|Publication number||US3640787 A|
|Publication date||Feb 8, 1972|
|Filing date||Mar 17, 1967|
|Priority date||Mar 23, 1966|
|Also published as||DE1704531A1, DE1704531B2|
|Publication number||US 3640787 A, US 3640787A, US-A-3640787, US3640787 A, US3640787A|
|Original Assignee||Rudolf Heller|
|Export Citation||BiBTeX, EndNote, RefMan|
|Patent Citations (12), Referenced by (61), Classifications (42)|
|External Links: USPTO, USPTO Assignment, Espacenet|
United States Patent Heller 5]. Feb. 8, 1972  METHOD OFPRODUCING SHAPED BODIES OF LOW SPECIFIC GRAVITY  Inventor: Rudolf Heller, Mattackerstrasse 43, Zu-
rich, Switzerland  Filed: Mar. 17, 1967 21 Appl. No.: 623,882
 Foreign Application Priority Data Mar. 23,1966 Switzerland ..420l/66 July 1, 1966 Switzerland ..960l/66  References Cited UNITED STATES PATENTS 3,488,714 1/1970 Walters et a1 ..l6l/161 3,515,625 6/1970 Sedlak etal ..161/l61 X 2,770,965 11/1956 Engel ..72/4l 2,693,922 11/1954 Ellison et al. .,161/16l X 2,806,509 9/1957 Bozzacco et a1. 1 61/161 2,972,559 2/1961 Allen et al 161/161 X 3 ,247,294 4/1966 Sabouni ..264/42 3,314,838 4/1967 Erwin ..156/7l 3,318,697 5/1967 Shrewsbury ..96/l 3,396,923 8/1968 Windecker ..244/ l 23 3,434,854 3/1969 Voss ..52/404 X Primary Examinerl'larold Ansher Attorney-Michael S. Striker  ABSTRACT Bodies of low specific gravity produced by coating a mass of roundish hollow granules, such as expanded or swelled polystyrene granules, with a hardenable liquid binder material, mixing the mass of thus coated granules with a pulverulent solid material so as to adhere particles of the solid material to the coating, and hardening the hardenable binder coating, and shaped cellular structures formed by compressing the mass of hardenable binder coated hollow granules having pulverulent material adhering to the coating during or prior to the hardening of the hardenable liquid binder material.
19 Claims, 4 Drawing Figures PATENTEBFEH 91972 $640,787
' sum 1 or 2 INVENTOR RUDOLF HELLER SHEET 2 0F 2 .PATENTEDFEB 8 mm METHOD OF PRODUCING SHAPED BODIES OF LOW SPECIFIC GRAVITY BACKGROUND OF THE INVENTION The present invention relates to shaped bodies of low specific gravity which consist essentially of a hollow shell formed of hardened binder material having solid particulate material incorporated therein and including in the interior of the hollow shell, only partly filling such interior, a plastic material which may be in the form of a hollow granule adhering to the inner face of the respective shell. The present invention is also concerned with a cellular structure comprising cell walls consisting of hardened binder material having incorporated therein solid pulverulent particles and including in substantially each cell of the cellular structure, either as a thin layer adhering to theinner face of the cell walls, or otherwise partly filling the interior of the cell, a plastic material which at least during the first stages of producing such structure was present in the form of discrete roundish hollow granules.
The present invention thus relates to bodies of low specific gravity and a method of producing the same. The product of the present invention may be a loose mass of roundish bodies, for instance of spheric or spheroid shape, which may be introduced as aggregate into a concrete-forming mass, a gypsum mass or other casting masses, in order to reduce the specific gravity or heat-conductivity thereof and/or to increase the mechanical strength thereof. The mass of roundish granules formed according to the present invention may also serve as additive as described above in place of the conventional roundish and porous granules of swelling clay. Granules of swelling clay are available at relatively low cost and also possess considerable strength and shape-retention, however, they have a specific gravity of between about 0.9 and 1.5 and thus are relatively heavy. Furthermore, they possess considerable heat conductivity. In addition, swelling clay granules are capable of absorbing water more or less like a sponge. Thus, for instance, building walls of concrete including swelling clay granules as an additive dry only very slowly and, under unfavorable climatic conditions, will become moist again. In moist condition, the heat-conductivity and heat capacity of granules of swelling clay is of the same magnitude as that of concrete formed without such additive.
If granules of swelling clay are introduced as additive into foamed masses, for instance of polystyrene or hardenable urethane foam, in order to reduce costs or to increase strength or to improve acoustic insulation, the addition of swelling clay granules will increase the specific weight and heat-conductivity of the foamed structure to such a large extent that the introduction of swelling clay granules into such lightweight building elements is generally completely impractical.
Furthermore, a loose flowable mass of roundish granules of very low specific gravity, as obtained in accordance with the present invention, may be used as filler material for the filling of cavities, for instance in structural elements, for the purpose of obtaining heat-insulating properties. The loose mass which may be produced in accordance with the present invention thus will replace comminuted cork or bricks.
The term roundish is used throughout the present specification and claims to define a curved, more or less spherical or spheroid configuration. The shape of the granules of the loose mass which may be obtained in accordance with the present invention will more or less depend on the foamed material which is utilized in the process, for instance swelled polystyrene granules. When replacing comminuted cork or bricks as filler material, it is an advantage of the granular mass produced according to the present invention that the same will not absorb water and is of very low specific gravity. Furthermore, filler materials of vegetable origin, such as comminuted cork, tentito rot when exposed to moisture for long periods of time, and this danger obviously does not exist when utilizing the granular mass of the present invention.
The granular mass of the present invention is also eminently qualified for replacing spun rock wool or spun glass fibers as a filler material and will not be subject to the disadvantage connected with the use of the last-mentioned conventional filler materials, namely the tendency to felt and bake together and thereby to lose heat-insulating capacity. Furthermore, the flowable granular mass of the present invention can be much more easily introduced into the cavities which are to be filled therewith than fibrous material and the like.
For the above-described and other purposes there exists a great need for a loose granular uniform material of very low specific gravity and correspondingly little heat-conductivity, which material should absorb very little water, should not be subject to decomposition under unfavorable climatic conditions, but should at the same time possess a relatively considerable mechanical strength and shape-retention. Thus, the desired granular material should not be squashed when exposed to a low degree of elevated pressure as would be the case with, for instance, exfoliated mica or swelled polystyrene granules which have not been processed according to the present invention. Furthermore, the granular material should not be subject to destruction when exposed to contact with certain solvents such as acetone.
A field of application of the bodies of low specific gravity such as may be produced in accordance with the present invention, which is even more important from a technical and economic point of view, may be found in building elements, i.e., shaped bodies, for instance plates or other shapes, which, according to the present invention, may have a specific gravity as low as between about 0.1 and 0.3, a correspondingly excellent heat-insulating capacity but nevertheless relatively high strength and shape-retention even at temperatures above ambient temperature. The strength characteristics of the shaped bodies of low specific gravity are desired to correspond about to those of bodies formed by compressing mixtures of fibrous material and synthetic resins, or should be corresponding to those of concrete or brick walls.
It is known that such requirements basically are best met by hollow cellular structures, for instance sandwich structures, which comprise outer solid and tight shells which shells are filled with one or more hollow cellular structures, possibly including reinforcing elements.
Known compound structures including such hollow cellular elements, comprise, for instance, interior honeycomb structures formed of prefolded and stripwise connected cardboard, synthetic resin or metal foils, which are so arranged as to form six-edged hollow tubes, whereby the initially open frontal ends of the tubes are glued to outer shells or intermediate layers. Apart from the fact that honeycomb structures of this kind are resistant against tensile and pressure forces only in the direction of the honeycomb axes and show considerably less resistance against deforming forces acting in directions transverse thereto, the heat-insulating effect of such structures is not very good because unimpeded air convection is possible within the cells of the honeycomb structure from one end thereof to the other. In cases where a better heat-insulating effect is required, it has been attempted to overcome this disadvantage of the above-described conventional honeycomb structures by arranging plates of foamed material or of fibrous material at the opposite from ends of the honeycomb structure, or by filling the honeycomb structure with foamed material prior to closing the same. The production of such composite building elements with an inner honeycomb structure is generally economically possible only in the case of plates having parallel opposite surfaces which plates preferably are of relatively small thickness. This is particularly so because the frontal terminal planes of the honeycomb arrangements have to be cut in advance into the desired shapes and dimensions of the compound structure which is to be produced. In most cases, it is attempted to obtain the desired heat-insulating properties and the low specific gravity of a lightweight building element by filling the mold cavity for a cast or compressed body of desired shape with a foamable mass or blowable material and to cause foaming or blowing thereof in the closed mold, thereby also achieving a certain limited degree of strengthening of the thus formed cellular body. This method is carried out, for instance, with respect to initially liquid masses of synthetic material, for instance polyurethane which may be foamed in a mold, or with foarnable or blowable granules of synthetic material, for instance polystyrene granules, which may be swelled upon application of heat, such as are available under the trade name Styropor.
By using polyurethane, it is possible to obtain a hollow cellular structure with small cells which is relatively shape-retainingand load-supporting, however, only as long as the temperature does not rise substantially above 50 C. If the temperature rises beyond this range, softening of the material takes place and a potentially dangerous gasexpansion.
On the other hand, polystyrene is sufficiently stable at temperatures of up to about 110 C., however even at lower temperatures the mechanical strength and shape-retention of cellular polystyrene bodies is much too small to permit the use of this material for load-carrying structural elements or for producing plates which during use will be exposed to mechanical stress. Only in cases where such material is covered on all sides with strong solid plates has a partial usefulness been found. These disadvantages cannot be remedied by embedding in the foamed material occlusion bodies of greater strength, for instance swollen clay granules.
Furthermore, it has been proposed to produce hollow cellular structures by introducing into a mold cavity a mixture of rigid hollow spheres and liquid hardenable binding agents, particularly if the mold cavity is at least partially lined with a foil which is destined to form the outer shell of the thus produced building element of cellular structure. The entire mass of hollow spheres and binding agents inside the foil lining of the mold is then subjected to pressure, which is maintained until hardening of the binding agent has been completed. However, it has been found that it is not easy to produce such stable hollow spheres on a large scale in a sufficiently economical manner, and, furthermore, particularly when using smooth-walled and substantially shape-retaining hollow spheres, the liquid hardenable binding material will tend upon pressing of the hollow spheres against each other to escape from the contacting portions of adjacent hollow spheres into the interstices therebetween and this results in an insufi'rcient adherence of the hollow spheres to each other.
SUMMARY OF THE INVENTION The present invention proposes a method of producing shaped bodies of low specific gravity, which comprises the steps of wetting a mass of discrete roundish hollow granules with a hardenable, preferably heat-hardenable, liquid binder material so as to cause substantially complete wetting of the outer surfaces of the granules and the formation of a coating of the liquid binder material thereon. This is followed by mixing the thus formed mass of wetted granules with a pulverulent solid material so as to adhere particles of the solid pulverulent material to the liquid binder coating on the hollow granules, in such a manner as to form on each of the hollow granules an outer shell which will consist of the coating of hardenable binder material and particles of the solid pulverulent material adhering thereto and at least partially embedded therein, and
which outer shell encloses a nucleus constituted by the respective hollow granule.
Upon subsequent. hardening of the hardenable binder material of the outer shell, granules are obtained which form a mass of shaped bodies of low specific gravity consisting of a plurality of roundish hollow bodies or granules, each comprising a hard outer shell consisting of the hardened binder material and the pulverulent material adhering thereto, and also including the plastic material of the initial hollow granule, for instance a foamed or blown polystyrene granule. The material of the polystyrene granule or the like may adhere as a thin inner layer to the inner surface of the outer shell, or may be disposed in the interior of the outer shell in some other manner, however, in any event, only partially filling such interior space.
It is also within the scope of the present invention to apply pressure during the hardening of the hardenable binder material so as to deform the mass of coated granules into a shaped coherent polyhedric cellular structure.
The cell walls of such cellular structure preferably are relatively thin down to about 0.05 mm., and. the pulverulent material incorporated in the cell walls preferably has a maximum dimension somewhat smaller than the thickness of the cell wall and may be as small as about 0.01 mm.
The individual hollow granules, such as swelled polystyrene granules, which are initially subjected to being coated with the liquid hardenable binder material and the pulverulent material, may be of any desired size; but very good results are achieved with hollow granules having diameters of between about 2 and'8 mm.
The novel features which are considered as characteristic for the invention are set forth in particular in the appended claims, The invention itself, however, both as to its construc-' tion and its method of operation, together with additional objects and advantages thereof, will be best understood from the following description of specific embodiments when read in connection with the accompanying drawing.
BRIEF DESCRIPTION OF THE DRAWING FIG. 1 is a schematic illustration of the first essential step of the process of the present invention, namely the wetting of the blown polystyrene granules with a hardenable liquid epoxy resin;
FIG. 2 is a schematic illustration of the second essential step of the process, namely the adhering of pulverulent solid material to the liquid binder-coated polystyrene granules;
FIG. 3 is a schematic illustration of the compressing and hardening of the mass obtained according to FIG. 2; and
FIG. 4 is an enlarged schematic illustration of a section of the walls of the cellular structure obtained as illustrated in FIG. 3.
DESCRIPTION OF THE PREFERRED EMBODIMENTS According to the present invention, hollow bodies of low specific gravity and the above-described desirable properties, particularly with respect to strength, shape-retention and resistance against chemical and atmospheric attacks, may be produced by wetting a loose mass of roundish foamed or swelled granules of synthetic material with a liquid hardenable binder material, for instance a mixture of an epoxy resin and a conventional hardener therefor, until at least nearly complete wetting of the entire surfaces of all foamed granules is achieved. Thereafter, solid pulverulent material is admixed to the mass of liquid-coated hollow granules until the liquid binder coating is at least substantially coated with pulverulent material. Thereby a dry loose mass is obtained consisting of roundish swelled granules of synthetic plastic material, for instance of polystyrene, each granule being covered by an outer shell consisting of the hardenable binder and solid pulverulant material adhering thereto and at least partially embedded therein.
Preferably, the swelled granules will consist of thermoplastic material which, at least at elevated temperatures below the softening point of the thermoplastic material, are resilient and which have a smooth rather than a rough surface. This assumes, on the one hand, that the pulverulent particles can become partially embedded in the material of the granules, and on the other hand, that the granules are coated evenly over their outer surface.
In order to produce a loose mass of roundish hard-shelled granules of very low specific gravity such as may be used'as aggregate for easing masses or as filler material for the filling of cavities in structural elements or the like, as described further above, or also suitable for use as filler material for air filters or air humidifiers in air conditioning installations, the abovedescribed dry and loose mass of coated swelled granules is exposed to heat, preferably in loose and moving condition, for instance bypassing a stream of warm air therethrough. The heat serves for hardening of the hardenable binder material forming part of the outer shell of each granule. In this manner, roundish granules are obtained, each including a continuous closed outer shell consisting of hardened binder material with solid pulverulent material embedded therein. It is generally advantageous if in the interior of the shell the initial foamed granules are maintained and serve, in contact with the inner face of the shell, as a reinforcing element which will help to protect the outer shells against destruction under the influence of localized pressure or impact. However, if,- for instance due to excessively high temperatures during the drying of the hardenable binder material or due to the presence of certain chemical substances in the binder material, wall portions of the swelled granules of plastic material are destroyed, the hollow shells which now surround the material of the foamed plastic granules will nevertheless be capable of fulfilling their above-described functions.
Thus, the present invention provides a loose, flowable granular mass on the basis of foamed or swelled granules preferably of synthetic resin which satisfies all of the abovediscussed requirements and which consists essentially of roundish foamed granules of synthetic material, preferably roundish polystyrene granules which have been swelled to the maximum possible extent, whereby each of the swelled granules is encapsulated in a thin-walled closed roundish shell of hardened synthetic resin binder material with solid particles embedded therein or adhering to the outer face thereof. The
flowable granular mass of the present invention as described above has the following characteristics:
a. low weight per unit of volume which generally ranges from a maximum of 300 kg./m. to a preferred weight of 100 l(g./m. b. considerable pressure-resistance and shape-retention of the individual granules which will prevent destruction of the same upon compressiomtransportation and mixing of the granular mass, for instance when incorporating the same into a concrete-forming mass.
. c. resistance against unfavorable climatic conditions such as high humidity, extensive temperature changes and contaminations of the air.
d. high resistance against microbes, insects and other biological pests.
It is also within the scope of the present invention to produce unitary bodies-of cellular structure, low specific gravity and relatively high pressure resistance and shape retention; which cellular structures possess high resistance :against climatic and chemical attacks. Such bodies can be produced by compressing the above-described dry and loose mass of foamed granules of synthetic material which are coated with a mixture of hardenable binder material and pulverulent solid material, under simultaneous hardening of the hardenable binder, so as to obtain a hollow cellular structure with interconnected hardened polyhedric cell walls and the material of the initial blown granules of synthetic material such as polystyrene located within the individual cells,
preferably covering the inner faces of the walls of the individual cells.
E Preferably, such body of cellular structure consists of a uni- =tary arrangement of cell walls forming a plurality of at least substantially closed cells and consisting of the hardened binder material, preferably a synthetic material such as a hardened epoxy resin, and of particles of pulverulent material embedded therein. Such pulverulent material, according to one preferred embodiment of the present invention, is mineral material such as quartz or chalk powder having particle sizes which generally are only slightly below the thickness of the cell walls, the'latter preferably having a thickness of at least 0.05 mm. The individual polyhedric cells defined by the cell walls preferably are of substantially equal width, length and thickness, and each of these three main dimensions of the cells preferablyis between about 2 mm. and 8 mm.
It will be understood that the above-described cellular structure possesses excellent strength and shape-retaining characteristics and is resistant against stresses exerted in all directions toan extent which may be comparable with the stress resistance of concrete and bricks. In addition, the cellular structure of the present invention is of very low specific gravity and correspondingly low heat-conductivity and, particularly if a-high-quality binding agent which is stable at elevated temperatures of up to 200-300 C., has been used for producing the cell walls, the structure will maintain its strength and shape even at higher than normal surrounding temperatures and when exposed to extensive sun radiation. Furthermore, such cellular structure is not sensitive to moisture, does not form a. nutrient medium for micro-organisms and will not be eaten up by animals, particularly insects, for instance termites. I
Preferably, the swelled plastic granules will have an average diameter within the range of between 1 and l0 nun., however in extreme cases the average diameter may be smaller or also greater, for instance up to mm.
Advantageously, loose, more or less strongly preswelled polystyrene granules, for instance granules having diameters of between 2 mm. and 8 mm., are used as the roundish foamed granules, Foamable polystyrene in granular form is comercially available for instance, under the trade name Styropor and may be foamed by being immersed in hot water or exposed to superheated steam, to a foamed granular mass having a weight per liter of less than 0.01 kg. By closing the granular polystyrene mass in an unconfined space, individual blown granules of approximately spheric or egg-shaped configuration and rather smooth surfaces are formed. Such blow polystyrene granules form an excellent heat-insulating material and are hydrophobic, i.e., they absorb practically no water and are highly resistant against water or biologic-organic decomposition as long as the temperature does not rise above 100 C. However, these granules are not resistant against specific solvents, such as acetone. At higher temperatures or under the effect of specific solvents, the granules collapse and only a small amount of the residual material remains. Furthermore, the polystyrene granules are of low inflammability and generally are self-extinguishing when ignited.
The lack of shape-retention or the lack in mechanical strength of the blown polystyrene granules is important for the purposes of the present invention. If the blown polystyrene granules after having been wetted with a liquid binder and coated with the dry sand or pulverulent material are adhered to the liquid binder so that dry solid shells have been formed about each blown granule, are subjected to pressure, the initially roundish shaped polystyrene granules with the shells thereon will .be deformed into polyhedrons which contact each other along relatively large surface areas. Thereby, the closely adjacent particles of solid material are partially compressed into the resiliently yielding surface of the polystyrene granule so that the liquid binder material cannot escape laterally or be pushed aside on pressure contact between adjacent polyhedrons, but will be squeezed outwardly between the adjacent solid particles. Thereby a mixture of liquid hardenable binding agent and solid particles is formed, and this mixture is then hardened by application of heat into a unitary polyhedric hollow cellular structure of considerable mechanical strength.
Suitable pulverulent materials include mineral sands of low porosity and low water absorption and metal powders which can be bound to the binder material, such as steel or aluminum.
A quartzsand with particle size of between 0.01 and 0.02 mm. has been found particularly suitable as the pulverulent solid material which adheres to the liquid binder coating. However, in order to avoid absorption of binder liquid other mineral and: stone powders of more or less corresponding particle sizes, for instance impregnated chalk powder or ground ceramic fragments may be utilized. Highly suitable binder materials are epoxy resins which are used in liquid form with a suitable hardener admixed thereto, so that they will harden at the desired speed under the influence of elevated temperatures.
The hardenable binder materials must not give up gases during hardening. This condition is met, for instance by epoxy resin and polyester resin hardeners. The hardenable binder material may be applied in the form of a liquid or as a paste having a viscosity of up to SAE 10.
It is essential that the hardenable binder and the solid pulverulent material as well as the material of the initial swelled granules are compatible with each other so that the liquid binder will form a coherent coating on the swelled granules and the pulverulent solid material will be easily adhered to the liquid binder, thereby facilitating the formation of thin but mechanically highly stable hard shells. In certain cases it is advantageous to use as the pulverulent material a metal powder, for instance aluminum powder. This is particularly desirable if a somewhat higher degree of heat-transmission throughout the completed cellular structure is desired, or a higher degree of acoustic insulation, or a somewhat higher specific gravity.
With solid pulverulent materials of somewhat larger particle size, for instance 0.1 mm., and by using a relatively small proportion of the liquid hardenable binder it will still be possible to obtain an average thickness of the walls of the hardened hollow cellular structure of the same magnitude and thus of a good average strength, as described above. By using more finely subdivided solid pulverulent material and an even smaller proportion of liquid hardenable binder, a correspondingly less resistant hollow cellular structure of smaller cell wall thickness and even lesser specific gravity will be obtained. On the other hand, utilization of solid pulverulent material of relatively coarse granules, for instance pulverulent material of a particle size of between about 0.2 and 0.4 mm. and of somewhat more viscous hardenable binder material in a larger proportion, will result in a hollow cellular structure having thicker cell walls and possessing higher mechanical strength. The heating of the coated mass of foamed granules in a mold under pressure may be carried out by placing the mold into a suitable furnace, or, for instance, by exposure to a highfrequency alternating electric field.
The hardening temperature in the case of swelled polystyrene granules preferably will be between 80 and 90 C., but will also depend on the characteristics of the hardenable-binder material the speed of hardening of which will increase with increasing temperatures.
Since the hardening of the epoxy resin is an exothermic process and the heat produced thereby is only slightly absorbed by the foamed granules and cause, due to the low heat capacity of the granules of a relatively quick rise in temperature, it frequently suffices to heat the compressed mass of coated foamed granules from the outside in order to progressively effect the heat-hardening of the hardenable resin throughout the interior of the mass. Generally it is preferred to carry out the compression of the loose mass of coated foamed granules, i.e., granules coated with the hardenable binder and the pulverulent material adhering thereto at pressures of at least 1 atmosphere above atmospheric pressure, so as to reduce the volume of the compressed mass to at most 75 percent, preferably between 50 percent and 60 percent of the initial volume of the loose mass of coated granules.
The amount of binder material preferably should be sufficient to fill the portion of the interstices between the swelled granules which is not taken up by the pulverulent material.
It is also possible without difficulty to incorporate into the loose mass of coated foamed granules prior to compression of the same solid bodies having dimensions larger than the dimension of the coated granules and consisting of material of higher specific gravity, such as swelled clay bodies, so that these occlusions will become integral with the hollow cellular structure during compression and formation of the same.
Primarily, it has been found advantageous to form during compression of the coated granular mass in the mold a compound structure consisting of the polyhedric cellular structure formed as described above and substantially planar, resistant and for instance smooth and suitably colored cover materials, such as plates, sheets, foils, mats, for instance mats of synthetic resin impregnated glass or asbestos fibers, whereby it is frequently advantageous to wet these plates or the like prior to introduction into the mold with the liquid hardenable resin. It is also within the scope of the present invention to incorporate in the walls during the compression of the same connecting elements such as door fittings, screws, jointing members and the like, which may themselves act as or may be i replaced by or be in addition to supporting or reinforcing elements which may be completely or partially embedded in the cellular structure so as to be integral therewith. Particular types of reinforcing elements are not part of the invention. On the other hand, it is also within the scope of the present invention to adhesively adhere a covering sheet material to the hollow cellular structure after completion of compression of the same and of hardening of the binder material thereof. Such covering material may be in the form of plates, sheets, foils, mats and the like. 7
Mold portions and inserted elements such as tubular cores which during compressing of the coated granules should not become part of the thereby fonned cellular structure should be coated with conventional separating agents, for instance silicone or fluorocarbon-based products such as those commercially available under the trade name TEFLON.
It is, for instance, possible, and frequently desirable, to in sert tubular cores into the mold cavity and to pass heated fluids such as air or liquids through the tubular core in order to harden the hardenable binder constituent of the coating of the blown granules which are compressed to form a unitary cellular structure. Broadly, practically all conventional pressure casting techniques can be applied or adjusted for use in connection with the present invention.
The present invention also encompasses the compressed cellular body produced as described above, which body comprises polyhedric cell walls which are integral with each other and form practically closed cells. The cell walls consist essentially of hardened binder material with solid pulverulent particles embedded therein. Each of the cells defined by the cell walls will contain either, a blown granule of, for instance, polystyrene, which will form a thin layer on the interior face of the cell, or at least the material of such granule even though the same may no longer adhere to the inner surface of the cell. For the purpose of the present invention, it is of little consequence whether the initially present blown granule forms an inner layer on the cell-defining walls of whether the material of the granule, due to overheating or the effect of solvents or for other reasons, while still contained within the cell, no longer adheres to the inner face thereof. The strength of the unitary cellular body is primarily determined by the cell walls formed of the hardened binder and the pulverulent material embedded therein. Nevertheless, it is somewhat preferred to have the material of the initial swelled granule of synthetic material within the cell forming a layer on the inner face of the cell-defining walls.
The compressed unitary cellular body thus formed according to the present invention may be, during compression and hardening of the binder material, or subsequently, covered or adhesively adhered with planar cover layers, for instance aluminum or steel sheets or also plates of asbestos cement or any desired fibrous material-synthetic resin combination, or with foils of such or other material. Such cover layers may be applied during the compression and hardening of the binder material so that the adherence is elTected by the hardening binder material, or the cover layers may be subsequently adhered to the unitary cellular body, or the unitary cellular body may be inserted into shells of cover material and preferably adhesively adhered thereto. In such cases, cover layers, for instance aluminum or steel sheet, or of asbestos cement plates, as well as glass fiber reinforced foils of synthetic resin act also as reinforcing elements by giving to the entire composite body comprising the unitary cellular structure and such cover layer not only a surface which is resistant against mechanical attack,
but in addition the cover layer will also considerably improve the tension and the bending resistance of the hollow cellular structure.
It is also possible within the scope of the present invention to incorporate in the hollow cellular structure, during formation of the same by compression and hardening or subsequently thereto, connecting or supporting elements, for instance door fittings, screws, and the like.
It is sometimes of advantage to use profiled plates in combination with the hollow cellular structure, which profiled plates may be of undulating or sharp-edged ribbed shape. The mechanical strength, the heat-insulating and acoustic-insulating properties, the resistance against moisture and other corrosive influences can be adjusted, as desired, in so many different ways that the unitary hollow cellular structure of the present invention in the shape of a building element may, with or without cover layers and/or at least partially embedded reinforcing and other elements, used for self-supporting wall portions, windowsills, doors and door frames, thresholds, floor coverings, ceilings, table tops, as a substitute for fumitureboard and as roofing materials. Furthermore, the shaped unitary hollow cellular structures of the present invention, due to their high strength and low specific gravity, may also be used in the manufacture of machines and apparatus and for the construction of automobiles and other vehicles, particularly the body portions thereof.
Referring now to the drawing, and particularly to the schematic illustration shown in FIG. 1, swelled polystyrene granules 10 are introduced from a storage vessel 2 into a mixing container 1 provided with stirring equipment (not shown). Swelled polystyrene granules 10 are of roundish shape and have a weight of between about 5 and grams per liter and an average diameter of between 3 and 6 mm. For each about 10-15 liters of blown polystyrene granules introduced into the mixing container 1, between about 250 and 300 grams of a liquid hardenable epoxy resin are introduced into the mixing container 1 from storage vessel 3. The hardenable liquid epoxy resin may be, for instance, of the type commercially available under the trade name ARALDIT and will include the required hardening agent. The swelled granules and the hardenable liquid are intimately mixed until all of the granules 10 are evenly wetted and coated with a layer 30 of the liquid hardenable binder materials.
Depending on the proportion of hardenable liquid binder and the viscosity, thereof, the coating of hardenable liquid binder material on the blown polystyrene granules will be of varying thickness. However, it is preferred that the average thickness of the liquid hardenable material coating will be between about 0.08 and 0.25 mm.
As shown in FIG. 2, to the thus coated granules in the mixing container 1, finely subdivided pulverulent material such as quartz sand 40 is introduced and intimately mixed with the liquid-coated granules in container 1. Quartz sand 40 may be replaced with other suitable solid pulverulent materials, for instance impregnated chalk powder or metal powder, such as aluminum powder having a particle size of between about 0.05 and 0.25 mm. The particle size of the pulverulent material preferably will be close to or somewhat below the thickness of coating 30. The amount of the pulverulent material which is admixed should be sufficient to cover the liquid binder coated blown polystyrene granules 10 with an outwardly dry, finely particulate sand layer 40, the individual particles of which adhere to liquid binder coating 3.
If the thus produced double coated polystyrene blown granules, i.e., coated with the hardenable liquid binder material and the solid particulate material are then exposed to a stream of hot air in order to harden the liquid hardenable binder material, roundish extremely lightweight cellular granules with thin hard shells are formed which are excellently suitable as aggregate for incorporation into casting masses, as filler material for filling cavities in a variety of structural and other elements, or as similar material for air purification and air humidifying. The thus produced loose mass of hardened binder material coated polystyrene granules, furthermore provided with a cover layer of solid finely subdivided particles, is excellently suitable as filler material for producing a composite building plate, as illustrated in FIG. 3.
FIG. 3 shows a mold cavity which is defined by mold members 51 and 52..The mold cavity has been filled successively with a lower metal sheet 61, tubular cores 62, a mass of filler material 60 which consisted of swelled polystyrene granules covered with a layer or coating of set binder material and an outer layer of finely particulate solid material the particles of which are partially embedded in the hardened binder layer, such as the granule I0, 30, 40 illustrated in FIG. 2. Finally, on top of the mass of coated granules, an upper metal sheet 63 was introduced into the mold. Cover sheets 61 and 63 were previously coated at their faces directed towards the interior of the mold cavity with hardenable binder material. The entire contents of the mold are then compressed to less than one-half of their original volume, which can be accomplished with a gauge pressure of between about 1-5 atmospheres, assuming that the finished plate should have a thickness of about 6 cm. During such compression, the resiliently yielding polystyrene granules are deformed to polyhedric bodies contacting each other along relatively large surface portions. The plastic liquid hardenable binder material 30 is thereby squeezed outwardly between the solid particles 40, so that solid particles 40 become completely embedded in binder material 30. On the other hand, the sand or the like particles 40 will partially penetrate into the soft polystyrene walls of granules l0 and thereby will prevent the squeezing out of the still fiowable hardenable binder 30 from between the contacting surface portions of adjacent granules. While maintaining pressure, mold 51, 52 and, if desired also tubular cores 62 are heated, for instance by passing heating fluid through tubular cores 62 so that the contents of the mold will be heated, for instance to a temperature of between 5090 C., causing complete hardening of the hardenable binder material.
In this manner, a unitary, polyhedric hollow cellular structure is formed which is adhesively attached to'metal sheets 61 and 63. The inner surface portions of the mold directly adjacent the material filling the mold and the outer face of tubular core 62 had been previously treated with separating agents, for instance silicone or the like, so that these mold portions can be easily separated from the compressed body formed in the mold. It may also be provided for heating the contents of the mold, after hardening of the binder material, for a short period of time to a higher temperature, for instance C., whereby it will be achieved that the polystyrene granules within the interior of the individual hollow polyhedric cells will collapse and lose their resiliency.
FIG. 4 is a fragmentary enlarged illustration of a portion of the cellular structure produced in mold 51, 52 as shown in FIG. 3.
The cellular structure, as shown in FIG. 4, consists essentially of cell walls which comprise the hardened binder material 30 with solid particles 40 embedded therein. Each of the polyhedric cell chambers 23 contains the material of one of the original blown polystyrene granules (not shown), which material, as described above, may either adhere to the inner face of the cell walls or may be collapsed.
The wall thickness of the swelled polystyrene granules, for instance, may be of the magnitude of 0.1 mm., and the weight per cubic meter of such swelled polystyrene granules preferably will be between 5 and 15 kg.
By way of example, for producing one cubic meter of the completed unitary cellular structure according to the present invention, there may be required:
12 kg. 30 percent swelled Styropor granules of 2-8 mm.
60 kg. i 30 percent quartz powder of about 0.1 mm. particle size,
12 kg. i 30 percent epoxy resin with required hardener addition.
1 1 Thus the total weight will be 84 kg./m :30 percent. The unitary cellular structure may be formed, as described further above, by compressing the binder-powder covered granules at a gauge pressure of about two atmospheres.
Without further analysis, the foregoing will so fully reveal the gist of the present invention that others can by applying.
current knowledge readily adapt it for various applications withoutomitting features that, from the standpoint of prior art, fairly constitute essential characteristics of the generic or specific aspects of this invention and, therefore, such adaptations should and are intended to be comprehended within the meaning and range of equivalence of the following claims.
What is claimed as new and desired to be protected by Letters Patent is set forth in the, appended claims.
1. A method of producing shaped bodies of low specific gravity, comprising the steps of introducing into a mixing container a mass of discrete roundish hollow granules; thereupon introducing intosaid mixing container a hardenable liquid binder material and stirring the resulting mixture so as to cause substantially complete wetting of the outer surfaces of said granules with said liquid binder material and formation of a coating of said liquid binder material on said outer surfaces; stirring into the thus formed mass of wetted granules a pulverulent solid material so as to adhere particles of said solid pulverulent material to said binder material coating on said hollow granules to thereby form a flowable dry nonadhering mass composed of said hollow granules which are provided, respectively, with a shell consisting of said coating of hardenable binder material and particles of said pulverulent material adhering thereto and at least partially embedded therein; and subjecting said flowable mass to elevated pressure while cause ing hardening of said binder material, to thereby obtain a coherent, shaped cellular body.
2. A method as defined in claim 1, wherein the mass of shell-covered hollow granules is subjected to an elevated pressure sufficient to reduce the volume of said mass by at least 25 percent during deformation thereof into said shaped body.
3. A method as defined in claim 1, wherein said roundish hollow granules are foamed particles of plastic material and said hardenable binder material is heat hardenable.
4. A method as defined in claim 3, wherein said roundish hollow granules are expanded polystyrene granules.
5. A method as defined in claim 3, wherein said solid pulverulent material is a mineral material.
6. A method as defined in claim 3, wherein said solid pulverulent material is a metal powder.
7. A method as defined in claim 3, wherein said hollow foamed granules of plastic material, respectively, have diameters of between about 2 and 8 mm.
8. A method as defined in claim 3, wherein said particles of pulverulent solid material, respectively, have a size of between about 0.01 and 0.4 mm.
9. A method as defined in claim 1, wherein said hardening of said hardenable binder material is carried out by blowing hot gas through the mass of shell-covered hollow particles.
10. A method as defined in claim 9, wherein said hot gas is hot air.
11. A method as defined in claim 1, and including the step of adhesively adhering a substantially planar cover material to at least a portion of said shaped, coherent cellular body.
12. A method as defined in claim 1, and including the step of incorporating in said mass of shell-covered hollow granules, prior to subjecting said mass to said elevated pressure, at least one solid body having a specific gravity higher than that of said shaped, coherent cellular body.
13. A method as defined in claim 1, and including the step of adhering to at least a portion of the surface of said shaped, body, during compression of same and hardening of the hardening binding material thereof, a substantially planar surface layer.
14. A method as defined in claim 13, wherein said planar layer consists of a sheet material.
15. A method as defined in claim 14, wherein said sheet material is a metal sheet.
-16. A method as defined in claim 14, wherein said sheet material is a foil of nonmetallic material.
17. A method as defined in claim 1, and including the step of anchoring and at least partially embedding at least one auxiliary member in the mass of shell-covered hollow granules during compressing of the latter.
18. A method as defined in claim 17, wherein said auxiliary member is a connecting member.
19. A method as defined in claim 17, wherein said auxiliary member is a reinforcing member.
|Cited Patent||Filing date||Publication date||Applicant||Title|
|US2693922 *||Jan 19, 1952||Nov 9, 1954||Northrop Aircraft Inc||Leading edge structure for airfoil|
|US2770965 *||Aug 4, 1952||Nov 20, 1956||David Engel||Insulated hollow building panel|
|US2806509 *||Jun 11, 1956||Sep 17, 1957||Goodyear Aircraft Corp||Sandwich structures|
|US2972559 *||Jun 10, 1957||Feb 21, 1961||Architectural Porcelain Constr||Method of making laminated panels with expanded polystyrene core|
|US3247294 *||Nov 14, 1963||Apr 19, 1966||Bahidj B Sabouni||Concrete products and methods for making same|
|US3314838 *||Aug 26, 1964||Apr 18, 1967||Minnesota Mining & Mfg||Pressure sensitive adhesives containing hollow spheroidal particles|
|US3318697 *||Apr 28, 1964||May 9, 1967||Minnesota Mining & Mfg||Copy sheet having a layer of thermally rupturable hollow microcapsules on a conductive backing and the method of use|
|US3396923 *||Nov 21, 1966||Aug 13, 1968||Dow Chemical Co||Structure and method for the fabrication thereof|
|US3434854 *||Mar 12, 1965||Mar 25, 1969||Aeronca Inc||Method and material for making joints between refractory panels|
|US3470059 *||Dec 22, 1965||Sep 30, 1969||Minnesota Mining & Mfg||Matrix for molding a positive relief impression|
|US3488714 *||Sep 19, 1966||Jan 6, 1970||Dow Chemical Co||Formed laminate structure and method of preparation|
|US3515625 *||Apr 20, 1965||Jun 2, 1970||Steve Sedlak||Composite flexible material containing a high proportion of filler particles|
|Citing Patent||Filing date||Publication date||Applicant||Title|
|US3791912 *||Jul 16, 1971||Feb 12, 1974||Francois Allard||Construction member|
|US3967005 *||Dec 11, 1974||Jun 29, 1976||Mario Cattaneo||Method for enveloping pellets of foamed poly-styrene suitable for producing lightened manufactured articles of cement|
|US4056647 *||Dec 29, 1975||Nov 1, 1977||Armstrong Cork Company||Powder edge coating for ceiling tile|
|US4327046 *||Dec 7, 1979||Apr 27, 1982||Southern Research Institute||Method for producing a rigid, shaped mass support system|
|US4331472 *||May 21, 1981||May 25, 1982||Ktrom Industries, Inc.||Metal removal apparatus and method|
|US4331473 *||May 21, 1981||May 25, 1982||Ktrom Industries, Inc.||Silver removal apparatus and method|
|US4596682 *||May 11, 1984||Jun 24, 1986||Benjamin Mosier||Method of manufacturing fire retardant polystyrene insulating board|
|US4631228 *||Dec 16, 1985||Dec 23, 1986||Lear Siegler, Inc.||Method for making a porous rigid structure and the porous rigid structure made thereby|
|US4714715 *||Mar 7, 1986||Dec 22, 1987||Benjamin Mosier||Method of forming fire retardant insulating material from plastic foam scrap and the resultant product|
|US5112657 *||Jul 11, 1990||May 12, 1992||Pierce & Stevens Corporation||Simulated marble products|
|US5230850 *||May 16, 1991||Jul 27, 1993||Lewis Raymond O||Fan blade reinforcement using bonded hollow spheres|
|US5800658 *||Oct 8, 1997||Sep 1, 1998||Cirrus Ab||Method and means by manufacture of a product of expanded polymer|
|US6146051 *||Aug 2, 1999||Nov 14, 2000||Conventry University||Paving system for spillage and flood management|
|US6301722||Sep 1, 1999||Oct 16, 2001||Brock Usa, Llc||Pads and padding for sports gear and accessories|
|US6357054||Feb 17, 2000||Mar 19, 2002||Brock Usa, Llc||Protective padding for sports gear|
|US6453477||Mar 4, 2002||Sep 24, 2002||Brock Usa, Llc||Protective padding for sports gear|
|US6572920||Feb 3, 2000||Jun 3, 2003||Cycle Group Limited Of Delaware||Method of coating granulated material|
|US6611980 *||Mar 23, 2001||Sep 2, 2003||Patrick L. Wempe||Molded cushion and method of making the same|
|US6739101 *||Jan 16, 2002||May 25, 2004||Cardinal Ig Company||Methods and apparatus for manufacturing muntin bar assemblies|
|US7073508||Oct 13, 2004||Jul 11, 2006||Loma Linda University Medical Center||Method and device for registration and immobilization|
|US7076927||Apr 5, 2004||Jul 18, 2006||Cardinal Ig Company||Apparatus for manufacturing muntin bar assemblies|
|US7244477||Aug 20, 2003||Jul 17, 2007||Brock Usa, Llc||Multi-layered sports playing field with a water draining, padding layer|
|US7638080 *||May 5, 2003||Dec 29, 2009||Trysome Limited||Forming composite structures|
|US7662468||Oct 15, 2003||Feb 16, 2010||Brock Usa, Llc||Composite materials made from pretreated, adhesive coated beads|
|US7696499||Apr 13, 2010||Loma Linda University Medical Center||Modular patient support system|
|US7746978||Oct 8, 2007||Jun 29, 2010||Loma Linda University Medical Center||Path planning and collision avoidance for movement of instruments in a radiation therapy environment|
|US7789560||Sep 7, 2010||Loma Linda University Medical Center||Method and device for delivering radiotherapy|
|US7949096||May 24, 2011||Loma Linda University Medical Center||Path planning and collision avoidance for movement of instruments in a radiation therapy environment|
|US7984715||May 8, 2006||Jul 26, 2011||Loma Linda University Medical Center||Method and device for registration and immobilization|
|US8083408||Dec 27, 2011||Loma Linda University Medical Center||Method and device for delivering radiotherapy|
|US8093569||Apr 12, 2010||Jan 10, 2012||Loma Linda University Medical Centre||Modular patient support system|
|US8184773||May 22, 2012||Loma Linda University Medical Center||Path planning and collision avoidance for movement of instruments in a radiation therapy environment|
|US8210899||Nov 20, 2007||Jul 3, 2012||Loma Linda University Medical Center||Device and method for immobilizing patients for breast radiation therapy|
|US8269195||Sep 18, 2012||Loma Linda University Medical Center||Patient alignment system with external measurement and object coordination for radiation therapy system|
|US8376613||Feb 19, 2013||Loma Linda University Medical Center||Method and device for delivering radiotherapy|
|US8418288||Apr 16, 2013||Loma Linda University Medical Center||Modular patient support system|
|US8479743||Jul 22, 2011||Jul 9, 2013||Loma Linda University Medical Center||Method and device for registration and immobilization|
|US8523630||Jul 2, 2012||Sep 3, 2013||Loma Linda University Medical Center||Device and method for immobilizing patients for breast radiation therapy|
|US8569720||Aug 24, 2012||Oct 29, 2013||Loma Linda University Medical Center||Patient alignment system with external measurement and object coordination for radiation therapy system|
|US8784709 *||May 23, 2012||Jul 22, 2014||Sto Se & Co. Kgaa||Method for manufacturing a formed body with a cavity structure for sound and/or heat insulation and formed body for sound and/or heat insulation|
|US8981324||Oct 24, 2013||Mar 17, 2015||Loma Linda University Medical Center||Patient alignment system with external measurement and object coordination for radiation therapy system|
|US9084886||Aug 30, 2013||Jul 21, 2015||Loma Linda University Medical Center||Device and method for immobilizing patients for breast radiation therapy|
|US20030121103 *||Feb 18, 2003||Jul 3, 2003||Wempe Patrick L.||Method for forming a molded cushion|
|US20040187407 *||Apr 5, 2004||Sep 30, 2004||Cardinal Ig Company||Methods and apparatus for manufacturing muntin bar assemblies|
|US20040224139 *||May 5, 2003||Nov 11, 2004||Trysome Limited||Forming composite structures|
|US20050042394 *||Aug 20, 2003||Feb 24, 2005||Sawyer Daniel C.||Multi-layered sports playing field with a water draining, padding layer|
|US20050284490 *||Oct 13, 2004||Dec 29, 2005||Moyers Michael F||Method and device for registration and immobilization|
|US20080042076 *||Feb 6, 2007||Feb 21, 2008||Loma Linda University Medical Center||Modular patient support system|
|US20080187097 *||Oct 8, 2007||Aug 7, 2008||Cheng Chieh C||Path planning and collision avoidance for movement of instruments in a radiation therapy environment|
|US20080240350 *||Feb 19, 2008||Oct 2, 2008||Loma Linda University Medical Center||Method and device for delivering radiotherapy|
|US20090067577 *||Nov 4, 2008||Mar 12, 2009||Rigney Nickolas S|
|US20100067659 *||Nov 20, 2007||Mar 18, 2010||Loma Linda University Medical Center||Device and method for immobilizing patients for breast radiation therapy|
|US20100173116 *||Feb 9, 2010||Jul 8, 2010||Bainbridge David W||Composite materials made from pretreated, adhesive coated beads|
|US20100192303 *||Aug 5, 2010||Loma Linda University Medical Center||Modular patient support system|
|US20110218679 *||Sep 8, 2011||Loma Linda University Medical Center||Path planning and collision avoidance for movement of instruments in a radiation therapy environment|
|US20120301700 *||May 23, 2012||Nov 29, 2012||Sto Ag||Method for manufacturing a formed body with a cavity structure for sound and/or heat insulation and formed body for sound and/or heat insulation|
|USRE33986 *||Mar 28, 1988||Jul 7, 1992||Method of manufacturing fire retardant polystyrene insulating board|
|EP0227201A1 *||May 19, 1986||Jul 1, 1987||Lear Siegler, Inc.||Method for making a porous rigid structure and the porous rigid structure made thereby|
|EP0227897A1 *||Oct 2, 1986||Jul 8, 1987||Ipa-Bauchemie Gmbh||Ductile shaped body and its application, method of its production and reaction resin component for this method|
|EP1180635A2 *||Aug 1, 2001||Feb 20, 2002||E. Missel GmbH & Co.||Damping material for pipes|
|WO1993016129A1 *||Jan 21, 1993||Aug 19, 1993||Siemens Aktiengesellschaft||Syntactic foam|
|U.S. Classification||156/77, 264/122, 156/279, 156/296, 264/123, 428/407, 252/62, 264/DIG.700, 52/325|
|International Classification||C04B26/02, C08J9/236, F16L59/14, B29C70/00, B29C44/12, B29C67/20, C04B20/12, E04C2/20, C08J9/22, C04B26/10|
|Cooperative Classification||B29K2309/08, C08J9/236, F16L59/14, C04B20/12, Y10S264/07, C04B26/10, C04B26/02, B29C70/00, B29K2105/06, B29C67/207, C08J9/22, E04C2/205, B29C44/12|
|European Classification||B29C44/12, C04B26/10, B29C70/00, F16L59/14, C04B26/02, B29C67/20E, C08J9/22, C04B20/12, C08J9/236, E04C2/20B|