|Publication number||US3547130 A|
|Publication date||Dec 15, 1970|
|Filing date||Feb 12, 1968|
|Priority date||Feb 12, 1968|
|Publication number||US 3547130 A, US 3547130A, US-A-3547130, US3547130 A, US3547130A|
|Inventors||Flint John Roderick, Harlow Edward S|
|Original Assignee||American Tobacco Co|
|Export Citation||BiBTeX, EndNote, RefMan|
|Referenced by (69), Classifications (6), Legal Events (1)|
|External Links: USPTO, USPTO Assignment, Espacenet|
2,755,206 7/1956 Statia Edward S. Harlow;
John Roderick Flint, Richmond, Va. 704,915
Feb. 12, 1968 Dec. 15, 1970 The American Tobacco Company New York, N.Y.
a corporation of New Jersey inventors Appl. No. Filed Patented Assignee METHOD OF COOLING CIGARETTE SMOKE 1 Claim, 1 Drawing Fig.
U.S. Cl 131/9, 131/10.1, 131/266 Int. Cl A24f 25/00, A24f 13/02 Field oiSearch 131110.], 2618, 10, 261-267, 9
References Cited UNITED STATES PATENTS 2,863,461 12/1958 Frost l31/10.1
3,366,121 l/1968 Carty l3l/l0.l
3,390,686 7/1968 lrby et a1 l3l/l0.lX
3,428,049 2/1969 Leake et a1. l3l/l0.l
OTHER REFERENCES Rose, A. (ed.), The Condensed Chemical Dictionary, 6th Ed..NY. Reinhold, 1961. p. 4578.QD5 C5 1961 C. 18.
Primary Examiner-Melvin D. Rein Atmrney-Pennie, Edmonds, Morton, Taylor and Adams ABSTRACT: A method of cooling cigarette smoke is disclosed utilizing ethanol-filled rupturable capsules contained within the filter section of a cigarette. The filter material utilized is preferably a crepe paper of high absorbency and porosity and is free of absorbent material or other material for which the ethanol is a solvent to the extent of releasing a sensible heat of solution when the ethanol is released into the filter.
The invention relates to a method of effecting cooling of cigarette smoke and more particularly to the incorporation of frangible ethanol-filled rupturable capsules in a filter to effect this.
PATENTED UECI 5 I970 INVENTORS Edward S. Harlow John Roderick Him ATTORNEYS METHOD OF COOLING CIGARETTE SMOKE It has been proposed heretofore to provide a tobacco smoke filter with a liquid such as water to-cool the smoke. In the more effective embodiments of this type of filter, the water is contained in at least one capsule positioned within the filter where it can release the water when the capsule is ruptured by compression. In order to control the release of water vapor progressively into successive puffs of smoke, it has been necessary to provide adsorbent material within the filter so that the smoke passing through the filter can, by selective adsorption, exchange some of its constituents for water held by the adsorbent material. Such an arrangement will slightly lower the temperature of the smoke, but its cooling effect is not its primary attribute.
We have experimented extensively with other liquids more volatile than water with the aim of producing a more pronounced cooling effect on the smoke. Sensitive instrumentation demonstrated, however, that puffing on an unlit cigarette provided with an active carbon-containing filter or with a cellulose acetate tow filter injected with such a volatile liquid shows a temperature rise in the air drawn through the filter in at least the early puffs, and the same temperature rise appears when the cigarette is smoked. Our investigations have shown that both the heat evolved by adsorption of the vaporized liquid on the adsorptive material and the heat evolved by dissolution of conventional filament plasticizers in the volatile liquid tend to defeat the cooling effect of vaporization of the liquid. We have discovered, accordingly, that a tobacco smoke filter capable of cooling the smoke can be obtained by positioning within a flexible outer wrapper, and in contact with a filler therewithin capable of entraining a cooling liquid for the smoke, at least one capsule having walls rupturable by compressive pressure and containing a nontoxic liquid substantially more volatile than water, provided that the filler is substantially free of adsorbent material and free of substances sufficiently soluble in the liquid to evolve a sensible amount of heat of solution when the capsule is ruptured and releases the liquid into the filler.
The invention will be more fully understood from the following description taken in conjunction with the drawing in which the single FIG. is a longitudinal cross-sectional view of a filter embodying the invention. I
As shown in the drawing, utilized in the method the filter element of the invention.
As shown in the drawing, the filter element utilized in the method of the invention comprises a resilient outer wrapper 5 surrounding a filler 6 having passages 7 arranged to permit axial flow of smoke therethrough with the customary total resistance to air and smoke flow through a cigarette with the filter attached of, say, about 5 to 30 cc. per second under a suction pressure of 2% inches of water. The filler further comprises at least one frangible capsule 8 containing a smokecooling liquid 9.
The tubelike outer wrapper 5 can be conventional plug wrap paper used in making cigarette filter plugs. It does not have to possess significant wet strength because the liquid in the microcapsules is not released until after the filter element is enclosed in the stronger tipping paper conventionally used to secure the filter element to a cigarette or-cigar, or the like. lt should, however, have sufficient resilience so that it can permit the filter element to be compressed when the tube 'is squeezed yet will return substantially to its initial tubular shape when this squeezing pressure is released.
The filler material used in the filter element of the invention must be capable of entraining a significant amount of the released liquid so as to hold the liquid in the pores or passages of the filler material through and past which the smoke is to be drawn. By entraining the released liquid, the liquid is restrained from passing into the tobacco portion of a cigarette or cigar, or into the smokers mouth, or into an adjacent section of a multiple-component filter assembly. The degree of entrainment of the liquid is also generally commensurate with its surface area available for contact with the liquid. The greater this area, the greater the amount of liquid which can be exposed to the smoke stream for evaporation cooling. Thus, the filler should be characterized by a high degree of porosity such as that provided by fibrous or granular filler materials. If the filler material is fibrous, it is advantageously resilient not only when dry but also when wet with the liquid so as to permit the filter element to be distorted for the purpose of rupturing the liquid-containing capsules yet spring back substantially to its precompressed smoke-filtering form in order to resume its normal filtering position within the filter tube. 1f the filler material is granular, it need not be resilient because when it is admixed with a number of small microcapsules containing the liquid, the shells of the microcapsules constitute a major portion of their volume and remain as a filler after their cooling liquid content has been released by rupture of the microcapsules. Thus, although the filler may be a fibrous mass, such for example as cotton, or a granular mass, such as expanded mica or minute clay pellets, our present preference for the filler material is conventional smoke filter paper having both good absorbency and wet strength. Paper of this type is generally of sufficient resiliency, even when wet, to satisfy the most demanding requirements of a filter element, but further resilience can be imparted to the paper by coating it with starch or other porous stiffening material.
We have found, however, that certain components frequently present in tobacco smoke filters are incompatible with the smoke-cooling effect of the aforementioned liquids. For example,we have ascertained from test data that the presence of an adsorbent material in the stream of smoke cooled by evaporation of the cooling liquid selectively adsorbs at least a portion of the cooling liquid vapor and in doing so liberates sufficient heat to offset the cooling effect of the evaporated liquid. Accordingly, adsorbent materials such as active carbon and silica should not be present in the filter ele ment of our invention or in any other filter element downstream of the smoke passage. In addition, we have ascertained from test data that substances which are significantly soluble in the cooling liquid or its vapor liberate, by their exothermic heat of solution, enough heat to warm the smoke. Cellulose acetate tow and plasticizers such as triacetin appear to be dissolved to a significant extent by the cooling liquids and, when present in the smoke stream containing the cooling liquid or its vapor, cause a temperature rise rather than a temperature drop in the smoke. Tobacco produces the same effect, and thereforethe cooling effect of the volatile liquid is lost if the liquid-containing capsules are embedded in the tobacco portion of a cigarette or cigar.
Theliquid-containing capsule positioned within the filler portion of the filter element utilized in the method of the invention can be a single relatively large capsule or can be a number of capsules which range in diameter between about 0.001 and 0.12 inch. The large size capsules are generally made by conventional techniques used in the pharmaceutical industry, and the miniature capsules can-be made by a coacervation process of liquid-solid exchange process. Suitable microcapsules can also be produced mechanically with a single or multiorifice encapsulating device which forces drops of a liquid to be encapsulated through a thin film of coatingforming material. Centrifugal devices can also be used in a similar fashion. Some of these and other microencapsulating procedures, are described in U.S. Pat. Nos. 2,800,457, 2,800,458, 2,969,330, 2,969,331, 3,015,128 and 3,041,289, in an article by H. W. Mattson entitled Miniature Capsules," published in the Apr. 1965, issue of International Science and Technology (New York, NY.) pages 66 et. seq., and in Microencapsulation by C. E. Anderson et al. Management Reports, (American Management Association), pp. 1-103, 1963.
The capsule used pursuant to our invention comprises an outer frangible sheath enclosing the smoke-cooling liquid and consists of a material which is not reacted upon or dissolved by the liquid. The sheath advantageously is composed of a hard petroleum wax or of a thermoplastic or thermosetting resin such as vinylidene chloride copolymers, polyethylene,
smoke additives can be incorporated in the cooling liquid polypropylene, ethylene-vinylacetate'copolymers, polyesters, phenol-formaldehyde and urea-formaldehyde resins, or of gelatin, or the like. There is no limitationon the composition of the sheath material other than its ability to form and maintain en encapsulating but frangible sheath about the treating liquid.
The cooling liquid within the rupturable capsules is one which is nontoxic and which is significantly more volatile than water but capable of being stored in frangible capsules. Such liquids generally have high vapor pressure at ambient temperature and have a relatively highheat of vaporization. Advantageously, the liquid has a boiling point above about 35 C. and below about 120 C. so that it will evaporate quickly when exposed to a puff of smoke drawn through the filter butwill not be so volatile as to cause the capsule to rupture at ambient temperatures. However, if the'cooling liquid is combined with another less volatile solvent liquid, the boiling point of the cooling liquid can be as low as about minus 21.6 F., as in the case qf dichlorodifluoromethane, and as low as minus 35 F. in the case of other volatile cooling materials dissolved in a normally liquid solvent therefor. The heat of evaporation of the cooling liquid, being endothermic, causes the evaporating liquid to remove heat from the surrounding stream of smoke. Examples of suitable cooling liquids include: alcohols such as ethanol; esters such as methyl, ethyl, n-butyl, n-amyl, iso-butyl, sec-amyl, t-butyl, n-propyl and .iso propyl acetates, methyl, ethyl and iso-propyl formates; methyl, ethyl, propyl, iso-propyl and allyl propionates; methyl and ethyl butyrates; and ethyl isobutyrate; hydrocarbons such 'as n-pentane, n-hexane, cyclohexane and cyclohexene; ketones such as acetone; aldehydes such as acetaldehyde; and halogenated hydrocarbons such as dichlorofiuoromethane, brornotrifluoromethane, dichlorodifluoromethane, 1 ,2-dichloro-1,l,2,2- tetrafluoroethane and 1,1 ,2,2- ftetrachloro- 1,2- difluoromethane. These cooling liquids can be used either alone or in admixture with up to about 70 percent water, ethyl acetate, methyl acetate or other liquid solvents for the cooling liquid, and mixtures thereof. Flavoring agents and other eitherby deliberate addition or by choice-of a flavored cooling liquid such as whiskey, brandy, rum or liqueur as the cooling liquid. p The amount of cooling liquid which, in encapsulated form, is incorporated in the filter element should be substantially that which, when completely evaporated during sm o king,will temhe, d sire icd iir d allliif'tfie so. uid h u n I c. dt ia jw jl he. l tmals ial but the 'ter t ing iswasteful. 4,
u pped inchdh 'diarheter. The thermoeouple waspe'rrnanenfly cem'e'nted' intothe holderfwith the junction exactly on the axis' and located '1 frornflthe end of the cigarette filter tip. The thermocoupleleads, which were brought out on oppositejsi de's of the holder, led to 'tl'i reference junction atfarnbient tern perature and then to the Y-input terminals of of an X Y recorder. An amplifier was used to boost the thermocouple signal to a level affording a recorder sensitivity of 0.2 inch' per Centigrade degree. The X-inputs were supplied with a signal from an external time-base signal generator providing a l inch-per-minute scan rate. The standard smoking procedure was adopted, using one head of a smoking machine adjusted to take a 35 cc., 2 second puffonce per minute.
The maximum temperature difference which could be recorded with this apparatus under thesete'st conditions was 35 C. with ambient temperaturebeing'set arbitrarily on the recorder chart by means of a zeroing control on the recorder. Temperature differences observed during smoking then showed on the recorder chart as either positive or negative deflections of the recorder pen depending on whether thf; probe junction was hotter or cooler, respectively, than the ambient temperature. v
1. Ten of the filter cigarettes were smoked to determine the temperature level of smoke on a normal cigarette. No sol,- vent was injected into the filter. A slight heating of about 0.25 to 05 C. was observed during each puff up to puffs nos. 6 or 7 with the subsequent puffs displaying an addi tional temperature rise due to the shorter lengths of the unsmoked portion of the cigarette. The temperature difference during the puff is attributable to the sum of adiabatic cooling and smoke temperature. a 2. Cigarettes were puffed in the standard manner but contained no solvent and were not lit. A decrease in temperature was observed during each puff and was attributed to adiabatic cooling. This temperature difference was of the order of 0.5 C. and remained fairly constant throughout the first ten puffs.
. Ten cigarettes were smoked to determine the cooling, during each puff, due to the evaporation of 50 mcl. of percent ethanol injected into the filter. A definite lowering of the mainstream smoke temperature was observed and was attributed mainly to the evaporation of the solvent. A slight initial temperature rise of about 5 C. for the first puff and less than 1 C. for the second and third puffs was observed which was followed by cooling on each of the 3 puffs. We have attributed this initial heating mainly to the heat of solution provided by the dissolution of the cellulose acetate plasticizer (triacetin) by the ethanol.
A c garettewassmoked? un wi h m lfethano! in manner; The effects due to smoke temperature were thereby eliminated. The observed temperature difference was thenthe sum of the effects due to adiabatic coolin the heat of solution bythe celluloseacetate, and vapo 5' ti 1 f s l tific n ng was obs rve 1 the rst ew b f and wa a ributed m i y lh' t, of 5 tion'of the cellulose acetate plasticizer in the alcohol.
5. The cigarette puffed in test No. 4 was lighted and smoked in norrrial fashion, Cooling was observed. Lightingthe cigarette didnot affect the level of cooling. f I p 6. cig'aretteliwastested after removing the .ce.ll ulose aqet tplug and ,i j st n 5. "1 1- of hano ht fihs ctionj Much greatericooling was observed corn in t al ea ng was on es mi est d m onstrated that the cellulose 9131 9! ujmiwr antrolein she site wer sr kedwi h .50 n !t f hylac etate edfl'nto the paper sec'tion ofthe'filt'er. lntenseinitial g'lpuffsil and' Z) was observed; Cooling of sub: 's e uent'puffs was intense but tapered off rapidlygdueltd gh vapor prcs sureof the methylacetate. iCo gli as much as 9? was observed.
8. Ten cigarettes were injected with 25 mid. of methyl acetate. Essentially the same effect was noted a's'for the 50 mclaadditionin test No. 7 except that the h'eatingand cooling intensities werehalved.
9. Ten cigarettes were injected with 25 mcl. of ethanol. The same effect was observed as for the 50 mcl. addition in test No. 3 except that the cooling and heating intensities were halved. Cooling by 34 C. with about 25 ml. of injected ethanol was considered to be equivalent to the cooling attainable with an amount of ethanol which could be added readily to the filter in encapsulated form.
10. Cigarettes having 20 mm. paper filter, injected with 25 mcl. of ethanol, were smoked and were observed to show no initial heating. Cooling of the puffs averaged about 2 C.
l l. The cigarettes used in test No. 10 were injected with 25 mcl. of ethyl acetate. Very little initial heating was observed and cooling tapered off sharply as pufis were taken.
12. Cigarettes having a mm. paper filter into which rncl. of 50-50 ethyl acetate-ethanol mixture was injected were smoked. No initial heating was observed. The temperature-time trace appeared to be a combination of that oftests Nos. 10 and ll.
l3. Runs were made of cigarettes with plain absorbent cotton filters, with filters of absorbent cotton plus 60 mg. active carbon, and with filters of absorbent cotton plug 50 mg. of active carbon which had previously been wetted with 95 percent ethanol and allowed to dry. Heating was observed for all three types of cigarettes, but those containing carbon showed a greater temperature rise than those containing cotton alone.
14. Cigarettes were prepared with microcapsules containing a 50-50 ethanol-water solution embedded in the paper section of the filter. The capsules weighed about 50 mg. per cigarette of which about 50 percent comprised the alcohol-water mixture. The smoke was-cooled by about 1 .5 C.
15. Cigarettes whose filters were injected with 25 mcl. of
various concentrations of ethanol in water were smoked.
On the basis of puffs 4, 5, 6 and 7, the following average results were obtained:
Ethanol: Cooling, C. one 0. 505 25% 1. 22 37.5% 1. 56 50% 2. 06 67.5% 2. 52 75% 2. 26 3. 82
It will be readily seen from the tests reported in the foregoing example that a tobacco smoke filter can be obtained by positioningwithin a flexible outer wrapper, and in contact with a filler therewithin capable of entraining a cooling liquid, at least one rupturable capsule containing a liquid substantially more volatile than water, provided that the filler is substantially free of adsorbent material and free of substances sufficiently soluble in the liquid to evolve a significant amount of heat of solution when the capsule is ruptured and releases the liquid into the filler.
1. The method of effecting cooling of cigarette smoke which comprises locating a plurality of spaced, rupturable capsules containing ethanol within the body of an absorbent free filler of crepe paper at the mouth end of a cigarette, said paper being characterized by good absorbency, resiliency and wet strength, said filler being encased within an outer resilient wrapper of high wet strength and further characterized by being free of substances sufficiently soluble in the ethanol to evolve a sensible heat of solution when the ethanol is released from the capsules, said filler being highly porous so as to further constitute a smoke filter of high exposed surface area and which permits the axial flow of the cigarette smoke therethrough, said capsules being ruptured by the smoker by compression immediately prior to smoking to effect the desired cooling.
'"" UNITED S'IA'IICS PATENT OFFICE CERTIFICATE OF CORRECTION Patent No. 3 Dated December 15 1970 In n fl EDWARD s. HARLOW et '31.
It is certified that error appears in the above-identified patenl and that; said Letters Patent are hereby corrected as shown below:
Column 1 lines 44-45 "As shown in the drawing utilized in the method the filter element of the invention should be deleted.
Column 3 line 5 "en" should read -an Column 5 line 23 "plug" should read -p1us SIGNED W9 SEALED 1 an?) SEA mam-mam! Mum of mint:
|Citing Patent||Filing date||Publication date||Applicant||Title|
|US4966169 *||Jan 28, 1988||Oct 30, 1990||C. A. Blockers, Inc.||Process for manufacturing cigarettes|
|US4967772 *||Aug 13, 1987||Nov 6, 1990||C.A. Blockers, Inc.||Tobacco smoking article and treatment of tobacco smoke with at least one alcohol|
|US5016655 *||Jan 27, 1989||May 21, 1991||C.A. Blockers, Inc.||Cigarette manufacturing process|
|US7115085||Sep 12, 2003||Oct 3, 2006||R.J. Reynolds Tobacco Company||Method and apparatus for incorporating objects into cigarette filters|
|US7381277||Jul 29, 2004||Jun 3, 2008||R.U. Reynolds Tobacco Company||Flavoring a cigarette by using a flavored filter plug wrap|
|US7479098||Sep 23, 2005||Jan 20, 2009||R. J. Reynolds Tobacco Company||Equipment for insertion of objects into smoking articles|
|US7654945||Aug 4, 2006||Feb 2, 2010||R.J. Reynolds Tobacco Company||Method and apparatus for incorporating objects into cigarette filters|
|US7793665||Aug 14, 2006||Sep 14, 2010||R.J. Reynolds Tobacco Company||Filtered cigarette incorporating a breakable capsule|
|US7833146||Dec 23, 2009||Nov 16, 2010||R.J. Reynolds Tobacco Company||Method and apparatus for incorporating objects into cigarette filters|
|US7836895||Jun 23, 2003||Nov 23, 2010||R. J. Reynolds Tobacco Company||Filtered cigarette incorporating a breakable capsule|
|US7878962||May 2, 2006||Feb 1, 2011||Philip Morris Usa Inc.||Cigarettes and filter subassemblies with squeezable flavor capsule and methods of manufacture|
|US7972254||Jun 11, 2007||Jul 5, 2011||R.J. Reynolds Tobacco Company||Apparatus for inserting objects into a filter component of a smoking article, and associated method|
|US7984719||Oct 12, 2010||Jul 26, 2011||R. J. Reynolds Tobacco Company||Filtered cigarette incorporating a breakable capsule|
|US8066011||Sep 30, 2003||Nov 29, 2011||R. J. Reynolds Tobacco Company||Filtered cigarette incorporating an adsorbent material|
|US8142339||Oct 19, 2010||Mar 27, 2012||R.J. Reynolds Tabacco Company||Method and apparatus for incorporating objects into cigarette filters|
|US8186359||Feb 1, 2008||May 29, 2012||R. J. Reynolds Tobacco Company||System for analyzing a filter element associated with a smoking article, and associated method|
|US8262550||Mar 19, 2009||Sep 11, 2012||R. J. Reynolds Tobacco Company||Apparatus for inserting objects into a filter component of a smoking article|
|US8308623||Oct 28, 2008||Nov 13, 2012||R.J. Reynolds Tobacco Company||Apparatus for enhancing a filter component of a smoking article, and associated method|
|US8459272||Jan 10, 2011||Jun 11, 2013||Philip Morris Usa Inc.||Cigarettes and filter subassemblies with squeezable flavor capsule and methods of manufacture|
|US8470215||Jan 25, 2008||Jun 25, 2013||R. J. Reynolds Tobacco Company||Process for manufacturing breakable capsules useful in tobacco products|
|US8475348||Sep 28, 2010||Jul 2, 2013||Aiger Group Ag||Apparatus and method for assembly of multi-segment rod-like articles|
|US8512213||Feb 20, 2012||Aug 20, 2013||R.J. Reynolds Tobacco Company||Method and apparatus for incorporating objects into cigarette filters|
|US8574141||Aug 9, 2012||Nov 5, 2013||R.J. Reynolds Tobacco Company||Apparatus for inserting objects into a filter component of a smoking article|
|US8622882||Sep 27, 2010||Jan 7, 2014||Aiger Group Ag||Apparatus and method for insertion of capsules into filter tows|
|US8671951||Mar 26, 2010||Mar 18, 2014||Philip Morris Usa Inc.||Methods of manufacturing cigarettes and filter subassemblies with squeezable flavor capsule|
|US8739802||Oct 2, 2006||Jun 3, 2014||R.J. Reynolds Tobacco Company||Filtered cigarette|
|US8808153||Jul 14, 2009||Aug 19, 2014||Aiger Group Ag||Apparatus for assembly of multi-segment rod-like articles|
|US8820331||Jun 21, 2006||Sep 2, 2014||V. Mane Fils||Smoking device incorporating a breakable capsule, breakable capsule and process for manufacturing said capsule|
|US8882647||Dec 8, 2008||Nov 11, 2014||R.J. Reynolds Tobacco Company||Equipment for insertion of objects into smoking articles|
|US8905243||Aug 11, 2010||Dec 9, 2014||R.J. Reynolds Tobacco Company||Apparatus for sorting objects, and associated method|
|US9028385||Dec 1, 2011||May 12, 2015||R.J. Reynolds Tobacco Company||Equipment for insertion of objects into smoking articles|
|US9089163||Nov 30, 2011||Jul 28, 2015||Tobacco Research And Development Institute (Proprietary) Limited||Feed mechanism|
|US9101166||May 29, 2014||Aug 11, 2015||Tobacco Research And Development Institute (Proprietary) Limited||Feed mechanism|
|US9131730||Jan 7, 2010||Sep 15, 2015||Aiger Group Ag||System and apparatus for registration of different objects in rod shaped articles|
|US9210952||May 31, 2011||Dec 15, 2015||R.J. Reynolds Tobacco Company||Apparatus for inserting objects into a filter component of a smoking article, and associated method|
|US9247770||Aug 9, 2012||Feb 2, 2016||R.J. Reynolds Tobacco Company||Method of forming a rod for use in the manufacture of cigarette filters|
|US9282768||Jun 20, 2013||Mar 15, 2016||R.J. Reynolds Tobacco Company||Method and apparatus for incorporating objects into cigarette filters|
|US9339060||Oct 21, 2013||May 17, 2016||V. Mane Fils||Smoking device incorporating a breakable capsule, breakable capsule and process for manufacturing said capsule|
|US9398777||Jun 20, 2013||Jul 26, 2016||R.J. Reynolds Tobacco Company||Equipment for insertion of objects into smoking articles|
|US9462828||Mar 9, 2010||Oct 11, 2016||British American Tobacco (Investments) Limited||Apparatus for introducing objects into filter rod material|
|US9486010||Oct 3, 2013||Nov 8, 2016||R. J. Reynolds Tobacco Company||Apparatus for inserting objects into a filter component of a smoking article|
|US9554594||Oct 24, 2011||Jan 31, 2017||R.J. Reynolds Tobacco Company||Filtered cigarette incorporating an adsorbent material|
|US20040261807 *||Jun 23, 2003||Dec 30, 2004||Dube Michael Francis||Filtered cigarette incorporating a breakable capsule|
|US20050070409 *||Sep 12, 2003||Mar 31, 2005||Deal Philip Andrew||Method and apparatus for incorporating objects into cigarette filters|
|US20060021624 *||Jul 29, 2004||Feb 2, 2006||Brown & Williamson Tobacco Corporation||Flavoring a cigarette by using a flavored filter plug wrap|
|US20060272663 *||Aug 14, 2006||Dec 7, 2006||Dube Michael F||Filtered cigarette incorporating a breakable capsule|
|US20060293157 *||Aug 4, 2006||Dec 28, 2006||R.J. Reynolds Tobacco Company||Method and apparatus for incorporating objects into cigarette filters|
|US20070012327 *||May 2, 2006||Jan 18, 2007||Philip Morris Usa Inc.||Cigarettes and filter subassemblies with squeezable flavor capsule and methods of manufacture|
|US20070068540 *||Sep 23, 2005||Mar 29, 2007||Thomas Timothy F||Equipment for insertion of objects into smoking articles|
|US20080302373 *||Jun 11, 2007||Dec 11, 2008||R.J. Reynolds Tobacco Company||Apparatus for Inserting Objects into a Filter Component of a Smoking Article, and Associated Method|
|US20090050163 *||Jun 21, 2006||Feb 26, 2009||Didier Hartmann||Smoking device incorporating a breakable capsule, breakable capsule and process for manufacturing said capsule|
|US20090208568 *||Jun 21, 2006||Aug 20, 2009||V Mane Fils||Gellan Seamless Breakable Capsule and Process for Manufacturing Thereof|
|US20100089149 *||Mar 18, 2009||Apr 15, 2010||Automation And Control Technology, Inc||System and process for non-destructive density and moisture inspection|
|US20100294290 *||Jan 25, 2008||Nov 25, 2010||Wenhui Zhang||Process for manufacturing breakable capsules useful in tobacco products|
|US20110023896 *||Oct 12, 2010||Feb 3, 2011||R. J. Reynolds Tobacco Company||Filtered cigarette incorporating a breakable capsule|
|US20110059831 *||Oct 19, 2010||Mar 10, 2011||R.J. Reynolds Tobacco Company||Method and apparatus for incorporating objects into cigarette filters|
|US20110100387 *||Jan 10, 2011||May 5, 2011||Philip Morris Usa Inc.||Cigarettes and filter subassemblies with squeezable flavor capsule and methods of manufacture|
|US20110230320 *||May 31, 2011||Sep 22, 2011||R.J. Reynolds Tobacco Company||Apparatus for inserting objects into a filter component of a smoking article, and associated method|
|US20110232659 *||Mar 26, 2010||Sep 29, 2011||Philip Morris Usa Inc.||Methods of manufacturing cigarettes and filter subassemblies with squeezable flavor capsule|
|US20140209111 *||May 11, 2012||Jul 31, 2014||British American Tobacco (Investments) Limited||An additive release assembly, a filter for a smoking article, a smoking article and a method of manufacturing|
|US20140360518 *||Nov 2, 2012||Dec 11, 2014||Philip Morris Products S.A.||Smoking article with liquid delivery material|
|EP2537426A2||Sep 18, 2006||Dec 26, 2012||R. J. Reynolds Tobacco Company||Equipment for insertion of objects into smoking articles|
|EP2554060A1||Aug 1, 2011||Feb 6, 2013||JT International S.A.||Filter element incorporating a breakable capsule, method of manufacturing a cigarette having a filter element incorporating a breakable capsule and apparatus for manufacturing the cigarette having a filter element incorporating a breakable capsule|
|WO2007038053A1||Sep 18, 2006||Apr 5, 2007||R.J. Reynolds Tobacco Company||Equipment for insertion of objects into smoking articles|
|WO2010107756A1||Mar 16, 2010||Sep 23, 2010||R. J. Reynolds Tobacco Company||Apparatus for inserting objects into a filter component of a smoking article, and associated method|
|WO2011094171A1||Jan 25, 2011||Aug 4, 2011||R. J. Reynolds Tobacco Company||Apparatus and associated method for forming a filter component of a smoking article|
|WO2012021638A2||Aug 10, 2011||Feb 16, 2012||R. J. Reynolds Tobacco Company||Apparatus for sorting objects, and associated method|
|WO2013017624A1||Aug 1, 2012||Feb 7, 2013||Jt International S.A.||Filter element incorporating a breakable capsule, method of manufacturing a cigarette having a filter element incorporating a breakable capsule and apparatus for manufacturing the cigarette having a filter element incorporating a breakable capsule|
|WO2013027066A3 *||Aug 24, 2012||Aug 1, 2013||British American Tobacco (Investments) Limited||Smoking article filter with a cooling system|
|U.S. Classification||131/337, 131/274|
|International Classification||A24D3/00, A24D3/06|
|Nov 26, 1986||AS||Assignment|
Owner name: AMERICAN TOBACCO COMPANY, THE
Free format text: MERGER;ASSIGNOR:AMERICAN BRANDS, INC., A NJ. CORP. (MERGED INTO);REEL/FRAME:004666/0798
Effective date: 19851219