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Publication numberUS3539519 A
Publication typeGrant
Publication dateNov 10, 1970
Filing dateFeb 14, 1969
Priority dateFeb 23, 1968
Also published asDE1814439A1
Publication numberUS 3539519 A, US 3539519A, US-A-3539519, US3539519 A, US3539519A
InventorsWeimer Dean R
Original AssigneeContinental Oil Co
Export CitationBiBTeX, EndNote, RefMan
External Links: USPTO, USPTO Assignment, Espacenet
Low foaming nonionic detergents
US 3539519 A
Abstract  available in
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Claims  available in
Description  (OCR text may contain errors)

United States Patent 3,539,519 LOW FOAMING NONIONIC DETERGENTS Dean R. Weimer, Ponca City, Okla, assignor to Continental Oil Company, Ponca City, Okla, a corporation of Delaware Continuation-impart of abandoned application Ser. No. 707,401, Feb. 23, 1968. This application Feb. 14, 1969, Ser. No. 799,519

Int. Cl. Clld 1/72 US. Cl. 252-89 6 Claims ABSTRACT OF THE DISCLOSURE A high foaming monionic surfactant in the form of an alkyl polyethoxyethanol is further condensed with butylene oxide to provide a low foaming modification thereof having the general formula R(O*CH CH (OC I-I ),,OH.

CROSS REFERENCE TO RELATED APPLICATION This application is a continuation-in-part of pending application entitled Low Foaming Nonionic Detergents," UJS. Ser. No. 707,401, filed Feb. 23, 1968 by Dean R. Weimer now abandoned.

BACKGROUND OF THE INVENTION Field of the invention This invention relates to a low foaming nonionic detergent composition consisting essentially of a mixture of surface active compounds serially containing a hydrophobic alkyl group, a hydrophilic polyoxyethylene segment and a terminal hydroxy butoxy group.

Description of the prior art -An important class of nonionic detergent is exemplified by those compositions, generally designated ethoxylates, which are obtained by condensing a hydrophobic compound having a replaceable hydrogen atom with a plurality of moles of ethylene oxide. Particularly suitable compounds providing the hydrophobic portion of such ethoxylates are either the higher aliphatic monoalcohols or an alkyl substituted phenol. These nonionic compositions are excellent detergents and are characterized as high foamers in that they are prone to result in profuse sudsing in any cleaning operation involving highly turbulent agitation conditions. In some industrial and in many household cleaning applications of the aforesaid type, it is very desirable to maintain a low level of foam during the cleansing or treating operation. For example, in various household cleaning operations conducted in mechanical washers excessive foaming of the nonionic detergent is objectionable because the foam interferes with proper rinsing and in some cases impairs cleansing efficiency. Furthermore, high foaming detergents are ultimately apt to give rise to mechanical difliculties. It is well know in the syndet art that the wetting and/or detergency power of a surface active agent is not necessarily synonymous with its foaming ability. Consequently, considerable investigation has hitherto been directed toward providing modifications of high foaming nonionic detergents Whereby the inherent tendency to foam is abated without significantly detracting from the detergency power exhibited by the unmodified nonionic.

The nonionics with which this invention is concerned are basically a chemostructural combination of a hydrophobic group and a segment of hydrophilic units as can be perceived from the foregoing discussion. It has been proposed to terminate the hydrophilic portion with a radical having somewhat lesser hydrophilic characteristics in order to provide a lower foaming but equally effective Patented Nov. 10, 1970 modification thereof from the standpoint of detergency. This has been generally accomplished heretofore by further condensing the ethoxylate with propylene oxide to provide a terminal polyoxypropylene segment. The disadvantage of this approach is twofold in nature. For one, the hydrophobic radical of such modified compositions must be relatively low in molecular weight thereby necessitating the use of an alcohol which does not yield optimum detergency characteristics. Secondly, if the preferred higher molecular weight alcohols or alkyl substituted phenols are utilized to prepare such modified nonionics, the terminal polyoxypropylene segment must be undesirably large. Too large a terminal segment of this type poses problems not only in regard to biodegradability but also has an adverse effect with respect to a variety of more subtle aspects.

OBJECT OF THE INVENTION The primary objective of this invention is to provide a modified nonionic detergent composition of the alcohol ethoxylate type exhibiting low foaming characteristics in combination with good biodegradability, Water solubility and physical appearance properties.

SUMMARY OF THE INVENTION The present invention is directed to nonionic detergent compositions comprising a mixture of surface active compounds corresponding to the following general formula:

where R is a C C alkyl group, and it indicates a range of integers representing the statistical distribution of oxyethylene units obtained by condensing from about 3.5 to 10 moles of ethylene oxide with a [mole of the compound providing said hydrocarbon groups, namely, a higher aliphatic monoalcohol, and x indicates a range of integers of from about 0.5 to 1.5.

DESCRIPTION OF THE PREFERRED EMBODIMENTS The compounds having replaceable hydrogen atoms useful to prepare the base ethoxylates of this invention are the various detergent grade aliphatic mono-alcohols. The term aliphatic monoalcohols as used in this disclosure pertains to those monoalcohols whose carbon atoms are arranged in chains only. Such alcohols include linear and branched primary and secondary monoalcohols. How ever, the linear alcohols, are more biodegradable. Therefore, the preferred monoalcohols are the linear alcohols such as exemplified by the primary alcohols obtained in accordance with the Ziegler synthesis method or the secondary alcohols prepared by the OX0 process. Particularly desirable alcohols are the linear primary alcohols. Broadly inclusive of the latter, as well as the linear secondary alcohols, are those containing from 8 to 18 carbon atoms. Especially useful alcohols within this range are the C 4) alcohols and mixture thereof. For the purpose of making low foaming nonionic detergents for household cleaninng applications, n-decanol or mixture thereof With minor amounts of dodecanol and/ or tetradecanol provide surface active substances having an optimum balance of properties.

Ethoxylates of the foregoing compounds containing a replaceable hydrogen atom can be prepared by conventional methods. Either acid or base catalysis is applicable. Base catalysis, however, is preferred in effecting the condensation of ethylene oxide with the alcohol. Exemplary of suitable bases are the alkali metal hydroxides such as LiOH, KOH and NaOH. Sodium hydroxide is the preferred base catalyst for effecting condensation. Exemplary of suitable acid catalysts are SbCl SnCl, and BF Boron trifluoride is the preferred acid catalyst for effecting condensation.

The general procedure for carrying out the condensation reaction involves adding the requisite amount of ethylene oxide to the alcohol together with the catalyst selected and heating the reactants to an elevated temperature under autogenous pressure. The ethoxylation or condensation reaction can be carried out in a temperature range of from about 320 to 380 F. The preferred temperature range is from about 340 to 360 F. The foregoing temperature ranges are applicable for the preferred catalyst, specifically sodium hydroxide. When using an acid catalyst, such as boron trifiuoride, a lower temperature is to be observed. A range of from about 175 to 220 F. is suitable for such catalysis.

The amount of ethylene oxide to be reacted with the monoalcohol is primarily dependent upon the molecular weight of said alcohol. As the molecular weight of the hydrophobe portion increases, the use of correspondingly greater amounts of ethylene oxide is the customary practice. 'For the broad range of alcohols contemplated herein the corresponding amount of ethylene oxide ranges from about 3.5 to 10 moles per mole of the alcohol. An ethylene oxide range of from 3.5 to 6 moles per mole of the preferred C to C alcohols is applicable. However, in order to produce a nonionic low foaming composition having excellent solubility properties I prefer to employ from about 5.2 to 5.7 moles of ethylene oxide per mole of the C to C alcohols or blends thereof. Desirable results have also been obtained where the resultant condensate is the reaction product of a mole of a C -C alcohol and from about to 6 moles of ethylene oxide. The preferred weight ratio of ethylene oxide to any given alcohol in the resultant condensate is in the To further illustrate the best manner contemplated for carrying out the invention the following working examples are set forth. As indicated, the examples are primarily given by way of illustration, and accordingly any enumeration of details set forth therein are not to be interpreted as a limitation on the invention except as such limitations are indicated in the appended claims. All parts are parts by weight unless otherwise stated.

EXAMPLE I A series of butylene oxide capped alcohol ethoxylates was prepared following the general procedure of reacting ethylene oxide with the alcohol at about 350-360 F. in the presence of NaOH catalyst in the amount of about 0.125 percent based on the weight of the alcohol. Capping of the resultant ethoxylates was accomplished in those runs employing base catalysis by adding the requisite amount of 1,2-butylene oxide and heating at approximately the temperature observed in effecting ethoxylation. In the run in which capping with the butylene oxide was conducted in the presence of BF catalyst (about 0.1 percent based on the weight of the ethoxylate) the crude ethoxylate product was first neutralized with glacial acetic acid and then filtered. All of the capped products were then heated at from 340 to 360 F. and at about 10 mm. Hg to remove any light ends contained by the product. Following removal of the light ends, the products were neutralized and filtered. Details as to the respective compositions of these runs as well as their comparative performance in several loW foam testing methods and their wetting ability as determined by the standard Draves test are given in the following Table 1. Also indicated in the table is the general resistance of the various products to biological assimilation in a standorder of from 1.3 to 1.8. Especially when using a monoard biodegradation test.

TABLE 1 Moles Low foam tests Percent Moles BO per Wetting E0 in E0 in mole of Num Num- Nom- Numtest Biodegrad- Primary alcohol or mixture ethoxylate ethoxylate ethoxylate her 1 her 2 her 3 bar 4 No. 5 ability 85% Clo-8% C12"7% C14 58 5. 2 0 2. 8 2.0 0.9 1. 3 6.3 Good. 2. 85% Clo-8% Gig-7% C 3. 7 l 1 0. 6 0.6 0. 4 0. 6 D0. 3. 85% C o-8% G g-7% C 59 5. 5 1 1.2 0. 4 0.3 0.7 7. 2 Do. 4. 85% Clo-8% (Em-7% C 60 5. 7 1 1.2 0. 5 0.3 0. 8 7.0 Do. 5.-. 85% Clo-8% Cir-7% C 61 6. 0 1 1.7 0. 5 O. 5 0.7 6. 2 D0. 6 85% C o-8% Gig-7% CM 58 5. 2 1 1 1. 6 0. 4 0. 3 0.8 9.2 Do.

1 BEE) used as catalyst for capping.

alcohol, the aforesaid range of ethylene oxide provides about the optimum balance of properties for the resultant condensate.

In accordance with this invention the ethoxylates described hereinabove are then reacted with butylene oxide in a manner whereby a substantial portion of the ethoxylated compounds are terminated with a hydroxy butoxy grouping. An applicable amount of butylene oxide for achieving such capping is from 0.5 to 1.5 moles of butylene oxide per mole of the ethoxylate. The preferred compositions are those obtained by condensing the ethoxylated product with about 0.75 to 1.25 moles of butylene oxide. Especially desirable results have been obtained wherein the ethoxylated product is condensed with about 1 mole of butylene oxide. Again, either base or acid catalysis can be used to achieve capping of the ethoxylate. A- base such as sodium hydroxide is preferred from the standpoint of convenient processing. However, the use of an acid catalyst such as boron trifiuoride for this purpose results in a product having somewhat better physical appearance than those capped materials prepared using base catalysis for the capping step. The respective ranges of temperatures, including the preferred ranges discussed hereinabove in connection with preparing the ethoxylate, are precisely applicable in achieving A summary of the various test methods used are as follows:

Test No. 1.0.1% surfactant in 200 ml. aqueous solution. Stirred on malt mixer at high speed at 75 F. for 3 minutes. Solution allowed to stand 2 minutes and the foam height measured in centimeters.

Test No. 2.Same as No. 1 except that test is run at F.

Test No. 3.0.006% surfactants and 0.194 sodium silicate in 200 ml. aqueous solution. Stirred on malt mixer at high speed and 140 F. for 3 minutes. Solution allowed to stand 45 seconds and foam height measured in centimeters.

Test No. 4.0.006% surfactant, 0.194% sodium silicate and 0.1% powdered milk in 200 ml. aqueous solution. Test procedure is the same as Test No. 3. Tests 3 and 4 measure the defoaming ability of the surfacant for use where proteinaceous material is present.

Test No. 5.Measures wetting time of 0.1% solution of the surfactant at 75 F. A 5 gm. Draves cotton skein and a 3 gm. hook used.

The above data clearly indicates that a nonionic compound having the general formula R(OCH CH (OC H OH where R is a linear a-lkyl radical having 10 to 14 carbon atoms, n is an integer 3.7 to 6.0 and x is 1 possesses excellent cotton wetting properties and good biodegradable properties. The data further illustrates that by incorporating 1 mole of butylene oxide into a high foam nonionic, such as in Run No. 1, the resulting nonionic compound possesses desired low foam properties without sacrificing the above-mentioned desirable properties.

EXAMPLE II A series of propylene oxide capped ethoxylates was prepared following the general procedure outlined in Example I except that propylene oxide was substituted for the 1,2-butylene oxide. Details as to the respective compositions of these runs as well as their comparative performance in several low foam testing methods and their Wetting ability as determined by the standard Draves test are given in the following Table 2.

R(OCH CH (OC H OH wherein R is a C to C alkyl group, n is an integer of TABLE 2 Percent E Moles E O Moles P0 Low foam tests Wetting in 1n per test Biodegrad- Run Primary alcohol or mixture ethoxylate ethoxylate mole of N0. 1 N o. 2 No. 3 ability ethoxylate 6 45% 08-55% Cw 60 5 0.5 0 16.7 Poor. 7 85% C1u-3% C12-7% C14..- 73 10. 4 0 5. 2 4. 1 24.0 Good. 8 85% G n-8% C12 7% C14 78 10.4 1 4.5 2.7 19.2 Fair. 9 40% -30% e -20% Ora-10% c 62.5 8.1 0 4.0 3.1 Good.

40% (hr-30% C Gu -10% C13..- 65 9 3. 5 3. l 1. 6 P001.

(In- C14"20% C1e* C18"- 66 9. 5 7 3. 3 0. 6 D0.

Summary of the various test methods used are as from about 3.5 to 10 and x is an integer from about 0.5 follows: to 1.5.

Test No. 1.O.1% surfactant in 200 ml. aqueous solu- 2. The compositions of claim 1 wherein x is from 0.75 tion. Stirred on malt mixer at high speed at 75 F. for 3 to 1.25. minutes. Solution allowed to stand 2 minutes and the 30 3. The compositions according to claim 1 wherein foam height measured in centimeters. x is about 1.

Test No. 2.Same as No. 1 except the test is run at 4. The compositions according to claim 3 wherein 140 F. R is a C to C linear group and n is from about 3.5

Test No. 3.Measures wetting time of 0.1% solution to 6. of the surfactant at 75 F. A 5 gm. Draves cotton skein 5. The compositions according to claim 4 wherein n and a 3 gm. hook used. is about 5.2 to 5.7.

Referring to the above data Run NO. 8, When C m- 6. The compositions according to claim 3 wherein R pared with Run No. 7, illustrates that when 1 mole of is a C to C linear group and n is from about 5 to 6. propylene oxide is employed to cap the original ethoxylate the small decrease in foam of the propylene Exide References Ci capped nonionic is not sufficient to make it a 0W oam nonionic. In order to get good defoaming properties the UNITED STATES PATENTS propylene oxide ratio to the ethoxylate must be relatively 2,671,115 3 1954 KOSmlIl. high. This is illustrated in Runs No. 6 and 11 where the 2,370,220 /1959 Carter. ratio of ethylene oxide to propylene oxide is approxi- 2,903,486 9/ 1959 Brown et al. mately 1:1. However, the nonionics containing an effec- 2,965,678 12/1960 Jllfldbelg et a1- tive amount of propylene oxide exhibit poor biodegrad- 3,101,374 8/1963 i ability. The data also illustrates that the wetting speed 3 3 9/ 1967 Welbertof the propylene oxide capped nonionic is substantially FOREIGN PATENTS poorer than the butylene oxlde capped llOl'llOIllC of Example I- 538,843 3/1957 Canada.

Therefore, when comparing the results of Table I and Table II, i.e., butylene oxide capped nonionic and pro- LEON D. ROSDOL, Pflmary Examlnel pylene oxide capped nonionic, one can readily see that the butylene oxide capped nonionic produces superior SCHULZ Assistant Examiner results. Further, the butylene oxide capped nonionic has Us Cl X R a much lower ratio of butylene oxide to ethylene oxide than the propylene oxide to ethylene oxide ratio in the 615 propylene oxide capped nonionic.

The foregoing discussion and description has been

Patent Citations
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Referenced by
Citing PatentFiling datePublication dateApplicantTitle
US3862243 *Feb 17, 1972Jan 21, 1975Int Flavors & Fragrances IncMixed oxyalkylates employed as antifoamers
US4038296 *Jan 3, 1975Jul 26, 1977Basf AktiengesellschaftAlkylene oxide derivatives based on polytetrahydrofuran copolymers
US4087356 *Nov 4, 1976May 2, 1978Snamprogretti S.P.A.Method for depolluting fresh and sea water from petroleum products
US4102795 *Apr 18, 1977Jul 25, 1978Kao Soap Co., Ltd.Softener composition for fabrics or hair
US4207421 *Apr 6, 1979Jun 10, 1980Olin CorporationBiodegradable, alkali stable, non-ionic surfactants
US4448697 *Jan 22, 1982May 15, 1984Texaco Inc.Secondary recovery process
US5456847 *Dec 22, 1993Oct 10, 1995Ciba-Geigy CorporationLow foaming, nonsilicone aqueous textile auxiliary compositions and the preparation and use thereof
US8138136 *Oct 29, 2007Mar 20, 2012Kao CorporationProcess for production of alkylene oxide adducts
US8334323Dec 23, 2008Dec 18, 2012Dow Global Technologies LlcAlkylene oxide-capped secondary alcohol alkoxylates useful as surfactants
US8357823Sep 17, 2009Jan 22, 2013Dow Global Technologies LlcAlkylene oxide capped secondary alcohol ethoxylates as fermentation foam control agents
US20100056821 *Oct 29, 2007Mar 4, 2010Kao CorporationProcess for production of alkylene oxide adducts
US20100075389 *Sep 17, 2009Mar 25, 2010David Bradley WurmAlkylene oxide capped secondary alcohol ethoxylates as fermentation foam control agents
US20100267844 *Dec 23, 2008Oct 21, 2010Varineau Pierre TAlkylene oxide-capped secondary alcohol alkoxylates useful as surfactants
DE3237608A1 *Oct 11, 1982Apr 28, 1983Basf AgUse of non-ionic surfactants prepared from fatty alcohols, THF and ethylene oxide in cleaning and dishwashing compositions
WO2010036555A2 *Sep 17, 2009Apr 1, 2010Dow Global Technologies, Inc.Alkylene oxide capped secondary alcohol ethoxylates as fermentation foam control agents
WO2010036555A3 *Sep 17, 2009Jul 1, 2010Dow Global Technologies, Inc.Alkylene oxide capped secondary alcohol ethoxylates as fermentation foam control agents
Classifications
U.S. Classification568/625, 510/535, 510/506
International ClassificationC11D1/722
Cooperative ClassificationC11D1/722, C11D3/0026
European ClassificationC11D1/722, C11D3/00B5
Legal Events
DateCodeEventDescription
Oct 1, 1984ASAssignment
Owner name: VISTA CHEMICAL COMPANY, 15990 NORTH BARKERS LANDIN
Free format text: ASSIGNMENT OF ASSIGNORS INTEREST. SUBJECT TO TERMS OF AGREEMENT DATED JUNE 26,1984;ASSIGNOR:CONOCO INC.;REEL/FRAME:004349/0285
Effective date: 19840720