone extends from the wall of well 12 to line 50 at the end of a substantial steaming period. The zone between the wellbore and line 46 contains superheated 'steam. The steam injection phase of the operation proit-invades the stratum via the wellbore and the several fractures in the stratum. Up'on contacting the hot stratum containing the superheated steam adjacentwelllZ, the residual coke and/or shale oil is ignited to establish a combustion front which moves slowly away from the injection well as air injection is continued-Acombustion catalyst may be utilized, if desired.

The combustion phase of the operation not only consumes aportion of the coke and oil as fuel but also fiuidizes additional kerogen and semi-solid hydrocarbon material to drive additional shale oil from the stratum,

and it also imparts additional heat to the stratum and expands the pyrolysis zone as illustrated at line 5'4. During the combustion step, the additional produced oil is recovered thru tubing string 24 as before. The combustion step and the expansion of the pyrolysis zone opens up additional stratum for passage of gas (steam, air, and/or combustion gases), materially increasing the permeability I of the stratum adjacent the fractures. By repeating the steam injection'and combustion steps, the' stratum is opened up completely between the fractures so that sub-' staniially all of the oil in the shale is produced and production is continued. until the pyrolysis zone is extended completely to the production well and until further injec: tion of steam and air fails to result in economic produc tion of oil.

' Certain modifications of the invention will become apparent to those, skilledinthe art and the illustrative details disclosed are notto' be construed as imposing unnecessary limitations on the invention.

We claim: 1. A process for producmg oil from an oil shale stratum penetrated by an injection well and a production well,

which comprises the-steps of:- 7

4 (n) fracturing said stratum from one well to the other and holding resulting fracture) open during the following steps; (b) injecting superheated steam at a temperature of at least 800 F. thru said injection well into said stratum thru said fractureht) so as to heat a substantial sec-- tion of said stratum extending from said injection well part of the distance to said production'well and produce oi] therefrom thru said fracture(s) and thru said production well;

(c) terminating steam injection of step (b) and injecting a combustion-supporting, -containinggas into said stratum thru said injection well so as to initiate and maintain a direct drive in situ combustion front thru the hotresidual hydrocarbon and coke in th section of stratum heated in step (b);

(d) recovering thru said production well oil produce in step (c);

(e) when the combustion front of step (c) has been driven thru a substantial portion of the section of stratum heated in step (b) terminating the injection of said combustion-supporting, o -containing gas;

and

(f) repeating steps (b), (c), (d) and (e) a plurality of times to alternately establish a new steam heated portion of said stratum-extending an additional portion of the distance between said injection well and production well and then establish and maintain an in situ combustion front in said new steam heated portion of said stratum until the in situ combustion front has been driven thru asubstantial portionof said new steam heated portion, until the in situ com-- bustion front reaches completely to said production well. 2. The process of claim 1 wherein said stratum is fractured at several different levels in step (a). p

3. The process of claim 1 wherein solid particulate propping agent is injected into the fracture(s) to hold same open. r

4. The process of claim 1 wherein said fractures are held open during injection in steps (b) and (c). by pres: sure of the injected gas. 5.; The process of claim 1 wherein said gas is air..

' References Cited UNITED STATES PATENTS --2,780,449 2/1957 Fisher et al. 166-11 2,813,583 11/1957 Marx an. 166-11 3,149,670 9/l964 Grant 166-11 3,221,813 12/1965 -Closrnann et al. 166ll 3,284,281 11/1966 Thomas ....-L 166 2 3,342,258 9/1967 Prats 166-ll STEPHEN .l. NovosAnPrimr Examiner.

Patent Citations
Cited PatentFiling datePublication dateApplicantTitle
US2780449 *Dec 26, 1952Feb 5, 1957Sinclair Oil & Gas CoThermal process for in-situ decomposition of oil shale
US2813583 *Dec 6, 1954Nov 19, 1957Phillips Petroleum CoProcess for recovery of petroleum from sands and shale
US3149670 *Mar 27, 1962Sep 22, 1964Smclair Res IncIn-situ heating process
US3221813 *Aug 12, 1963Dec 7, 1965Shell Oil CoRecovery of viscous petroleum materials
US3284281 *Aug 31, 1964Nov 8, 1966Phillips Petroleum CoProduction of oil from oil shale through fractures
US3342258 *Mar 6, 1964Sep 19, 1967Shell Oil CoUnderground oil recovery from solid oil-bearing deposits
Referenced by
Citing PatentFiling datePublication dateApplicantTitle
US3468376 *Feb 10, 1967Sep 23, 1969Mobil Oil CorpThermal conversion of oil shale into recoverable hydrocarbons
US3596993 *Feb 14, 1969Aug 3, 1971Mc Donnell Douglas CorpMethod of extracting oil and by-products from oil shale
US3978925 *Jun 21, 1974Sep 7, 1976Texaco Exploration Canada Ltd.Method for recovery of bitumens from tar sands
US4006778 *Jun 21, 1974Feb 8, 1977Texaco Exploration Canada Ltd.Thermal recovery of hydrocarbon from tar sands
US4036299 *Sep 22, 1975Jul 19, 1977Occidental Oil Shale, Inc.Enriching off gas from oil shale retort
US4061190 *Jan 28, 1977Dec 6, 1977The United States Of America As Represented By The United States National Aeronautics And Space AdministrationIn-situ laser retorting of oil shale
US4089375 *May 13, 1977May 16, 1978Occidental Oil Shale, Inc.In situ retorting with water vaporized in situ
US4105072 *Jan 27, 1977Aug 8, 1978Occidental Oil ShaleProcess for recovering carbonaceous values from post in situ oil shale retorting
US4148359 *Jan 30, 1978Apr 10, 1979Shell Oil CompanyPressure-balanced oil recovery process for water productive oil shale
US4200152 *Jan 12, 1979Apr 29, 1980Foster John WMethod for enhancing simultaneous fracturing in the creation of a geothermal reservoir
US4263970 *Jul 31, 1978Apr 28, 1981Occidental Oil Shale, Inc.Introducing an oxidizing gas
US4408665 *Oct 2, 1978Oct 11, 1983Equity Oil CompanyIn situ recovery of oil and gas from water-flooded oil shale formations
US4458757 *Apr 25, 1983Jul 10, 1984Exxon Research And Engineering Co.In situ shale-oil recovery process
US4484630 *Mar 8, 1983Nov 27, 1984Mobil Oil CorporationMethod for recovering heavy crudes from shallow reservoirs
US4687058 *May 22, 1986Aug 18, 1987Conoco Inc.Solvent enhanced fracture-assisted steamflood process
US4860827 *Jan 11, 1988Aug 29, 1989Canadian Liquid Air, Ltd.Process and device for oil recovery using steam and oxygen-containing gas
US4892147 *Dec 28, 1987Jan 9, 1990Mobil Oil CorporationHydraulic fracturing utilizing a refractory proppant
US7441603Jul 30, 2004Oct 28, 2008Exxonmobil Upstream Research CompanyHydrocarbon recovery from impermeable oil shales
US7516785Oct 10, 2007Apr 14, 2009Exxonmobil Upstream Research CompanyMethod of developing subsurface freeze zone
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US7631691Jan 25, 2008Dec 15, 2009Exxonmobil Upstream Research CompanyMethods of treating a subterranean formation to convert organic matter into producible hydrocarbons
US7647971Dec 23, 2008Jan 19, 2010Exxonmobil Upstream Research CompanyMethod of developing subsurface freeze zone
US7647972Dec 23, 2008Jan 19, 2010Exxonmobil Upstream Research CompanyFracturing fluid is injected into well to form fracture at depth of subsurface formation, providing fluid communication between first and second depths in well; cooling fluid is circulated under pressure through well into fracture to cause fluid to flow into subsurface formations, lowering temperature
US7669657Oct 10, 2007Mar 2, 2010Exxonmobil Upstream Research CompanyEnhanced shale oil production by in situ heating using hydraulically fractured producing wells
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Classifications
U.S. Classification166/258, 166/269, 166/259, 166/271, 166/272.3
International ClassificationE21B43/16, E21B43/247
Cooperative ClassificationE21B43/247
European ClassificationE21B43/247