US3616152A

US3616152A - Resin films

Info

Publication number: US3616152A
Application number: US733576A
Authority: US
Inventors: Edmond A Chandler
Original assignee: USM Corp
Current assignee: USM Corp
Priority date: 1968-05-31
Filing date: 1968-05-31
Publication date: 1971-10-26
Anticipated expiration: 1988-10-26
Also published as: DE1927569C3; FR2009782A1; ES368224A1; GB1273451A; JPS4937114B1; SE384466B; DE1927569B2; DE1927569A1

Abstract

This invention is concerned with a thin film of thermoplastic resin adhesive with a special arrangement of slits or cuts and a method of adhesive deposition or bonding in which the film of adhesive is applied to one surface, heat is applied to bring the adhesive to active condition and cause the film to assume a pattern directly related to the arrangements of slits or cuts and particularly effective for bonding.

Description

ilite tates Patent [72] Inventor Edmond A. Chandler Winchester, Mass. [21] Appl. No. 733,576 [22] Filed May 31, 1968 [45] Patented Oct. 26, 1971 [73] Assignee USM Corporation Boston, Mass.

[54] RESIN lFlLMS 7 Claims, 7 Drawing Figs.

[52} [1.5. CI. 161/109, 117/4,117/37,117/122 H,156/84, 156/85, 161/117, 16l/DIG. 6 [51] lnt.C1 1332b 3/10 [50] Field of Search... 117/4, 37, 122 H, 62.2; 156/248, 247, 85, 84', 161/109, 117

[56] References Cited UNITED STATES PATENTS 2,337,525 12/1943 Peik 161/109 Primary Examiner-Alfred L. Leavitt Assistant ExaminerM. F. Esposito AnorneysW. Bigelow Hall, Richard A. Wise and Benjamin C. Pollard ABSTRACT: This invention is concerned with a thin film of thermoplastic resin adhesive with a special arrangement of slits or cuts and a method of adhesive deposition or bonding in which the film of adhesive is applied to one surface, heat is applied to bring the adhesive to active condition and cause the film to assume a pattern directly related to the arrangements of slits or cuts and particularly effective for bonding.

RESIN FILMS FIELD OF THE INVENTION Adhesive processes for bonding articles, for example, for bonding outsoles to shoe uppers are known in which a band of thermoplastic synthetic polymeric resin adhesive is applied in molten form to one of the attaching surfaces and, at the time the attaching is to be completed, the adhesive band is reheated and assembled against the heated attaching surface of the shoe upper. Excellent bonds are obtained; but the process requires the separate steps of applying molten adhesive to the tread member to form an adhesive band and the further steps of reheating the adhesive and the surface which is to be placed against it. Also because of irregularities in the attaching surface, aband of adhesive of substantial thickness has been required.

Another procedure forming the subject of US. Pat. No. 3,483,581 entitled Adhesive Processes" issued Dec. l6, 1969 in the names of Edmond A. Chandler and Kenelm W. Winslow, involves laying down a coherent adhesive sheet of thin interconnected strands of thermoplastic resin adhesive on a surface to be bonded and thereafter heating the adhesive sheet and both of the surfaces which are to be joined by the adhesive. This procedure is effective to form strong bonds rapidly using a minimum amount of adhesive, however, the making of a sheet composed of thin interconnected strands introduces an element of expense and imposes rather difficult problems in forming a sheet of the desired uniformity.

it is an object of the present invention to provide an inexpensive, uniform adhesive sheet or film and a method of bonding using that film to deposit adhesive in a regular uniform open pattern of molten adhesive by a heating step effective to activate the adhesive and preheat the surface on which the adhesive sheet is disposed.

To these ends and in accordance with a feature of the present invention, l have provided a novel adhesive article in the form of a thin sheet or film of thermoplastic polymeric resin adhesive with spaced cuts or slits arranged to give a pattern of adhesive on heating. The sheet or film initially provides a large surface area effective to absorb activating heat and when laid on a surface to be bonded and subjected to heat is converted by that heat to a regular open pattern of adhesive and exposes to the activating heat substantial portions of the surface on which it was laid. After assembly and pressing of another surface against the heated adhesive and its associated surface, and cooling the assembly, a strong bond is obtained.

The invention will be described further in connection with the attached drawings forming part of the disclosure.

In the drawings,

FIG. 1 is an angular view of a film of adhesive illustrative of one embodiment of the invention disposed on a surface of a workpiece and showing a radiant heat source disposed to convert the adhesive film to an open pattern and to activate the adhesive;

FIG. 2 is a plan view of the surface of the workpiece and the adhesive after being heated to convert the film to an open pattern of adhesive;

FIG. 3 is an elevational view of an assembly of a second workpiece with the workpiece carrying the open pattern of adhesive developed in FIG. 2;

FIG. 4 is a plan view ofa second illustrative embodiment of the invention with cuts disposed in a different pattern in the adhesive film;

FIG. 5 is a plan view showing the pattern of adhesive developed by heating the adhesive film of FIG. 4;

FIG. 6 is a plan view of another embodiment of the invention with parallel rows of slits arranged with slits opposite slits and uncut portions opposite uncut "portions in the adhesive film; and

FIG. 7 is a plan view of the pattern of adhesive developed by heating the adhesive film of FIG. 6.

As shown in the drawings, see FIGS. 1, 4 and 6, the novel adhesive sheet 10 is a thin synthetic polymer resin adhesive film with spaced slits or

cuts

12, 32 and 42, respectively, so arranged that when the film is softened by heat, the film draws in at the edges of the slits or cuts to form an open pattern such as intersecting lines or beads 14 (FIG. 2) of softened, usually molten adhesive extending approximately along the median lines of the portions of the film between slits or cuts 12. The pattern or configuration of the adhesive is determined by the size, spacing and relative position of the slits or cuts 12 in the initial adhesive film 10. Although only three arrangements are shown, a wide variety of patterns or configurations of adhesive can be provided by arranging the spacing and relative position of the slits or cuts.

According to the method of the present invention the new thermoplastic adhesive sheet 10 is supported on the surface 16 ofa workpiece l7 and subjected to heat to soften it and cause it to assume the desired open pattern such as an intersecting line configuration. Since movement of the adhesive under the action of heat is an important feature, the sheet 10 is not clampedtightly between surfaces, but it is generally preferred that it be merely supported on thesurface 16 and subjected to a heat source 18 such as radiant heat or hot gases in order that the movement of the adhesive not be restrained.

The sheet or film 10 can also be reduced to the open adhesive pattern by heating it on a hot surface. While the supporting surface on which the adhesive sheet is subjected to heat is shown as the surface 16 of the workpiece to be bonded by the adhesive, it may be a release surface such as a silicone or polytetrafluoroethylene coated surface from which the adhesive may be stripped after heating to give it the desired configuration and cooling to solidify it. The open pattern adhesive sheet so obtained may be assembled with surfaces to be bonded and activated to wet and adhere to those surfaces. On cooling such assembly a strong bond is obtained.

ln general, thin films are converted to line patterns more readily than thicker film and when the films are over about 0.03 inch, the opening effect is not reliable. The width of film section between cuts should not be over about three-sixteenths inch and with films of about 0.03 inch in thickness, the width should be not over about one'eighth inch. it appears im' portant that the thickness of the film be not more than onethird, preferably considerably less than one-third the width of the space between adjacent lines or cuts. Also in an arrangement of slits or cuts it is preferred that the length of the slits or cuts be at least equal to and preferably at least three times the greatest distance between any point on the edge ofa slit or cut and the closest point on the slit or cut nearest the first-mentioned point.

The term greatest distance between any point on the edge of a slit or cut and the closest point on the slit or cut nearest to the first-mentioned point" may be more readily understood from the following discussion. From each point on a first slit or cut the distance can be measured to the closest point on the slit or cut nearest to the first-mentioned point. The distances will be greater from some points on the first-mentioned slit or cut to the slit or cut nearest to such points; and there will be one point on the slit or cut for which the distance to the closest point on the slit or cut nearest to it will be greatest. It is this greatest distance that is referred to above and in the claims by use of the quoted language.

A preferred pattern of adhesive slits or cuts is shown in F IG. 1 and comprises spaced parallel lines 20 ofinterrupted cuts 12 with the cuts of one line 20 disposedo pposite uncut portions 22 of adjacent lines 20 of interrupted cuts and with the ends of the cuts of one line overlapping the ends of the cuts of adjacent lines. Desirably the end of a cut in one line may overlap the end ofa cut in an adjacent line by from about 15 to about 40 percent of the length of the cut. This arrangement is particularly satisfactory since stresses, developed in the course of shrinking of the film, may be relieved by movement ofthe narrower portions of film between overlapping portions of the cuts of adjacent rows of cuts. As shown in HO. 2 a reticulated pattern is formed on heating which comprises portions 24 of the lines 14 corresponding to the segments of film between the ends of cuts in a given line and portions 26 of the line 14 from the portions of film where the slits or cuts of adjacent lines overlapped, which link the portions 24 to form a network.

The open pattern of heat softened adhesive provides a uniform effective distribution of the adhesive enabling good coverage with a minimum quantity of adhesive. When a second workpiece 27 (FIG. 3) is laid down on the heat softened adhesive and the workpieces are pressed together as shown in FIG. 3 the

lines

24 and 26 of adhesive establish wetting contact with the surfaces and give an excellent adhesiveness.

An alternative pattern of cuts is shown in FIG. 4 and comprises rows of spaced parallel cuts or slits 32 extending in from the

opposite edges

28, 29 of a strip 30 of the adhesive sheet material I leaving a central uncut portion 31. As in the case of the adhesive film shown in FIG. I and described above, it is desired that the length of the slits 32 be at least equal to and preferably at least three times the width of the segments 34, between adjacent parallel slits and it is important that the thickness of the adhesive film or sheet be not more than one-third the width of the segments 34 of adhesive film 30 between adjacent parallel slits 32. In the article shown in FIG. 4, the slits 32 are arranged at an angle other than a right angle to the direction of the strip 30 of adhesive in order to provide a greater length of the segments 34 relative to their width. On heating, the adhesive of the central uncut portion 31 of the strip forms a somewhat irregular backbone 37, as shown in FIG. 5. while the adhesive of the segments 34 forms angularly extending lines 39 somewhat in the nature of a herringbone pattern.

A further alternative form is shown in FIG. 6 in which spaced parallel lines 42 of interrupted cuts 44 are disposed in a strip 40 so that the cuts 44 of one line are opposite the cuts of adjacent lines and uncut portions are opposite uncut portions. Heating such a strip results in pulling-in of the adhesive to form openings 46, as shown in FIG. 7 which have some advantage in allowing gas trapped under the film to escape. But this pattern of film does not offer the full advantage of developing lines or beads as in the forms of the adhesive sheet shown in FIGS. I and 4.

As the adhesive of which the sheet is formed, it is preferred to use high molecular weight thermoplastic synthetic polymer resin, for example, relatively high molecular weight polyesters, polyamides, polyesteramides and thermoplastic polyester glycol urethanes or polyether glycol urethanes. Other normally solid heat-softenable polymeric adhesive materials may be used which, either alone or in admixture, can be formed into thin, nontacky films which retract on heating, and which are capable of melting to a condition for wetting and adhering surfaces to be joined and of hardening to provide an adhesive bond.

The following examples are given to aid in understanding the invention but it is to be understood that the invention is not limited to the particular materials, dimensions or arrangemerits of cuts shown in the examples nor to the particular procedures or conditions employed.

EXAMPLE I A polyamide from condensation of a mixture of 85 percent dimerized linoleic acid and mol percent of azelaic acid with a mixture of diamines comprising 85 mol percent of ethylene diamine and I5 mol percent of hexane diamine was formed into a thin film about 0.010 inch in thickness. This polyamide had a softening point (Ball and Ring) of about 275 F. and a viscosity at 355 F. as determined with a three thirty-seconds inch falling steelball of from 50 to 60 seconds. Parallel cuts were made in the film in a pattern similar to that shown in FIG. I in which the slits were about one-halfinch long and adjacent lines ofslits were spaced about three thirty-seconds inch.

A I-inch wide strip of the material was disposed on the surface of a piece of butadiene styrene copolymer synthetic rubber shoe-sole stock and was subjected to radiant heat at a distance of 2 inches for a period of about l5 seconds. During the heating the film softened and shrank in from the cut edges to form a reticulated pattern of lines of molten adhesive as shown in FIG. 2. As the adhesive film shrank in, the underlying portions of shoe sole stock were exposed to the radiant heat and brought to elevated temperature for effective union with the adhesive in subsequent steps.

At the same time that the strip of stock with the adhesive film on it was subjected to heat, another piece of outsole stock was subjected to comparable heating. Directly on completion of the heating steps the strip of sole stock with the reticulated pattern of adhesive on it was pressed against the second piece of shoe-sole stock to squeeze the molten adhesive and force it into wetting adhesive engagement with the surfaces of each of the pieces of soling stock. On cooling of the assembly it was found that the pieces of soling stock were held together with strength adequate for sole attaching.

EXAMPLE II A crystallizable copolyester was prepared by condensation and polymerization of a 5.0:4.l:0.9 mol ratio mixture of terephthalic acid, isophthalic acid and dibutyl sebacate with 1,4 butane diol having a melting point of about 280 F. was formed into a 0.010 inch -inch thick continuous film and the film was cut into strips I inch in width. Spaced parallel slits were cut in extending from opposite edges of the strip of adhesive sheet material. The slits were spaced about three-sixteenths inch apart and were exposed at an angle of about 45 to the direction of the strip leaving an uncut portion of the strip along the center about three-sixteenths inch wide as shown in FIG. 4.

A length of the adhesive Filmstrip was disposed on the surface of a piece of outsole stock and was subjected to heating and assembled with a heated second section of outsole stock as in example I. The heated sections. were pressed together with the adhesive between them. In the process of heating, the adhesive shrank in from the cut edges to form lines of molten adhesive arranged in a roughly herringbone pattern as shown in FIG. 5.

After assembly and pressing together of the strips, the strips were allowed to cool. On cooling it was found that the strips were bonded together with a strength sufficient for outsole attaching on shoes.

EXAMPLE III A thermoplastic adhesive composition was prepared comprising about 40 parts by weight of a polyterpene resin (Schenectady Resin St 5115) having a melting point of l 15 C. and understood to be a polymer of beta-pinene, 56 parts by weight of a resinous polyethylene and about 4 parts by weight of butyl rubber. This adhesive composition had a falling ball viscosity as determined at 196 C. using a three-sixteenths inch steel ball of from 40 to 50 seconds.

A 0.010 inch -inch thick film was formed of this adhesive and the film was slit in the same pattern as that used in FIG. I.

A l-inch wide strip of the slit film was disposed on paper and subjected to radiant heat at a distance of I inch from the radiant heat source for IS seconds. The adhesive shrank to form a reticulated pattern comparable to that shown in FIG. 2. When a second piece of paper was pressed against the molten adhesive on the surface of the first piece, a strong bond was formed promptly. After cooling, the pieces of paper could not be separated without destroying the paper.

Having thus described my invention whatl claim as new and desire to secure by Letters Patent of the United States is:

I. As an article for disposing normally solid heat-softenable polymerresin adhesive in a predetermined open pattern when placed on a surface and heated, a thin free film of said resin adhesive having a thickness not over about 0.3 inch and less than about one-third the width of the space between adjacent slits, said resin adhesive film when heat-softened to a condition capable of wetting and adhering surfaces being capable of drawing itself into a line pattern, said film being formed with slits spaced at distances of not over about three-sixteenths inch and being disposed and arranged to determine said pattern, said slits having lengths at least about equal to the greatest distance between any point on the edge of a slit and the closest point on a slit nearest to said first-mentioned point.

2. An article as defined in claim l in which said slits are arranged in parallel rows with slits of one row opposite unslit portions of an adjacent row of slits.

3. An article as defined in claim 2 in which the ends of slits in one row overlap the ends of slits in an adjacent row by from about percent to about 40 percent of the length of the slits.

d. An article as defined in claim 1 in which said film is a strip having a row of parallel slits extending in from an edge of said strip leaving a continuous portion of said strip extending lengthwise of said strip.

5. An article as defined in claim 4 in which said slits are disposed at an angle other than a right angle to the longitudinal direction of said strip. a

6. An article as defined in claim 5 having rows of parallel slits extending in from opposite edges of said strip leaving a continuous portion of said strip extending centrally of said strip.

7. As an article for disposing normally solid heat-softenable polymer resin in a predetermined open pattern when placed on a surface and heated, a thin free film of said resin having a.

"Q UNITED STATES PATENT OFFICE CERTIFICATE OF CORRECTION Patent No. 3,616, 152 Dated Octooer 26 U7] Inventor(s) Edmond Chandler It is certified that error appears in the above-identified patent and that said Letters Patent are hereby corrected as shown below:

column H, Last line "0.3" should read --0.03--

Signed and sealed this 5th day of December 1972.

(SEAL) Attest:

EDWARD M.FLETCHER,JR. ROBERT GOTTSCHALK Commissioner of Patents Attesting Officer

Claims

2. An article as defined in claim 1 in which said slits are arranged in parallel rows with slits of one row opposite unslit portions of an adjacent row of slits.
3. An article as defined in claim 2 in which the ends of slits in one row overlap the ends of slits in an adjacent row by from about 15 percent to about 40 percent of the length of the slits.
4. An article as defined in claim 1 in which said film is a strip having a row of parallel slits extending in from an edge of said strip leaving a continuous portion of said strip extending lengthwise of said strip.
5. An article as defined in claim 4 in which said slits are disposed at an angle other than a right angle to the longitudinal direction of said strip.
6. An article as defined in claim 5 having rows of parallel slits extending in from opposite edges of said strip leaving a continuous portion of said strip extending centrally of said strip.
7. As an article for disposing normally solid heat-softenable polymer resin in a predetermined open pattern when placed on a surface and heated, a thin free film of said resin having a thickness not over about 0.03 inch and less than about one-third the width of the space between adjacent slits, said resin film when heat-softened being capable of drawing itself into a line pattern, said film being formed with slits spaced at distances of not over about three-sixteenths inch and being disposed and arranged to determine said pattern, said slits having lengths at least about equal to the greatest distance between any point on the edge of a slit and the closest point on a slit nearest to said first-mentioned point.