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Publication numberUS3448034 A
Publication typeGrant
Publication dateJun 3, 1969
Filing dateAug 24, 1966
Priority dateAug 24, 1966
Publication numberUS 3448034 A, US 3448034A, US-A-3448034, US3448034 A, US3448034A
InventorsFrank E Calvery, Leonard F Craft
Original AssigneeFrank E Calvery, Leonard F Craft
Export CitationBiBTeX, EndNote, RefMan
External Links: USPTO, USPTO Assignment, Espacenet
Fluid stabilizer
US 3448034 A
Abstract  available in
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Claims  available in
Description  (OCR text may contain errors)

L.F.CRAFT ETAL FLUID STABILI ZER Filed Aug. 24. 1966 Figz INVENTORS Croft Frank E. Colvery Leonard F.

ATTORNEY United States Patent O 3,448,034 FLUID STABILIZER Leonard F. Craft, Box 96, Andrews, Tex. 79714, and Frank E. Calvery, Box 25, Florey, Tex. 79732 Filed Aug. 24, 1966, Ser. No. 574,665 Int. Cl. C23f .I3/00 U.S. Cl. 204-197 3 Claims ABSTRACT F THE DISCLOSURE This invention relates to apparatus for stabilizing liquids, such as produced from oil and water wells, or other types of ilow tubes, as in steam boilers, and the like, to prevent precipitation of solids contained in the liquids such as calcium sulphate, sodium salts, iron oxide, and other minerals which tend to be deposited as scale to clog and corrode the flow tubes.

In the production of oil the well fluids often contain substantial quantities of corrosive elements which have a destructive effect on the tubing, pump rods, and other equipment in the well. The accumulation of parafn is detrimental to eicient operation of the pumping equipment and presents the problem of shutting down the production while the operation of removing the parain buildup is completed, resulting in loss of production, labor costs, and other expense.

The production and flow of water wells, and the distribution of water therefrom often presents similar problems, especially when the water is laden with undesirable substances, such as calcium sulphate, sodium salts, iron oxide, and other destructive minerals which are injurious to the flow tubes and pumping equipment. In both oil and water wells there exists minerals which are detrimental to the economical production and handling of the liquids which, if retained in suspension, could not precipitate and adhere to the contacted surfaces of the ow lines through which the liquids are passed or the containers into which they are deposited.

While a major problem in the production of oil is the accumulation of parain in the flow tubes in the wells, as Vwell as other corrosive substances, water production and distribution also presents problems. Minerals having a variety of characteristics are present in varying quantities to effect depositions of solids in the flow lines, and even destroy them. Calcium sulphate, sodium salts, iron oxide, and the like, being the prime offenders. This factor is particularly detrimental to steam boilers such as those used in laundries and cleaning establishments.

The phenomena which encompasses the invention is not wholly understood but extensive experimentation and tests have definitely proved its utility and effectiveness. Other apparatus have been devised for a like purpose, such as elements composed of copper and zinc, or compositions of so-called dissimilar metals, but such devices have not been proved to be effective for any appreciable periods due to the self-sacrificing character of the elements used. For example, zinc alone, or zinc with copper, will dissipate in relatively short periods and cannot withstand the eroding action of some of the elements suspended in most liquids.

It is important that the metals employed in the composition of the stabilizing element of the invention be of ice a crystalline structure and have non-conductive characteristics, or at least possess low conductivity to afford the best output of the desired energy and insure against electrolysis in the iiow tube, and the rod string, when the latter is used. A constant movement of the liquid in contact with the stabilizing element will produce the best results, and the more rapid the movement less precipitation of the solids in the liquids will occur.

It is also important that the stabilizing element be insulated from outside contacts, such as soil or other inuences, which could affect its potentials. `It will become apparent that the element is in direct contact, when unitized, with its casing and the entire unit should be out of contact with surrounding metal or soil.

A primary object of the invention is that of providing a metallic rod or core adapted to be enclosed within a flow tube through which liquids can be passed while flowing from a well, or a supply line, and composed of a plurality of crystalline nonferrous metals having a polarizing effect on the liquids to eliminate any ainity between the mineral substances therein and the metallic flow tubes or pump rods through and about which the liquids are caused to flow and thus prevention of precipitation of such minerals in solid form from being deposited on the tubing walls and other surfaces is made possible.

Another object of the invention resides in theprovision of a device by which electrolysis in flow tubes, and other equipment exposed to the liquids, can be minimized or completely eliminated to prevent deterioration of such equipment.

Broadly, the invention seeks to comprehend the provision of apparatus by which the solid substances in liquids, such as oil and water, can be stabilized and maintained in a fluid state at all times, and whereby such substances cannot separate and form undesirable deposits and encrustations in the ow tubes and on other contacted surfaces.

While the foregoing objects are paramount, other and lesser objects will become apparent as the description proceeds, when vconsidered in connection with the appended drawings.

FIGURE l is a longitudinal sectional view of the invention installed in a well bore, the well casing, perforated tail pipe and part of the tubing being shown in section.

FIGURE 2 is a longitudinal sectional view of the invention, on an enlarged scale, showing the poly-metallic rod or core partially in elevation.

FIGURE 3 is a top plan View of the invention.

FIGURE 4 is a transverse sectional view, on line 4-4 of FIGURE 2.

FIGURE 5 is an inverted plan view of the invention, and

FIGURE 6 is a fragmentary perspective View of the rod or core element.

The invention primarily consists of a rod or coremember 10 which is composed of a plurality of crystalline metals, the preferred composition being substantially as follows:

Percent by weight Other elements may obviously be substituted for those enumerated with satisfactory results although exhaustive experimentation has proved that the foregoing formula will accomplish the purpose of the invention and provide the necessary elements to carry out its intent. The percentages, of necessity, are approximated since close tolerances are not critical.

The rod or core is preferably cast in any desired lengths, depending upon the use to which it is applied. When installed in an oil well, for example, the length of the rod or core 10 would depend upon the lift, or the depth of the well. Lengths of the element 10 may be from four to eight feet, or a plurality of shorter lengths may be installed. In common flow lines in distribution systems shorter lengths may be employed.

The member 10 has planar sides 11 and is arcuate at each opposing edge 12, as shown in FIGURES 4 and 6, having its ends chamfered at 13 and 14 to form a peak 15 parallel and intermediate its sides 11. The core 10 is concentrically encased within a tube 16 and impinged at its lower end by an internally threaded sleeve 17 which is concentrically received in the lower end of the tube 16 and integrated circumferentially therewith by a weld 18, as shown in FIGURE 2. The upper end of the core 10 is engaged by a nipple 19, concentrically inserted into the tube 16 and secured by a weld 20. The nipple 19 has external threads 21 at its upper end.

The assembled unit 22, as shown in FIGURE 2, when installed in an oil or water well, is threaded into the lower end of a standing valve 23, or a traveling valve (not shown), as illustrated in FIGURE 1. The installation shown in FIGURE 1 is merely typical and includes a seating nipple 24 connected to the lower end of the flow tube 25. The unit 22 is enclosed within a perforated tube 26 having a bull plug 27 threaded into its lowermost end. Fluid from the producing formation 28 flows into the tube 26 through the perforations therein and up through the tube 16 and the passages 29 therein on each planar side 11 of the core 10 and out through the iiow tube past the standing valve 23, or other device, and thence to the surface.

The unit 22 may be installed ina iiow line of a distribution system for oil or water in a horizontal position. Ample ow passages 29 are provided in any position of the device. The chamfered surfaces 13 and 14 provide for an unirnpeded ilow at each end of the element 10, as best shown in FIGURE 2. A strainer (not shown) may be threaded into the internally threaded sleeve 17.

Cil

The invention as described is obviously capable of certain changes and modifications, by persons skilled in the art, without departing from the spirit and intent thereof or from the scope of the appended claims.

What is claimed is:

1. Apparatus for stabilizing fluids for connection in a flow line, comprising: a rod composed of approximately 58% copper; 17% zinc; 14% nickel; 7% lead; 3% tin; .69% iron; .12% antimony; .07% sulphur, and .05% manganese, and a cylindrical casing circumferentially surrounding said rod with said rod having surfaces engaging the inner walls thereof and having other surfaces exposed to said iluids in the passage thereof through said casing and capable of polarizing said fluids.

2. A uid stabilizer as described in claim 1, the said rod containing about 58% copper, 31% comprised of substantially equal quantities of zinc and nickel; 7% lead and 3% tin, and about 1% of a mixture of iron, antimony, sulphur and manganese.

3. A uid stabilizer for connection in a flow channel comprising: a metal rod composed of about 5 8% copper; 17% zinc; 14% nickel; 7% lead; 3% tin, and about 1% of a mixture comprised of iron, antimony, sulphur and manganese, a casing embracing said rod and having means for connection in a flow channel, the said rod having at least two surfaces engaging the inner walls of said casing, and other surfaces spaced from said walls and exposed to iiuids passing through said casing.

References Cited UNITED STATES PATENTS 851,159 4/1907 Case 252-81 1,608,709 11/1926 Mills 204-149 2,392,033 1/1946 Eaton 204-197 2,401,546 6/1946 Brown 204-197 2,805,988 9/1957 Rader 204-197 X 2,829,099 4/1958 Marsh 204-197 2,846,385 8/1958 Buchan 204-197 X 3,137,642 6/1964 Johns 204-148 MICHAEL E. ROGERS, Primary Examiner.

U.S. Cl. X.R.

Patent Citations
Cited PatentFiling datePublication dateApplicantTitle
US851159 *Jan 24, 1907Apr 23, 1907George W CaseCompound for the removal of boiler-scales.
US1608709 *Sep 10, 1924Nov 30, 1926Peter Q NyceMethod of and means for preventing corrosion of well tubing, casing, and working barrels
US2392033 *Nov 1, 1941Jan 1, 1946Bethlehem Steel CorpSucker rod coupling with zinc inserts
US2401546 *Nov 20, 1942Jun 4, 1946Brown Ual JScale remover and scale and corrosion preventer
US2805988 *Jan 11, 1954Sep 10, 1957Rader Clarence MElectrolytic liquid treating device
US2829099 *Dec 29, 1954Apr 1, 1958Pure Oil CoMitigating corrosion in oil well casing
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US3137642 *Apr 13, 1960Jun 16, 1964Winthrop A JohnsMethod and means for protecting structures, machinery containers, etc. made of steel, copper, brass, bronze or similar materials against corrosion
Referenced by
Citing PatentFiling datePublication dateApplicantTitle
US3919068 *May 31, 1974Nov 11, 1975Wildon A GarySystem stabilizer
US3974071 *Feb 26, 1975Aug 10, 1976Marlan CompanyWater conditioning device
US4606828 *Feb 26, 1985Aug 19, 1986Wells Marvin EScale formation preventor and/or remover
US4713159 *May 7, 1986Dec 15, 1987Fluid MechanicsCompact and cleanable apparatus for preventing scale formation in liquid systems
US4715325 *Jun 19, 1986Dec 29, 1987Walker Claud WPollution control through fuel treatment
US4789031 *May 22, 1987Dec 6, 1988Walker Claud WGas anchor and treating device
US4820422 *May 4, 1988Apr 11, 1989Envirecon Services LimitedMethod for countering scale formation in fluid conduits
US4933089 *Feb 16, 1988Jun 12, 1990Newton George DApparatus and process for paraffin abatement
US5006214 *Feb 5, 1990Apr 9, 1991Burchnell Donald HCathodic protection apparatus
US5059217 *Oct 10, 1990Oct 22, 1991Arroyo Melvin LFluid treating device
US5197446 *Mar 26, 1991Mar 30, 1993Daywalt Clark LVapor pressure enhancer and method
US5204006 *Feb 18, 1992Apr 20, 1993Santoli Joseph PIn-line static water conditioner and method for inhibiting scale formation
US5258108 *Dec 27, 1991Nov 2, 1993Blue Star Technologies, Ltd.Fluid-treatment and conditioning apparatus and method
US5368705 *Nov 1, 1993Nov 29, 1994Blue Star Technologies, Ltd.Fuel treatment and conditioning apparatus
US5451273 *Dec 21, 1994Sep 19, 1995Hydro-Petro Technology, Inc.Cast alloy article and method of making and fuel filter
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US5665221 *Dec 3, 1996Sep 9, 1997A Rx Technologies Inc.Electrical apparatus for controlling liquid contaminants
US6955746Nov 27, 2002Oct 18, 2005Jim YuleCorrosion-inhibited system and method for providing a utility service to a plurality of consumers
US6989095Jul 15, 2004Jan 24, 2006Corrosion Inhibitor Systems, LlcFluid conditioner for reducing scale, corrosion and paraffin buildup in hydrocarbon piping
US7481922Jan 5, 2005Jan 27, 2009Edward Horton MaddenFluid treatment apparatus
US20040099539 *Nov 27, 2002May 27, 2004Jim YuleCorrosion-inhibited system and method for providing a utility service to a plurality of consumers
US20050040112 *Jul 15, 2004Feb 24, 2005Melton Linda K.Method and apparatus for reducing scale, corrosion, and paraffin buildup in hydrocarbon piping
US20060144795 *Jan 5, 2005Jul 6, 2006Madden Edward HFluid treatment method and apparatus
DE3602333A1 *Jan 27, 1986Aug 14, 1986Envirecon Serv LtdVorrichtung, die der bildung von ablagerungen in einem stroemungsmittelsystem entgegenwirkt
EP0399658A2 *Apr 24, 1990Nov 28, 1990Luis GomezPurification of fluids
WO1992017699A1 *Mar 26, 1992Oct 15, 1992Daywalt Clark LVapor pressure enhancer and method
Classifications
U.S. Classification204/196.15, 422/240, 210/696, 166/304, 23/301, 204/293, 204/196.22, 204/248
International ClassificationC22C9/04, C02F1/48, C22C9/06, E21B41/02
Cooperative ClassificationC22C9/06, E21B41/02, C22C9/04
European ClassificationC22C9/06, C22C9/04, E21B41/02
Legal Events
DateCodeEventDescription
Feb 1, 1985AS02Assignment of assignor's interest
Owner name: CRAFT,MERLE R.
Owner name: HYDRO-PETRO TECHNOLOGY,INC. A COLORADO CORP.
Effective date: 19841210
Feb 1, 1985ASAssignment
Owner name: HYDRO-PETRO TECHNOLOGY,INC. A COLORADO CORP.
Free format text: ASSIGNMENT OF ASSIGNORS INTEREST.;ASSIGNOR:CRAFT,MERLE R.;REEL/FRAME:004356/0882
Effective date: 19841210
Dec 31, 1984AS02Assignment of assignor's interest
Owner name: FLUID MECHANICS, INC. LAFAYETTE, IN A CORP. OF IN
Effective date: 19841112
Owner name: M. & C. DISTRIBUTING COMPANY, INC.
Dec 31, 1984ASAssignment
Owner name: FLUID MECHANICS, INC. LAFAYETTE, IN A CORP. OF IN
Free format text: ASSIGNMENT OF ASSIGNORS INTEREST.;ASSIGNOR:M. & C. DISTRIBUTING COMPANY, INC.;REEL/FRAME:004346/0065
Effective date: 19841112
Jun 13, 1984ASAssignment
Owner name: M. & C. DISTRIBUTING COMPANY, INC., LAFAYETTE, IN
Free format text: ASSIGNMENT OF ASSIGNORS INTEREST.;ASSIGNORS:CRAFT, LEONARD F.;CALVERY, FRANK E.;REEL/FRAME:004279/0032
Effective date: 19750304
Jun 13, 1984AS02Assignment of assignor's interest
Owner name: CALVERY, FRANK E.
Effective date: 19750304
Owner name: CRAFT, LEONARD F.
Owner name: M. & C. DISTRIBUTING COMPANY, INC., LAFAYETTE, IN