|Publication number||US3560389 A|
|Publication date||Feb 2, 1971|
|Filing date||Aug 8, 1967|
|Priority date||Aug 11, 1966|
|Also published as||DE1617067A1|
|Publication number||US 3560389 A, US 3560389A, US-A-3560389, US3560389 A, US3560389A|
|Inventors||Anthony L L Hunting|
|Original Assignee||Cyclo Chemicals Ltd|
|Export Citation||BiBTeX, EndNote, RefMan|
|Referenced by (43), Classifications (15)|
|External Links: USPTO, USPTO Assignment, Espacenet|
United States Patent Olfice 3,560,389 Patented Feb. 2, 1971 3,560,389 LIQUID DETERGENT BLEACH COMPOSITION Anthony L. L. Hunting, London, England, assignor to 'Cyclo Chemicals Limited, London, England, a British company No Drawing. Filed Aug. 8, 1967, Ser. No. 661,761 Claims priority, application Great Britain, Aug. 11, 1966, 36,041/ 66 Int. Cl. Clld 7/54 US. Cl. 252-95 7 Claims ABSTRACT OF THE DISCLOSURE A liquid detergent bleach composition comprising an aqueous mixture of a detergent, a bleaching or oxidizing agent, and a hydrotrope in :which the components are present in such an amount so as to provide a clear liquid at room temperature is disclosed.
This invention relates to a stable, liquid detergentbleach composition.
Much effort has been directed towards an attempt to formulate a liquid detergent containing a bleaching agent, such as sodium hypochlorite which is perhaps the most commonly used, cheapest and most effective bleaching agent for liquid compositions.
This problem has been solved to some extent in the dry state, and typical dry powdery compositions previously proposed have included sodium or calcium hypochlorite and a detergent, together with compounds such as alkali metal phosphates, silicates, carbonates and/or sulphates. These dry compositions are intended to be mixed with water immediately prior to use. Other previously proposed compositions have included a quaternary ammonium compound and, whilst a reasonably effective clear solution may be obtained, the quaternary ammonium compound is neither a very potent detergent nor is it cheap.
The difficulties encountered in formulating a suitable inexpensive liquid preparation have been to find a washactive material which is soluble and also sufiiciently inert that the oxidising or bleaching agent does not react with it, thereby causing the preparation to lose its oxidising and/or detergent powers.
We have, for example, found that sodium lauryl ether sulphate, which is a commercially available water-soluble detergent, is incompatible with sodium hypochlorite in that when the two are mixed a heavy precipitate of insoluble matter is produced making the product unsuitable as a commercial proposition.
We have now discovered, however, that hydrotropes, such as for example, sodium xylene sulphonate, which are known clarifying agents, when added to such a preparation not only produce a liquid which is clear at room temperature and in some cases even down to C., but also that the mixture of the three components retains its detergent power, and retains its oxidising power over a length of time at least substantially equal to that which would be expected from sodium hypochlorite alone.
Based on this discovery, the present invention provides a liquid detergent bleach composition, comprising an aqueous mixture of a detergent, a bleaching or oxidising agent, and a hydrotrope which is an alkali metal or alkaline earth metal salt of a monoor polyalkylated benzene or naphthalene sulphonate of which the alkyl groups contain from 1 to 4 carbon atoms, the three components being present in amounts such as to provide a clear liquid at room temperature.
Whilst such three component compositions are stable, we have also found that there is an optimum level for alkalinity of the composition due to the presence of hydroxyl ions and this alkalinity is preferably between 1 and 2% expressed in terms of free sodium hydroxide, although in fact the alkalinity may be due to other cations provided by compounds such as magnesium hydroxide, potassium hydroxide or lithium hydroxide. The optimum alkalinity depends upon the particular formulation and quality of the raw materials. Thus, for example, when the bleaching agent is sodium hypochlorite, it is preferred to use a quality of sodium hypochlorite with the lowest possible sodium chloride content, but a higher content of sodium chloride can be tolerated by appropriate adjustment of the alkalinity of the mixture.
The detergent of the present composition may be any of those detergents commonly employed and may be used alone, or in admixture with other detergents. A first class of detergents which may be employed in the present compositions is the metal alcohol sulphates of which the alcohol contains from 6 to 22 carbon atoms. The alcohol may be a synthetic alcohol, a branched chain alcohol or a fatty alcohol. The alcohols may be pure or may be mixtures of alcohols, particularly such mixtures of fatty alcohols as are available commercially. Examples of suitable detergents in this class include sodium lauryl sulphate, sodium decyl sulphate, sodium myristyl sulphate, and the corresponding lithium salts. The metal component of the detergents of this class is preferably an alkali metal such as sodium or lithium, or an alkaline earth metal such as magnesium.
The second class of detergents which may be employed in the present compositions is the metal alcohol ether sulphates, of which the alcohol is the same as that of the first class of detergents and of which the metal is preferably an alkali metal or an alkaline earth metal.
The alcohol ethers from which the second class of detergents is derived are made by reacting the alcohol with an olefin oxide. The preferred alcohol ethers are made by reacting the alcohol with ethylene oxide to give an ethoxylated alcohol of which the average composition comprises from 1 to 4 mols of ethylene oxide per mol of alcohol. Examples of this class of detergent are sodium lauryl ether sulphate (including the commercially available material which also comprises sodium decyl ether sulphate and sodium myristyl ether sulphate) and lithium lauryl ether sulphate.
A third class of detergent which may be employed in the present compositions is the alkali metal alkyl aryl sulphonates including for example sodium dodecyl benzene sulphonate and lithium dodecyl benzene sulphonate.
A fourth class of detergents which may be employed in the present compositions is the oxidation products of fatty amines and derivatives thereof, which products are generally known in the detergent industry as amine oxides and which are employed as detergents in their own right or as builders. An example of a suitable detergent in this class is dimethyl cocoamine oxide.
Other classes of detergents, not specifically mentioned above, may also be employed, such other classes being well known.
As indicated above, the detergents may be employed alone or in admixture with one another, including mixtures of detergents within the same class and mixtures of detergents in different classes. While all the above mentioned detergents are compatible with one another, detergents in other classes not specifically mentioned may not be entirely compatible with one another and mixtures of incompatible detergents should be avoided. In particular, it is preferred not to employ mixtures of cationic and anionic detergents.
As indicated above, the hydrotropes employed in the present compositions are a well known family of clarifying agents comprising the alkali metal or alkaline earth metal salts of monoor polyalkylated benzene or naphthalene sulphonates of which the alkyl groups contain from 1 to 4 carbon atoms. The preferred hydrotrope is sodium xylene sulphonate which is commercially available as an unspecified mixture of the isomeric sulphonates, but other hydrotropes, such as the water-soluble alkali metal and alkaline earth metal salts, e.g., the sodium, patassium, lithium and magnesium salts of xylene or toluene sulphonic acid may be used.
The range of proportions of the three components of the mixture may be varied within wide limits but will generally be interrelated in the sense that the amount of hydrotrope required will depend upon the amount of detergent present and the nature of the detergent and the amount of detergent which may be added to the composition will depend upon the amount of hydrotrope present.
In general the ratio by weight of hydrotrope to detergent Will be from 2:1 to 1:2, with a preferred ratio of 1:1 for most general commercial purposes. However, as indicated above, the ratio may depend upon the particular detergent may be increased to 5:1 or more for detergents which are not readily water-soluble, such as sodium lauryl sulphate. The amount of bleaching or oxidising agent may be varied widely and the compositions of the present invention include not only compositions which are primarily regarded as bleaching or oxidising compositions and which contain a large amount of bleaching or oxidis ing agent and a small amount of detergent for wetting purposes, such as may be used for sterilizing dairy equipment, but also compositions which are primarily regarded as detergent compositions and which contain a large amount of detergent and a small amount of bleaching or oxidising agent, such as may be used for washing diapers.
The bleaching or oxidising agent is preferably sodium hypochlorite or lithium hypochlorite, but other agents may be. employed.
The composition may, of course, contain conventional additives such as odorifiers, builders, brightening agents and solubilisers, provided that they are compatible with the bleaching or oxidising agent.
The invention will now be illustrated by the following examples:
Examples 1 2 3 4 Sodium hypochlorite (10.75% available chlorine 100 100 100 100 Sodium lauryl ether sulphate (26% active)* 5 5 10 Sodium xylene sulphonate (30% active) 10 0 Available chlorine at day 0 9. 25 9. 8. 5 10. 3 Loss of available chlorine after 16 days percent 2. l 2. 2 3. 5 1. 9 Loss of available chlorine after 1 month percent 6. 9 9. 4 7.0 7. 7 Clarity at room temperature." C C C C Clarity after 24 gours at 0 C H H C C Made from an cthoxylated commercial grade of lauryl alcohol. Measured as percent of original. N OTE.C =clear; H=slight haze but still essentially clear.
Examples 5 6 1 To adjust alkalinity to 1.2% free NaOH. 2 Clear.
In the above examples, the amount of detergent, sodium lauryl ethersulphate, determined at the end of the test period was substantially the same as at the beginning,
showing that the compositions had retained their detergent power.
The following examples illustrate compositions which have a clarity at ambient temperature, and 0 C., and stability, comparable to the composition of Example 15.
EXAMPLE 7 Sodium hypochlorite (14.4% )2 70 g.
Sodium xylene sulphonate (30%) 15 g.
Sodium lauryl ether sulphate (26%): 15 g.
Sodium hydroxide: to adjust alkalinity to 1.0% free NaOH EXAMPLE 8 Sodium hypochlorite (14.4% )1 g.
Sodium lauryl sulphate 1.1 g.
Sodium xylene sulphonate (30%): 16.7 g.
Water: 2.2 g.
Sodium hydroxide: to adjust alkalinity to 1.0% free NaOH EXAMPLE 9 Sodium hypochlorite (14.4% 70 g.
Lithium lauryl sulphate 30% 15 g.
Sodium xylene sulphonate (30% 15 g.
Sodium hydroxide: to adjust alkalinity to 1.0% free NaOH EXAMPLE 10 Sodium hypochlorite (14.4% 70 g.
Dimethyl cocoamine oxide (30% 15 g.
Sodium xylene sulphonate (30% 15 g.
Sodium hydroxide: to adjust alkalinity to 1.0% free NaOH EXAMPLE 1 1 Sodium hypochlorite (14.4% )2 70 g.
Dimethyl cocoamine oxide (30% 1.5 g.
Sodium lauryl ether sulphate (26%) 13.5 g.
Sodium xylene sulphonate (30% 15 g.
Sodium hydroxide: to adjust alkalinity to 1.0% free NaOH I claim:
1. A liquid detergent bleach composition, consisting essentially of (a) water; (b) a detergent selected from the group consisting of alkali metal and alkaline earth metal alcohol sulphates of which the alcohol contains from 6 to 22 carbon atoms, alkali metal and alkaline earth metal alcohol ether sulphates of which the alcohol contains from 6 to 22 carbon atoms and an average of 1 to 4 moles of ethylene oxide per mole of alcohol, alkali metal alkyl benzene sulphonates and fatty amine oxides; (c) an alkali metal hypochlorite bleaching agent; and (d) a hydrotrope selected from the group consisting of alkali metal and alkaline earth metal salts of monoand polyalkylated benzene and naphthalene sulphonates of which the alkyl groups contain from 1 to 4 carbon atoms; the proportions of the components (a), (b), (c) and (d) being interrelated such as to provide a clear liquid at room temperature.
2. A composition as claimed in claim 1, wherein the alkalinity of said composition due to the presence of hydroxyl ions and expressed in terms of free sodium hydroxide, is between 1 and 2%.
3. A composition as claimed in claim 1, wherein the ratio by weight of hydrotrope to detergent in the composition is from 2:1 to 1:2.
4. A composition as claimed in claim 1, wherein said bleaching agent is selected from the group consisting of sodium hypochlorite and lithium hypochlorite.
5. A composition as claimed in claim 1, wherein said detergent is sodium lauryl ether sulphate.
6. A composition as claimed in claim 1, wherein said detergent is sodium or lithium lauryl sulphate.
5 6 7. A composition as claimed in claim 3, wherein the 3,303,136 2/1967 Bright 25299X hydrotrope is a sodium xylene sulphonate. 3,402,128 9/1968 Puchta, et a1 25299 References Cited MAYER WEINBLATT, Primary Examiner UNITED STATES PATENTS 5 US. Cl. X.R. 3,042,622 7/1962 Kirschenbaurer 25295X 3,172,861 3/1965 Steinhauer et a1 25295X 25294,96,99,103,187
|Citing Patent||Filing date||Publication date||Applicant||Title|
|US3876551 *||Nov 8, 1972||Apr 8, 1975||Int Flavors & Fragrances Inc||Perfumed aqueous hypochlorite composition and method for preparation of same|
|US3962112 *||Aug 26, 1974||Jun 8, 1976||Charles William Shaheen||Composition and process for removing sulfur dioxide from combustion gases|
|US4051056 *||Sep 4, 1975||Sep 27, 1977||The Procter & Gamble Company||Abrasive scouring compositions|
|US4071463 *||May 24, 1976||Jan 31, 1978||The Dow Chemical Company||Stable cleaning agents of hypochlorite bleach and detergent|
|US4235732 *||Feb 8, 1978||Nov 25, 1980||The Procter & Gamble Company||Liquid bleaching compositions|
|US4240919 *||Nov 29, 1978||Dec 23, 1980||S. C. Johnson & Son, Inc.||Thixotropic abrasive liquid scouring composition|
|US4282109 *||May 15, 1980||Aug 4, 1981||Reckitt & Colman Products Limited||Aqueous hypochlorite solutions|
|US4289640 *||Jan 21, 1974||Sep 15, 1981||Colgate-Palmolive Company||Cleaning compositions|
|US4377489 *||Mar 16, 1981||Mar 22, 1983||Ceil Clean Corporation, Inc.||Inorganic persulfate cleaning solution for acoustic materials|
|US4388204 *||Mar 23, 1982||Jun 14, 1983||The Drackett Company||Thickened alkali metal hypochlorite compositions|
|US4390448 *||Oct 22, 1981||Jun 28, 1983||International Flavors & Fragrances Inc.||Perfumed stable aqueous hypochlorite bleach compositions containing 2-methyl-2-octanol and thickened variation thereof|
|US4485028 *||Mar 10, 1983||Nov 27, 1984||Ceil Clean Corporation, Inc.||Inorganic persulfate cleaning solution for acoustic materials|
|US4599186 *||Apr 20, 1984||Jul 8, 1986||The Clorox Company||Thickened aqueous abrasive scouring cleanser|
|US4657692 *||Apr 26, 1985||Apr 14, 1987||The Clorox Company||Thickened aqueous abrasive scouring cleanser|
|US4783283 *||May 23, 1986||Nov 8, 1988||The Procter & Gamble Company||Cleaning compositions|
|US4842771 *||Sep 29, 1987||Jun 27, 1989||Akzo N.V.||Thickened aqueous cleaning compositions|
|US4853146 *||Sep 29, 1987||Aug 1, 1989||Akzo N.V.||Thickening compositions and thickened aqueous acid solutions|
|US4863633 *||Aug 7, 1987||Sep 5, 1989||The Clorox Company||Mitigation of stress-cracking in stacked loads of fragranced bleach-containing bottles|
|US4946619 *||Jul 19, 1988||Aug 7, 1990||The Clorox Company||Solubilization of brighter in liquid hypochlorite|
|US5011538 *||Sep 6, 1989||Apr 30, 1991||The Clorox Company||Viscoelastic cleaning compositions and methods of use therefor|
|US5034150 *||May 3, 1989||Jul 23, 1991||The Clorox Company||Thickened hypochlorite bleach solution and method of use|
|US5055219 *||Nov 17, 1987||Oct 8, 1991||The Clorox Company||Viscoelastic cleaning compositions and methods of use therefor|
|US5080826 *||Jul 24, 1989||Jan 14, 1992||The Clorox Company||Stable fragranced bleaching composition|
|US5227366 *||Dec 31, 1991||Jul 13, 1993||The Clorox Company||Mitigation of stress-cracking in fragranced bleach-containing bottles|
|US5279758 *||Oct 22, 1991||Jan 18, 1994||The Clorox Company||Thickened aqueous cleaning compositions|
|US5389157 *||Jun 8, 1993||Feb 14, 1995||The Clorox Company||Viscoelastic cleaning compositions with long relaxation times|
|US5462689 *||Oct 17, 1994||Oct 31, 1995||The Clorox Company||Composition and method for developing extensional viscosity in cleaning compositions|
|US5549842 *||May 26, 1995||Aug 27, 1996||Reckitt & Colman Inc.||Thickened alkali metal hypochlorite composition|
|US5705467 *||Nov 3, 1995||Jan 6, 1998||Choy; Clement K.||Thickened aqueous cleaning compositions and methods of use|
|US5804545 *||Mar 15, 1996||Sep 8, 1998||West Argo, Inc.||Stable alkaline chlorine compositions|
|US5833764 *||Aug 4, 1995||Nov 10, 1998||Rader; James E.||Method for opening drains using phase stable viscoelastic cleaning compositions|
|US5916859 *||Jun 7, 1995||Jun 29, 1999||The Clorox Company||Hexadecyl amine oxide/counterion composition and method for developing extensional viscosity in cleaning compositions|
|US6413925||Jan 16, 2001||Jul 2, 2002||The Clorox Company||Method for increasing brightness retention of laundered fabrics|
|US6506718||Sep 1, 1999||Jan 14, 2003||The Procter & Gamble Company||Bleaching compositions|
|US6649583||Nov 21, 2002||Nov 18, 2003||Procter & Gamble Company||Bleaching compositions|
|DE2855776A1 *||Dec 22, 1978||Jun 28, 1979||Unilever Nv||Fluessiges reinigungsmittel|
|EP0518451A1 *||Aug 2, 1988||Dec 16, 1992||The Clorox Company||Homogeneous fragrance preblend|
|EP0594314A1 *||Sep 30, 1993||Apr 27, 1994||The Clorox Company||Composition and method for developing extensional viscosity in cleaning compositions|
|EP0984059A1 *||Sep 1, 1998||Mar 8, 2000||THE PROCTER & GAMBLE COMPANY||Bleaching compositions|
|EP0990696A1 *||Dec 19, 1998||Apr 5, 2000||THE PROCTER & GAMBLE COMPANY||Stable bleaching compositions|
|EP0992576A1 *||Oct 1, 1998||Apr 12, 2000||THE PROCTER & GAMBLE COMPANY||Stable bleaching compositions|
|WO2000012668A1 *||Sep 1, 1999||Mar 9, 2000||Procter & Gamble||Bleaching compositions|
|WO2000018866A1 *||Sep 28, 1999||Apr 6, 2000||Briatore Andrea||Stable bleaching compositions|
|U.S. Classification||510/370, 510/108, 252/187.26, 252/187.29, 510/303, 510/350|
|International Classification||C11D3/395, C11D17/00, C11D3/34|
|Cooperative Classification||C11D3/3418, C11D3/3956|
|European Classification||C11D3/395D, C11D17/00B, C11D3/395H, C11D3/34B|