|Publication number||US3558052 A|
|Publication date||Jan 26, 1971|
|Filing date||Oct 31, 1968|
|Priority date||Oct 31, 1968|
|Publication number||US 3558052 A, US 3558052A, US-A-3558052, US3558052 A, US3558052A|
|Inventors||Dunn John P|
|Original Assignee||F I N D Inc|
|Export Citation||BiBTeX, EndNote, RefMan|
|Patent Citations (6), Referenced by (100), Classifications (16)|
|External Links: USPTO, USPTO Assignment, Espacenet|
United States Patent  lm entor John P. Dunn Elmira, NY.  Appl. No. 772,320 [22 Filed Oct. 31. 1968  Patented Jan. 26, 1971  Assignee F.1.N.D.1nc. Elmira, N.Y. a corporation of New York  METHOD AND APPARATUS FOR SPRAYING ELECTROSTATIC DRY POWDER 19 Claims, 10 Drawing Figs.
 US. Cl 239/3, 239/124:117/93.4  Int. Cl B05b 5/02  Field ofSearch 239/3,15. 379, 124; 222/193, 318;51/8. l l; l18/30831 l, (Church),93.4;117/17 [561 References Cited UNITED STATES PATENTS 3,000,752 9/1961 Jackson et a1. 117/17 2,900,138 8/1959 Strate 239/85(X) Primary ExuminerLloyd L. King Assistant Examiner fiene A. Church AltarneySughrue, Rot-l well, Mion, Zinn and Macpeak ABSTRACT: Dry nonconductive powder passes from a hopper by means of a vibrating plate through an adjustable, nonclogging eductor and is directed by means of a current of air issuing through a rectangular orifice from a variable volume plenum chamber into a venturi. The powder particles pass into the entrance of the venturi in a stream of air having a rectangular flow pattern or cross section and from the venturi through a discharge nozzle and from the discharge nozzle onto a substrate to be coated. Corona wires are located in the proximity of the issuing end of the discharge nozzle so as to charge the powder particles in order to direct them onto a substrate. A positive draft is maintained downstream from the venturi entrance and serves to pick up excess powder particles which are pneumatically conveyed back to the feed hopper.
SHEET 2 OF 2 Hes INVENTOR JOHN PAUL DUNN ATTORNEYS METHOD AND APPARATUS FOR SPRAYING ELECTROSTATIC DRY POWDER BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates broadly to the field of spraying dry nonconductive powders onto various substrates for coating purposes and, more particularly, to an apparatus which pneumatically conveys the powder particles in a patterned flow through a discharge nozzle, into an area were the powder particles are charged and finally directed onto the surface of a substrate to be coated.
2. Prior Art The broad concept of directing dry particles of powder or like material onto a substrate through the .use of a directed flow of air or like conveying fluid is generally well-known in the art. However, in the practice of these prior art methods and associated devices directed to the electrostatic spraying of dry nonconductive powders, difliculties are often encountered in attempting to apply coating of uniform thickness and density. It is generally recognized that uniformity of the deposited coating of powder can best be accomplished if the spray consists of discrete and evenly dispersed particles, flowing through and from the discharge nozzle at a uniform rate.
Prior art systems encounter problems of uniform coating in that the resultant spray is a mixture of discrete and agglomerated particles A number of limitations on the existing spray systems are caused directly by the high specific gravity of the powder or like materials being sprayed. A powder having a high specific gravity has a tendency to settle and collect or buildup within the apparatus of the spray system. This, of course, tends to clog the discharge nozzles and other delivery conduits through which the powders are being pneumatically conveyed. To overcome this settling problem, prior art-spraying systems have utilized high velocity fluid flow for conveying the powder particles. This, in turn, has created a number of additional problems which also leads to a nonuniform coating of the particles onto the desired substrate. To overcome this settling problem, the velocities of the conveying air or fluid, and consequently, the velocities of the conveyed powder particles, are normally greater than 600 feet per minute and often reach a velocity in excess of 1000 feet per minute. The flow of air and powder at this velocity through the discharge nozzles of the spraying devices, while eliminating the problem of settling within the nozzles, created turbulence and resulted in the particles striking the desired substrate with such force as to bounce off or ricochet from the surface of the substrate thereby creating an uneven coating. Consequently, the existing spray systems are limited to spraying powders having a specific density in a somewhat limited range because spraying powders having a relatively high specific density necessitates the need of a high velocity air flow resulting in the above-mentioned problems.
SUMMARY OF THE INVENTION This invention relates to a spray system for spraying dry nonconductive powder particles uniformly onto various substrates. The apparatus of the invention includes a feed bin containing dry powder particles which is delivered into the air stream of an eductor system. The powder cascades, in the shape of a substantially uniform ribbon of powder, downwardly through the eductor system to a point where it is picked up by an airjet issuing from a variable volume plenum chamber through a rectangular orifice. The air jet directs the powder particles into the entrance of a rectangular-shaped venturi where the particles are evenly dispersed through the action of the air jet and the pressure differential created by the venturi. The powder continues to flow through a rectangularshaped issuing nozzle and the particles are eventually charged by corona or like conducting wires arranged in the proximity of the issuing end of the nozzle. The charge particles are then attracted to the oppositely charged substrate to provide an even coating on the surface of the substrate.
The quantity of powder delivered to the surface of the sub strate is proportional to the rate of powder feed into the eductor system. to the velocity of the air or other conveying fluid and to the volume of conveying fluid which is a function of the plenum chamber orifice. Consequently, in the present invention. the necessity for a high velocity gas flow is eliminated through the use of a gas plenum orifice having a rectangularshape and by delivering a uniform curtain or ribbon of powder to the entrance to the venturi section.
The purpose of combining a system using a ribbon of powder and a powder delivery system having a rectangular cross section is to overcome the problems encountered when converting a flow of powder having a circular cross section into a flow powder having a rectangular flow pattern or cross section. When converting a circular flow pattern to a rectangular flow pattern, a larger pressure differential occurs causing a particle velocity differential across the section or pattern of the flow. This results in a nonuniform flow and also in a nonuniform deposition of the powder onto the substrate. The present invention minimizes this pressure differential and creates an even laminar flow of powder by forming the desired crosssectional pattern in the flow of powder at the entrance to the venturi and accordingly designing the nozzle section following the venturi so as to maintain the laminar flow.
If the powder delivered to the venturi has a circular crosssectional pattern, then the flow of powder traveling in the marginal portions of the circular cross section are traveling at a slower velocity than the flow of powder traveling in the central portion of the circular cross section. If the powder traveling through the system has a sufficiently high specific gravity, the slower velocity powder has a tendency to settle which results in clogging of the system as previously mentioned. Consequently, to prevent settling, the velocity of the powder in the slower traveling portions of the circular pattern flow is increased resulting in a proportional increase of the powder in the central portion of the circular pattern. This greatly increased powder velocity creates the problem of bounding or ricocheting of the particles from the substrate as previously described. When a relatively uniform rectangular cross section of powder is delivered to the venturi the powder in all portions of the cross-sectional pattern are traveling at approximately the same rate, consequently, the conveying gas may be allowed to travel at a relatively lower velocity without the worry of clogging of the system due to the settling of powders having a high specific gravity. While it is recognized that when spraying powders having a relatively high specific gravity, the velocity of the conveying gas will have to be increased, the present invention eliminates the need of a relatively high velocity gas which results in the problems previously described.
BRIEF DESCRIPTION OF THE DRAWINGS FIG. 1 s a side elevation view of the spray system with a partial sectional view of the eductor and delivery portions of the apparatus;
FIG. 2 is a top plan view of the nozzle and corona wire support means;
FIG. 3 is a cross-sectional view taken on line 3-3 of FIG. I through the plenum chamber viewing the plenum chamber orifice;
FIG. 4 is an enlarged top longitudinal sectional view taken on line 4-4 of fig. l of the plenum chamber, plenum chamber orifice and venturi portion;
FIG. 5 is a side sectional view of a delivery nozzle arranged to coat a substrate passing the discharge end of the nozzle in a horizontal plane;
FIG. 6 is a top plan view of FIG. 5;
FIGS. 7 and 8 are perspective views of two embodiments of a corona wire or like electrode structure which may be used with the present invention;
FIG. 9 is a perspective view of yet another embodiment of a corona wire arranged in the proximity of the discharge end of the nozzle, and
FIG. is a side elevational partially schematic view of a plurality ofdischarge nozzles operated from a central eductor.
DESCRIPTION OF PREFERRED EMBODIMENTS The apparatus of the present invention comprises a feed hopper I0 arranged above a vibrating pan I2 which is activated into vibrating movement by a vibrating source [4. FIG. 1. The vibrating pan I2 communicates directly with the upper portion of eductor I6. The width of the eductor can be ad justed to vary in proportion to the size of the substrate and accordingly the quantity of powder to be ejected. The eductor communicates and leads past orifice plate 34 in which is located rectangular orifice 32. During operating, a jet of air is directed from variable volume chamber 24 through rectangu lar orifice 32 into the entrance of venturi 36. The rectangular orifice 32 and the entrance 35 of the venturi 36 are axially aligned and are located on opposite sides of the eductor 16. The variable volume plenum chamber 24 includes an air inlet conduit 26 channeling air into the variable volume chamber 24 from a source which is not shown. The conduit 26 is supported within the housing 22 by a support member 28 and is maintained in proper position by set screw 30.
FIG. 4 is an enlarged view of the plenum chamber and orifice plate 34. The orifice plate 34 is removably mounted within the spray housing so as to be able to change the size of the orifice opening 32. The adjustable mounting means include various notches 36 formed by a plurality of ribs 38 arranged on each of the internal walls of housing 22. Altemately to the embodiment shown in FIG. 4, the air plenum chamber itself may be movably mounted within the spray housing by mechanically securing together plates 28 and 34 which define the chamber 24 so that they may be movably mounted as a unit but immovable relative to one another. In other words, plate 28 could be mechanically connected to orifice plate 3 that longitudinal sliding movement of plate 28 would result in the movement of plate 34 either towards or away from the falling ribbon of powder 18. The effect of the relative position of plate 34 to the ribbon of falling powder 18 will be described in greater detail later.
The eductor 16 has a lower portion 17 in which a positive draft is created through an air flow entering through conduit 19 and check valve 21 from a source which is not shown. A second venturi 23 is connected by coupling 37 to the lower portion 17 of the eductor. A current of air is directed into the entrance of venturi 23 through conduit 27 from a source which is not shown. Coupled to the exiting orifice 31 is a funnel or conical-shaped member 39 and a powder return conduit 29. The return conduit 29 extends from the second venturi to the feed hopper l0 and serves to deliver by recirculation the excess powder particles which were not taken into the entrance 35 of the first venturi 36. The feed hopper has a vent such as a screen top 41 so that pressure of the delivery stream can be relieved.
As previously mentioned, the entrance 35 of the venturi 36 is arranged in axial alignment and on opposite sides of eductor 16. A discharge nozzle 38 having a rectangular cross section has a connection 40 to the diverging outlet 43 of the venturi 36.
Corona wires or like conducting wires 42 are mounted on a forklike structure 4 in close proximity and behind the outlet 46 of nozzle 38. The forklike mounting structure 44 of corona wire 42 is itself supported by arm member 48 which is adjustably attached by pivotal mount 50 secured to the housing of the venturi by braces 52, or like mounting means, and which may be manually adjusted by knob 54 FIGS. 5 and 6 show an additional embodiment of the present invention comprising another shaped nozzle 55 attached to venturi 36. The nozzle 55 of this embodiment also has a rectangular cross section and is positioned to coat a substrate passing the exit 58 of the nozzle in a horizontal direction. Consequently, the longitudinal sides of orifice 58 are arranged in a vertical plan rather than in a horizontal plane as shown in FIGS. I and 2. It should be noted that entrance 57 to nozzle 55, as well as any other nozzle useable with the device ofthe present invention. has the same configuration as nozzle 38 of FIGS. l and 2, so as to allow rapid removal and insertion of dilierent nozzles when a change in nozzles is desired.
FIGS. 8 and 9 are directed to different embodiments of a corona or like conductor used to create the ionization field between the outlet of the discharge nozzle and the substrate. FIG. 8 shows a plurality of electrodes 60 arranged on a crossbar support 62 which is attached to a supporting arm 64 in a manner similar to that previously described in the embodiments shown in FIGS. I and 2. FIG. 9 is an embodiment ofthe present invention which includes the arrangement of corona wires 66 in a rectangular-shape in the proximity of but behind the exit 46 of discharge nozzle 38. The wires 66 are supported in a generally rectangular-shape by means of support arms 68 which may or may not be attached to the housing of the spray device. The designations AL indicated in FIGS. 8 and 9 represent the length of the corona wires or distances between the electrodes which may be varied in order to effect the spray pattern issuing from the orifice 46 of the nozzle. as will be more fully explained later.
FIG. [0 discloses another embodiment ofthe present invention which includes a plurality of nozzles 70, 72 and 74 directing powder or like material onto a vertically traveling substrate 76. Each of the nozzles is associated with a separate variable volume plenum chamber and venturi generally indicated at 76, 78 and 80, and operate in the same manner as the embodiment shown in FIG. I. All of the nozzles, however, can operate from acommon feed hopper 84 and common eductor arrangement 82 and are serviced by a common return system generally indicated at 86.
The operation of the preferred embodiment shown in FIG. I will now be described and will substantially the same as the operation of the system utilizing the various embodiments shown in FIGS. 5 through I0.
The powder particles are delivered by means of gravity from feed hopper 10 into the fibrating screen or tray 12. The dry powder particles are delivered into the upper portion of eductor I6 in a substantially uniform curtain or ribbon I8. The uniform ribbon of powder then passes into the air jet issuing from variable volume plenum chamber 24 through rectangular orifice 32. As explained previously, the position of orifice plate 34 may be varied relative to the position of the falling ribbon of powder 18 and the entrance 35 to the venturi. By ad justing the distance between the orifice plate 34 and the ribbon of falling powder, the position of the intersection between the air stream issuing from orifice 32 and the powder curtain is changed. Accordingly, the point of intersection between the issuing stream of air and the powder curtain determines the air flow pattern entering the venturi entrance 35. Consequently, a regulation of the powder transfer and the powder dispersion is established by changing the intersection between the directed flow of air and the falling curtain of powder.
For example, considering that the position of the falling curtain of powder is relatively fixed in relation to the air chamber orifice 32 and the venturi entrance 35 and further assuming that the cross-sectional area of the falling curtain of powder is generally constant, then by adjusting the air chamber orifice plate 34 closer to or away from the powder curtain, the ratio of powder sprayed into the entrance to the venturi in relation to the amount returned through the return portion of the eductor 17 can be regulated. It is obvious that the current of air issuing from orifice 32 starts to diverge immediately upon clearing orifice 32. Consequently, it is apparent that the farther away orifice plate 34 is from the falling curtain of powder, the larger the air flow pattern of the issuing air current will be when it intersects the falling curtain of powder. This results in a larger patter and increased cased amount of particles traveling in the air flow beyond the point of intersection.
A flow of particles having the desired cross-sectional flow pattern then enters the venturi 36 where separation of the particles occurs. The principle of using a converge-diverge member or venturi section is to cause particle separation by virtue of the air velocity differential and the shear force established by the venturi. The particles then flow into the entrance of nozzle 38 which also has a rectangular cross section as described above. the dry nonconductive powder particles issue from orifice 46 of nozzle 38 where they may be charged due to the action on the particles by a corona wire 42 or like conductive wire.
The charging electrodes have been made adjustable and interchangeable to control the patterns of the flow of particles as they issue from the exit 46 and are deposited onto the surface of a substrate (not shown). By changing the dimensions and/or position of the charging electrode, the electric field distribution established between the electrode and the substrate is also changed, resulting in the ability to establish various spray patterns which may adequately serve to coat difficulty shaped parts or substrates. lt is also important to note that the charging electrodes 42 are arranged behind the nozzle orifice in order to prevent powders from adhering to the fine wires. Dust or powders accumulating on these electrodes reduce their operating efficiency which eventually results in wire breakdown and a nonuniform coating. ln the specific embodiment shown in FIG. 1, the arms 48 are connected directly to a pivoted mount 50 which may be manually adjusted by means of knob 54. Consequently, the conducting wires 42 are allowed to move in an are which, as previously mentioned. varies the pattern of the issuing powder particles. The pattern of the issuing particles may also be varied by changing the length AL (FIGS. 8 and 9) of the conductor wires thereby changing the ionization field between the issuing orifice 46 of the nozzle and the substrate.
Only a portion of those particles cascading from vibrating screen 12 into the upper portion of eductor 16 are picked up by the air jet issuing from orifice 32. The excess particles fall through the lower portion 17 of the eductor and, if necessary, their travel may be aided by a positive draft by an air flow-entering portion 17 through an inlet conduit 19. The air is provided from a source which is not shown and may be controlled by check valve 21. Due to the positive draft, the excess particles fall into a second venturi 23 into which a stream of air is directed from a source not shown through inlet conduit 27. The particles are directed into return conduit 29 through which they are conveyed back to the feed hopper for reuse. Although air has been mentioned as the carrier gas, it will be apparent that other gases, preferably inert to the powder and substrate, could be used. Further, the invention can, if desired, be utilized without the corona discharge wires.
l. A dry powder spray apparatus comprising;
a. a spray housing including a venturi with a powder-gas entrance;
b. a gas inlet for admitting gas under pressure to the housing, a gas inlet chamber directly communicating with the gas inlet and located ahead of the venturi, the gas from said inlet directed toward the venturi through the gas inlet chamber;
c. a powder inlet to the spray housing above the inlet chamber, positioned such that the powder falling by gravity from the powder inlet is picked up by the gas flowing from the gas inlet into the venturi, and
. an excess powder exit from the spray housing below the powder inlet and the gas inlet chamber so that the excess powder which has not been picked up by the entering gas may flow from the housing.
2. Apparatus as in claim I further comprising a nozzle attached to the venturi exit.
3. Apparatus as in claim 2 wherein the nozzle is interchangeable with other nozzles having different crosssectional outlet openings and the same inlet openings cooperating with the venturi exit end.
4. Spray apparatus as in claim 1 wherein the venturi is rectangular in cross section and the venturi entrance is rectangular in section.
5. Apparatus as in claim 1 wherein one wall of the gas inlet chamber has an orifice therein through which gas is directed into the venturi entrance, the wall being adjustable to vary the gas flow pattern of the gas entering the venturi entrance.
6. A spray apparatus as in claim 5 wherein the adjustable wall is movable relative to the venturi entrance.
7. A spray apparatus as in claim 1 wherein one wall of the gas inlet chamber has an orifice therein through which gas is directed into the venturi entrance, the gas inlet chamber movably mounted within the spray housing, whereby said wall is adjustably positioned relative to the falling powder so as to vary the pattern of gas entering the venturi entrance.
8. A spray apparatus as in claim I further comprising a return eductor connected to the excess powder exit for returning excess powder to a powder feed means.
9. A spray apparatus as in claim 8 further comprising: a gas inlet in the excess powder exit prior to the return system whereby said inlet creates a positive draft serving to guide the excess powder into he return eductor system.
10. A spray apparatus as in claim I wherein the powder feed means includes a powder hopper. a vibratory screen, and a conduit connected to the powder inlet.
11. An apparatus as in claim 1 wherein particle charging conductors are mounted adjacent the powder exit but upstream from the powder exit.
12. An apparatus as in claim 9 wherein said conducting wires are mounted so as to completely surround the powder exit.
13. An apparatus as defined in claim 12 wherein said conductors are arranged in a rectangular configuration.
14. A spray apparatus as defined in claim 13 wherein the conductors are adjustably attached to the outside of the spray housing.
IS. A spray apparatus as defined in claim 14 wherein a conductor is supported by an arm pivotally mounted on the spray housing so as to be capable of positioning said conductor in one of a number of positions along an arcuate path in the proximity of the powder exit.
l6. An apparatus as in claim I wherein there are a number of spray housings connected in series with a single feed hopper and a common eductor system.
17. A method for the electrostatic spraying of dry particles onto a substrate, said method comprising:
a. feeding by gravity a uniform ribbon of powder particles past a directed gas flow; V
b. forming a directed gas flow having a specifically and uniformly shaped cross section;
c. directing said gas flow onto the flow of particles traveling transversely to said directed gas flow;
d. directing a portion of said powder particles carried by said gas flow and said gas flow into a venturi;
e. conveying powder particles not carried by the gas flow into the venturi to recycle the powder particled;
f. separating the powder particles in the venturi from each other through the action of the venturi;
g. guiding the particles into an electrical charging zone adjacent the venturi outlet, and
h. charging said particles and directing them onto a substrate.
18. A method of spraying particles as described in claim 17 further comprising forming said gas flow so as to have a rectangular cross section whereby said flow of particles in the venturi has a rectangular cross section.
19. Apparatus as in claim 1, wherein the gas flow for carrying powder is less than 600 feet per second.
|Cited Patent||Filing date||Publication date||Applicant||Title|
|US2900138 *||Apr 5, 1954||Aug 18, 1959||Strate Frank R||Metal powder welding apparatus|
|US3000752 *||Dec 30, 1957||Sep 19, 1961||Armco Steel Corp||Coating metallic sheet or strip material with powdered annealing separator substances|
|US3132967 *||Nov 3, 1961||May 12, 1964||Rheem Mfg Co||Method and apparatus for applying a material to an object|
|US3195264 *||Oct 1, 1963||Jul 20, 1965||Martha W Chapman||Nozzle for electrostatic dusting devices|
|US3212217 *||May 28, 1963||Oct 19, 1965||Tex Tube Inc||Cleaning device|
|US3237805 *||Oct 28, 1964||Mar 1, 1966||Halliburton Co||Method and apparatus for dispensing particulate material|
|Citing Patent||Filing date||Publication date||Applicant||Title|
|US3630441 *||Oct 30, 1970||Dec 28, 1971||Tunzini Sames||Electrostatic spraying apparatus|
|US3793049 *||May 25, 1971||Feb 19, 1974||R Probst||Electrostatic coating method|
|US3866571 *||Aug 15, 1973||Feb 18, 1975||Nat Steel Corp||Apparatus for electrostatically depositing a uniform coating of finely divided coating material on moving substrates|
|US3871580 *||Aug 8, 1973||Mar 18, 1975||Plastic Coatings Ltd||Electrostatic spraying|
|US3951340 *||Feb 8, 1973||Apr 20, 1976||Air-Industrie||Electrostatic powder projection system and method|
|US4110486 *||Sep 24, 1976||Aug 29, 1978||Adrien Lacchia||Electrostatic powder coating method|
|US4314669 *||Nov 13, 1979||Feb 9, 1982||Gema Ag||Method for spraying powdered to granular bulk material|
|US4770344 *||Dec 8, 1986||Sep 13, 1988||Nordson Corporation||Powder spraying system|
|US4905953 *||Oct 4, 1988||Mar 6, 1990||Jewell Wilson||Fifth wheel stabilizer|
|US4922651 *||Nov 25, 1987||May 8, 1990||Dfc New Zealand Limited||Apparatus for effecting or improving pollination of plants|
|US4971829 *||Jun 6, 1988||Nov 20, 1990||Canon Kabushiki Kaisha||Spraying process for corona charges spacer material and attracting the same to plate having an electrical potential|
|US5069221 *||Jun 18, 1990||Dec 3, 1991||Densa Limited||Displacement sensor and medical apparatus|
|US5297734 *||Oct 11, 1991||Mar 29, 1994||Toda Koji||Ultrasonic vibrating device|
|US5356577 *||May 21, 1993||Oct 18, 1994||Dr. Karl Thomae Gmbh||Controlled release of metered quantities of finely divided solids with a venturi nozzle and regulated control|
|US5456829 *||Mar 11, 1993||Oct 10, 1995||William Fishman||Method and apparatus for recycling wastewater|
|US5474609 *||Jun 30, 1992||Dec 12, 1995||Nordson Corporation||Methods and apparatus for applying powder to workpieces|
|US5520735 *||Sep 20, 1994||May 28, 1996||Nordson Corporation||Nozzle assembly and system for applying powder to a workpiece|
|US5612096 *||Apr 25, 1995||Mar 18, 1997||Nordson Corporation||Methods and apparatus for applying powder to workpieces|
|US5624690 *||Jun 1, 1995||Apr 29, 1997||Dr. Karl Thomae Gmbh||Controlled release of metered quantities of finely divided solids with a venturi nozzle and regulated control|
|US5908162 *||Feb 25, 1998||Jun 1, 1999||Nordson Corporation||Spray gun having an anti-back-ionization probe with a control system therefor|
|US5938117 *||Apr 5, 1995||Aug 17, 1999||Aerogen, Inc.||Methods and apparatus for dispensing liquids as an atomized spray|
|US5938126 *||Mar 23, 1998||Aug 17, 1999||Nordson Corporation||Spray gun having a current monitored anti-back-ionization probe|
|US5957396 *||Oct 28, 1997||Sep 28, 1999||Nordson Corporation||Mounting assembly for spray gun with anti-back-ionization probe|
|US6014970 *||Jun 11, 1998||Jan 18, 2000||Aerogen, Inc.||Methods and apparatus for storing chemical compounds in a portable inhaler|
|US6205999||Sep 8, 1998||Mar 27, 2001||Aerogen, Inc.||Methods and apparatus for storing chemical compounds in a portable inhaler|
|US6235177||Sep 9, 1999||May 22, 2001||Aerogen, Inc.||Method for the construction of an aperture plate for dispensing liquid droplets|
|US6467476||May 18, 2000||Oct 22, 2002||Aerogen, Inc.||Liquid dispensing apparatus and methods|
|US6540153||May 27, 1999||Apr 1, 2003||Aerogen, Inc.||Methods and apparatus for dispensing liquids as an atomized spray|
|US6543443||Jul 12, 2000||Apr 8, 2003||Aerogen, Inc.||Methods and devices for nebulizing fluids|
|US6546927||Mar 13, 2001||Apr 15, 2003||Aerogen, Inc.||Methods and apparatus for controlling piezoelectric vibration|
|US6550472||Mar 16, 2001||Apr 22, 2003||Aerogen, Inc.||Devices and methods for nebulizing fluids using flow directors|
|US6554201||May 2, 2001||Apr 29, 2003||Aerogen, Inc.||Insert molded aerosol generator and methods|
|US6629646||Dec 7, 1993||Oct 7, 2003||Aerogen, Inc.||Droplet ejector with oscillating tapered aperture|
|US6640804||Aug 15, 2002||Nov 4, 2003||Aerogen, Inc.||Liquid dispensing apparatus and methods|
|US6732944||May 2, 2001||May 11, 2004||Aerogen, Inc.||Base isolated nebulizing device and methods|
|US6755189||May 18, 1999||Jun 29, 2004||Aerogen, Inc.||Methods and apparatus for storing chemical compounds in a portable inhaler|
|US6782886||Mar 20, 2001||Aug 31, 2004||Aerogen, Inc.||Metering pumps for an aerosolizer|
|US6852948||Jun 13, 2001||Feb 8, 2005||Thermark, Llc||High contrast surface marking using irradiation of electrostatically applied marking materials|
|US6855910||Nov 6, 2001||Feb 15, 2005||Thermark, Llc||High contrast surface marking using mixed organic pigments|
|US6926208||May 2, 2003||Aug 9, 2005||Aerogen, Inc.||Droplet ejector with oscillating tapered aperture|
|US6948491||Mar 20, 2001||Sep 27, 2005||Aerogen, Inc.||Convertible fluid feed system with comformable reservoir and methods|
|US6978941||Apr 9, 2004||Dec 27, 2005||Aerogen, Inc.||Base isolated nebulizing device and methods|
|US7032590||Jan 5, 2004||Apr 25, 2006||Aerogen, Inc.||Fluid filled ampoules and methods for their use in aerosolizers|
|US7040549||Mar 21, 2003||May 9, 2006||Aerogen, Inc.||Systems and methods for controlling fluid feed to an aerosol generator|
|US7066398||Mar 30, 2001||Jun 27, 2006||Aerogen, Inc.||Aperture plate and methods for its construction and use|
|US7083112||Jun 6, 2005||Aug 1, 2006||Aerogen, Inc.||Method and apparatus for dispensing liquids as an atomized spray|
|US7100600||Mar 20, 2001||Sep 5, 2006||Aerogen, Inc.||Fluid filled ampoules and methods for their use in aerosolizers|
|US7104463||Oct 6, 2005||Sep 12, 2006||Aerogen, Inc.||Base isolated nebulizing device and methods|
|US7108197 *||May 9, 2005||Sep 19, 2006||Aerogen, Inc.||Droplet ejector with oscillating tapered aperture|
|US7134618 *||Dec 3, 2003||Nov 14, 2006||Honda Motor Co., Ltd||Dry powder injector|
|US7174888||Sep 5, 2003||Feb 13, 2007||Aerogen, Inc.||Liquid dispensing apparatus and methods|
|US7195011||Jun 30, 2004||Mar 27, 2007||Aerogen, Inc.||Convertible fluid feed system with comformable reservoir and methods|
|US7201167||Mar 14, 2005||Apr 10, 2007||Aerogen, Inc.||Method and composition for the treatment of lung surfactant deficiency or dysfunction|
|US7267121||Sep 30, 2004||Sep 11, 2007||Aerogen, Inc.||Aerosol delivery apparatus and method for pressure-assisted breathing systems|
|US7290541||Jun 30, 2004||Nov 6, 2007||Aerogen, Inc.||Aerosol delivery apparatus and method for pressure-assisted breathing systems|
|US7322349||Jun 18, 2003||Jan 29, 2008||Aerogen, Inc.||Apparatus and methods for the delivery of medicaments to the respiratory system|
|US7331339||Nov 23, 2004||Feb 19, 2008||Aerogen, Inc.||Methods and systems for operating an aerosol generator|
|US7360536||Jan 7, 2003||Apr 22, 2008||Aerogen, Inc.||Devices and methods for nebulizing fluids for inhalation|
|US7600511||Oct 30, 2002||Oct 13, 2009||Novartis Pharma Ag||Apparatus and methods for delivery of medicament to a respiratory system|
|US7628339||May 5, 2006||Dec 8, 2009||Novartis Pharma Ag||Systems and methods for controlling fluid feed to an aerosol generator|
|US7677467||Apr 20, 2005||Mar 16, 2010||Novartis Pharma Ag||Methods and devices for aerosolizing medicament|
|US7748377||Oct 30, 2007||Jul 6, 2010||Novartis Ag||Methods and systems for operating an aerosol generator|
|US7771642||Apr 1, 2005||Aug 10, 2010||Novartis Ag||Methods of making an apparatus for providing aerosol for medical treatment|
|US7814933 *||Nov 29, 2004||Oct 19, 2010||Samsung Electronics Co., Ltd.||Apparatus and method for stabilizing concentration of aerosol|
|US7946291||Apr 20, 2004||May 24, 2011||Novartis Ag||Ventilation systems and methods employing aerosol generators|
|US7971588||Mar 24, 2005||Jul 5, 2011||Novartis Ag||Methods and systems for operating an aerosol generator|
|US8196573||Jan 23, 2008||Jun 12, 2012||Novartis Ag||Methods and systems for operating an aerosol generator|
|US8235692 *||Dec 21, 2007||Aug 7, 2012||Kikusui Seisakusho Ltd.||Nozzle structure|
|US8336545||Jan 16, 2007||Dec 25, 2012||Novartis Pharma Ag||Methods and systems for operating an aerosol generator|
|US8398001||Jun 19, 2006||Mar 19, 2013||Novartis Ag||Aperture plate and methods for its construction and use|
|US8539944||Apr 8, 2008||Sep 24, 2013||Novartis Ag||Devices and methods for nebulizing fluids for inhalation|
|US8561604||Feb 12, 2007||Oct 22, 2013||Novartis Ag||Liquid dispensing apparatus and methods|
|US8578931||Apr 18, 2000||Nov 12, 2013||Novartis Ag||Methods and apparatus for storing chemical compounds in a portable inhaler|
|US8616195||Apr 27, 2004||Dec 31, 2013||Novartis Ag||Nebuliser for the production of aerosolized medication|
|US8684284||Nov 26, 2007||Apr 1, 2014||Honda Motor Co., Ltd.||Injector for large amount of aerosol powder for synthesis of carbon nanotubes|
|US9027506||May 2, 2011||May 12, 2015||Nordson Corporation||Dense phase powder coating system for containers|
|US9108211||Apr 17, 2006||Aug 18, 2015||Nektar Therapeutics||Vibration systems and methods|
|US20010013554 *||Mar 30, 2001||Aug 16, 2001||Scott Borland||Aperture plate and methods for its construction and use|
|US20040139968 *||Jan 5, 2004||Jul 22, 2004||Aerogen, Inc.||Fluid filled ampoules and methods for their use in aerosolizers|
|US20040188534 *||Apr 9, 2004||Sep 30, 2004||Aerogen, Inc.||Base isolated nebulizing device and methods|
|US20040256488 *||Jun 30, 2004||Dec 23, 2004||Aerogen, Inc.||Convertible fluid feed system with comformable reservoir and methods|
|US20050011514 *||Apr 27, 2004||Jan 20, 2005||Aerogen, Inc.||Nebuliser for the production of aerosolized medication|
|US20050118110 *||Nov 29, 2004||Jun 2, 2005||Samsung Electronics Co., Ltd.||Apparatus and method for stabilizing concentration of aerosol|
|US20050121545 *||Dec 3, 2003||Jun 9, 2005||Avetik Harutyunyan||Dry powder injector|
|US20050172954 *||Nov 23, 2004||Aug 11, 2005||Aerogen Inc.||Methods and systems for operating an aerosol generator|
|US20050178847 *||Apr 1, 2005||Aug 18, 2005||Aerogen, Inc.||Methods of making an apparatus for providing aerosol for medical treatment|
|US20050199236 *||Apr 20, 2005||Sep 15, 2005||Aerogen, Inc.||Methods and devices for aerosolizing medicament|
|US20050205089 *||Jan 19, 2005||Sep 22, 2005||Aerogen, Inc.||Methods and devices for aerosolizing medicament|
|US20050217666 *||Mar 24, 2005||Oct 6, 2005||Aerogen, Inc.||Methods and systems for operating an aerosol generator|
|US20050229926 *||Mar 14, 2005||Oct 20, 2005||Aerogen, Inc.||Method and composition for the treatment of lung surfactant deficiency or dysfunction|
|US20050229928 *||Jun 30, 2004||Oct 20, 2005||Aerogen, Inc.||Aerosol delivery apparatus and method for pressure-assisted breathing systems|
|US20050263608 *||May 9, 2005||Dec 1, 2005||Aerogen, Inc.||Droplet ejector with oscillating tapered aperture|
|US20050279851 *||Jun 6, 2005||Dec 22, 2005||Aerogen, Inc.||Method and apparatus for dispensing liquids as an atomized spray|
|US20060054655 *||Aug 26, 2004||Mar 16, 2006||Mishra Rajiv S||Selective reinforcement of metallic bodies|
|US20070023547 *||Jun 19, 2006||Feb 1, 2007||Aerogen, Inc.||Aperture plate and methods for its construction and use|
|US20070044792 *||Aug 30, 2005||Mar 1, 2007||Aerogen, Inc.||Aerosol generators with enhanced corrosion resistance|
|US20070075161 *||Sep 18, 2006||Apr 5, 2007||Aerogen, Inc.||Droplet Ejector With Oscillating Tapered Aperture|
|EP0401371A1 *||Dec 26, 1988||Dec 12, 1990||Institut Gidrodinamiki Imeni M.A. Lavrentieva Sibirskogo Otdelenia Akademii Nauk Sssr||Device for feeding powder into the barrel of a detonation installation|
|WO1987004643A1 *||Feb 4, 1987||Aug 13, 1987||Nordson Corp||Method of intermittently spraying powder and a gun therefor|
|WO2005082543A1 *||Dec 17, 2004||Sep 9, 2005||Illinois Tool Works||Powder dispensing nozzle with rectangular cross section|
|U.S. Classification||239/3, 427/477, 239/124|
|International Classification||B05B5/025, B05B5/03, B05B7/14, B05B5/00, B05B5/16|
|Cooperative Classification||B05B5/1683, B05B7/1477, B05B5/032, B05B7/1468|
|European Classification||B05B7/14A21, B05B7/14A17, B05B5/16B, B05B5/03A|