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Publication numberUS3468744 A
Publication typeGrant
Publication dateSep 23, 1969
Filing dateAug 13, 1964
Priority dateAug 13, 1964
Also published asDE1569197A1
Publication numberUS 3468744 A, US 3468744A, US-A-3468744, US3468744 A, US3468744A
InventorsThomas J Reinhart
Original AssigneeMinnesota Mining & Mfg
Export CitationBiBTeX, EndNote, RefMan
External Links: USPTO, USPTO Assignment, Espacenet
Color changeable embossable label tape
US 3468744 A
Abstract  available in
Previous page
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Claims  available in
Description  (OCR text may contain errors)

Sept- 23. 1969 T. J. REINHART 3,468,744

COLOR CHANGEABLE EMBOSSABLE LABEL TAPE Filed Aug. 13, 1964 Y, INVENTOR. Z/OMAL/ Pim/#4W BY United States Patent O 3,468,744 COLOR CHANGEABLE EMossABLE LABEL TAPE Thomas J. Reinhart, Bloomington, Minn., assignor to Minnesota Mining and Manufacturing Company, St. Paul, Minn., a corporation of Delaware Filed Aug. 13, 1964, Ser. No. 389,363 Int. Cl. B441 1/08; B32b 7/02, 27/08 U.S. Cl. 161-6 3 Claims ABSTRACT OF THE DISCLOSURE This invention relates to embossable pressure-sensitive adhesive label tape.

During the past few years label tape has gained a remarkable acceptance in the marketplace. One popular tape is made on a plastic backing which crazes and becomes opaque when subjected to fairly mild stresses such as are imparted by mating cold embossing dies, the embossed areas standing out white against the surrounding unstressed background. Such tapes are typically made by coating a desired color on the back surface of a lighttransmitting film of the type described, thereafter applying a layer of pressure-sensitive adhesive over the colored coating and protecting the adhesive with a removable liner. As supplied to the consumer, the color shows through the film, imparting a more or less uniform appearance. When the tape is embossed, the resultant stress locally opacifies and whitens the plastic backing, thereby preventing the background color from showing through in the areas of embossing, the embossrnents thus appearing white against the colored background. If a pigmented opaque film (other than one which transmits light) is used, the embossed areas may appear to be either white or a light pastel version of the background color.

Although popular, the label tape just described suffers from certain disadvantages which limit its utility. The fact that it has been possible to obtain only white, or Very light pastel, colors in the embossed areas has reduced the eye appeal, and limited the sales, of the product. Additionally, the face surface of the film typically has an imperfect, blemished appearance, e.g., rough, dull, pitted or scratched. To the best of my knowledge, no one was able to overcome these deficiencies prior to my invention.

I have now devised a product having the desirable features of the prior art labeling tape but avoiding its disadvantages. Products made in accordance with my invention have a uniformsrnooth outer surface, a lustrous appearance, and the embossed letters or other indicia may be any desired color, eg., yellow, blue, green, red, etc. The effects are dramatic, and these novel products lend themselves to a Wide variety of uses and markets heretofore unattainable.

In the accompanying drawing,

FIGURE 1 is a cross-sectional view of a tape product made in accordance with my invention and FIGURE 2 is a cross-sectional view of the product shown in FIGURE l after it has been embossed.

In the drawings, a sheet of clear film 11 (which is of the type which opacifices under mild stress) is colored by providing its back surface with a colored layer 12 and ICC its face surface with a transparent colored layer, or topcoat, 13. `Over colored layer 12 is applied a layer of conventional normally tacky and pressure-sensitive adhesive 14, which is protected by removable liner 15. When viewed from the face side the tape products color is an additive blend of colored layers 12 and 13; eg., if layer 12 is cyan and layer 13 is yellow, the overall effect is green. When the tape is embossed, as shown in FIGURE 2, film 11 opacifies to a whitish color in areas 20 Where it has been subjected to embossing strain, thereby preventing the transmission of any cyan color to the face side. In the embossed areas the embossments are, in effect, yellow coated on white and hence appear yellow. The embossed tape thus has an appearance of yellow indicia embossed on a green background. If layer 12 were yellow and 13 were cyan, the embossed tape would have cyan indicia on a green background.

The following specific example is given to indicate the way in which my invention can be made, but is, of course, only illustrative.

EXAMPLE To one surface of a l0 mil Luvitherm unplasticized polyvinyl chloride film was applied a thin coating of a black vinyl ink, obtained by diluting MRX-9243 Black Vinyl lnk (sold by Crescent lnk and Color Company) from its normal 39% solids content to 24%, using methyl ethyl ketone as the solvent. MRX-9243 comprises carbon black pigment in a phthalate-plasticized polyvinyl chloride: polyvinyl acetate binder resin in methyl ethyl ketone. As used, the ink had a viscosity of 23 seconds when measured in a Zahn G-3 Open Cup Viscosimeter of the type commonly employed in the ink industry. The ink was applied to the surface of the Luvitherm film with a line knurled ruling mill at room temperature, the coating containing on the order of 1/2 to l grain of solid material per 24 square inches. The coated film was then dried 1'0 seconds in an air circulating oven maintained at 210 F., this brief exposure to heat serving to drive out the methyl ethyl ketone solvent after it had served to promote adhesion of the ink to the film but before it had deleteriously affected the film itself.

The coated film was next treated by applying to the opposite surface a blue vinyl ink, substantially identical to the ink applied to the back surface except that the pigment used was copper phthalocyanine and the viscosity was l5 seconds When measured as described in the preceding paragraph. The ink was applied with a 20G-line pyramid-pattern knurled roll, after which the coated sheet was dried as before.

When viewed from either side, the coated film had a smooth, lustrous black appearance. When bent sharply back upon itself the film opacified along the line of bending in the conventional manner, thereby preventing the transmission of color through the film in the vicinity of the fold. Thus, when the fold line was viewed from the black-coated side, it appeared indistinguishable from the remainder of the tape `but when viewed from the bluecoated side it appeared blue against a black background. Although this double-coated film is generally considered an intermediate product, it was suitable for embossing to provide blue indicia on a black background, the embossed film then being atiixed to a surface, inserted in a plastic name plate, etc.

To the black-coated surface of the coated film just described was applied a heptane solution of a 95.5:4.5 isooctylacrylatetacrylic acid copolymer pressure-sensitive adhesive of the type described in Ulrich U.S. Patent 2,- 884,126. (A Wide variety of normally tacky and pressuresensitive adhesives may be used, but acrylate adhesives of this type display high holding power, solvent resistance, heat-resistance, and age-resistance.) 'Ille solvent was then evaporated, leaving 12-14 grains of adhesive solids per 24 square inches, and the adhesive protected by applying a 4-mil polyethylene ilm liner. The finished tape product was slit to the desired width for use in an embossing machine for the manufacture of labels. The face of the tape showed none of the blemished and irregular elect typical of conventional embossable tape products, even when viewed in obliquely directed light. When embossed, the finished tape showed blue indicia against a uniform lustrous black background.

The Luvitherm ilm employed in the foregoing example is an oriented rigid polyvinyl chloride (Vinoex 377 resin, marketed by Badische Anilin und Soda Fabrik, containing certain processing aids and minute particles of incompatible material). The iilm contains about 2-3% f a soap used in emulsion polymerizing the polyvinyl chloride, 0.15% diphenylthiourea and 0.2-0.3% Na2CO3 to enhance heat stability, and about 5% E wax (a hard, brittle crystalline waxy ester of Montan acids having a melting point of 79-82 C., serving as a lubricant during calendering of the iilm). Manufacturing procedures are set forth in DeBell & Richardson, German Plastics Process, Department of Commerce, 1946, page 399 et seq. Equivalent rigid polyvinyl chloride iilms are sold under the trade names of Polytherm, Genotherm, Nicotherm, and Craytherm. The fact that translucent rigid polyvinyl chloride iilms become opaque when embossed has been known for over 20 years; see Krannich, Kunststotfe im technischen Korrosionsschutz, I. F. Lehmanns Verlag/Mnchen-Berlin 1943, pp. 347-352.

'Other compositions useful in forming light-transmitting iilms which are normally clear, hazy, or opalescent, but which opacify when embossed include blends of isotactic polypropylene and butyl rubber, and polystyrene-poly- Ibutadiene blends. Rubber-resin blends similar to those used in normally tacky and pressure-sensitive adhesives also display the characteristic of light-transmission before, and opacity after, stretching; although not generally selfsupporting, such compositions may be coated on iilms whose clarity is not affected by stretching. Each of these and other, alternative iilm structures may be used in the practice of my invention. It is noted that each composition named includes finely dispersed incompatible matter; it is believed that stretching causes the formation of minute voids in the areas immediately adjacent the inclusions, and that such voids cause opacity by changing the lilms overall diffraction.

'Ihe amount of ink applied to each face of the iilrn can be varied, but if an excessive quantity is applied to the upper surface of the iilm, the transparent elect is diminished and the lower color does not show through. When such is the case, of course, the embossed indicia do not have the desired contrast with the background. If the back color is black, the topcoat can be any other color; the general overall appearance will be black, but embossed letters will have the color of the topcoat. Especially when colors other than black are used, the exact color effect can be varied by changing the amount of ink applied to the back surface, the face surface, or both. For example, tape having a magenta topcoat and a yellow back coat has a generally orange appearance; when embossed, the resultant letters appear magenta against an orange background. Likewise, when the topcoat is yellow and the back coat is magenta, a somewhat lighter orange appearance is achieved; embossed letters in this case appear yellow. Omission of the adhesive layer permits films coated yellow on one Side and magenta on the other to be used to make labels having either yellow or magenta embossed indicia against an orange background. In certain instances I may employ back and face coats of the same color; in such event, embossed indicia standout relatively pale against a deeply colored background.

Although the use of vinyl inks to impart color is simple, effective, versatile and hence generally preferred, it will 4 be appreciated that other coatings and coloring techniques may be employed. To illustrate, a metal foil or patterned lamina (e.g., wood grain), may be adhered to the back of the iilm, or the back surface can be vapor-coated with aluminum, gold, or some other suitable metal. lf desired, the adhesive itself may be colored, thereby obviating the need for a separate colored layer. It will also be apparent that if only the topcoat in the tape structure is colored, all other strata being clear, the color of the substrate to which the tape is applied will blend with the color of the topcoat, embossed indicia displaying the color of the topcoat alone. Similarly, although somewhat more costly than simple coatings, extremely thin, iiexible transparent colored ilms of Saran or similar materials may be laminated to the upper surface of the structure. My invention likewise contemplates the use of white-opacifying iilms which are internally dyed or pigmented, thereby obviating the need for a colored back coat. As in the previous illustrations of my invention herein, the product has an original appearance which is an additive blend of the film color and the topcoat color; upon embossing, the background retains the same color, while the embossed indicia assume a color which is an additive blend of the topcoat and the now white or pastel iilm. In any event, the topcoat must be transparent, or at least display a high degree of light transmission, to obtain the desired eifect. It is also important that the top coat be suiiciently adherent, exible, and extensible that it does not fall ott, flake, or check during embossing.

What I claim is:

1. A colored adhesive tape in which a backing of the kind which normally allows transmission of light but becomes opaque when subjected to a mild cold drawing operation, such as embossing, is overlaid on the side opposite the adhesive by a light transmitting lilm, so that in areas which are rendered opaque the tape takes up the color of the film Whereas in other areas it takes up a color which is a combination of the color of the iilm and color beneath the iilm.

2. The tape of claim 1 in which the backing is rigid transparent polyvinyl chloride and the light transmitting colored ilm is a vinyl ink coating.

3. A smooth, lustrous plastic sheet material having a first color and capable of being embossed to provide indicia of either a second color or a third color, as desired, against a background of said iirst color, said sheet material comprising in combination: a transparent plastic iilm backing of the type which opaciiies when subjected to mild cold deformation, a transparent second-colored layer uninformly adhered to one face of said backing and a transparent third-colored layer uniformly adhered to the other face of said backing, said sheet material having a rst color which is the additive combination of said second color and said third color.

References Cited UNITED STATES PATENTS 3,03 6,927 5/1962 Ierothe 117-7 3,079,270 2/ 1963 Cortez 117-36.7 3,332,829 7/1967 Avery 16l-33 1,741,683 12/1929 Dickey.

1,985,480 12/1934 Carpenter 156-209 X 2,392,594 1/1946 Karol et al 161-130 X 2,477,300 7/ 1949 Karol et al. 161-120 2,748,042 5/ 1956 Borgese 161-254 X 3,036,945 5/1962 Souza 161-406 X 3,048,510 8/1962 Wisotzky 161-6 3,068,118 12/1962 Biskup et al 117-76 3,309,257 3/1967 Borack 161-6 ROBERT F. BURNETT, Primary Examiner W. A. POWELL, Assistant Examiner U.S. Cl. XR. 40-2, 135, 136; 156-196; 161-120, 406, 413

Notice of Adverse Decision In Interference In Interference No. 97 ,257 involving Patent N o. 3,468,744, T. J. Reinhart, COLOR CHANGEABLE EMBOSSABLE LABEL TAPE, final judgment adverse to the patentee was rendered July 13, 1972, as to claims 1 and 2.

[ycz'al Gazette December 12, 1.972.]

Patent Citations
Cited PatentFiling datePublication dateApplicantTitle
US1741683 *May 2, 1928Dec 31, 1929August Goertz & Co IncMeans and method of producing decorative surfaces
US1985480 *Oct 7, 1932Dec 25, 1934Frederick Carpenter JohnFlexible decorating web
US2392594 *Nov 4, 1944Jan 8, 1946Royal Lace Paper WorksComposite decorative material
US2477300 *May 12, 1945Jul 26, 1949Virts IncDecorative shelf edging
US2748042 *Nov 23, 1954May 29, 1956Del Linoleum SocLaminated materials
US3036927 *Nov 30, 1959May 29, 1962Toscony IncMethod of coating vinyl film with a surfacing color
US3036945 *Oct 27, 1958May 29, 1962Dymo Industries IncEmbossable plastic assembly
US3048510 *Dec 2, 1957Aug 7, 1962American Biltrite Rubber CoLaminated floor and wall covering
US3068118 *Jan 12, 1962Dec 11, 1962Congoleum Nairn IncDecorative surface covering
US3079270 *Mar 6, 1959Feb 26, 1963Lamford Paper Internat LtdAuto copy paper and methods of making the same
US3309257 *Oct 22, 1963Mar 14, 1967Tapeprinter IncColor changeable embossable laminate
US3332829 *Feb 18, 1964Jul 25, 1967Avery Adhesive Products IncArticle for multiplicate marking
Referenced by
Citing PatentFiling datePublication dateApplicantTitle
US3703779 *Nov 14, 1969Nov 28, 1972Goldman AllanTranslucent sign
US3887734 *Oct 29, 1973Jun 3, 1975Dymo Industries IncEmbossing tape
US3908065 *Apr 15, 1974Sep 23, 1975Minnesota Mining & MfgMagnetic embossable label tape laminate
US3971866 *Jun 7, 1974Jul 27, 1976Minnesota Mining And Manufacturing CompanyThermoformable release liner
US3993815 *Oct 7, 1974Nov 23, 1976Avery Products CorporationAnaerobic pressure sensitive adhesive stocks
US4077145 *Oct 18, 1976Mar 7, 1978Smoczynski Frank ENumber plates for racing vehicles
US4082711 *Oct 19, 1976Apr 4, 1978Hoechst AktiengesellschaftShaped articles on the basis of vinyl chloride polymers having an increased white fracture effect
US4489841 *Feb 18, 1983Dec 25, 1984Tri-Tech Systems International, Inc.Tamper evident closures and packages
US4557505 *Jan 5, 1984Dec 10, 1985Minnesota Mining And Manufacturing CompanyStress-opacifying tamper indicating tape
US4663214 *Oct 11, 1985May 5, 1987Coburn Jr Joseph WPhosphorescent material and process of manufacture
US4695336 *Sep 18, 1986Sep 22, 1987Coburn Jr Joseph WPhosphorescent material and process of manufacture
US4905851 *Dec 30, 1988Mar 6, 1990Tri-Tech Systems International, Inc.Tamper evident closures and packages with color changing means and separable portions of the closures and method of forming the same
US5143570 *Sep 3, 1991Sep 1, 1992Avery Dennison CorporationComposite facestocks and liners
US5155878 *Apr 15, 1991Oct 20, 1992Dellis Edward AMoldable hand grip
US5186782 *Oct 17, 1990Feb 16, 1993Avery Dennison CorporationMethod for high speed labelling of deformable substrates
US5372669 *Apr 15, 1993Dec 13, 1994Avery Dennison CorporationComposite facestocks and liners
US5376236 *Oct 29, 1993Dec 27, 1994At&T Corp.Process for etching titanium at a controllable rate
US5468523 *Mar 15, 1993Nov 21, 1995Minnesota Mining And Manufacturing CompanyMethod and apparatus for forming prefabricated self-forming self-adhering pull bow and pull bow formed thereby
US5516393 *Apr 29, 1993May 14, 1996Avery Dennison CorporationLabelling of substrates
US5614274 *Jun 6, 1996Mar 25, 1997Minnesota Mining And Manufacturing CompanyPreformed self-adhering bow
US5628846 *May 17, 1995May 13, 1997Minnesota Mining And Manufacturing CompanyMethod and apparatus for forming prefabricated self-forming self-adhering pull bow and pull bow formed thereby
US5700564 *May 12, 1995Dec 23, 1997Avery Dennison CorporationComposite facestocks
US5830571 *Oct 31, 1996Nov 3, 1998Avery Dennison CorporationHeat resistant pressure sensitive adhesive constructions
US5985075 *Oct 14, 1997Nov 16, 1999Avery Dennison CorporationMethod of manufacturing die-cut labels
US6040027 *Dec 5, 1997Mar 21, 2000Avery Dennison CorporationComposite facestocks
US6099927 *Nov 27, 1995Aug 8, 2000Avery Dennison CorporationLabel facestock and combination with adhesive layer
US6156252 *Oct 14, 1997Dec 5, 2000Avery Dennison CorporationMethod of preparing roll or sheet facestock
US6245418Dec 5, 1997Jun 12, 2001Avery Dennison CorporationComposite facestocks
US6299956Dec 4, 1998Oct 9, 2001Avery Dennison CorporationPressure sensitive adhesive constructions
US6461555Mar 3, 2000Oct 8, 2002Avery Dennison CorporationMethod of preparing facestock for labels
US6579602Dec 5, 1997Jun 17, 2003Avery Dennison CorporationComposite facestocks
US6627283Dec 5, 1997Sep 30, 2003Avery Dennison CorporationComposite facestocks
US6835462Sep 6, 2002Dec 28, 2004Avery Dennison CorporationConformable and die-cuttable biaxially oriented films and labelstocks
DE2444616A1 *Sep 16, 1974Apr 30, 1975Minnesota Mining & MfgDurch spannung undurchsichtig werdendes anzeigeelement zum nachweis des unbefugten oeffnens eines behaelters
EP0148030A2 *Dec 28, 1984Jul 10, 1985Minnesota Mining And Manufacturing CompanyStress-opacifying tamper indicating tape
EP0148030A3 *Dec 28, 1984May 20, 1987Minnesota Mining And Manufacturing CompanyStress-opacifting tamper indicating tape
WO2005075591A1 *Feb 2, 2005Aug 18, 20053M Innovative Properties CompanyMethod of producing colored graphic marking films
U.S. Classification428/520, 428/913, 428/41.6, 156/196, 40/616, 427/209, 428/354, 427/208, 40/615
International ClassificationB32B27/00, C09J7/02
Cooperative ClassificationC09J7/0296, C09J2201/162, B32B27/00, Y10S428/913
European ClassificationC09J7/02K9F, B32B27/00