|Publication number||US3772137 A|
|Publication date||Nov 13, 1973|
|Filing date||Jun 8, 1971|
|Priority date||Sep 30, 1968|
|Publication number||US 3772137 A, US 3772137A, US-A-3772137, US3772137 A, US3772137A|
|Original Assignee||Du Pont|
|Export Citation||BiBTeX, EndNote, RefMan|
|Patent Citations (3), Referenced by (97), Classifications (20)|
|External Links: USPTO, USPTO Assignment, Espacenet|
I United States Patent 1191 1111 3,772,137
Tolliver 1 Nov. 13, 1973 POLYESTER PILLOW BATT 2,999,296 9/1961 Breen et al. 161/169 Inventor: J es w. ouive Kinston NC. 3,014,237 12/1961 Breen 18/8  Assignee: E. l. du Pont de Nemours and Company, Wilmington, Del. Primary Examiner-Harold Ansher Assistant Examiner-M. E. McCamish  Flled' June 1971 Attorney-Norris E. Ruckman  Appl. N0.: 151,009
Related US. Application Data  Continuation-impart of Ser. No. 763,841, Sept. 30,
1968, abandoned.  ABSTRACT 52 us. 01 161/169, 5/337, 5/361, A ban having high filling power and bulk under load 18/8, 161/141, 161/173, 161/178 comprising crimped hollow polyester filaments. Criti-  Int. Cl. A47c 27/22 l r ng f r th p n void, denier, crimp r  Field of Search 161/169, 139, 140, q n y, n imp in r efin d for he fibers 161/141, 172, 177, 173, 178; 5/337, 361; which interact to provide batts having higher bulk 57/140; 18/8 under load than would be expected by virtue of the voids alone when compared with the bulk of solid 11-  References Cited bers. Also disclosed is a process for making the batts.
UNITED STATES PATENTS 3,630,823 12/1971 Bonner 161/169 2 Claims, 5 Drawing Figures Patented Nov .13, 1973 3,772,137
FIG-1 INVENTOR JAMES w. TOLLIVER MZMW ATTORNEY POLYESTER PILLOW BATT REFERENCE TO RELATED APPLICATION This is a continuation-in-part of my copending application Ser. No. 763,841, filed Sept. 30, 1968, and now abandoned.
BACKGROUND OF THE INVENTION 1. Field of the Invention:
This invention relates to filling structures and more particularly to novel filling structures containing hollow fibers.
2. Description of the Prior Art:
Synthetic hollow fibers are known to the art and the advantage of using such fibers as a filling material, i.e., essentially the same volume of fibers of the same diameter at substantially less weight, also is known. In U.S. Pat. No. 2,171,805, fibers containing bubbles are suggested for use in filling materials. U.S. Pat. No. 2,399,259 teaches that crimped hollow fibers may be converted to staple and used to prepare carded mats for filling cushions. The teachings of U.S. Pat. No. 2,999,296 include the preparation of hollow fibers that can be modified and used as a substitute for kapok fiber. The hollow-fiber filling structures of the prior art are, however, unsuitable for the production of desired, high-bulk filling structures.
In the manufacture of pillows, cushions, comforters, insulated underwear, sleeping bags and the like, a lowdensity, high bulk filling material is required. Further, it is desirable that the high bulk of the filling material possess, to the greatest extent possible, certain special characteristics. That is, the bulk of the material should be both an effective bulk and a resistive bulk. Effective bulk of a filling material is the property that permits the material to fully and effectively fill the space in which it is placed. Materials having a high level of effective bulk are said to have good filling power because of their ability to provide a high crown or plump appearance to the filled article. It is also desirable that the filling materials should resist deformation under an applied stress with the resistance increasing with increasing stress. Structures such as these will not have a padlike feeling under load and will provide some measure of resilience support even under high stresses. Materials with resistive bulk show a high bulk level under load and thus provide filled articles having good support bulk or high insulative protection.
The low-density filling structures of the prior art prepared from hollow fibers are not suitable for providing the desired properties in filled articles.
In accordance with the present invention there is provided novel filling structures of hollow fibers that are eminently suited for providing filled articles having a high level of initial height while providing good support bulk under load. In addition, these novel filling structures show good bulk durability and do not readily mat m use.
SUMMARY OF THE INVENTION tral continuous longitudinal void throughout the length which comprises 13 to 25 per cent of the volume of the filament and is free from collapse at crimp points.
BRIEF DESCRIPTION OF THE DRAWINGS FIG. 1 shows a three-slot spinneret orifice as viewed from either top or bottom which is suitable for producing a round filament having a triangular void as shown in FIG. 2.
FIG. 3 shows a four-slot spinneret orifice as viewed from either top or bottom which is suitable for producing a round filament with a square void as shown in FIG. 4.
FIG. 5 shows a preferred form of four-slot spinneret orifice.
DESCRIPTION OF PREFERRED EMBODIMENTS The hollow filaments used in the practice of the present invention are characterized as having a round cross-section with a hole centrally located in the filament and forming a hollow core extending throughout the length of the filament. A hollow core having a nonround cross section which approximates the shape of a triangle or square is illustrated as making possible the best filling power and support bulk values, but the present invention also provides unusually high values when the hollow cores are approximately circular in cross section. The percent void content of the hollow fiIa ment is the percent of the filament cross section that is hollow or, alternatively, it is times the ratio of the cross-sectional area of the hollow core to the crosssectional area of the entire filament. The fibers of this invention have a void content of about 13 percent to about 25 percent.
In order to provide suitable filling structures, the hollow fibers of this invention must be crimped. The hollow fibers can be crimped using gear crimping means or a stuffer-box crimper so as to provide fibers having at least five crimps per inch (two crimps per centimeter), e.g., from about seven to about 12 crimps per inch (2.8 to about 4.8 crimps per centimeter) and preferably from about six to about nine crimps per inch (2.4 to about 3.6 crimps per centimeter). By crimps per inch is meant the number of crimps imparted to each inch of uncrimped filament wherein a crimp is one cycle of deformation of the fiber, similar to the cycle of a sine wave, and will usually have peaks in a sawtoothed type of configuration. In determining crimps per inch, the total number of crimps in a staple fiber is found and the fiber length measured when the fiber is extended to just straighten out the crimps. The crimps per inch of extended fiber is then calculated. Filling structures prepared from hollow filaments having less than five crimps per inch (two crimps per centimeter) are deficient in support bulk.
The crimp index of the hollow fibers used in the practice of this invention markedly affects the bulk properties of the filling structures. Crimp index relates the length of the crimped fiber to the length of the extended fiber and thus it is influenced by crimp amplitude, crimp frequency, and the ability of the crimps to resist deformation. Crimp index is calculated from the formula wherein 1.. represents the extended length (fibers having under an added load. of 0.13 :02 gpd. for a period of 30 seconds) and represents the crimped length (length of the same fibers hanging under no added weight after relaxing for 60 seconds from the first extension). Fibers suitable for this invention have a crimp index of at least about 23 and preferably from about 25 to about 35. When the crimp index of the fibers is low. both the effective bulk and the support bulk of the filling material drop to undesirable levels.
In addition to the crimp characteristics of the hollow fibers. the denier of the fibers also is important. Fibers having a denier per filament greater than have much less filling power than do fibers having values in the range of 4 to 6 denier.
While the applicant does not wish to be held thereto, it is believed that the improved results provided by the hollow fibers of this invention are associated with the stiffness properties of crimped hollow fibers. It is postulated that at relatively low void content hollow fibers and solid round fibers of the same diameter have essentially the same properties, but that as the void content increases and the fibers become more tube-like, the fibers tend to collapse at the crimp points. Such a weak ened fiber would then be less capable of resisting deformation under stress. Also, as the void content increases much beyond 30 percent, it becomes increasingly difficult to produce high-quality fibers. Conceivably, variations in the fiber, such as in the shape of the hollow core, could also give rise to crimped fibers having a reduced tendency to resist an applied stress.
A preferred method for melt spinning the hollow filaments utilizes spinneret orifices of the type illustrated in FIGS. 1, 3 and 5. The molten filament segments exhibit bulging as they leave the face of the spinneret and coalesce to form the desired hollow filament. Air which enters the filament around the filament segments prior to coalescing prevents the filament from collapsing and thus maintains a hollow core. In practicing the invention, care should be taken to provide appropriate spinnerets since their dimensions are critical. Changes in the void content can be made by changing dimensions of the spinning orifice. Changes in void content can also be made by changing other process variables, e.g., void content increases with increased quenching and increased relative viscosity and decreases with increasing spinning temperature.
In crimping the hollow fibers, it is desirable to use an elevated temperature since the temperature of the yarn in the crimper influences the crimp index. The yarn temperature should be about 35-l00 C. and, if desired, this temperature may be obtained by running the crimper with hot (e.g., 90 C.) finish or steam. When the crimped filaments are dried, and relaxed, relaxation at 130200 C. yields a crimp index within the range needed for the product of this invention.
The filling material of the present invention may be formed in ways known to the art for producing lowdensity structures. Preferably the low-density structure will be a batt produced by forming a web, e.g., as by garnetting, and cross-lapping the web onto a moving apron to form the batt. The batt may, for example, then be cut into sections of such a length that it will provide a sufficient mass for filling a pillow ticking in the desired manner. When such a batt section is rolled and inserted in a ticking, a pillow of outstanding aesthetics is obtained. The ticking may be of the down-proof type and can be treated with a fire retardant.
For some purposes, a more desirable pillow will be obtained if the rolled batt is first encased in a net-type ticking before the batt is inserted in the regular ticking. The net-type ticking may be of a woven, knit, or nonwoven fabric. Preferably the net-type ticking will be of a marquisette fabric.
Ordinarily, an oriented web is produced continuously on a garnetting machine and is folded or cross-lapped on an apron moving across the direction of web delivery, to build up a layered batt containing usually from about two to sixteen layers. Because of the relative motions of web and apron, the successive layers of web cross each other at angles. In general practice, the size of the angle depends somewhat on the width of the batt to be made and the number of web layers desired. The angle formed will generally be in the range of from about 30 to 50", the angle being measured with reference to a line perpendicular to the side (edge) of the apron.
If desired, the layers may be of different widths so as to provide a greater quantity of fiber at the center scc tion than at the edge. Such batts will, of course, result in pillows having tapered ends and are a preferred structure. Such tapered batts can be formed by any conventional means. For example, in the cross-lapping, constant long strokes and constant short strokes in a periodic sequence can be utilized. Alternatively, the means used can be to progressively reduce the size of the strokes in a repeat fashion.
The batts for pillows will normally be prepared in a width of about 2 feet so as to correspond to the length of a standard-size pillow ticking of 20 X 26 inches. Since machine settings of the garnett have a pronounced effect on the thickness of the web and relatively little effect on the amount of web, batting weights are commonly expressed on a weight per unit of area basis rather than density. For example, a batt weighing 0.8 ounces per square foot (0.024 grams per square centimeter) may be about 1.5 to 3.0 inches (3.8 to 7.6 centimeters) in thickness. Suitable batts for pillows have a weight of about 0.3 to 1.5 ounces per square foot (0.0092 to 0046 grams per square centimeter) and a density of about 3.2 to 6.4 ounces per cubic foot (3.2 to 6.4 kilograms per cubic meter). Preferably, the batt will have a weight of about 0.4 ounces per square foot (0.012 grams per square centimeter) and will be about 0.9 to about 1.1 inches (2.29 to about 2.79 centimeters) in thickness.
In some instances, it may be desirable to augment the favorable properties of batts of this invention, for instance as by spraying or otherwise treating them, so as to provide the batts with a small quantity of a flexible, non-tacky resinous substance. For example, it may be desirable to spray the batt with an emulsion of an acrylic resin, such as those formed by the addition poly merization of acrylic esters, to minimize fiber movc ment and thus reduce the migration of fibers from the batt through the ticking. If desired, the acrylic resin binder may be used in conjunction with a lubricant such as a polysiloxane, for example, a dimethyl polysiloxane, a rnethylhydrogen polysiloxane and/or a polysiloxane/polyoxyethylene copolymer.
in the examples that follow, pillows are prepared from low density filling structures and subjected to tests for determination of their bulk properties. The pillows are prepared by producing a batt of a cross-lapped web. The batt is cut to suitable lengths for providing the desired weight and rolled and inserted into a cotton ticktioning cycle under a load of 2 pounds) for heights at loads of 0.01 (H,) and 0.2 (H,,) pounds per square inch (0.0007 and 0.014 kilograms per square centimeter) gage. H, is the initial height and is a measure of filling grams). The stack height is recorded (after one condiing measuring 20 x 26 inches (50,8 x 66,0 5 power and H is the height under load and is a measure centimeters) when flat. The values for measurements of pp r bulkon the filling structures reported in the examples are n h EXamplC the p r ent void is measured by an averaged values. apparent density method in carbon tetrachloride-N- Pillows fabricated from filling material having the heptane 5011150113- most effective bulk or filling power will have the great- EXAMPLE I est center height. The center height of the pillow under no load, H0, is determined by mashing in the Opposite This example illustrates how a filling structure of this corners of the pillow several times and placing the pilinvention may be used to P e Piiiews with low on the load-sensitive table of an lnstron tester and Proved bulk Properties at iess Weight f greaiiy measuring its height at zero load. The lnstron tester is proved bulk Properties at equiveieht Weight as equipped with a metal-disc presser foot that is 4 inches pared to a fining Structure of soild fibers' (10.2 centimeters) in diameter. The presser foot is then Hollow round filaments of polyethylene terephthai' caused to apply a load of 10 pounds (4.54 kilograms) ate i have a Percent vciid F h are Spun from to the center section of the pillow and the height of the f Splnneret cntammg 199 W i orifices of the type pillow at this point is recorded as the load height, H illustrated m which filmensions B c Before the actual H and H measurements, the pillow are 0025 "W (0'064 centimeters)j 0019 inches is subjected to one cycle of 20 pounds (9.08 kilograms) f centimeter) and 0003 inches (0076 compression and load release for conditioning. A load cenglmehers) respecmfeiy The filaments are Spun at of 10 pounds (4.5 kilograms) is used for the HL f i g' g ygg g g l rg i ggz igtg measurement because it approximates the load applied minute) P filamzms s a relative viscosit ofpzs to a pillow under conditions of actual use. lillows havand con'tain O 3% z a delustram) The zelativa mg i highest vahies are the most reslsnve to defer viscosity refers to the ratio of the viscosity of a solution manon and i i Provlde h greatest PP of 2.15 grams of the polyester polymer in question dis- Bulk durability is determined by submitting the filling 3O structure to repeated cycles of compression and load solved m 20 Ofa mixture of 10 parts of phenol and seven parts of 2,4,6-trichlorophenol to the viscosity of release' repeated l or p of the pm the phenol trichlorophenol mixture per se, measured in lows are carried out by placing the pillow on a turntable the Same units at C The hollow Spun filaments are assofiiated with. two pairs of 4 X 12 inch (102, X hot-wet drawn 3.7 times undrawn length at 95 C., mecentlmeter) powered feet which are chanically crimped in a stuffer box crimper in the presmounted above the turntable in such a fashion that durence of Steam relaxed at C. and cut to 20 inch ing one revolution essentially the entire contents are (51 centimetrs) Stap1e subjected to compression and release. Compression is Corresponding Solid round filaments are spun in a accomplished by powering the Worker feet with 80 conventional manner and processed to 2.0 inch (5.1 pounds per square nch (5.62 kilograms per squar 40 centimeter) staple under conditions similar to that decenilmeter) gauge pressure such that they exeljt a scribed above for the hollow filaments. The solid fibers Static iead of appreiiimaieiy 125 Pounds (56-6 kilo are prepared at a slightly higher denier per filament so grams) when in contact with the turntable. The turntathat the two kinds of fibers have approximatdy the ble rotates at a speed of l revolution per 110 seconds Same diameter some typical tow properties for these and each of the worker feet compresses and releases two fibers are shown in Table L the filling material 17 times per minute. After being re- These fibers are the used to prepare bans for pip P y Compressed for Specified Period of time, the lows. Four similar kinds of pillows are prepared and Piiiew is refiuffed y mashing in the pp comers tested as described hereinabove. One kind of pillow Severai times As before, the pillow is Subjected to 3 contains 17.8 ounces (504 grams) of the hollow fibers, conditioning eyeie and the o and L yaiiies deter one kind contains l7.8 ounces (504 grams) ofthe solid mined. fibers, one kind contains 19.8 ounces (56l grams) of The buik Properties of baits of this invention are the solid fibers, and the remaining kind contains 19.8 iem'iihed y compressing the fiiiihg Structure on an ounces (561 grams) of the hollow fibers. Properties stron tester and determining the height under load. The d results b i are Show in Table 1 TABLE i Tenacity, Elonga Boil-oil Percent Denier/ grams/ Lion, shrinkage, Crimp Crlmp/ Fiber void filament denier percent percent index inch (cm) Solid round 0 4.85 4.0 37 0.0 25 8 (a. 2) Hollow round 15 4. 27 3.3 41 0.7 27 8 (3. 2)
test hereinafter referred to as the total b ulk range mea- TABLE 1A surement (TBRM) test, is carried out by cutting 6-inch Pillow proinirtius (15.25-centimeters) squares from a carded web andmuwmm' fl adding tham to a Stack i a l d manner il Fiber ounces (grams) inches ((Im inulns (Cm their total wei ht is 20 grams. The entire area is then 17.8 (50 7.7 (nits 2.8 7.1 compressed ur ider a load of 50 pounds (22.7 kiloh g3 $58 258: 10.8 (561) 8.3 1 1) 1.3 (10.9
From the above it can be seen that filling structures of this invention have bulk properties superior to filling structures of round fibers at percent less weight and highly superior bulk properties at equivalent weight.
The 17.8-ounce (504-gram) pillows are then subjected to the bulk durability test previously described for 1 hour and again the H and H, values are deter mined. The l! values are 7.0 inches (17.8 centimeters) and 7.1 inches (18.0 centimeters) and the H values are 2.1 inches (5.3 centimeters) and 2.7 inches (6.9 centimeters) for the solid and the hollow fibers, respectively. It is thus seen that the filling structures of this invention have good bulk durability.
EXAMPLE 11 This example illustrates the improved bulk properties that the fibers of this invention yield when in the form of carded batts.
The fibers are used to prepare webs that are crosslapped to produce batts. Pillows are prepared from each batt and tested as described above. Results ob tained are shown in Table 3.
As can be seen from reference to Table 3, bulk properties increase with increasing void content at about the same batt weight. It also can be seen that the support bulk begins to deteriorate as the void content approaches percent.
EXAMPLE 1V This example illustrates the bulk properties of batts of this invention and also provides a comparison with batts having unsatisfactory bulk properties.
In eight separate runs, hollow round fibers are prepared as in Example 111, using spinneret orifices of the type illustrated in FlG. 3. The conditions are altered somewhat in each run so as to provide fibers having TABLE 2 various levels of void content, crimps per inch and Filament Description TBRM heights (inches) at load of crimp index.
Pg-52 U04 0 2 (H 30 The above-produced fibers are then used to prepare Solid 6 carded webs which are used for providing 6-inch (15.3 Hollow centimeters) squares for testing as described above. Calculated Increase in v Suppl," Bulk liarncnt properties and the results obtained are given Actual Increase 0.52 0 31 in T ztble 4.
TABLE 4 T8 RM livights at load 0l ltrcr-nt Crimp/inch Crimp Denier 0.01 p.s.i. (lli), 0.2 p.s.i. (11), ltun void (cuntimvivrl index filament in. (our) in. (cm) 1 0 r. s 11 4.31; 3.40 04.153) 0.77 1.00 1 1:1 s.1 :1 1.60 3.13 s70) 0.s0 03) :5 17 0s "1 32 1.73 4.02 (10.02) (is: 2.0s 20 7. 1 I 27 .1.s.-t 1.30 (10.00) use 2.11) 5 :0 11. 1 .01 '17 t. 011 3.25 251 1. 011 2. 54) 0 10 7.7 0.01 12 4. 0 2. -14 0.20 0. (1.40) 7 20 .5) 211 4.111 3.40 3.03 0.50 1.42
- u i 15 a1 (3.2) as 12.1 2.50 (0.35) 0.110 (2. 2s)
EXAMPLE lll This example illustrates the effect of filament void content on pillow bulk properties.
In four separate runs, hollow round fibers are prepared using procedures similar to those described in Example I, but using spinneret orifices of the type illustrated in HS. 3 to give void contents of 9 percent, 13 percent, 23 percent and 27 percent. In all other significant aspects, the fiber characteristics are essentially equivalent.
The height at 0.01 p.s.i. is a measure of the initial bulk, while the height at 0.2 is a measure of support bulk.
As can be seen from comparing Runs 1-5 with Runs 68, high denier fibers, and fibers with low crimp index and crimps per inch values produce a loss in one or more of the measured bulk properties. More specifically, comparing Runs 2 and 6 shows that a low crimp index l2 in Run 6 vs. 23 in Run 2) gives low initial and support bulk. Applicants desired range of crimp index is from about 25 to 35. Likewise, comparing Runs 7 and 4 shows that whenever the crimp frequency is below applicants range of 5-12 crimps per inch, the bulk properties drop. A comparison of Runs 8 and 1 shows the undesirable effect of high denier per filament on initial bulk properties.
EXAMPLE V This example illustrates the desirable bulk properties of fibers of this invention spun from spinneret orifices of the type illustrated in FIG. 5.
Hollow round filaments of polyethylene terephthalate are spun from a spinneret containing 450 spinning orifices of the type illustrated in FIG. in which dimensions A, B, C, D and R are 0.003 (0.0076 centimeter), 0.0067 (0.017 centimeter), 0.033 (0.084 centimeter), 0.004 (0.0102 centimeter) and 0.008 (0.020 centimeter) inches, respectively. The filaments are spun at 275 C. into quench air at room temperature and are wound up at 930 yards (850 meters) per minute. The relative viscosity of the filaments is about 27. The hollow, spun filaments are hot, wet drawn 3.67X at 95 C., mechanically crimped in a stuffer box crimper in the presence of steam, relaxed at 180 C. and cut to 2.0-inch (5.1- centimeter) staple. Samples of the fibers so produced are characterized and found to have a denier per filament of about 4.8 and a void content of 131 5 percent. Crimping conditions are varied to provide different crimp indices. Fibers produced to have 7.1 crimps per inch and a crimp index of 35 are found to have TBRM heights of 3.95 inches H,- and 0.90 inches 11,. Fibers produced to have 7.1 crimps per inch and a crimp index of 26 are found to have TBRM heights of 3.85 inches H,- and 0.90 inches 11,.
l. A polyethylene terephthalate pillow batt which has high filling power and bulk under load, consisting of intermingled hollow round filaments having a denier per filament within the range of 4 to 6, a saw-toothed type of crimped configuration, a crimp frequency within the range of five to 12 crimps per inch, and a crimp index within the range of 25 to 35; the filaments being characterized by a central continuous longitudinal void of nonround cross section throughout the length which comprises 13 to 25 percent of the volume of the filament and is free from collapse.
2. A polyethylene terephthalate pillow batt which has high filling power and bulk under load, consisting of intermingled, hollow, 4 to 6 denier filaments crimped in a saw-toothed type of configuration to impart a crimp frequency of six to nine crimps per inch of uncrimped filament and a crimp index within the range of 25 to 35; the filaments being characterized by a round cross section with a single hole of square shape centrally located in the filament and forming a hollow core extending throughout the length of the filament, the hollow core being 13 to 25 percent of the volume of the filament and free from collapse.
|Cited Patent||Filing date||Publication date||Applicant||Title|
|US2999296 *||Mar 25, 1957||Sep 12, 1961||Du Pont||Novel filaments and fabrics|
|US3014237 *||Mar 25, 1957||Dec 26, 1961||Du Pont||Spinneret|
|US3630823 *||Sep 16, 1969||Dec 28, 1971||Du Pont||Cocarded blend of microcellular and conventional fibers|
|Citing Patent||Filing date||Publication date||Applicant||Title|
|US3892909 *||May 10, 1973||Jul 1, 1975||Qst Industries||Synthetic down|
|US3905057 *||Jul 6, 1973||Sep 16, 1975||Cww Research And Dev Company||Fiber-filled pillow|
|US3924988 *||May 24, 1972||Dec 9, 1975||Du Pont||Hollow filament spinneret|
|US3981948 *||Jan 2, 1975||Sep 21, 1976||Eastman Kodak Company||Arrangements in spinnerets of spinning orifices having significant kneeing potential|
|US4129675 *||Dec 14, 1977||Dec 12, 1978||E. I. Du Pont De Nemours And Company||Product comprising blend of hollow polyester fiber and crimped polyester binder fiber|
|US4167604 *||Jun 30, 1978||Sep 11, 1979||Warnaco Inc.||Thermal insulation material comprising a mixture of down and synthetic fiber staple|
|US4281042 *||Aug 30, 1979||Jul 28, 1981||E. I. Du Pont De Nemours And Company||Polyester fiberfill blends|
|US4288494 *||Mar 12, 1979||Sep 8, 1981||Extracorporeal Medical Specialites, Inc.||Non-uniform cross-sectional area hollow fibers|
|US4304817 *||Feb 28, 1979||Dec 8, 1981||E. I. Dupont De Nemours & Company||Polyester fiberfill blends|
|US4336307 *||Jul 14, 1980||Jun 22, 1982||Teijin Limited||Hollow water absorbing polyester filaments and a process for producing the same|
|US4376746 *||Sep 17, 1981||Mar 15, 1983||Ametek, Inc.||Formation of hollow tapered brush bristles|
|US4850847 *||May 10, 1988||Jul 25, 1989||E. I. Du Pont De Nemours And Company||Spinneret for hollow fibers having curved spacing members projecting therefrom|
|US4933084 *||Jan 11, 1985||Jun 12, 1990||Akzo Nv||Dialysis membrane of cellulose in the shape of a hollow fiber, and process for the production thereof|
|US5104725 *||Apr 30, 1990||Apr 14, 1992||E. I. Dupont De Nemours And Company||Batts and articles of new polyester fiberfill|
|US5224292 *||Apr 11, 1990||Jul 6, 1993||E. I. Du Pont De Nemours And Company||Fibrous mat for growing plants|
|US5277976 *||Oct 7, 1991||Jan 11, 1994||Minnesota Mining And Manufacturing Company||Oriented profile fibers|
|US5484650 *||Jun 2, 1995||Jan 16, 1996||E. I. Du Pont De Nemours And Company||Hollow fiber identification|
|US5527611 *||Jun 2, 1995||Jun 18, 1996||E. I. Du Pont De Nemours And Company||Relating to hollow fiber identification|
|US5538735 *||Feb 19, 1993||Jul 23, 1996||Ahn; Sam S.||Method of making a drug delivery system using hollow fibers|
|US5540993 *||Jun 2, 1995||Jul 30, 1996||E. I. Du Pont De Nemours And Company||Relating to fiber identification|
|US5540994 *||Jun 2, 1995||Jul 30, 1996||E. I. Du Pont De Nemours And Company||Fiber identification|
|US5723215 *||Feb 3, 1997||Mar 3, 1998||E. I. Du Pont De Nemours And Company||Bicomponent polyester fibers|
|US5731248 *||May 28, 1996||Mar 24, 1998||Eastman Chemical Company||Insulation material|
|US5837625 *||Jan 28, 1997||Nov 17, 1998||Eastman Chemical Company||Insulation material|
|US5882794 *||Nov 14, 1997||Mar 16, 1999||E. I. Du Pont De Nemours And Company||Synthetic fiber cross-section|
|US5891568 *||Oct 1, 1997||Apr 6, 1999||E. I. Du Pont De Nemours And Company||Polyester fiber|
|US6329051||Apr 27, 1999||Dec 11, 2001||Albany International Corp.||Blowable insulation clusters|
|US6329052||Jun 14, 1999||Dec 11, 2001||Albany International Corp.||Blowable insulation|
|US6458455||Aug 22, 2001||Oct 1, 2002||E. I. Du Pont De Nemours And Company||Poly(trimethylene terephthalate) tetrachannel cross-section staple fiber|
|US6599850 *||Feb 10, 2000||Jul 29, 2003||Raphael Heifetz||Flexible reflective insulating structures|
|US6746230||May 8, 2001||Jun 8, 2004||Wellman, Inc.||Apparatus for high denier hollow spiral fiber|
|US6752945||Aug 22, 2001||Jun 22, 2004||E. I. Du Pont De Nemours And Company||Process for making poly(trimethylene terephthalate) staple fibers|
|US6754919||May 24, 2001||Jun 29, 2004||Kimberly-Clark Worldwide, Inc.||Protective cover article|
|US6797209||Feb 12, 2003||Sep 28, 2004||Wellman, Inc.||Method and apparatus for high denier hollow spiral fiber|
|US6835339||Jun 24, 2002||Dec 28, 2004||E. I. Du Pont De Nemours And Company||Process for preparing poly(trimethylene terephthalate) tetrachannel cross-section staple fiber|
|US6872352||Aug 22, 2001||Mar 29, 2005||E. I. Du Pont De Nemours And Company||Process of making web or fiberfill from polytrimethylene terephthalate staple fibers|
|US7001664||Sep 27, 2004||Feb 21, 2006||Wellman, Inc.||Method and apparatus for high denier hollow spiral fiber|
|US7229688||Sep 13, 2005||Jun 12, 2007||Wellman, Inc.||Method and apparatus for high denier hollow spiral fiber|
|US7244444||Mar 30, 2005||Jul 17, 2007||Cook Incorporated||Graft material, stent graft and method|
|US7790639||Dec 23, 2005||Sep 7, 2010||Albany International Corp.||Blowable insulation clusters made of natural material|
|US7874624 *||Mar 29, 2007||Jan 25, 2011||Ts Tech Co., Ltd.||Cushion body, seat, and method of manufacturing the same|
|US7887576||Feb 15, 2011||Cook Incorporated||Endoluminal device with extracellular matrix material and methods|
|US8025495||Sep 27, 2011||Cook Medical Technologies Llc||Apparatus and method for making a spider occlusion device|
|US8211168||Jul 3, 2012||Cook Biotech Incorporated||Graft material, stent graft and method|
|US8291730||Oct 23, 2012||Certainteed Insulation Canada, Inc.||Spinner for manufacturing dual-component irregularly-shaped hollow insulation fiber|
|US8308752||Nov 13, 2012||Cook Medical Technologies Llc||Barrel occlusion device|
|US8480707||Jul 31, 2009||Jul 9, 2013||Cook Medical Technologies Llc||Closure device and method for occluding a bodily passageway|
|US8614154 *||Oct 5, 2004||Dec 24, 2013||3M Innovative Properties Company||Cellulose fibre based insulation material|
|US8617205||Jun 10, 2010||Dec 31, 2013||Cook Medical Technologies Llc||Closure device|
|US8734483||Aug 27, 2007||May 27, 2014||Cook Medical Technologies Llc||Spider PFO closure device|
|US9023074||May 1, 2012||May 5, 2015||Cook Medical Technologies Llc||Multi-stage occlusion devices|
|US9332977||Nov 8, 2013||May 10, 2016||Cook Medical Technologies Llc||Closure device|
|US20030071394 *||Jun 24, 2002||Apr 17, 2003||Hernandez Ismael A.||Process for preparing poly(trimethylene terephthalate) tetrachannel cross-section staple fiber|
|US20030118763 *||Feb 12, 2003||Jun 26, 2003||Travelute Frederick L.||Method and apparatus for high denier hollow spiral fiber|
|US20030153230 *||Feb 13, 2002||Aug 14, 2003||Hung-Jung Chen||Resilient laminated textile product|
|US20030232552 *||Jan 3, 2003||Dec 18, 2003||So Peter K.F.||Bonded polyester fiberfill battings with a sealed outer surface having improved stretch and recovery capability|
|US20040058608 *||Feb 9, 2001||Mar 25, 2004||Raphael Heifetz||Flexible reflective insulating structures|
|US20040170836 *||Dec 15, 2003||Sep 2, 2004||The Procter & Gamble Company||Hollow fiber fabrics|
|US20050037196 *||Sep 27, 2004||Feb 17, 2005||Travelute Frederick L.||Method and apparatus for high denier hollow spiral fiber|
|US20050118915 *||Dec 30, 2004||Jun 2, 2005||Raphael Heifetz||Flexible reflective insulating structures|
|US20050158518 *||Dec 16, 2004||Jul 21, 2005||Invista North America S.A R.L.||Vertically stacked carded web structure with superior insulation properties|
|US20050220848 *||Mar 30, 2005||Oct 6, 2005||Bates Brian L||Graft material, stent graft and method|
|US20060009835 *||Jul 7, 2005||Jan 12, 2006||Osborne Thomas A||Graft, stent graft and method|
|US20060014015 *||Sep 13, 2005||Jan 19, 2006||Travelute Frederick L||Method and apparatus for high denier hollow spiral fiber|
|US20070033737 *||Aug 9, 2005||Feb 15, 2007||Florence Melton||Self-adjusting head and neck pillow|
|US20070082021 *||Sep 28, 2006||Apr 12, 2007||Bates Brian L||Coated vaso-occlusion device|
|US20070148426 *||Dec 23, 2005||Jun 28, 2007||Davenport Francis L||Blowable insulation clusters made of natural material|
|US20070184732 *||Feb 7, 2006||Aug 9, 2007||Lunsford David J||High strength polyvinyl acetate binders|
|US20070209307 *||Oct 5, 2004||Sep 13, 2007||Carsten Andersen||Cellulose Fibre Based Insulation Material|
|US20070231519 *||Jun 11, 2007||Oct 4, 2007||Wellman, Inc.||Method and Apparatus for High Denier Hollow Spiral Fiber|
|US20070237973 *||Feb 20, 2007||Oct 11, 2007||Purdy James D||Graft material, stent graft and method|
|US20070293937 *||Jun 1, 2007||Dec 20, 2007||Med Institute, Inc.||Endoluminal medical device for local delivery of cathepsin inhibitors, method of making and treating|
|US20080178812 *||Jan 31, 2008||Jul 31, 2008||Topet Usa, Inc.||Pet bed and method for making same|
|US20090061136 *||Aug 27, 2007||Mar 5, 2009||Cook Incorporated||Apparatus and method for making a spider occlusion device|
|US20090062838 *||Aug 27, 2007||Mar 5, 2009||Cook Incorporated||Spider device with occlusive barrier|
|US20090062844 *||Aug 27, 2007||Mar 5, 2009||Cook Incorporated||Spider pfo closure device|
|US20090062845 *||Aug 27, 2007||Mar 5, 2009||Cook Incorporated||Barrel occlusion device|
|US20090089928 *||Oct 3, 2007||Apr 9, 2009||Alina Kasbohm||Pacification blanket|
|US20090108494 *||Mar 29, 2007||Apr 30, 2009||Mika Ito||Cushion body, seat, and method of manufacturing the same|
|US20090248144 *||May 19, 2009||Oct 1, 2009||Cook Biotech Incorporated||Endoluminal device with extracellular matrix material and methods|
|US20090320528 *||Oct 31, 2008||Dec 31, 2009||Joseph Skarzenski||Spinner for manufacturing dual-component irregularly-shaped hollow insulation fiber|
|US20100030246 *||Jul 31, 2009||Feb 4, 2010||Dusan Pavcnik||Closure Device and Method For Occluding a Bodily Passageway|
|US20100239839 *||Mar 5, 2008||Sep 23, 2010||Invista North America S.A.R.L||Continuous filament tow for fiber batts|
|US20110068498 *||Mar 24, 2011||Mika Ito||Method of manufacturing and forming a cushion body|
|DE2937280A1 *||Sep 14, 1979||Apr 2, 1981||Warnaco Inc||Thermal insulation for garments and sleeping bags - is formed from carded web of down and hollow polyester staple fibres|
|DE3034340C2 *||Feb 14, 1980||Jan 17, 1991||E.I. Du Pont De Nemours & Co., Wilmington, Del., Us||Title not available|
|DE4119441A1 *||Jun 13, 1991||Dec 17, 1992||Heimbach Gmbh Thomas Josef||Paper making blanket - is composed of hollow monofilaments with pressure sealed inner gas volumes to absorb or eliminate vibration at the web|
|EP0544167A1 *||Nov 14, 1992||Jun 2, 1993||Thomas Josef Heimbach GmbH & Co.||Papermaking fabric, in particular dryer felt|
|EP0677601A1 *||Apr 12, 1995||Oct 18, 1995||Ems-Inventa Ag||Polyester fibres with improved bulk and process for their production|
|EP0783607A1 *||Sep 28, 1995||Jul 16, 1997||E.I. Du Pont De Nemours And Company||Improvements in pillows and other filled articles and in their filling materials|
|EP2345376A1||Sep 28, 2006||Jul 20, 2011||Cook Incorporated||Coated vaso-occlusion device|
|WO1980001031A2 *||Feb 14, 1980||May 15, 1980||Du Pont||Polyester fiberfill blends|
|WO1980001031A3 *||Feb 14, 1980||Aug 21, 1980||Du Pont||Polyester fiberfill blends|
|WO1993011292A1 *||Nov 25, 1992||Jun 10, 1993||E.I. Du Pont De Nemours And Company||New fiberfill battings|
|WO1997013896A1 *||Oct 12, 1995||Apr 17, 1997||E.I. Du Pont De Nemours And Company||Improvements in and relating to hollow fiber identification|
|WO2002067731A1||Feb 22, 2002||Sep 6, 2002||E. I. Du Pont De Nemours And Company||Filled articles comprising blown fibers|
|WO2004063434A1 *||Dec 16, 2003||Jul 29, 2004||The Procter & Gamble Company||Hollow fiber fabrics|
|U.S. Classification||428/369, 5/952, 425/382.2, 428/398|
|International Classification||A47C27/22, D04H1/42, A47C27/12, B68G1/00, D01D5/24|
|Cooperative Classification||D04H1/42, B68G1/00, Y10S5/952, D01D5/24, A47C27/22, A47C27/12|
|European Classification||D04H1/42, A47C27/22, B68G1/00, D01D5/24, A47C27/12|