|Publication number||US3613792 A|
|Publication date||Oct 19, 1971|
|Filing date||Dec 11, 1969|
|Priority date||Dec 11, 1969|
|Publication number||US 3613792 A, US 3613792A, US-A-3613792, US3613792 A, US3613792A|
|Inventors||John W Hyde, William J George|
|Original Assignee||British Petroleum Co|
|Export Citation||BiBTeX, EndNote, RefMan|
|Patent Citations (8), Non-Patent Citations (2), Referenced by (54), Classifications (10)|
|External Links: USPTO, USPTO Assignment, Espacenet|
United States Patent  Inventors [2 1 Appl. No.  Filed  Patented  Assignee 54 on. WELL AND METHOD FOR vnonucrron or on. THROUGH PERMAFROST zone 24 Claims, 4 DrawingFigs.
52 US. I 166/315, 166/57, 16611316. 1 51 Int. Cl. 1221b 43/00  Field otSearch 166/302,
303, 315, 57, DIG. l
3,456,735 7/1969 McDougall et a1. 3,498,381 3/1970 Earlougher 166/303 FOREIGN PATENTS 184,205 1/1967 U.S.S.R. 166/57 OTHER REFERENCES Gatlin, Carl. Petroleum Engineering. Englewood Cliffs, NJ. Prentice-Hall, 1960, pp. 269, 270 (Copy in Group 350).
Slope Operators Plan Subsidence Eight. ln Oil 8: Gas 1., Dec. 8, 1969, pp. 69 72. (Copy in l66 302).
Primary Examiner-Ian A. Calvert Attorney-Morgan, Finnegan, Durham & Pine ABSTRACT: Production oil wells for extracting warm oil from ground containing a permafrost zone without causing the oil to melt the permafrost comprise a pipe extending down into the oil pool, an inner casing surrounding the pipe and running down through the permafrost zone, an outer casing running down through the permafrost zone, surrounding the inner casing and spaced to define an airgap or annulus with the inner casing and means, such as a liquid heat exchange fluid or a refrigerating boiling liquid, in the annulus to inhibit heat transfer from the pipe to the ground surrounding the outer casing. in preferred embodiments a second annulus or airgap, optionally filled with insulation, is provided between the inner casing and the pipe.
SHEET 10F 4 PATENTEDum 19 Ian INVENV'IURVS aomv w. HYDE WILLIAM .r. GEORGE 5 I. M, a l .Q 7.? (v u 1H 9 4 x m 2 84 1 v a 4 6v 2 v PATENTEDUET 19ml sum 20F a l u r m In \& hunk H. 2 9 are NX o a c o \Rw A Mm \w z 4 2 B 00 6 Z OIL WELL AND METHOD FOR PRODUCTION OF OIL THROUGH PERMAFROST ZONE This invention relates to an oil well and to methods for producing oil. More particularly, it concerns wells for extracting oil from ground containing a permafrost zone.
BACKGROUND OF THE INVENTION Oil has recently been found under the north slope of Alaska and in this location (and also in other locations) below the earths surface is a zone consisting of a material usually known as permafrost. In this specification the term permafrost will be used to denote a geological formation which contains ice in such quantities that the mechanical properties of the formation depend on the ice so that there would'be a substantial change in the mechanical properties should the formation heat to a temperature at which the ice melts and this definition extends to a formation which consists solely of ice. In Alaska the permafrost consists of a mixture of rock, gravel and ice in which the ice content varies with location and depth but 90 percent ice is often encountered at the surface. Permafrost can extend to 2,000-foot depths.
Oil usually issues from a production well at a temperature above 32 F. (in Alaska the oil will be at l70-l75" F., for example) and there is danger of melting the ice in the permafrost which surrounds a production well. Melting of ice in the permafrost will cause subsidence. This subsidence can impose compressive and/or tension loads high enough to fracture the well casing and hence allow the escape of oil. Moreover, unless suitable measures are taken, the producing completed oil will will become surrounded by a crater lake and the soil area will become very unstable.
It is a primary object of this invention to provide a well for recovering oil from ground containing permafrost.
It is another object of this invention to reduce the contamination risk of an oil production well passing through permafrost.
Still another object of this invention is to provide a means to prevent the soil area surrounding an oil well drilled through permafrost to become unstable.
DESCRIPTION OF THE INVENTION According to this invention an oil production will which passes through permafrost comprises a pipe extending from the earth's surface down into the oil pool, an inner casing surrounding the pipe extending from the earths surface down to a point between the lower level of the permafrost but above the oil pool, and an outer casing in contact with the permafrost zone and extending to the base thereof, surrounding the inner casing and separated therefrom so as to form an annular space or airgap into which is introduced a means to inhibit transfer of heat from the pipe to the ground containing the permafrost.
in a preferred embodiment the inner casing is in a space relationship with the pipe so as to create an insulating airgap or annulus optionally adapted to contain thermal insulation.
The invention also contemplates a method of producing oil at a temperature above the freezing point from a well which passes through permafrost. The method comprises drilling a first hole down through the permafrost and putting down an outer casing, drilling a second hole smaller in diameter than the first down from the bottom of the first hole to a point above the oil pool and putting down an inner casing in spaced relationship with the outer casing to provide an airgap or annulus, drilling a third hole smaller than the second from the bottom of the second down into the oil pool and putting down a pipe extending from the pool to the earth's surface, and then introducing into the airgap or annular zone between the inner and outer casing means for inhibiting heat transfer from the pipe to the pennafrost.
When used herein and in the appended claims the term means for inhibiting or to inhibit) heat transfer contemplates materials introduced into the airgap or gaps which function to impede the movement of heat from the oil to the 'ground containing permafrost. Broadly, these will be fluids,
liquid or gaseous, and solids of varying densities They will comprise a class of materials of limits well understood by those skilled in the are of engineering thermodynamics. See, for example, the disclosure in Perry's Chemical Engineer's Handbook, 4th Edition, McGraw-l-Iill, Sections 9 through 13, which is incorporated herein by reference. MOre particularly, suitable means will comprise heat transport fluids, e.g., liquids and vapors, and insulating liquids, gases and solids of low thermal conductivity. The heat transport fluids can comprise liquid heat exchange fluids and refrigerating boiling liquids. lllustrative of the liquid heat exchange fluids are water, oils of low pour point, alcohols, e.g., methanol, ethanol, i-propanol and the like, glycols, e.g., ethylene glycol, propylene glycol, glycerine, and the like, and mixtures thereof, as well as brines, e.g., calcium or sodium chloride brines, and other aqueous solutions, inhibited if desired by addition of conventional additives to minimize corrosion of the equipment. It has been found that very suitable liquid heat exchange fluids comprise brine, inhibited aqueous ethylene glycol and mixtures of methanol and water. Illustrative of the refrigerating boiling liquids are ammonia, carbon dioxide, halogenated liquid hydrocarbons, such as methyl chloride, methylene chloride, trichloroethylene; a class of nonflammable liquid fluorinated hydrocarbons known as the Freons, e.g., Freon 1 l4, Freon 21, Freon 11 and Freon 12, the latter being, for example, dichlorodifluoromethane, hydrocarbons, such as propane, butane, and the like; ethers, such as methyl ethyl ether, diethyl ether, ethyl n-propyl ether, and the like; esters, such as methyl forrnate; amines, such as methyl amine; and other refrigerating liquids, e.g., sulfur dioxide, nitrous oxide, carbon disulfide, mixtures thereof, and the like. It has been found that very suitable refrigerating boiling liquids comprise propane, ammonia or a nonflammable gaseous of liquid fluorinated hydrocarbons, i.e., Freons. Such refrigerating boiling liquids are also denoted refrigerant.s" by those skilled in the art; see Perry's Chemical Engineers Handbook, 4th Edition, 1963, Section 12-3, particularly, FIG. 12-2.
Illustrative of thermally insulating liquids, gases and solids of low thermal conductivity are air, cork, balsa wood, reflective foils, e.g., aluminum foil, especially in multiplayers, fiber mats, e.g., fiber glass mats or papers, nylon net, aluminized plastic films, powders, particularly evacuated powders, such as perlite, silica aerogel, phenolic spheres, lampblack, diatomaceous earth, alumina, and the like; foamed plastics such s polystyrene, epoxy resin, polyurethane, foamed rubber, silica and cellular glass, and the like; and insulating minerals such as vermiculite, mineral wool, and the like. It has been found that in addition to the use of an airgap, heat transfer is inhibited especially conveniently with expanded plastics such as polyurethane and polystyrene, and with minerals, such as vermiculite.
A number of ways to introduce the means to inhibit heat transfer into the annular zone or zones can be used. Several that will work especially well are shown in the drawings and will be described in detail hereinafter.
DESCRIPTION OF THE DRAWINGS The invention will now be described by way of examples with reference to the accompanying drawings in which, in cross section:
FIG. 1 shows diagrammatically a production well according to this invention.
FIGS. 2 and 3 illustrate the upper portion of wells according to this invention in embodiments wherein two different means are used to introduce a liquid heat exchange fluid into the airgap between the casings. FIG. 4 illustrates an oil well in another embodiment which includes a means to introduce a refrigerating boiling liquid into the annulus or airgap between the casings.
The well illustrated in FIG. 1 comprises an outer casing 2 of any suitable material, e.g., steel, and diameter, e.g., 20 inches,
which extends from the earth's surface 26, to just below the base 6 of the permafrost 4. In atypical Alaskan production well this casing would normally average about 1,000 feet long but could be as much as about 2,000 feet long. In accord with standard practice it is shown to be cemented to the sides of the hole with a cement layer 8.
An inner casing 10 of suitable diameter, e.g., 13% inches, extends from the surface to a median point between the oilbearing formation or pool 24 and the bottom of the outer casing. The depth of the median point will be determined by the geological formation and the need, for example, to keep the formation from caving in, and to keep gas and other fluids from becoming uncontrollable during or after the drilling operation, and by other safety and economic reasons. The upper section of casing 10 is situated inside of outer casing 2 so as to create an annular space 12. Below the permafrost the inner casing 10 may also be cemented to the formation with cement layer 14 in accord with standard practice. In a typical Alaskan production well, inner casing 10 could be about 4,000 feet long.
A pipe 16 of suitable diameter, e.g., diameter 9% inches, extends from the surface to the level of the producing formation, i.e., the oil pool or reservoir. In a typical Alaskan production well, pipe 16 would be about 9,000 feet long.
The uppermost section of pipe 16 is situated inside the inner casing 10. In its broadest aspects, the present invention contemplates oil wells wherein the outer wall of pipe 16 and the inner wall of inner casing 10 are together, i.e., there is no airgap or annulus between the pipe and the inner casing. The lowermost section of pipe 16 preferably is cemented to the formation and to inner casing I up to just below the level of the permafrost although, in the oil well illustrated, in FIG. 1 this has not been done. Instead a conventional packer 18 has been located to define an upper insulation chamber in airgap or annulus 20, extending from the surface to just below the base of the permafrost.
The outer annular space 12, which is situated a permafrost level, is adapted to filled with means (described hereinabove) to inhibit the transfer of heat from the pipe 16 to the ground surrounding outer casing 2.
As has been mentioned, broadly, the oil wells according to this invention will comprise only one annular space 12 which is filled with the means to inhibit heat transfer. In the preferred embodiments shown in the drawings, however, there are two annular spaces 12 and 20, 12 being filled with means to inhibit heat transfer and 20 being an empty annular space (as shown in FIG. 2) or preferably (as shown in FIGS. 1, 3 and 4), filled also with means to inhibit heat transfer.
as it issues from the production well the oil is at a temperature of about 170 F. and the means shown in annular space 12 functions to inhibit heat transfer from pipe 16 to the permafrost 4 so that the permafrost does not melt.
In the embodiment shown in FIG. 2, the means in annular space 12 would be a circulating liquid heat exchange fluid of the type illustrated above, e.g., brine, methanol-water, or aqueous ethylene glycol solution, and the like. This is circulated with pump 32 down a dip tube 34, up through the annular space 12, out through exit port 36, to a heat exchanger 30 to remove the heat gained during circulation, then back to pump 32. In accordance with good engineering practice, it is preferred for best efficiency to circulate a cold liquid. The initial temperature and flow rate will be selected to ensure that heat transfer through annular space 12 is impeded to such an extent that the permafrost is not melted. One way to accomplish this is to provide that the liquid emerging from the top of annular space 12 at point 36 remains below about 32 F. A sensing device (not shown) at this location may be used to measure the temperature. The conduction of heat from the hot oil in pipe 16 to the outer wall of inner casing will be reduced if an optional air gap 20 is provided as in shown in FIG. 2. This reduces the power consumption needed to remove heat picked up by the liquid heat transfer fluid circulating in annular space 12. The power will be reduced even more if air gap 20 is filled with means to inhibit heat transfer (as defined above), especially with thermal insulation of low conductivity, e.g., expanded polyurethane, expanded polystyrene or vermiculite.
In the embodiment shown in FIG. 3, the means circulated through annular space 12 would (as in FIG. 2) be a circulating liquid heat exchange fluid. In this embodiment annular space 12 is divided into two chambers by separator casing 40 to provide a down-up path for circulating the liquid, in the direction shown by the arrows.
In the embodiment shown in FIG. 4, the means in annular space 12 would be a circulating refrigerating boiling liquid of the type illustrated above, e.g., propane, ammonia, a Freon, and the like. This is circulated in a closed system with a pump 30 through a heat exchanger, e.g., a compressor, 42, and a holding tank 44, being introduced as a liquid through port 38 and being distributed by means of spiral guide 46 or other suitable means, such as a perforated dip tube, splash plates, Raschig rings and the like, (not shown) into annular space 12, volatilizing therein and removing the heat being introduced into the chamber by oil in pipe 16, leaving as a vapor at exit port 36 and returning to pump 30. In a preferred manner of operation, a small pool of refrigerating liquid 48, e.g., about l0 feet deep in a 2,000-foot annulus, will be allowed to collect at the bottom of the annulus 12. The level of the pool can be measured with an appropriate sensing device (not shown In addition to the features illustrated in the drawings the wells comprise conventional tubing strings and wellhead equipment in accordance with standard practice. The casings, 2 and 10, and pipe 16 are suspended from wellhead equipment so that the upper portions remain in tension. In the embodiments of FIGS. 2, 3 and 4 for example, flange 28 can be fastened to a mating flange in a system of control valves placed at the upper end of the pipe and casings conventionally used to cap a well and known as a Christmas tree.
From the foregoing description and examples, it is obvious that a simple and efficient method for producing oil from permafrost-containing formations has been discovered. Obvious modifications will suggest themselves to those skilled in art. For example, oil strings or production strings can be included in the wells; liners with many holes in them can be used; and conventional modifications will be made to accommodate the different kinds of underground pressure driving the oil to the surface Of course, the oil can also be pumped from the well.
The invention is not to be limited by the above description but is to be defined only by the appended claims.
What is claimed is:
l. A well for extracting oil from ground containing a permafrost zone comprising:
a. a pipe extending downwardly from the surface of the ground to the body of oil;
b. an inner casing surrounding the pipe and extending downwardly from the surface of the ground and terminating at a medial point along said pipe below the permafrost zone;
c. an outer casing surrounding the inner casing in spaced relationship to define with said inner casing an annulus extending downwardly from the surface of the ground to below the permafrost zone; and
d. liquid means in the annulus for inhibiting heat transfer from the interior of the pipe to the ground surrounding the outer casing.
2. A well as defined in claim I wherein said means for inhibiting heat transfer is liquid heat exchange fluid.
3. A well as defined in claim 2 wherein said liquid heat exchange fluid is brine, inhibited aqueous ethylene glycol solution or methanol-water.
4. A well as defined in claim 1 wherein said means for inhibiting heat transfer is a refrigerant liquid.
5. A well as defined in claim 4 wherein said refrigerant liquid is propane, ammonia or a nonflammable liquidfiuorinated hydrocarbon.
6. A well as defined in claim 1 wherein said inner casing is in a spaced relationship which defines with said pipe an inner annulus.
7. A well as defined in claim 6 wherein said inner annulus is provided with closure means at a location below the permafrost zone to provide an upper insulation chamber in said annulus.
8. A well as defined in claim 7 including means in said upper insulation chamber for inhibiting heat transfer from the interior of the pipe to the wall of the inner casing.
9. A well as defined in claim 8 wherein said means in the upper insulation chamber for inhibiting heat transfer is solid thermal insulation of low conductivity.
10. A well as defined in claim 7 wherein the annulus between the outer and inner casings contains a liquid heat exchange fluid or a refrigerant liquid.
11. A well as defined in claim 10 wherein the upper insulation chamber in the inner annulus between the inner casing and the pipe contains thermal insulation of low conductivity.
12. A process for completing a well for extracting oil from ground containing a permafrost zone which comprises the steps of:
a. drilling a first hole from the surface of the ground downwardly at least through the permafrost zone;
b. putting an outer casing down into said first hole;
c. drilling a second hole smaller in diameter than said first hole from the bottom of said first hole downwardly into the ground to a medial point between the oil level and the bottom of said first hole;
. putting an inner casing down into said second hole to line said second hole, the outer surface of said inner casing and the inner surface of said outer casing defining an annulus;
drilling a third hole smaller in diameter than said second hole downwardly from the bottom of said second hole through the ground into the oil reservoir;
f. putting a pipe down through said third hole into said oil reservoir, which pipe extends upwardly to the surface of the ground; and
g. introducing into said annulus liquid means for inhibiting heat transfer from the interior of said pipe to the earth surrounding said outer casing.
13. A process as defined in claim 12 wherein said means for inhibiting heat transfer is a liquid heat exchange fluid.
14. A process as defined in claim 13 wherein said liquid heat exchange fluid is brine, inhibited aqueous ethylene glycol solution or methanol-water.
15. A process as defined in claim 12 wherein said means for inhibiting heat transfer is refrigerant liquid.
16. A process as defined in claim 15 wherein said refrigerant liquid is propane, ammonia or a nonflammable 21 liquid-fluorinated hydrocarbon.
17. A process as defined in claim 12 wherein the outer surface of the pipe and the inner surface of the inner casing define an inner annulus.
18. A process as DEFINED in claim 17 including providing said inner annulus with closure means at a strategic location to provide an upper insulation chamber in said inner annulus.
19. A process as defined in claim 18 including introducing into said upper insulation chamber means for inhibiting heat transfer from the interior of THE pipe to the wall of the inner casing.
20. A process PROCESS as defined in claim 19 wherein said means in the upper insulation chamber for inhibiting heat transfer is a thermal insulation that has a low conductivity.
21. A process as defined in claim 20 wherein said thermal insulation is expanded polyurethane, expanded polystyrene or vermiculite.
22. A process as defined in claim 18 wherein the means for inhibiting heat transfer introduced into the annulus between the outer and inner casings is a liquid heat transfer fluid or a refzriferant liquid.
. A process as defined ll'l claim 22 wherein the means for inhibiting heat transfer introduced into the upper insulation chamber in the inner annulus between the inner casing and the pipe is a thermal insulation of low conductivity.
24. A well for extracting oil from ground containing a permafrost zone comprising:
a. a pipe extending downwardly from the surface of the ground to the body of oil;
b. an inner casing surrounding the pipe and extending downwardly from the surface of the ground and tenninating at a medial point along said pipe below the permafrost zone;
c. an outer casing surrounding the inner casing in spaced relationship to define with said inner casing an annulus extending downwardly from the surface of the ground to below the permafrost zone;
d. liquid means in the annulus for inhibiting heat transfer from the interior of the pipe to the ground surrounding the outer casing,
e. wherein said inner casing is in a spaced relationship which defines with said pipe an inner annulus;
f. said inner annulus being provided with closure means at a location below the permafrost zone to provide an upper insulation chamber in said annulus; and
g. said upper insulation chamber contains solid thennal insulation selected from expanded polyurethane, expanded polystyrene or vermiculite.
(5/69) WUENITEIISTATESPATENTCFFICE CERTIFICATE OF CORRECTION Patent No. 3,613,792 Dated October 19, 1971 Inventor(s) John W. Hyde and William J. George It is certified that error ap and that said Letters Patent are h peers in the above-identified patent ereby corrected as shown below:
Column 6, line I, delete "21"; line 6, delete "DEFINED", and insert defined line 11, delete "THE" and insert the and line 13, delete "PROCESS".
Signed and sealed this 9th day of May 1972.
EDWARD M.FLETCHER,JR. ROBERT GOT'I'SCHALK Attesting Officer Com issioner of Patents
|Cited Patent||Filing date||Publication date||Applicant||Title|
|US3142336 *||Jul 18, 1960||Jul 28, 1964||Shell Oil Co||Method and apparatus for injecting steam into subsurface formations|
|US3179528 *||Nov 26, 1962||Apr 20, 1965||Pan American Petroleum Corp||Low temperature cementing composition|
|US3397745 *||Mar 8, 1966||Aug 20, 1968||Carl Owens||Vacuum-insulated steam-injection system for oil wells|
|US3438442 *||Jul 29, 1966||Apr 15, 1969||Shell Oil Co||Low-temperature packer|
|US3456735 *||Feb 1, 1967||Jul 22, 1969||Exxon Production Research Co||Method for completing wells to prevent paraffin deposits|
|US3498381 *||Jul 25, 1968||Mar 3, 1970||Marathon Oil Co||Method for injection of hot fluids into an underground formation|
|US3561531 *||Aug 21, 1969||Feb 9, 1971||Exxon Production Research Co||Method and apparatus for landing well pipe in permafrost formations|
|SU184205A1 *||Title not available|
|1||*||Gatlin, Carl. Petroleum Engineering. Englewood Cliffs, N.J. Prentice-hall, 1960. pp. 269, 270 (Copy in Group 350).|
|2||*||Slope Operators Plan Subsidence Fight. In Oil & Gas J., Dec. 8, 1969, pp. 69 72. (Copy in 166 302).|
|Citing Patent||Filing date||Publication date||Applicant||Title|
|US3720267 *||Apr 5, 1972||Mar 13, 1973||Atlantic Richfield Co||Well production method for permafrost zones|
|US3763931 *||May 26, 1972||Oct 9, 1973||Mc Donnell Douglas Corp||Oil well permafrost stabilization system|
|US3766985 *||Dec 1, 1971||Oct 23, 1973||Univ Kansas State||Production of oil from well cased in permafrost|
|US3791443 *||Dec 13, 1971||Feb 12, 1974||Atlantic Richfield Co||Foundation for construction on frozen substrata|
|US3880236 *||Aug 9, 1972||Apr 29, 1975||Union Oil Co||Method and apparatus for transporting hot fluids through a well traversing a permafrost zone|
|US3948313 *||Feb 9, 1973||Apr 6, 1976||The Dow Chemical Company||Arrangement to control heat flow between a member and its environment|
|US3989108 *||May 16, 1975||Nov 2, 1976||Texaco Inc.||Water exclusion method for hydrocarbon production wells using freezing technique|
|US4036285 *||Dec 10, 1975||Jul 19, 1977||The Dow Chemical Company||Arrangement to control heat flow between a member and its environment|
|US5289881 *||Apr 1, 1991||Mar 1, 1994||Schuh Frank J||Horizontal well completion|
|US5607018 *||Sep 29, 1994||Mar 4, 1997||Schuh; Frank J.||Viscid oil well completion|
|US5607901 *||Feb 17, 1995||Mar 4, 1997||Bp Exploration & Oil, Inc.||Environmentally safe annular fluid|
|US6173783 *||May 17, 1999||Jan 16, 2001||John Abbott-Brown||Method of completing and producing hydrocarbons in a well|
|US6328110 *||Jan 20, 2000||Dec 11, 2001||Elf Exploration Production||Process for destroying a rigid thermal insulator positioned in a confined space|
|US6908886||Jan 9, 2003||Jun 21, 2005||M-I L.L.C.||Annular fluids and method of emplacing the same|
|US7829509||Nov 9, 2010||M.I. L.L.C.||Annular fluids and method of emplacing the same|
|US7863223||Oct 3, 2006||Jan 4, 2011||M-I L.L.C.||Oil-based insulating packer fluid|
|US8624072||May 25, 2012||Jan 7, 2014||Mcalister Technologies, Llc||Chemical reactors with annularly positioned delivery and removal devices, and associated systems and methods|
|US8669014||Feb 11, 2013||Mar 11, 2014||Mcalister Technologies, Llc||Fuel-cell systems operable in multiple modes for variable processing of feedstock materials and associated devices, systems, and methods|
|US8671870||Aug 13, 2012||Mar 18, 2014||Mcalister Technologies, Llc||Systems and methods for extracting and processing gases from submerged sources|
|US8673220||May 25, 2012||Mar 18, 2014||Mcalister Technologies, Llc||Reactors for conducting thermochemical processes with solar heat input, and associated systems and methods|
|US8673509||Aug 13, 2012||Mar 18, 2014||Mcalister Technologies, Llc||Fuel-cell systems operable in multiple modes for variable processing of feedstock materials and associated devices, systems, and methods|
|US8734546||Feb 11, 2013||May 27, 2014||Mcalister Technologies, Llc||Geothermal energization of a non-combustion chemical reactor and associated systems and methods|
|US8771636||Nov 26, 2012||Jul 8, 2014||Mcalister Technologies, Llc||Chemical processes and reactors for efficiently producing hydrogen fuels and structural materials, and associated systems and methods|
|US8821602||Aug 13, 2012||Sep 2, 2014||Mcalister Technologies, Llc||Systems and methods for providing supplemental aqueous thermal energy|
|US8826657||Feb 11, 2013||Sep 9, 2014||Mcallister Technologies, Llc||Systems and methods for providing supplemental aqueous thermal energy|
|US8888408||Feb 11, 2013||Nov 18, 2014||Mcalister Technologies, Llc||Systems and methods for collecting and processing permafrost gases, and for cooling permafrost|
|US8911703||Feb 11, 2013||Dec 16, 2014||Mcalister Technologies, Llc||Reducing and/or harvesting drag energy from transport vehicles, including for chemical reactors, and associated systems and methods|
|US8926719||Mar 13, 2014||Jan 6, 2015||Mcalister Technologies, Llc||Method and apparatus for generating hydrogen from metal|
|US8926908||Nov 26, 2012||Jan 6, 2015||Mcalister Technologies, Llc||Reactor vessels with pressure and heat transfer features for producing hydrogen-based fuels and structural elements, and associated systems and methods|
|US9039327 *||Aug 13, 2012||May 26, 2015||Mcalister Technologies, Llc||Systems and methods for collecting and processing permafrost gases, and for cooling permafrost|
|US9103548||Mar 17, 2014||Aug 11, 2015||Mcalister Technologies, Llc||Reactors for conducting thermochemical processes with solar heat input, and associated systems and methods|
|US9188086||Feb 14, 2011||Nov 17, 2015||Mcalister Technologies, Llc||Coupled thermochemical reactors and engines, and associated systems and methods|
|US9206045||Feb 14, 2011||Dec 8, 2015||Mcalister Technologies, Llc||Reactor vessels with transmissive surfaces for producing hydrogen-based fuels and structural elements, and associated systems and methods|
|US9222704||Apr 11, 2014||Dec 29, 2015||Mcalister Technologies, Llc||Geothermal energization of a non-combustion chemical reactor and associated systems and methods|
|US9302681||Aug 13, 2012||Apr 5, 2016||Mcalister Technologies, Llc||Mobile transport platforms for producing hydrogen and structural materials, and associated systems and methods|
|US9309473||Mar 17, 2014||Apr 12, 2016||Mcalister Technologies, Llc||Systems and methods for extracting and processing gases from submerged sources|
|US20040138070 *||Jan 9, 2003||Jul 15, 2004||Jones Andrew G.K.||Annular fluids and method of emplacing the same|
|US20050176591 *||Mar 1, 2005||Aug 11, 2005||M-I L.L.C.||Annular fluids and method of emplacing the same|
|US20070149412 *||Oct 3, 2006||Jun 28, 2007||M-I Llc||Oil-based insulating packer fluid|
|US20070163805 *||Jan 3, 2007||Jul 19, 2007||Soilmec S.P.A.||System for drilling the ground to obtain circulation of fluid in a plant for the exploitation of geothermal energy|
|US20080224087 *||Mar 11, 2008||Sep 18, 2008||Ezell Ryan G||Aqueous-Based Insulating Fluids and Related Methods|
|US20080227665 *||Mar 14, 2007||Sep 18, 2008||Ryan Ezell||Aqueous-Based Insulating Fluids and Related Methods|
|US20100200237 *||Feb 11, 2010||Aug 12, 2010||Colgate Sam O||Methods for controlling temperatures in the environments of gas and oil wells|
|US20100236784 *||Mar 22, 2010||Sep 23, 2010||Horton Robert L||Miscible stimulation and flooding of petroliferous formations utilizing viscosified oil-based fluids|
|US20100252259 *||Mar 31, 2010||Oct 7, 2010||Horton Robert L||Oil-based hydraulic fracturing fluids and breakers and methods of preparation and use|
|US20100263867 *||Oct 21, 2010||Horton Amy C||Utilizing electromagnetic radiation to activate filtercake breakers downhole|
|US20130094909 *||Aug 13, 2012||Apr 18, 2013||Mcalister Technologies, Llc||Systems and methods for collecting and processing permafrost gases, and for cooling permafrost|
|EP2481883A2||Oct 3, 2006||Aug 1, 2012||M-I L.L.C.||Oil-based insulating packer fluid|
|WO2004063521A2 *||Jan 9, 2004||Jul 29, 2004||M-I L. L. C.||Annular fluids and methods of emplacing the same|
|WO2004063521A3 *||Jan 9, 2004||Oct 28, 2004||Mi Llc||Annular fluids and methods of emplacing the same|
|WO2009023415A2||Jul 24, 2008||Feb 19, 2009||M-I Llc||Insulating annular fluid|
|WO2009112808A2 *||Mar 5, 2009||Sep 17, 2009||Halliburton Energy Services, Inc.||Improved aqueous-based insulating fluids and related methods|
|WO2009112808A3 *||Mar 5, 2009||Nov 26, 2009||Halliburton Energy Services, Inc.||Improved aqueous-based insulating fluids and related methods|
|WO2014160644A1 *||Mar 24, 2014||Oct 2, 2014||Halliburton Energy Services, Inc.||Aqueous-based insulating fluids and related methods|
|U.S. Classification||166/302, 166/57, 166/901|
|International Classification||E21B36/00, E21B33/10|
|Cooperative Classification||E21B36/003, E21B33/10, Y10S166/901|
|European Classification||E21B36/00C, E21B33/10|