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Publication numberUS3682809 A
Publication typeGrant
Publication dateAug 8, 1972
Filing dateFeb 24, 1970
Priority dateFeb 24, 1970
Publication numberUS 3682809 A, US 3682809A, US-A-3682809, US3682809 A, US3682809A
InventorsLewis Daniel M, Marquardson Kent F
Original AssigneeKennecott Copper Corp
Export CitationBiBTeX, EndNote, RefMan
External Links: USPTO, USPTO Assignment, Espacenet
Electrolytic cell constructed for high circulation and uniform flow of electrolyte
US 3682809 A
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Description  (OCR text may contain errors)

Aug 3, 1972 K. F. MARQUARDSON ETAL 3,682,809

ELECTHOLYTIC CELL CONSTRUCTED FOR HIGH CIRCULATION AND UNIFORM FLOW OF ELECTROLYTE Filed Feb. 24, 1970 N l ,IO 1 0 8 "u1 I 0 u 0 /00 i o 5' K o /2 o o 245" ML) 1;.- l

:tizi ooooooooo Jy ooooooooo ooooooooo ooooooooo "Qi ooooooogo oocoooooo ooooooooo oooo0oo4o Oooooooovo 000000090 INVENTOR. KENT F. MARQUARDSON DANIEL. M, LEWIS Ywwm AT TORNE YS United States Patent O ELECTROLYTIC CELL CONSTRUCTED FOR HIGH CIRCULATION AND UNIFORM FLOW OF ELEC'IROLYTE Kent F. Marquardson, Salt Lake City, and Daniel M. Lewis, Magna, Utah, assignors to Kennecott Copper Corporation, New York, N.Y. f'

Filed Feb. 24, 1970, Ser. No. 13,690

- Int. Cl. C23b 5/ 70 U.S. .CL 204-275 6 Claims ABSTRACT F THE DISCLOSURE Rapid circulation and uniform ilow of electrolyte between flat plate electrodes arranged transversely of an electrolytic cell for electrorening or electrowinning purposes are obtained by constructing they cell with a perforated baiile dividing an elongate and narrow electrolyte feed chamber along one side of the cell from the cell proper and with at least one vertical input pipe, having iniiow orices at intervals along its height and directed lengthwise of the feed chamber, for distributed input of electrolyte to such feed chamber. The electrodes are preferably deeply Irecessed intermediate their upper margins to provide an uninterrupted ow channel in the upper part of the cell and from end to end thereof.

BACKGROUND 0F THE INVENTION Field of the invention The invention is in the field of electrolytic cells, particularly those utilized for electrorening or electrowinning metals wherein iiat plate or slab electrodes are ar# ranged transversely of an elongate cell tank and electrolyte is circulated within the tank and between the electrodes.

State of the art Electrolytic cells of the type concerned are well known, but obtaining rapid and uniform circulation of the electrolyte through such cells has long been a problem. `Rapid circulation in electrowinning cells is highly desirable when the concentration of metal ions in the electrolyte is low, and is desirable in both electrowinning and electroreiining cells when high current densities are employed in order to increase the purity of the metal being deposited. Uniformity of circulation is always sought for both types of cells. Normally, however, circulation tends tobe ,sluggish and non-uniform due to the manner of introducing electrolyte into the cell.

RELATED APPLICATIONS This application bears a certain relationship to one filed Mar. 4, 1968 by the present applicants jointly with Joseph M. Lebrizzi, Ser. No. 710,040 now Patent No. 3,558,466. tBoth -applications have a common assignee.

SUMMAIRY IOF THE y'INVENTION The electrolytic cell of this invention has a baille, perforated throughout its height and breadth, dividing a feed chamber for electrolyte from the cell proper along one side of the cell and throughout the length and depth of the electrolytic bath in the cell tank. A vertical input pipe, closed at one end and having jet orifices at intervals along its height and directed along the length of the chamber, is `positioned in the chamber usually at one end thereof. For extra long cells, i.e. over fifteen feet in length, one or more additional input pipes can be used. As an aid to overall circulation throughout the cell in the vicinity of the electrodes, it is advantageous that such electrodes be deeply Irecessed or indented intermediate their top margins to form an uninterrupted flow channel in the upper Patented Aug. 8, 1972 ice The best mode presently contemplated of carrying out the invention is illustrated in the accompanying drawing in which:

(FIG. l is a view in perspective of an electrowinning cell in accordance with the invention, a portion of the cell tank being broken away to reveal details of the electrolyte feed chamber and input pipe;

FIG. 2, a longitudinal vertical section taken on the line 2--2 of FIG. 1;

LFIG. 3, a transverse vertical section taken on the line 3 3 of FIG. 1; and

EIG. 4, a fragmentary horizontal section taken on the line 4-4 of FIG. 3 to show details of the clip attachment of perforated baflle to anode slabs.

DETAILED DESCRIPTION OIF THE LLUSTRATED EMBODIMENT In the specific construction illustrated as representative of the best mode presently contemplated of carrying out the invention as applied to an electrowinning cell, e.g. for recovering copper ions from a leach solution, a concrete cell tank 10 of usual type is lined with a non-corrosive material 11, such as polyvinylchloride sheeting. Tank 10 is of customary elongate rectangular formation, having lateral side walls 10a extending longitudinally and adapted to support the cell electrodes, and having end Walls 10b.

As in the aforesaid related application Ser. No. 710,- 040, a perforated wall or partition 12 is provided within cell tank 10 in narrowly spaced parallel relationship with oneof the lateral side walls 10a thereof and extending throughout the length and effective height of the tank, i.e. at least as high as the maximum depth of electrolyte, to divide from the cell proper 13 an elongate and narrow feed chamber 14 for electrolyte.

' In the present instance, the wall or partition 12 is formed of rigid polyvinylchloride plastic or other inert material as a bafe plate separate from the tank 10, and is held in place by special spacer clips 15, FIGS. 3 and 4, attached to several of the slab anodes A at intervals along the length of the tank. This is a particularly advantageous arrangement for electrowinning cells wherein the wall 12 should ,be removable. For electrorening cells, such Wall can be made an integral part of the tank if desired.

As here shown, the slab anodes A are of lead with integral hanger lugs or ears and areperforated to enhance electrolyte circulation. However, they may be of any type. Cathodes C are the usual starter sheets, e.g. of copper, looped around electrically conductive hanger bars 16. Both anodes and ycathodes are closely spaced along the length of cell tank 10 within the cell proper 13 and are suspended from lateral walls 10a 0f the tank in customary manner. The spaces 17 between anode-cathode pairs confront perforated baiiie 12 for receiving direct ows of electrolyte from the perforations 12a thereof.

The clips 15 are preferably injection molded from polyvlnylchloride plastics or the like to provide anode-marginhugging clip numbers 15a, FIG. 4, extending from a member 15b to which bale 12 is attached as by means of stainless steel screws as shown. The anode margin is preferably recessed to receive and hold clip members 15a.

In accordance with the invention, electrolyte is introduced into the cell by means of an input pipe 18, closed at one end 18a, FIG. 2, and provided with a number of jet orifices 18b at intervals along its height and directed along the length of feed chamber 14. It has been found that, with this arrangement, the introduction of electrolyte into feed chamber 14 is effectively distributed from top to'bottom of the electrolyte bath and that the flow of electrolyte through the perforations 12a of batiie 12 toward the electrodes in cell proper 13 is substantially uniform through out the length of the cell despite the location of pipe 18 at one end of the feed chamber. The reason for this may be a Venturi action exerted by the input jet streams from pipe 18 with respect to the perforations 12a located nearest thereto, tending to draw some of the electrolyte from the cell proper into the feed chamber. Whatever the explanation, the flow of electrolyte into and through the cell proper and between the electrodes thereof is of signicantly higher velocity and greater uniformity than is obtainable when electrolyte is introduced into the feed chamber in a single large and undistributed stream.

Typical inside dimensions for the cell illustrated are overall width four feet with feed chamber four inches, height four and one-half feet, length fifteen feet. Input pipe 18 is typically two inch. For longer cells, one or more additional input pipes 18 may be used to maintain maximum velocity and uniformity of electrolyte ow. These may be variously arranged, but are spaced to give most elective coverage. The jet orifices 18b are typically threeeighths of an inch in diameter, as are the perforations 12a. The number of perforations may vary considerably, but the arrangement shown is typical. For electrowinning cells, the electrolyte input rate is typically from twenty to sixty gallons per minute; for electrorening cells such rate is typically from 'ive to fifteen gallons per minute.

Discharge of electrolyte from the cell is preferably by way of a Weir box 19 leading from cell proper 13 at the end of the cell opposite that at which pipe 18 is located. A height-adjustable Weir pipe 20, also conveniently of polyvinylchloride or the like, leads from Weir box 19 into a discharge pipe 21 with an O-ring 22 being interposed to prevent leakage. The usual pumping connections (not shown) between discharge pipe 21 and input pipe or pipes 18 are provided to effect recirculation of and the desired input rate for the electrolyte.

An optional feature of the invention in combination with the above is the recessing or indenting of the electrodes along and intermediate of their upper margins so as to provide a longitudinal ow channel 23 for electrolyte along the upper part of cell proper 13. As illustrated, the anode slabs A are each indented at 24 and the cathode starting sheets |C are each provided with a pair of spaced suspension loops 25 to form a recess 26, FIG. 1, such indentations and recesses extending below the normal level of electrolyte in the cell collectively forming llow channel 23 leading toward Weir box 19.

Whereas this invention is here illustrated and described and illustrated with respect to a certain preferred form thereof, it is to be understood that many variations are possible without departing from the inventive concepts particularly pointed out in the claims.

1. An electrolytic cell, comprising a cell tank adapted to hold a bath of electrolyte; dat plate electrodes extending ltransversely of and closely spaced along the length of the tank to provide circulation passagesfor electrolyte therebetween and with the Walls of the tank; a bae Within and extending longitudinally of the tank throughout the depth of said bath and spaced from a longitudinal wall thereof to form a relatively narrow feed chamber for electrolyte laterally of said electrodes, said baie being perforated throughout; a vertical input pipe for electrolyte at one end of said feed chamber and extending substantially throughout the height of said baille, said pipe being closed at one end and havinga series'of jet orices along its height directed longitudinally of said feed chamber; means for introducing electrolyte into said pipe under pressure; and means for discharging electrolyte from said cell. l

2. An electrolytic cell in accordance with claim 1, wherein the baille is a plate separate from the cell tank;

v and wherein removable clips secure said plate to electrodes along the length of the to the electrodes.

3. An electrolytic cell in accordance with claim 1, wherein the electrodes are pairs of anodes and cathodes for electrowinning purposes, the anodes being perforated slabs and the cathodes being starter' sheets for the metal to be won.

4. An electrolytic cell in accordance with claim 1' wherein the electrodes are recessed along anintermediate portion of their upper edges to provide an uninterrupted llow channel longitudinally of the cell in the upper part thereof.

5. An electrolytic cell in accordance with claim 4, wherein the means for discharging electrolyte comprises a weir box at the end of the cell opposite that at which the input pipe is located, and the tlow channel leads toward said Weir box.

6. An electrolytie cell in accordance with claim 5, wherein the Weir box is provided with a height-adjustable Weiilr pipe for establishing the level of electrolyte in the ce cell in spaced relationship References Cited UNITED STATES PATENTS 590,801 9/1897 Brown 204-275 1,182,096 5/1916 Mackay A 204-269 2,341,356 2/1944 Briggs 204-257 3,389,071 6/ 1968 Meyers O 204-275 3,558,466 1/1971 Lebri'zz et al. 2074-2775 FOREIGN PATENTS 1,132,341 v6/ 1962 Germany 204-275 JOHN H. MACK, Primary Examiner W. I. SOLOMON, Assistant Examiner -U.s. c1. xn. 204-255, 257, 269, 2,81, 286

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US3893902 *Apr 12, 1973Jul 8, 1975Diamond Shamrock CorpElectrolytic sea water process
US4100042 *Mar 2, 1977Jul 11, 1978Reed GooldProcess for electrowinning metals from a metal-bearing solids slurry
US4124480 *Feb 14, 1977Nov 7, 1978Paterson Candy International, LimitedBipolar cell
US4282082 *Jan 29, 1980Aug 4, 1981Envirotech CorporationSlurry electrowinning apparatus
US4288309 *Dec 17, 1979Sep 8, 1981EcopolElectrolytic device
US4634503 *Jun 27, 1984Jan 6, 1987Daniel NogavichPrinted circuits
US5066379 *Jun 14, 1990Nov 19, 1991Corrosion Technology, Inc.Container for corrosive material
US5079050 *Nov 29, 1989Jan 7, 1992Corrosion Technology, Inc.Container for corrosive material
US5514258 *Aug 18, 1994May 7, 1996Brinket; Oscar J.Substrate plating device having laminar flow
US5855756 *Nov 20, 1996Jan 5, 1999Bhp Copper Inc.Methods and apparatus for enhancing electrorefining intensity and efficiency
US6342136Apr 21, 1999Jan 29, 2002Outokumpu OyjBusbar construction for electrolytic cell
US7204919Dec 3, 2003Apr 17, 2007Pultrusion Technique Inc.Board for use to support anodes and cathodes within adjacent electrolytic cells
US8454818 *Aug 7, 2008Jun 4, 2013Mettop GmbhMethod for operating copper electrolysis cells
US20110056842 *Aug 7, 2008Mar 10, 2011Mettop GmbhMethod for operating copper electrolysis cells
EP0146732A1 *Nov 2, 1984Jul 3, 1985Holzer, Walter, Senator h.c. Dr.h.c.Ing.Process and apparatus for separating, for example, copper from a liquid electrolyte introduced into a pluricellular electrolyser
EP0431313A1Oct 31, 1990Jun 12, 1991Corrosion Technology, Inc.Container for corrosive electrolytes
WO1997020087A1 *Nov 27, 1996Jun 5, 1997Bhp Copper IncMethods and apparatus for enhancing electrorefining intensity and efficiency
WO1999057337A1 *Apr 21, 1999Nov 11, 1999Kivistoe TuomoBusbar construction for electrolytic cell
WO2001032962A1 *Nov 6, 2000May 10, 2001Garbutt Peter JohnAn electrolytic cell
WO2003083179A1Mar 20, 2003Oct 9, 2003Outokumpu OyTransfer and insulation device for electrolysis
U.S. Classification204/278.5, 204/255, 204/281, 204/269, 204/257
International ClassificationC25C7/00
Cooperative ClassificationC25C7/00
European ClassificationC25C7/00
Legal Events
Jan 17, 1991ASAssignment
Effective date: 19890630
Jul 11, 1989ASAssignment
Effective date: 19890628
Jun 25, 1987ASAssignment
Effective date: 19800520
Effective date: 19870320
Effective date: 19870220