|Publication number||US3574305 A|
|Publication date||Apr 13, 1971|
|Filing date||Sep 5, 1968|
|Priority date||Sep 9, 1967|
|Publication number||US 3574305 A, US 3574305A, US-A-3574305, US3574305 A, US3574305A|
|Inventors||Muhl Gerhard L|
|Original Assignee||Hellige & Co Gmbh F|
|Export Citation||BiBTeX, EndNote, RefMan|
|Patent Citations (3), Referenced by (9), Classifications (5)|
|External Links: USPTO, USPTO Assignment, Espacenet|
United States Patent Inventor Gerhard L. Muhl Freiburg Im Breisgau, Germany App]. No. 757,619 Filed Sept. 5, 1968 Patented Apr. 13, 1971 Assignee Fritz Hellige & Co., G.m.b.H.
Freiburg im Breisgau, Germany Priority Sept. 9, 1967 Germany ELECTRODE SERVING FOR THE DETECTION OF ELECTROPHYSIOLOGICAL POTENTIALS OR CURRENTS 7 Claims, 2 Drawing Figs.
US. Cl 128/2JR, 128/DIG.4, 252/514 Int. Cl A61b 5/04 Field of Search 128/206, 2.1, 404, 41 l, 417, 418, (Pickup Electrode Digest); 252/514, 518
 References Cited UNITED STATES PATENTS 2,654,945 10/1953 Richardson et a1. 252/514X 3,085,577 4/1963 Berman et a1 128/418 3,295,515 1/1967 Kahn l28/2.06
Primary ExaminerWilliam E. Kamm Attorneys-Franklin D. .lankosky, Richard Zentner, Alfred B.
Levine and Alan C. Rose ABSTRACT: A diagnostic device for facilitating the measurement of electrophysiological potentials or currents. An electrode of sintered construction and of disc configuration is retained within a holding member of the diagnostic device. The electrode is a mixture of silver powder and silver salt at defined ratios, and the silver salt being within a preferred solubility level. The holding member has a plurality of radial ribs adapted to provide free space wherein an electrolytically conductive paste may be placed so as to prevent direct contact between the electrode and the skin surface of the patient.
ELECTRODE SERVING FOR THE DETECTION OF ELECTROPHYSIOLOGICAL POTENTIALS OR CURRENTS FIELD OF THE INVENTION This invention relates to an electrode utilized with diagnostic equipment and more particularly to an electrode of a sintered body construction.
DESCRIPTION OF THE PRIOR ART Electrodes for facilitating the measurement of electrophysiological potentials or currents are well known. Various structural arrangements and various compositions of electrodes have been utilized depending upon the subject to be tested or the environment in which the tests are who conducted. Electrodes have been press fabricated of selected ratios of silver and silver halides, however, this approach has produced light sensitive surfaces owing to the decomposition of the silver chloride when it is exposed to light. The contact surface of the electrodes becomes black and unsightly so that they are no longer suited for a number of applications. In addition, the simple pressing procedure does not produce electrodes having a high degree of conductivity. Other electrodes have included a synthetic resin as a binding agent. In general, the electrodes which include such a binding agent are of poor quality due to insufi'icient conductivity.
Accordingly, it is an object of the present invention to provide a diagnostic device having a novel electrode of a sintered construction.
It is a further object of the present invention to provide a novel electrode that maintains its original composition and may be used repeatedly.
It is a still further object of the present invention to provide a novel electrode having high conductivity.
It is another object of the present invention to provide a novel electrode that substantially reduces polarization voltages and is not sensitive to light.
SUMMARY OF THE INVENTION In accordance with the objects set forth above, the present invention provides an electrode of sintered construction having high conductivity that may be used repeatedly. The electrode is held within a diagnostic device having radial ribs which are adapted to provide free space wherein an electrolytically conductive paste may be placed so as to prevent direct contact between the electrode and the skin surface of a patient. The electrode comprises a mixture of silver powder and silver salt at defined ratios, and the silver salt being within a preferred solubility level.
BRIEF DESCRIPTION OF THE DRAWINGS Additional objects, advantages, and characteristic features of the present invention will become readily apparent from the following detailed description of preferred embodiments of the invention when taken in conjunction with the accompanying drawings in which:
FIG. 1 is a sectional side view of a diagnostic device disclosed in FIG. 2 taken along lines l-l in accordance with the present invention; and
FIG. 2 is a bottom view of a diagnostic device in accordance with the present invention.
DESCRIPTION OF THE PREFERRED EMBODIMENTS Referring now to FIG. 1, there is shown a sectional side view of a diagnostic device in accordance with the principles of the present invention. The diagnostic device 10 includes a holding member 11, which may be constructed of any suitable rigid nonconductive material, for example, plastic. The holding member 11 comprises an outer rim 11a, six radial ribs 11b, and a mounting portion 110. Further included in the diagnostic device 10 is a terminal pin 14 having a bottom ridge 140 which may be constructed of any suitable conductive material. The terminal pin 14 may be connected to diagnostic equipment (not shown) via suitable conductive leads (not shown). The terminal pin 14 is retained within the holding member 11 by a snapring 15 which is adapted to fit against the bottom ridge 14a. A cover member 16 which may be of any suitable insulating material may be utilized to ensure proper covering of the snapring 15. The diagnostic device 10 is shown placed upon a skin surface 17 of a patient (not shown).
An electrode 12 is shown inserted within the holding member 11 and underneath the terminal pin 14. The electrode 12 is of a sintered construction, i.e., the electrode 12 is constructed of desired powders which have been cold-pressed into a desired shape then heated to fonn a strong cohesive body. The composition of the electrode 12 is preferably a mixture of silver powder with one or several of the following silver salts: silver cyanide, silver rhodanide, silver iodide or silver bromide. In the practice of this invention, the most favorable results have occurred by utilizing silver salts which have a solubility of below -l0 g. in 100 ml. H For example, the preferred solubility for the four above-mentioned silver salts would be as follows:
for Ag Br 12-10 g./ 100 ml.H 0 for Ag I 2 (12510 g./ 100 ml. H 0 forAg CN :2.8-l0g./ 100 m1.H 0 for Ag SCN l4- 10 g./ 100 m1. H 0
From experimentation, it has been found that the material most suited to form the electrode 2 is a sintered body consisting of a mixture of silver powder and silver salt with a solubility of less than 10010 g./ 100 ml. H 0, at a ratio of between 30:70 and 50:50, preferably in the ratio 40:60. The sintering process at sufficiently high temperatures and sufficiently high pressure creates conductive bridges of very low resistance in the sintered body. The absence of a synthetic resin as a binding agent further reduces the electrode resistance. With Ag CN, for instance, the light sensitivity of such a contact body is lowered by more than one order of magnitude than it is for materials with silver chloride as the second component. As far as the suppressing of polarization voltages is concerned, at least the same conditions as for silver chloride apply. If Ag Br is used, no deterioration due to light sensitivity occurs when the contact body is placed against electrolytically conductive pastes containing ammonia ions. The material composition suggested in accordance with the principles of this invention provides an electrode of superior quality since the silver salts especially selected, are characterized by low sensitivity and low solubility. The solubility also has an influence on the light sensitivity because the latter would go up considerably with the salt in a dissol ed condition. Thus, these advantages guarantee clean handling and troublefree functioning of the electrodes during the detection of electrophysiological potentials or currents or during the application of electrical stimulating currents or voltages.
Referring now to FIG. 2 there is shown a bottom view of the diagnostic device 10 in accordance with the principles of the present invention. The radial ribs 11b are shown along with the accompanying free space 13. The radial ribs 11b extend from the opening in the holding member 11 to approximately the outer rim 11a and provide the free space 13b of the diagnostic device 10. The free space 13 may be filled with an electrolytically conductive paste for facilitating proper electrical contact between the skin surface 17 and the electrode 12, the electrode 12 being of a disc configuration. The arrangement of the radial ribs 11b prevents direct contact between the skin surface 17 and the electrode 2, thus, ensuring that the contact resistance cannot change during measurement.
Thus although the present invention has been shown and described with reference to particular embodiments, for example, electrodes of a disc configuration and being a mixture of silver powder and silver salt at defined ratios and the silver salt being within a preferred solubility level, nevertheless, various changes and modifications obvious to a person skilled in the art to which the invention pertains, for example, electrodes of a wedge configuration, are deemed to lie within the spirit, scope, and contemplation of the invention as set forth in the appended claims.
1. A diagnostic device comprising:
a rigid nonconductive holding member having an opening from the top to the bottom thereof and further having a plurality of radial ribs adapted to hold an electrolytically conductive paste;
electrode means inserted within said opening of said holding member for detecting potentials and currents;
terminal means located within said opening of said rigid nonconductive holding member for maintaining said potentials and transferring currents between said electrode means and said terminal means; and
clamping means wedged between said terminal means and said opening of said rigid nonconductive holding member for retaining said terminal means against said electrode means.
2. A diagnostic device as recited in claim 1 wherein said opening is located in proximity of the center of said holding member and said radial ribs extend outwardly from said opening to approximately the outer rim of said holding member.
3. A diagnostic device as recited in claim 2 wherein said opening is of circular construction and said electrode means is of a disc construction.
4. A diagnostic device as recited in claim 1 wherein said terminal means has a bottom ridge of a larger diameter than the major portion of said terminal means and said clamping means is a snapring.
5. A diagnostic device as recited in claim 3 wherein said electrode means is of sintered construction comprising a mixture of silver powder and silver salt, said silver salt having a solubility of less thanlOO- 10" g./ l00 ml. H 0.
6. A diagnostic device as recited in claim 5 wherein said mixture includes said silver powder and said silver salt at a ratio of between 30:70 and 50:50.
7. A diagnostic device as recited in claim 5 wherein said mixture includes said silver powder and said silver salt at a ratio of 40:60.
UNITED STATES APAIENT OFFICE CERTIFICATE )F (:0 RR FA I'TION Pzai'ent .Io. 3,57g 3os anti April 1971 =3r1tur('s) Gez hard L. Muhl It is certified that urror appears in 23.: Save-identified paten; and that said Letters Patent are hereby COT'SQZEd as shown below:
should be: 1oo.1o' in 100 ml H2O Col. 2, line 23: 12.10 should be 12.1o'
Col. 2, line 24: o. 25.10 should be 0. 2s.1o' Col. 2, line 25: 2.840 should be 2.8.1O' Col. 2, line 26: 14.10 9 should be 14. 10 9 Col. 2, line 30: 100. 10 g should be lOO. 10 Col. 4, line 14: 10040 should be 1oo.1o'
Signed and sealed this 31 st day of August 19 7'1 (SEAL) Attest:
WILLIAM E. SGHUYLER, JR.
EDWARD M.FL1:.TGHER,JR' commissioner f Patents Attesting Officer
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|US2654945 *||Oct 11, 1948||Oct 13, 1953||Cutler Hammer Inc||Electrical contact|
|US3085577 *||Jun 12, 1961||Apr 16, 1963||Vector Mfg Company Inc||Body electrode|
|US3295515 *||Nov 5, 1963||Jan 3, 1967||Beckman Instruments Inc||Electrode assembly|
|Citing Patent||Filing date||Publication date||Applicant||Title|
|US3747590 *||Jun 21, 1971||Jul 24, 1973||Nat Cable Molding Corp||Biopotential electrode|
|US3834373 *||Feb 24, 1972||Sep 10, 1974||Sato T||Silver, silver chloride electrodes|
|US3896790 *||May 1, 1972||Jul 29, 1975||Neuronics Inc||Alpha brain wave sensor|
|US3923042 *||Sep 30, 1974||Dec 2, 1975||Medicor Muevek||Electrical detector/transducer/applicable on the skin surface for biometrical observations|
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|U.S. Classification||600/396, 252/514|