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Publication numberUS3643658 A
Publication typeGrant
Publication dateFeb 22, 1972
Filing dateAug 27, 1969
Priority dateSep 3, 1968
Also published asDE6933926U
Publication numberUS 3643658 A, US 3643658A, US-A-3643658, US3643658 A, US3643658A
InventorsSamuel Steinemenan
Original AssigneeStraumann Inst Ag
Export CitationBiBTeX, EndNote, RefMan
External Links: USPTO, USPTO Assignment, Espacenet
Implants of titanium or a titanium alloy for the surgical treatment of bones
US 3643658 A
A titanium or titanium implant with the novel feature of the surface layer formed as an oxide, nitride, carbide and carbonitride. The surface layer is applied to prevent abrasion and corrosion of the implant and to prevent fretting between contacting implants as well as to improve the appearance thereof.
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Description  (OCR text may contain errors)

United States Patent Steinemenan 1 Feb. 22, 1972 [54] IMPLANTS OF TITANIUM OR A 3,268,372 9/1966 Brotherton et al..... 148/20 TITANIUM ALLOY FOR THE 3,338,805 9/1967 Pochily et al. 204/56 U I L REA E OF BQNES 3,346,469 10/1967 Weigel .204/56 3,408,236 10/1968 l-lartesve1dt.... ...148/6.3 [721 lnvenmrl Samuel Steinemmn, hem! swltlefland 3,409,469 11/1968 Kuntz ..117/231 73] Assignee; Institute Relnhard Su-aumann, 3,442,720 5/1969 Bradley et al ..l48/6.3 Waldenburg, Switzerland 3,466,669 9/ 1969 Flatt ..3/ l

, 4 Filed: g 1969 3,508 95 4/1970 Wh1te et al I 17/ 106 Appl' 869428 Primary ExaminerRichard A. Gaudet Assistant Examiner-=1. Yasko [30] Foreign Application Priority Data Attorney-McGlew and Toren Sept. 3, 1968 Switzerland ..13217/68 [57] ABSTRACT [52] US. Cl. ..128/92 D, 117/106 C, 148/63 [51] Int. Cl. ..A61t 5/04 A htahlum 0T hmhlum Implant with the novel feature of the [58] Field of Search ..12s/92 A-92 E; Surface layer formed as an i e, i i carbide and 3/1; 1 17/ 106 C, 106 R, 127; 148/63, 6.11; 204/56 bonitride. The surface layer is applied to prevent abrasion and corrosion of the implant and to prevent fretting between con- [56] References Cited tacting implants as well as to improve the appearance thereof.

UNlTED STATES PATENTS 2 Claims, No Drawings IMPLANTS OF TITANIUM OR A TITANIUM ALLOY FOR THE SURGICAL TREATMENT OF BONES BACKGROUND OF THE INVENTION The present invention relates to an implant of titanium or an alloy based on titanium for the surgical treatment of bones. An alloy based on titanium is understood to be an alloy which has either a titanium content of more than 50 percent or in which at least the alloying component of the largest percentage is titanium. I

Such implants are already known per se and in use. Inter alia bone plates and screws are manufactured from technically pure titanium and titanium alloys. In modern methods of surgical treatment of bones, the bone fragments are subjected to pressure when set by means of implant plates and screws and these elements are strongly dimensioned, so that the fracture does not have to be immobilized for long. Furthermore, specially shaped longitudinal slots may be provided in the plates for tensioning. Thus, when the screws are inserted into the plate and when the treated operated bones are subjected to loads, large forces occur which cause a high degree of friction between the parts and fretting of the rubbing parts. The fretting corrosion at the point of metallic contact and the whole surface of the implant effects a considerably increased amount of metal destruction with its damaging consequences.

SUMMARY OF THE INVENTION According to the present invention there is provided an implant of titanium or an alloy based on titanium for the surgical treatment of bones comprising a surface layer from the group which includes an oxide, nitride, carbide and carbonitrite. Preferably, the layer is applied to the implant by anodic treatment. Alternatively, the layer may be formed at an elevated temperature either by reaction with gases or in a salt bath. The implant surface to which the layer is applied may be polished or matt and the layer when formed may, advantageously be colored by interference.

- DETAILED DESCRIPTION OF THE INVENTION The aforegoing and further features of the invention will be described with particular emphasis given to the advantages which may be attained.

The invention provides for an implant to be coated with a surface layer thereby ensuring that the surface coated implant possesses a greater resistance to abrasion than an implant LII without a surface layer.

This feature of the novel implant is particularly important for those implants of titanium or titanium alloy which rub against implants which likewise consist of this metal as is the case when a screw is inserted in a compression plate. The surface coating, especially when its thickness is greater than about 0.1 um, prevents the emergence of abrasion and also of mutual fretting because the oxides, nitrides, carbides and carbonitrides have great hardness.

The novel implant also possesses greater resistance to corrosion by tissue fluids, because the applied surface layers have a very low electrical conductivity not only on the parts pos sessing a large surface but, more important, the comparatively small depressions and apertures such as screw holes, screw slits, which are of particular sensitivity to corrosive attacks. in particular the fretting corrosion is suppressed or reduced.

The thickness of the surface layer of the novel implant may be chosen such that interference colors appear, the thickness for the first series of the colors gold, purple and blue being up to about 0.08 pm and repeating in a second series up to about 0.l5 pm. In this case, it is possible to obtain a very exact control over the corrosion behavior in the tissues since corrosive attacks can be particularly well observed in such a layer. even if only traces are concerned.

It is possible to coat the implant with a layer which has a color similar to that of the tissues, such a colored implant. which frequently lies closely under the skin and may glisten through it, will no longer appear offensive, in contrast to the previously used implants having a silver or nickel color. which because of their color are often so easily visible, that they disturb the wearer.

Whereas, implants without a layer often show spots, which occur when the implant is handled, and which are yet intensified on sterilizing so that frequently such implants have the appearance as if the surface treatment had not been carried out properly. These disadvantages, too, are not shown by implants in accordance with this invention.

We claim:

1. A ductile plate implant for the external fixation of bones and having means to facilitate the fastening of said plate to the bone and being formed of titanium or an alloy based on titanium for use in the surgical treatment of bones, comprising a surface layer formed on the implant from one of the group consisting of an oxide, nitride, carbide and carbonitride.

2. An implant as defined in claim I, wherein said surface layer having a thickness greater than 0.] pt.

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U.S. Classification606/76, 428/472, 148/317, 148/237, 148/278, 148/316, 428/472.1, 606/286, 606/907, 606/298
International ClassificationC22C14/00, A61B17/58, C23C22/00, C25D11/26
Cooperative ClassificationY10S606/907, A61B17/58
European ClassificationA61B17/58