|Publication number||US3639245 A|
|Publication date||Feb 1, 1972|
|Filing date||Jul 22, 1968|
|Priority date||Jul 22, 1968|
|Also published as||DE1937651A1, DE1937651B2, DE1937651C3|
|Publication number||US 3639245 A, US 3639245A, US-A-3639245, US3639245 A, US3639245A|
|Inventors||Robert B Nelson|
|Original Assignee||Minnesota Mining & Mfg|
|Export Citation||BiBTeX, EndNote, RefMan|
|Patent Citations (2), Referenced by (75), Classifications (18)|
|External Links: USPTO, USPTO Assignment, Espacenet|
United States Patent Nelson Feb. 1, 1972 ..G03g9/02 WhQ F P; in? Y- D- elestrivcal field Field of Search ..252/62.l, 62.53, 62.54 between and mm/cma D.C. electrical field, References Cited b. 2snrcllumber average particle diameter below 15 microns, UNITED STATES PATENTS c. a volume ratio of said electrically conductive particles to said total particle volume of between 0.01/100 and 3,345,294 10/1967 Cooper ..252/62.l 4/100 7/ I965 Seymour ..252/65.1 8 Claims, 1 Drawing Figure 3 G q \g l z km" E F /0' 3L -15 M 6 R F f g -a b /0 we 5mm DEVELOPER POWER OF THERMOPLASTIC SPECIAL PARTICLES HAVING CONDUCTIVE PARTICLES RADIALLY DISPERSED THEREIN lnventor: Robert B. Nelson, Lake Elmo, Minn.
Company, Saint Paul, Minn.
July 22, 1968 Filed:
Minnesota Mining and Manuiacturing Primary Examiner-George F. Lesmes Assistant Examiner-J. P. Brammer Attorney-Kinney, Alexander, Sell, Steldlt & Delahunt  ABSTRACT Flowable, heat fusible, dry powder suitable for use as a developer powder in electrographic recording which comprises thermoplastic, essentially spherical particles, the thermoplastic material of which has a conductivity of at most 10' mho/cm., in which are essentially completely embedded electrically conductive particles forming a radially disposed zone, said essentially spherical particles having:
a. an electronic conductivity ranging monatonically without decreasing from between about 10 and DEVELOPER POWER OF THERMOPLASTIC SPECIAL PARTICLES HAVING CONDUCTIVE PARTICLES RADIALLY DISPERSED TI-IEREIN This invention relates to a dry ink powder suitable for use in electrographic recording and a process for making such powder. In one aspect this invention relates to a developer powder having a good electrical conductivity in the presence of a relatively large impressed electric field, and low electrical conductivity (and hence good charge retention characteristics for the charge remaining on it) in the absence of this high impressed field. In still another aspect this invention relates to dry developer particles for electrophotography which are magnetizable. in still another aspect, this invention relates to a developer powder which has a pressure dependent conductivity, being more conductive under the influence of an impressed magnetic field during development, and less conductive (and hence having better individual charge retention characteristics) in the absence of this impressed magnetic field.
Electrostatic electrophotography originally employed two component dry ink powders, often called triboelectric mixtures," for charge development of the electrostatic image. Recently dry powders in which all of the particles are of the same composition have been described. The relatively conductive dry inks of U.S. Pat. No. 3,116,510 (Jan. 19, 1965; Charles P. West and Jacques Benveniste) contain thermoplastic resin particles in which about 35 to 55 percent of the total particle weight is carbon black dispersed throughout the resin particles. In U.S. Pat. No. 3,196,032 (July 20, 1965; David W. Seymour) an electrostatic printing ink having carbon powder partially embedded in or adhered to the surface of resin particles is prepared in a fluid bed reactor.
in a new electrographic process, described in French Pat. No. 1,456,993, an exposed photoconductive sheet is contacted with conductive developer powder applied from a conductive surface, to which it is adhered, while creating a differential electrical field between the photoconductive sheet (i.e., field electrode) and the conductive surface containing the developer powder. The developer powder is transferred selectively to the photoconductive sheet in the nonexposed areas. Separation of the photoconductive sheet from the source of supply of developer powder is made while still maintaining the influence of the electrical field, and provision can be made for continuing the attraction of the developer powder to the surface of the photoconductive sheet after such separation. The developer powder in this process is electronically conductive, usually having a conductivity of at least l mho per centimeter (ohm"cm.' preferably to 10' mho per centimeter, at the applied electrical field (preferably at least 1,000 DC volts per centimeter). Conductivity measurements are made with the developer powder compressed into a 1-centimeter cube between brass electrodes fitted in a rigid chamber, a pressure of 86 pounds per square inch (6.05 kg. per cm?) being applied across the sample before and during the measurement of conductance. If the developer powder is subsequently to be transferred from the photoconductive sheet to a receptor surface, it should also have electrical charge retention capability, to retain the electrical charge imparted to the developer particles by the applied electrical field during the development of the pattern on the field electrode. This may be accomplished by providing the developer particles with a highly resistive interior or core and a highly conductive surface or shell. However, the high conductivity of the developer particles desired to minimize voltage drop across them when they are in the electrical field, and the ability ofthe developer particles to retain the electrical charge, which characterizes high resistivity particles, are difficult to achieve satisfactorily, since one desirable characteristic is generally sacrificed to obtain the other.
It is therefore an object of this invention to provide new particles suitable for use as electrographic developers, particularly in the process of French Pat. No. 1,456,993, also referred to as the Electropowder process. Still another object of this invention is to provide powder particles having both high conductivity and good electrical charge retention. Yet another object is to provide a process for the manufacture of such developer particles.
The FIGURE is a plot of electrical conductivity vs. DC ap- I plied electrical field for developer particles of this invention.
The developer powders of this invention comprise thermoplastic, essentially spherical particles (i.e., spherules), the thermoplastic material of which has a conductivity of at most 10-" mho/cm, preferably at most 10" mho/cm, in which are essentially completely embedded electrically conductive particles forming a radially disposed layer or zone, said essentially spherical particleshaving an electronic conductivity which ranges monatonically without decreasing from between about 10' and about 10" mho/cm. (preferably between 10' and 10 mho/cm.) in a 100 v./cm. DC electrical field to between 10 and about 10' mho/cm. (preferably between 10 and 10 mho/cm.) in a 10,000 v./cm. DC electrical field, and having a number average diameter below 15, preferably below 10, microns. Preferably, the average particle size range is such that at least about 95 number percent of the particles have a diameter greater than about 2 microns, while no more than 5 number percent have a diameter greater than about 15 microns. These dry ink powders are flowable to such an extent that they have a flowability angle of repose ranging from about to 125 and preferably from 1 10 to 125. For purposes of this invention, flowability is measured by feeding a thin stream of powder to the upper flat surface of a 3-inch diameter circular pedestal from a vibrating funnel, thereby creating a conical deposit of powder on the pedestal. The angle of repose is defined by the angle measured between opposite sides of the conical deposit, i.e., the apex angle of the cone, at 25 C.
The dry ink powders of this invention and the thermoplastic materials used therein are preferably heat fusible in the range of 80 to 1 15 C., preferably from to 105 C. For determining fusion temperatures the Durrans Mercury method, as reported in SMS] 14, is employed. Any heat fusible thermoplastic material having a conductivity of at most 10' mho/cm. may be used to form the spherules, although thermoplastic organic polymers are preferred. Examples of suitable resins include B-stage (i.e., partially cured) phenol aldehyde polymers, polyvinyl acetate, epoxy resins, etc.
In general, any highly electrically conductive material (i.e., a material having a conductivity of at least 10 mho/cm., such as conductive carbon, metal, etc.) may be used in powdered form as the electrically conductive particles forming the conductive zone of the dry ink particles, provided the resulting electrically conductive particles have an average diameter below millimicrons, preferably under 40 millimicrons. Conductive carbon particles (e.g., those available under the trade name Vulcan XC-72R, sold by Cabot-Corporation) are preferred.
It has been found that the amount of conductive material in the embeddedzone of the dry ink particle, the type of conductive material used, the particle size of the embedded conductive particles, and the location of the embedded zone can influence the conductivity of the dry ink powder. Generally the volume ratio of electrically conductive material to the total particle volume in the ink powder can be in the range of 001/100 to 4.0/100, although 0.1/100 to 1.5/100 is preferred. The embedded zone of conductive particles is normally quite close to the surface of the ink particle and is preferably not thicker than one-tenth the radius of the essentially spherical developer particle. Although essentially all of the conductive particles are embedded, an occasional particle may protrude from the surface. The conductivity of these developer particles is field dependent," i.e., the conductivity under high electrical fields differs from the conductivity under low electrical fields. In fact, as mentioned earlier, the electrical conductivity of the developer particles is a monatonically, nondecreasing function of the applied DC electrical field. It is preferred that the slope of the conductivity vs. applied electrical field curve also increases monatonically with the applied electrical field. This has been found to be extremely valuable for developer powders used in the process of French Pat. No.
TABLE I Parts by weight Size distribution 3 Conductivity (ohm cm)" Pigment Resin 1 giarblpr i Silica 4 95% b% 100. v./cm. 10,000 v./cm.
e0 40 1. as .1 3. 7 e. 4 12. e 2. SXAO- 4x10-' 60 40 1.2 .1 3.1 6.7 13 0 3. 0x10 5 GXiO' 4O 1. 2 .1 2. 1 5. 8 12 3 3. 0X10 4. 1X10 16 6 83. 4 2 0 2. 2 7.0 31 1 5. 4X10" 2 0X10 50 1. 8 1 3. 0 7.8 13 6 2X10 K 0X10- 60 40 0. 8 1 1. 4 4. 8 22 0 6. 0X10 6. 6X10 1 Plgments'used are as follows: A, B, C, E-Magnetite (0.2%).8 micron diameter); D-Benzidine Yellow (Color Index No. 21090); F-niclrel zinc ferrite (0.20.8 micron diameter).
2 All Exam les except Example E used the resin of Example A. The resin of Example E was Epon 1002" (epichlorohy rin/blsphcnol A solid epoxy resin, melting olnt 75-85/C., cpoxlde equivalent 01600400, molecular weight of 1060, a trademarked product of Shell Chemica Company). 1
3 The size distribution data are percent by number greater than indicated sizes, which are in microns. For example in sample A, 96% of all the particles are larger than 3.7 50% are greater than 6.4 and 6% are greater than 12.6
4 CAB-O-SIL, a trademarked product of Cabot Corporation.
5 milllmicron diameter particle size, as measured by electron microscope.
1,456,993, since the developer particles display high conductivity under the high electrical field conditions of particle deposition on the field electrode and display lower conductivity (and hence better electrical charge retention) after they are removed from the high electrical field. As mentioned earlier, charge retention is particularly important when one desires to transfer the imagewisc pattern of developer particles from the field electrode to a receptor sheet without loss of particles. Although the mechanism is not completely understood, the field dependent conductivity of these particles is believed to be attributable to their being essentially completely immersed or embedded in the relatively insulative, thermoplastic material. At the higher electrical fields the electrical current is believed to tunnel" or pass through the thermoplastic material on the particle surface to reach the embedded zone or layer of conductive material. At the lower electrical fields the thermoplastic surface layer serves as an effective insulativc barrier to current flow, resulting in a lower particle conductivity and a higher electrical charge retention capability.
Various other materials may be usefully incorporated in or on the developer particles of this invention, c.g., plasticizers, dyestuffs, pigments, magnetically permeable particles, etc.
Magnetically permeable particles having an average diameter of 1 micron or less are particularly preferred, including magnctite, barium ferrite, nickel zinc ferrite, chromium oxide, nickel oxide, etc. A magnetically permeable core may also be used. Powdered flow agents may also be added to the dry particles to improve their flow characteristics.
The conductivity of these dry ink powders is related to the applied electric field across the powder particles, and measurement of conductivity is therefore made under standard conditions of sample size, sample compression and applied electric field. The following test procedure is used for the conductivity measurements presented herein.
The sample of ink is placed in a test cell between two brass electrodes of circular cross section, each with a cross-scctional area of about 0.073 cm.". An insulating cylindrical sleeve of polytetrafluoroethylene surrounds the ink and electrodes such that the ink sample is constrained to the shape ofa small pill box. At least one of the electrodes is free to move like a piston in the insulating sleeve to provide a predetermined comprcssion on the sample. The compression is obtained by placing a known weight on the movable electrode,
and typically one uses a 100 gram weight to give a pressure of l,370 g./cm. on the sample. One places enough ink into the cell such that the final electrode spacing under the above pressureis about 0.05 cm. to about 0.1 cm., and preferably as close to 0.05 cm. as possible. The final spacing is measured carefully using a cathctomctcr. A voltage is applied in a series circuit arrangement consisting of the ink sample, an electrical current mctcr (such as a Kcithlcy Model 601 Elcctromcteri, and the voltag'c'source. The ink conductivity is calculated from the voltage which appears across the sample electrodes and the current which flows through it in the usual manner. The voltage is varied and the resulting conductivity is calculated for various electric ficldsfrom about lO v/cm. to about from 1,000 to 4,000 v./cm. For fields higher than about 4,000
20 v./cm., the voltage cannot be applied to the sample for longer than a fraction of a second or so, before considerable heat develops in the sample, changing its characteristics, or causing it to break down" entirely. To measure the electrical conductivity at high fields, therefore, the applied voltage is rapidly in- 25 creased from about 0 to 2,000 v. or more (corresponding to 3 cial, high voltage ramp (or sweep) generator. To measure the current through the sample, when using the voltage sweep, the current meter described earlier is replaced by a current-sampling resistor, typically of about 10,000 ohms. The voltage across this sampling resistor, as monitored by an oscilloscope,
1 is proportional to the current flowing through the sample. Thc
voltage across the sample is also monitored on an oscil- ,loscope, using high voltage probes. Typically, the voltage across the current-sampling resistor is applied to the horizontal input to the oscilloscope, while the voltage across the ink sample itself is appliedto the vertical input to the same oscilloscope, giving a direct plot proportional to the current (ab- ;scissa) vs. voltage (ordinate) characteristics of the ink sample 3 on the oscilloscope screen, which is then photographed. From i this, the conductivity vs. field characteristics of the ink sample ,at very high fields can be calculated. The electrical conduc- Ltivity data given in Table l was obtained in the above manner. 1 The dry ink powder conductivity should be such that at high applied electric fields, it permits a relatively large current flow the development electrode to the intermediate photoconductivc imagcable surface during the development step, which is carried out with a relatively large series voltage impressed. However, the powder should not be so conductive that after one layer is deposited on the intermediate photoconductive imageable surface it thereafter electrically shiclds subsequent layers of powder from the intermediate surface, accepting their charge but preventing their deposition as would happen with a highly conductive powder. Additionally, at low or zero applied electric field, the conductivity should be considerably smaller so the powder which was deposited on the intermediate photoconductive imagcable surface retains its charge for a time period sufficient to permit transfer of the powder from the intermediate surface to a receptor sheet. After development is completed, the electric field holding the powder to the intermediate surface in areas where it is deposited is still relatively strong, but the nature of the interface in these areas is insulating enough to prevent the charge to flow from the powder into the intermediate itself. At the same time, the lateral electric field from particle to particle is very small or zero, so the charge on the deposited particles does not leak laterally to the more conductive areas on the intermediate surrounding the deposited powder. Furthermore, the electric field from layer to layer of deposited powder is smallaftcrdcvclopment, so the charge do es not readily leak from layers more rcmotcfrom thc intermediate surface to the' layers more adjacent to said surface. Thus all deposited particles remain strongly bound to the intermediate and retain their charge for a time.
In preparing the developer powders a dry-powdered blend of appropriate composition is first obtained by any of several standard means, for example, by melting a resin, stirring in the solid filler, if any, allowing the mixture to cool, then grinding and classifying to the appropriate particle size range of approximately 1 to microns diameter. This powder, which is pseudocubical in shape is then spheroidized" by the following method: the powder is aspirated into a moving gas stream, preferably air, thus creating an aerosol. This aerosol is directed at about 90 (:5") through a stream of hot air, which has been heated to about 900-1,l00 F., into a cooling chamber, where the powder is then allowed to settle by gravity while it cools. The resulting powder is now made up of substantially spherical particles. It is then dry blended with conductive powder, such as conductive carbon black, and the mixture is directed at about 90 (i5) through a stream of gas, preferably air, heated to a temperature (e.g., 700800 F.) which can at least soften and desirably melt the thermoplastic resin in the particles and maintain that softened or melted condition for a period of time sufficient to permit the conductive powder to become essentially completely embedded, due to the effects of surface tension. The particles are then collected, such as by cyclone separation, and are preferably blended with a flow agent, such as CAB-O-SIL (finely divided silica, a trademarked product of Cabot Corporation) to insure that it will be free flowing.
In an alternative preparation of the developer powders of this invention the conductive material may be deposited, as a powder or as a continuous film, on the surface of the essentially spherical particles, and a thin film ofinsulative material, e.g., a resin, may be superimposed or deposited thereon to ef fectively embed the conductive material as a zone in the parti+ cles.
The following procedure represents a preferred method for manufacturing the dry ink powder.
EXAMPLE A Four parts by weight of Epon 1004" (epichlorohydrin/bi sphenol A solid epoxy resin, melting point 95-105 C., epoxide equivalent of ENS-1,025, molecular weight of 1,400, a trademarked product of Shell Chemical Company) and 6 parts by weight of magnetite were blended thoroughly on a conventional heated-roll rubber mill. The resulting material was pulverized in an attrition-type grinder and was then classified in a standard air-centrifugal-type machine, the yield from which was about percent by weight in the desired particle size distribution range. Particle size analysis of the product showed it to be about 95% 1 .3u, 50% 4.1,u, 5% l2.6 .1r% (by number).
These particles, which are sharp edged and pseudocubical in shape, were then "spheroidized such that most of the particles were transformed into spherelike shapes or round-edged particles by the following process. The powder was fed to an air aspirator in a uniform stream of about 800 grams per hour. The aspirator sucks the particles into the airstream and disperses them, forming an aerosol. This aerosol was directed at 90 into a heated airstream, the temperature of which was about 950 1 ,000 F. The powder was then allowed to settle and was collected by filtration.
exactly as it was described above, except that the temperature of the hot a1rstream was ad usted to about 740 F. and the product was collected in a cyclone-type separator.
The final step in the process was to blend 0.1 percent by weight of a small particle size SiO flow agent to cause the powder to become sufficiently free flowing for use in the electropowder process. This ink was coded A, and the conductivity vs. applied electrical field curve is shown in the FIGURE.
Table I shows the properties obtained when several other formulations (B-F) were prepared by the method given in the above example, and the conductivity vs. applied electrical field curves are presented in the FIGURE. The two dotted lines in the FIGURE represented the upper and lower limits of conductivity over the range of applied DC electrical fields, as mentioned earlier.
What is claimed is:
l. Flowable, heat fusible, dry powder suitable for use as a developer powder in electrographic recording which comprises thermoplastic, essentially spherical particles, the thermoplastic material of which has a conductivity of at most 10 mho/cm., in which are essentially completely embedded electrically conductive particles having a conductivity of at least 10 mho/cm. and an average diameter below about 100 millimicrons forming a radially disposed zone, said essentially spherical particles having:
a. an electronic conductivity ranging monatonically without decreasing from between about 10" and 10 mho/cm. in a 100 v./cm. DC electrical field to between about 10 and 10' mho/cm. in a 10,000 v./cm. DC electrical field,
b. a number average particle diameter below 15 microns,
c. a volume ratio of said electrically conductive particles to said total particle volume of between 0.01/100 and 4/100.
2. The dry powder ofclaim 1 in which said essentially spherical particles contain therein magnetizable particles.
3. The dry powder of claim 1 in which said electrically con ductive particles are particles of highly conductive carbon having a conductivity of at least 10 mho/cm.
4. The dry powder of claim 1 in which the particle size range ofsaid spherical particles is such that at least about number percent of the particles have a diameter greater than about 2 microns and no more than 5 number percent have a diameter greater than 13 microns.
5. The dry powder of claim 1 in which said spherical particles have a flowability angle of repose between 80 and 125.
6. The dry powder of claim 1 in which said spherical particles have an electronic conductivity ranging monatonically without decreasing from between 10' and 10 mho/cm. in a v./cm. DC electrical field to between 10 and 10 mho/cm. in a 10,000 v./cm. DC electrical field.
7. The dry powder of claim 1 in which said thermoplastic material is an organic resin.
8. The dry powder of claim 1 which is heat fusible in the range offrom about 80 to 1 15 C.
UNITED STATES PATENT @FFECE CERTIFICATE OF CURREfiTEON Patent No. Dated February 1 1972 Inventor(s) Robert Nelson It is certified that error appears in the above-identified patent and that said Letters Patentare hereby corrected as shown below:
Col. 5, line 52 "5% l2.6u1r1/ 4(by number)" should read 5% 12.6u(by number) Signed and sealed this 18th day of July 1972.
EDWARD M.FLETCHER,JR. ROBERT GOTTSCHALK Commissioner of Patents Attesting Officer USCOMM'DC 60376-969 FORM PC3-1050 (10-69) e 0.5. aovznnnzm' ramrms OFFICE can o-ses-334.
|Cited Patent||Filing date||Publication date||Applicant||Title|
|US3196032 *||Feb 20, 1962||Jul 20, 1965||Burroughs Corp||Process for producing electrostatic ink powder|
|US3345294 *||Apr 28, 1964||Oct 3, 1967||American Photocopy Equip Co||Developer mix for electrostatic printing|
|Citing Patent||Filing date||Publication date||Applicant||Title|
|US3909258 *||Jan 2, 1974||Sep 30, 1975||Minnesota Mining & Mfg||Electrographic development process|
|US3925219 *||Jun 29, 1973||Dec 9, 1975||Minnesota Mining & Mfg||Pressure-fixable developing powder containing a thermoplastic resin and wax|
|US3929658 *||Dec 2, 1974||Dec 30, 1975||Du Pont||Magnetic recording compositions and elements of low abrasiveness and process for making them|
|US4082681 *||Nov 4, 1975||Apr 4, 1978||Mita Industrial Company||Magnetic developer for electrostatic photography and process for preparation thereof|
|US4108786 *||Dec 16, 1975||Aug 22, 1978||Mita Industrial Company Ltd.||Magnetic dry developer for electrostatic photography and process for preparation thereof|
|US4137188 *||Feb 1, 1978||Jan 30, 1979||Shigeru Uetake||Magnetic toner for electrophotography|
|US4146494 *||Jan 7, 1977||Mar 27, 1979||Oce-Van De Grinten N.V.||One-component developer powder and process for its preparation|
|US4148640 *||Mar 11, 1974||Apr 10, 1979||Eastman Kodak Company||Developer compositions having electrically conducting filaments in carrier particle matrix|
|US4174409 *||Aug 5, 1977||Nov 13, 1979||Minnesota Mining And Manufacturing Company||Depositing latent fingerprints and development thereof|
|US4176078 *||Jun 2, 1977||Nov 27, 1979||Xerox Corporation||Field dependent toner having chrome complex coated magnetic particles|
|US4185916 *||Apr 8, 1977||Jan 29, 1980||Xerox Corporation||Composite developer particles and apparatus for using same|
|US4189390 *||Oct 31, 1977||Feb 19, 1980||Hitachi Metals, Ltd.||One-component magnetic developer powder for developing electrostatic latent image and method of making same|
|US4210448 *||Oct 18, 1976||Jul 1, 1980||Elfotec A.G.||Process for electrophotographic image formation and transfer|
|US4212837 *||May 4, 1978||Jul 15, 1980||Tokyo Shibaura Electric Co., Ltd.||Method and apparatus for forming spherical particles of thermoplastic material|
|US4240723 *||May 16, 1975||Dec 23, 1980||Elfotec A.G.||Process for electrographic image production and an apparatus for carrying out this process|
|US4242434 *||Jun 21, 1978||Dec 30, 1980||Ricoh Company, Ltd.||Toner composition for multiple copy electrostatic photography|
|US4246331 *||Mar 5, 1979||Jan 20, 1981||Sublistatic Holding Sa||Electrophotographic developers containing sublaminate dyes|
|US4251616 *||Jun 23, 1977||Feb 17, 1981||Sublistatic Holding Sa||Magnetic toners and development process|
|US4258644 *||Jul 23, 1979||Mar 31, 1981||Minnesota Mining And Manufacturing Company||Depositing latent fingerprints and development thereof|
|US4259426 *||Mar 6, 1979||Mar 31, 1981||Canon Kabushiki Kaisha||Pressure fixable microcapsule toner and electrostatic image developing method|
|US4262076 *||Mar 1, 1979||Apr 14, 1981||Minolta Camera Kabushiki Kaisha||Method for manufacturing magnetically attractive toner particles and particle|
|US4264698 *||Oct 15, 1976||Apr 28, 1981||Mita Industrial Company Limited||Developer for electrostatic photography and process for preparation thereof|
|US4265992 *||Jul 31, 1978||May 5, 1981||Mita Industrial Company Limited||Coated magnetic developer particles for electrophotography containing vinyl and olefin resins|
|US4265993 *||Jun 26, 1979||May 5, 1981||Hitachi Metals, Ltd.||Magnetic toner for electrostatic images and transfer copying|
|US4273847 *||Dec 12, 1979||Jun 16, 1981||Epp Corp.||Inks for pulsed electrical printing and methods of producing same|
|US4273848 *||Mar 5, 1979||Jun 16, 1981||Minolta Camera Kabushiki Kaisha||Oriented magnetic toner|
|US4282302 *||Oct 22, 1979||Aug 4, 1981||TDK Electronics, Ltd.||Ferrite powder type magnetic toner used in electrophotography and process for producing the same|
|US4288519 *||Dec 20, 1977||Sep 8, 1981||Black Copy Company, Inc.||Dual purpose electrophotographic magnetic toner and process of making|
|US4291111 *||Feb 9, 1979||Sep 22, 1981||Xerox Corporation||Nitrogen-containing additives for magnetic toners having hydrophobic and hydrophilic moiety|
|US4293632 *||Apr 3, 1978||Oct 6, 1981||Xerox Corporation||Attrition process for alteration of toner particles containing conductive materials|
|US4296176 *||Dec 11, 1979||Oct 20, 1981||Epp Corp.||Inks for pulsed electrical printing|
|US4312933 *||Mar 30, 1981||Jan 26, 1982||Xerox Corporation||Method of imaging using nitrogen-containing additives for magnetic toners|
|US4345013 *||Feb 28, 1977||Aug 17, 1982||Black Copy Company, Inc.||Dual purpose magnetic toner|
|US4345015 *||Mar 23, 1977||Aug 17, 1982||Oce-Van Der Grinten N.V.||Dispersion-heat process employing hydrophobic silica for producing spherical electrophotographic toner powder|
|US4389478 *||Jun 22, 1981||Jun 21, 1983||Bell & Howell Company||Apparatus for and methods of making bimodal electrophotographic copies|
|US4442790 *||Sep 29, 1982||Apr 17, 1984||Eastman Kodak Company||Magnetic brush development apparatus|
|US4443527 *||Sep 2, 1982||Apr 17, 1984||Oce-Nederland B.V.||Colored magnetically attractable toner powder, its preparation, and developing images with such powder|
|US4451837 *||Jun 1, 1982||May 29, 1984||Xerox Corporation||Conductive single component magnetic toner for use in electronic printing devices|
|US4487825 *||Jan 22, 1981||Dec 11, 1984||Xerox Corporation||Conductive single component electrophotographic magnetic toner|
|US4496232 *||Jun 8, 1981||Jan 29, 1985||Bell & Howell||Apparatus for and methods of making bimodal electrophotographic copies|
|US4496644 *||Feb 28, 1983||Jan 29, 1985||Eastman Kodak Company||Electric field adjustment for magnetic brushes|
|US4514484 *||Jan 6, 1981||Apr 30, 1985||Compagnie Internationale Pour L'informatique Cii/Honeywell Bull (Societe Anonyme)||Powder for developing latent images and a method of producing the powder|
|US4526851 *||Sep 6, 1983||Jul 2, 1985||Trw Inc.||Magnetic developer compositions|
|US4540646 *||Jul 9, 1984||Sep 10, 1985||Konishiroku Photo Industry Co., Ltd.||Method of developing an electrostatic latent image|
|US4554232 *||Sep 23, 1980||Nov 19, 1985||Kazunori Tabaru||Magnetic toner|
|US4599292 *||May 31, 1985||Jul 8, 1986||Konishiroku Photo Industry Co., Ltd.||Method and device of developing an electrostatic latent image|
|US4601967 *||Dec 6, 1984||Jul 22, 1986||Ricoh Company, Ltd.||Toner particles having a relatively high specific volume resistivity coating layer|
|US4643960 *||Jun 6, 1984||Feb 17, 1987||Minnesota Mining And Manufacturing Company||Developing powder composition containing a fatty acid amide component|
|US4681830 *||Apr 24, 1986||Jul 21, 1987||Minnesota Mining And Manufacturing Company||Fluorinated carbon-containing developer composition|
|US4745418 *||Apr 30, 1986||May 17, 1988||Minnesota Mining And Manufacturing Company||Reusable developing powder composition|
|US4762765 *||Mar 24, 1986||Aug 9, 1988||Alpine Aktiengesellschaft Augsburg||Method of generating a spherical grain|
|US4913088 *||Mar 4, 1987||Apr 3, 1990||Canon Kabushiki Kaisha||Apparatus for developer transfer under electrical bias|
|US5032485 *||Jun 27, 1990||Jul 16, 1991||Canon Kabushiki Kaisha||Developing method for one-component developer|
|US5040027 *||Dec 12, 1989||Aug 13, 1991||Matsushita Electric Industrial Company, Ltd.||Printing apparatus|
|US5044310 *||Dec 22, 1989||Sep 3, 1991||Canon Kabushiki Kaisha||Developing apparatus for non-magnetic developer|
|US5096798 *||Mar 18, 1991||Mar 17, 1992||Canon Kabushiki Kaisha||Developing method for one-component developer|
|US5153616 *||Mar 6, 1991||Oct 6, 1992||Hitachi Metals, Ltd.||Method for recording images|
|US5194359 *||Aug 6, 1991||Mar 16, 1993||Canon Kabushiki Kaisha||Developing method for one component developer|
|US5202211 *||Feb 5, 1991||Apr 13, 1993||Oce-Nederland B.V.||Toner powder comprising particles having a coating of fluorine-doped tin oxide particles|
|US5350659 *||Mar 31, 1993||Sep 27, 1994||Xerox Corporation||Preparation of conductive toners using fluidized bed processing equipment|
|US5358811 *||Apr 29, 1993||Oct 25, 1994||Canon Kabushiki Kaisha||Electrophotographic method using an amorphous silicon light receiving member with a latent image support layer and a developed image support layer and insulating toner having a volume average particle size of 4.5 to 9.0 micron|
|US5385768 *||Apr 28, 1993||Jan 31, 1995||Diafoil Company, Limited||Electrically conductive film|
|US5457001 *||Jul 26, 1994||Oct 10, 1995||Oce'-Nederland, B.V.||Electrically conductive toner powder|
|US6594462 *||Mar 13, 2001||Jul 15, 2003||Canon Kabushiki Kaisha||Developing apparatus using toner with conductive particles|
|DE2313132A1 *||Mar 16, 1973||Sep 20, 1973||Oce Van Der Grinten Nv||Elektrofotografisches verfahren|
|DE2424350A1 *||May 20, 1974||Nov 27, 1975||Turlabor Ag||Verfahren zur elektrographischen bilderzeugung und vorrichtung zur ausfuehrung des verfahrens|
|DE2729946A1 *||Jun 29, 1977||Jan 5, 1978||Minnesota Mining & Mfg||Elektrographisches entwicklungsverfahren|
|EP0035573A1 *||Mar 9, 1981||Sep 16, 1981||Fujitsu Limited||Toner particles for electrophotography and electrophotographic process utilizing same|
|EP0035573A4 *||Mar 9, 1981||Aug 28, 1981||Fujitsu Ltd||Toner particles for electrophotography and electrophotographic process utilizing same.|
|EP0042224A1 *||May 27, 1981||Dec 23, 1981||Minnesota Mining And Manufacturing Company||Fluorinated carbon-containing developer composition|
|EP0154053A2 *||Dec 18, 1984||Sep 11, 1985||Philips Electronics N.V.||Projection screen|
|EP0154053A3 *||Dec 18, 1984||Jul 30, 1986||N.V. Philips' Gloeilampenfabrieken||Projection screen|
|EP0266579A2 *||Oct 11, 1987||May 11, 1988||EASTMAN KODAK COMPANY (a New Jersey corporation)||An electrostatographic method of making images|
|EP0266579A3 *||Oct 11, 1987||Jun 14, 1989||Eastman Kodak Company||An electrostatographic method of making images|
|WO1983002013A1 *||Nov 26, 1982||Jun 9, 1983||Kishi, Kenichi||Magnetic toner|
|U.S. Classification||430/108.1, 252/62.53, 430/111.4, 430/903, 252/62.54|
|International Classification||G03G9/087, G03G9/08|
|Cooperative Classification||G03G9/0827, G03G9/0823, G03G9/0819, G03G9/0808, Y10S430/104, G03G9/0825|
|European Classification||G03G9/08D, G03G9/08B4, G03G9/08T, G03G9/08P2, G03G9/08S|