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Publication numberUS3779919 A
Publication typeGrant
Publication dateDec 18, 1973
Filing dateAug 21, 1972
Priority dateAug 21, 1972
Publication numberUS 3779919 A, US 3779919A, US-A-3779919, US3779919 A, US3779919A
InventorsJ Nebzydoski, F Oberender, E Patmore, D Reed
Original AssigneeTexaco Inc
Export CitationBiBTeX, EndNote, RefMan
External Links: USPTO, USPTO Assignment, Espacenet
Synthetic aircraft turbine oil
US 3779919 A
Abstract
Synthetic lubricating oil composition comprising a major portion of an aliphatic ester-base oil having lubricating properties formed from the reaction of a pentaerythritol or trimethylolpropane and an organic monocarboxylic acid containing an amine salt of a substituted rhodanine.
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Description  (OCR text may contain errors)

United States Patent Patmore et al.

[ Dec. 18, 1973 SYNTHETIC AIRCRAFT TURBINE OIL Inventors: Edwin L. Patmore, Fishkill; David D. Reed, Lagrangeville; Frederick G. Oberender, Wappingers Falls; John W. Nebzydoski, Fishkill, all of NY.

Assignee: Texaco Inc., New York, NY.

Filed: Aug. 21, 1972 Appl. No.: 282,181

US. Cl 252/33.6, 252/47.5, 252/402, 260/306.7

Int. Cl. C10m l/38, ClOm l/32 Field of Search 252/33.6, 565, 47.5, 252/402; 260/306.7

References Cited UNITED STATES PATENTS 6/1957 Kluge et al 252/47.5 6/1957 Watson et al 252/47.5

2,796,404 6/1957 Levin 252/47.5 2,800,491 7/1957 Ellis 252/47.5 X 3,249,543 5/1966 Wilson 252/47.5

FOREIGN PATENTS OR APPLICATIONS 1,180,387 2/1970 Great Britain OTHER PUBLICATIONS Cohen Ind. Eng. Chem." Vol. 45, (1953) pages 1766-1774.

Primary ExaminerDaniel E Wyman Assistant ExaminerW. Cannon Att0rneyThomas H. Whaley et a].

10 Claims, N0 Drawings SYNTHETIC AIRCRAFT TURBINE OIL BACKGROUND OF THE INVENTION This invention is concerned with a lubricating oil composition for gas turbine or jet engines. Gas turbine engines employed in aircraft are operated under extreme environmental conditions. The lubricating oil must be fluid under sub-zero temperatures and must be thermally stable, non-corrosive and possess loadcarrying and anti-wear properties at engine temperatures of 400 to 500F. or above. The environmental and operating conditions put such a severe stress on the lubricating oil for a turbine engine that the most advanced mineral lubricating oil compositions cannot be employed inrthese engines, It is conventional to employ synthetic ester-base lubricating oil compositions containing suitable augmenting additive combinations for lubricating turbine engines. The ester-base oils are operative over a wide temperature range and exhibit good thermal stability, anti-wear, and oxidation-resistant properties while providing effective lubrication.

Newer and more powerful gas turbine engines designed to provide advanced levels of supersonic flight are under development. These engines put increasing stresses on the lubricating oil composition and improved oil compositions must be provided to meet the load-carrying, anti-wear, oxidation resistance and corrosion resistance requirements at higher levels of oxidative and thermal stress.

DESCRIPTION OF THE PRIOR ART SUMMARY OF THE INVENTION The synthetic lubricating oil composition of the invention comprises a major portion of an aliphatic esterbase oil having lubricating properties formed from the reaction of a pentaerythritol or trimethylolpropane and a mixture of hydrocarbyl monocarboxylic acids containing an effective load-carrying amount of an amine salt of rhodanine represented by the formula:

HiNR

in which R is a hydrocarbyl radical having from about four to 24 carbon atoms and R and R" represent hydrogen or a hydrocarbyl radical having from about four to 24 carbon atoms. In general, the compounded fluid will also contain an alkylphenyl or alkarylphenyl naphthylamine, a dialkyldiphenylamine, a polyhydroxyanthraquinone and a hydrocarbyl phosphate defined below.

DESCRIPTION OF THE PREFERRED EMBODIMENTS The amine salt of rhodanine suitable for the synthetic lubricating oil composition is represented by the following formula:

Hom

where R represents a hydrocarbyl radical having from about four to 24 carbon atoms and R and R each represent hydrogen or a hydrocarbyl radical having from about four to 24 carbon atoms. The preferred compounds are those in which R is an alkyl or aliphatic radical having from about 12 to 22 carbon atoms and in which R and R represent hydrogen. The most preferred compounds are those in which R is an aliphatic radical having from about 18 to about 22 carbon atoms and R and R" represent hydrogen.

In general, the prescribed amine salt of rhodanine is prepared by dissolving equimolar portions of a hydrocarbyl amine with rhodanine or a substituted rhodanine in a hydrocarbon solvent and reacting the mixture at a moderately elevated temperature. Reaction temperatures ranging from about room temperature up to about 60C. are highly effective. The reaction is continued until neutralization has been effected. On completion of the reaction, the solvent is removed to recover the amine salt of rhodanine.

The following examples illustrate the preparation of amine salts of rhodanine which can be employed in the synthetic aircraft turbine oil compositions of this invention.

EXAMPLE I t-C -C Alkyl Primary Amine Salt of Rhodanine 15.7 Grams (0.05 mole) of t-C -C alkyl primary amine were slowly added, with stirring, to a solution of 6.65 grams (0.05 mole) of rhodanine in 50 ml. of benzene. The temperature rose from 21 to 33C. The solution was then heated at 50C. for about 0.5 hour. The benzene was removed using a rotary evaporator to give 21.6 grams of product. The t-C -C- alkyl primary amine salt of rhodanine had the following values:

Neutralization N0. 127, calculated 125 percent Nitrogen 6.2, calculated 6.2

EXAMPLE II t-C, -C Primary Alkyl Amine Salt of Rhodanine 19.1 Grams (0.10 mole) of t-C -C primary alkyl amine were added dropwise, with stirring, to a solution containing 13.3 grams (0.10 mole) of rhodanine in m1. of benzene. The reaction mixture was heated at 50C. for one hour and concentrated on a rotary evaporator to afford 32.0 grams of product as a viscous oil. The product analyzed as follows:

percent Nitrogen 8.8 found, 8.7 calculated EXAMPLE III t-Octylamine Salt of Rhodanine 12.9 Grams (0.10 mole) of t-octylamine were added dropwise to a stirred solution containing 13.3 grams (0.10 mole) rhodanine in 70 ml. of benzene. After heating at 50C. for one hour, the reaction mixture was concentrated under reduced pressure to yield a pale yellow solid. After slurrying with pentane, filtration and drying, 23.5 grams of product were obtained having a melting point of 138 to 142C. The analysis was as follows:

Neutralization N0. 207, calculated 198 percent Nitrogen 10.9 found, calculated 10.8

EXAMPLE IV Z-Ethylhexylamine Salt of Rhodanine 26.6 Grams (0.2 mole) of rhodanine and 25.8 grams (0.2 mole) of 2-ethylhexylamine were heated at 150C., with stirring, for 1 hour. The reaction mixture was diluted with 30 ml. of ethanol, filtered and concentrated under reduced pressure to yield the product as a yellow oil. The analysis was as follows:

Neutralization N0. 262 found, calculated 272 percent Nitrogen 10.5 found, 10.8 calculated EXAMPLE V t-Butylamine Salt of Rhodanine 6.3 Grams (0.1 mole) of t-butylamine were added dropwise to a stirred solution containing 13.3 grams (0.1 mole) of rhodanine in 70 ml. of benzene. The reactants were heated at 50C. for 1 hour, cooled and filtered to yield 17.0 grams of product having a melting point of 168 to 170C. The analysis was as follows:

Neutralization N0. 292 found, calculated 272 percent Nitrogen 12.4 found, 13.5 calculated percent Sulfur 32.7 found, 31.0 calculated Examples of other amine salts of rhodanine which can be employed in the synthetic aircraft turbine oil composition of this invention include the following:

dodecylamine salt of rhodanine cyclohexylamine salt of rhodanine n-pentylamine salt of rhodanine sec-butylamine salt of rhodanine n-heptylamine salt of rhodanine t-butylamine salt of 5,5-dibutyl rhodanine Z-ethylhexylamine salt of 5,5-dibutyl rhodanine t-C -C primary alkylamine salt of 5,5-dioctyl rhodanine The prescribed amine salt of rhodanine is employed in the lubricating oil composition in an amount ranging from about 0.01 to 5 weight percent. In general, amounts ranging from about 0.04 to 0.5 percent are effective and are preferred for imparting load-carrying and corrosion resistance properties to the lubricant composition.

The base fluid component of the lubricant of the invention is an ester-base fluid prepared from pentaerythritol or trimethylolpropane and a mixture of hydrocarbyl monocarboxylic acids. Polypentaerythritols, such as dipentaerythritol, tripentaerythritol and tetrapentaerythritol, can also be employed in the reaction to prepare the base oil.

The hydrocarbon monocarboxylic acids which are used to form the ester-base fluid include the straightchain and branched-chain aliphatic acids, cycloaliphatic acids and aromatic acids, as well as mixtures of these acids. The acids employed have from about two to 18 carbon atoms per molecule, and preferably from about five to carbon atoms. Examples of suitable specific acids are acetic, propionic, butyric, valeric, isovaleric, caproic, decanoic, hexadecanoic, vinylbenzoic, dodecylbenzoic, pela-rgonic, cyclohexanoic, naphthenic, benzoic acid, phenylacetic, tertiary-butylacetic acid and 2-ethylhexanoic acid.

1n general, the acids are reacted in proportions leading to a completely esterified pentaerythritol or trimethylolpropane with the preferred ester bases being the pentaerythritol tetraesters. Examples of such commercially available tetraesters include pentaerythritol tetracaproate, which is prepared from purified pentaerythritol and crude caproic acid containing other C monobasic acids. Another suitable tetraester is prepared from a technical grade pentaerythritol and a mixture of acids comprising about 50 percent valeric, 12 percent 2-methyl pentanoic, 27 percent caprylic, 15 percent pelargonic, 9 percent heptylic, 5 percent caproic and minor amounts of isovaleric and capric acids. Another effective ester is the triester of trimethylolpropane in which the trimethylolpropane is esterified with a monobasic acid mixture consisting of 2 percent valeric, 9 percent caproic, 13 percent heptanoic, 7 percent octanoic, 3 percent caprylic, 65 percent pelargonic and 1 percent capric acids. Trimethylolpropane triheptanoate, trimethylolpropane tripentanoate and trimethylolpropane trihexanoate are also suitable ester bases.

The ester base comprises the major portion of the formulated synthetic ester-base lubricating oil composition. In general, this ester-base fluid is present in a concentration ranging from about to 98 percent of the composition.

The effectiveness of the lubricating oil compositions of the invention is enhanced by the addition of other additives to the oil composition. Alkyl or alkaryl phenyl naphthylamines are highly effective anti-oxidants for synthetic lubricating oils. These compounds are represented by the formula:

in which R is an alkyl or alkaryl radical having from about four to 12 carbon atoms. This radical can be a straightor branched-chain alkyl radical with the tertiary alkyl structure being preferred, or it can be an alkylaryl radical. The naphthylamine can be either an alpha or beta naphthylamine. Specific effective compounds of this class include N-(p-t-octylphenyl)-anaphthylamine, N-(p-cumylphenyl)-6-cumyl-B- naphthylamine, N-(p-t-octylphenyl)-B-naphthylamine and the corresponding p-t-dodecylphenyl, p-tbutylphenyl, and p-dodecylphenyl-aand -B-naphthylamines. An effective concentration for this additive is an amount from about 0.5 to 2.5 weight percent.

Another effective anti-oxidant for the lubricating oil composition of the invention is a dialkyldiphenylamine represented by the formula:

R ta.

in which R is an alkyl radical having from about four to 12 carbon atoms. Examples of these amines include dioctyldiphenylamine, didecyldiphenylamine, didodecyldiphenylamine, dihexyldiphenylamine and similar compounds. Dioctyldiphenylamine is the preferred compound and the preferred concentration is from about 0.5 to 2.0 percent.

An effective metal deactivator for a synthetic lubricating oil composition is a polyhydroxyanthraquinone. Effective suitable compounds in this class are the dior polyhydroxyanthraquinones, such as 1,4-dihydroxyanthraquinone, also known as quinizarin, 1,5-dihydroxyanthraquinone and 1,8-dihydroxyanthraquinone, and the higher polyhydroxy-anthraquinones. The preferred concentration of this component is from about 0.01 to 0.5 weight percent.

A valuable anti-wear component for a synthetic lubricating oil composition is a hydrocarbylphosphate ester, represented by the formula (RO) PO, in which R is a hydrocarbyl radical having from 2 to 12 carbon atoms. The hydrocarbyl radical can be an alkyl, aryl, alkaryl, cycloalkyl or aralkyl radical of the prescribed carbon chain length, although radicals having from 4 to 8 carbon atoms are preferred. Effective compounds include tricresylphosphate, cresyl diphenylphosphate, triphenylphosphate, tributylphosphate, tri-( 2-ethy1hexy1)-phosphate and tricyclohexylphosphate. These compounds are generally employed in a lubricating oil composition in a concentration ranging from about 0.5 to 5 percent.

The lubricating oil composition of the invention was tested for its oxidation and corrosion resistance and its load-carrying properties in the tests described below. A variety of base fluids containing conventional lubricating oil additives were employed for conducting these tests.

Base Fluid A was a compounded base fluid consisting predominantly of a commercial ester base from pentaerythritol and a mixture of C to C fatty acids containing 0.10 weight percent quinizarin, 1.00 weight percent dioctyldiphenylamine, 1.50 weight percent N-(4- cumylphenyl)-6-cumyl-2-naphthylamine and 2.00 weight percent of tricresylphosphate.

Base Fluid B was a compounded base fluid consisting predominantly of a commercial ester base from pentaerythritol and a mixture of C to C fatty acids containing 0.10 weight percent quinizarin, 1.00 weight percent dioctyldiphenylamine, 1.50 weight percent N-(4-tert.- octylphenyl)-l-naphthylamine and 2.00 weight percent tricresylphosphate.

Base Fluid C was a compounded base fluid consisting of the commercial ester base from Base Fluid B and containing the additives employed in Base Fluid A.

The 425F./48-Hour Oxidation and Corrosion Test was conducted in accordance with Method 5308.4 of Federal Test Method and Standard No. 791a (issued December 31, 1969), except for modifications to conform to Pratt and Whitney 521B specifications. The bath temperature is maintained at 425F. ilF. instead of at 250F. and the testis conducted for a period of 48 hours instead of 168 hours as specified in the original test.

The results of the Oxidation-Corrosion Test are given in Table below wherein blends containing the additive of the invention are compared to similar blends containing the additive rhodanine.

TABLE I.425 FJis-HOUR OXIDATION-CORROSION TEST Metal weight change Blend identification ing/cm!) Compound- TAN 5 Wt. ed base Run Additive percent fluid blend Cu 11g 1 Rhodanine. 0.5 A 2.11 6. 14 +0.10 2 0.2 A 0. 92 2. 10 0 3 Example 1.... 0.1 A 0.15 0.00 0 Example 11... 0.075 A 0.17 0.64 a 5 Example 1II- 0.06 A 0.16 0.78 0 1O 6. Example V 0.04 A 0.16 0.34 0 7. Example IV 0.06 A 0.11 +0.11 0 Rhodanine 0.50 B 2.38 7. 48 +0.23 0.1 B 0.48 0.93 0.04 0.5 B 0. 64 -o.35 0 0.1 B 0.17 0.54 0.04 0.5 c 0.60 -1.29 0.03 0.3 C 0.37 -0. s1 0.1 C 0.15 0.27 0.02

The Ryder Gear Test was employed to demonstrate the load-carrying properties of lubricating oil compositions of the invention. This test was conducted in accordance with the ASTM Dl947 Method, with a slight modification. The results are given in Table 1] below.

TABLE 1] RYDER GEAR LOAD-CARRYING TEST Blend Identification Compoundcd Failure Run Additive Wt. '7! Base Fluid Load. ppi 1 Example 1 0.1 A 3560 2 Example 11 0.075 A 3130 3 Example 1]] 0.06 A 3410 4 Example v 0.04 A 3512 5 Example 1V 0.06 A 3230 6 Example] 0.5 B 3408 7 Example] 0.1 B 3180 8 Example] 0.5 C 3710 9 Example 0.3 c 3540 10 Example] 0.1 C 3230 11 Rhodaninc 0.1 B 2910 12 Rhodaninc 0.2 A 3180 13 None A 2740 14 None B 2689 15 None C 2775 The foregoing tests demonstrate that the novel synthetic ester-base lubricating oil compositions containing the prescribed amine salts of rhodanine of the invention possess outstanding corrosion-inhibiting and load-carrying properties under high thermal stress encountered in turbine engines.

We claim: 1. A synthetic lubricating oil composition comprising a major portion of an aliphatic ester-base oil having lubricating properties formed from the reaction of a pentaerythritol or trimethylolpropane and a saturated hydrocarbyl monocarboxylic acid having from about two to 18 carbon atoms per molecule containing from about 0.01 to 5 weight percent of an amine salt of rhodanine represented by the formula:

RC-S 6B HiNR R" I :s e

in which R is a hydrocarbyl radical having from about four to 24 carbon atoms and R and R" represent hydrogen or a hydrocarbyl radical having from about four to 24 carbon atoms.

2. A lubricating oil composition according to claim 1 in which R represents an aliphatic hydrocarbon radical having from about 12 to 22 carbon atoms and R and R are hydrogen.

3. A lubricating oil composition according to claim 1 containing from about 0.04 to 0.5 weight percent of said amine salt of rhodanine.

4. A lubricating oil composition according to claim 1 in which said amine salt is t-C -C alkyl primary amine salt of rhodanine.

5. A lubricating oil composition according to claim 1 in which said amine salt is t-C -C alkyl primary amine salt of rhodanine.

6. A lubricating oil composition according to claim 1 in which said amine salt is t-octylamine salt of rhodanine.

7. A lubricating oil composition according to claim 1 in which said amine salt is Z-ethylhexylamine salt of rhodanine.

8. A lubricating oil composition according to claim 1 in which said amine salt is t-butylamine salt of rhodanine.

9. A lubricating oil composition according to claim 1 containing from about 0.5 to 2.5 percent of an alkylphenyl naphthylamine, from about 0.5 to 2.0 percent ofa dialkyldiphenylamine, from about 0.01 to 0.5 percent of a polyhydroxyanthraquinone and from about 0.5 to 5 percent of a hydrocarbyl phosphate ester.

10. A lubricating oil composition according to claim 1 in which said ester-base oil is formed from the reaction of pentaerythritol and a mixture of C to C saturated fatty acids.

Patent Citations
Cited PatentFiling datePublication dateApplicantTitle
US2796402 *Nov 16, 1953Jun 18, 1957Texas CoExtreme pressure lubricant compositions
US2796403 *Nov 30, 1953Jun 18, 1957Texas CoExtreme pressure lubricant compositions
US2796404 *Nov 30, 1953Jun 18, 1957Texas CoExtreme pressure lubricant compositions
US2800491 *Dec 14, 1954Jul 23, 1957Stauffer Chemical CoOxidation-resistant oleaginous materials
US3249543 *Apr 30, 1963May 3, 1966Monsanto Res CorpLubricant composition containing a rhodanine compound
GB1180387A * Title not available
Non-Patent Citations
Reference
1 *Cohen Ind. Eng. Chem. Vol. 45, (1953) pages 1766 1774.
Referenced by
Citing PatentFiling datePublication dateApplicantTitle
US4157970 *Dec 27, 1977Jun 12, 1979Texaco Inc.Aliphatic ester, a phenyl naphthylamine, a phosphate ester, a polyhydroxy anthraquinone, and an alkyl mercapto acid ester
US4157971 *Dec 27, 1977Jun 12, 1979Texaco Inc.Aliphatic ester, phenyl naphthylamines, phosphate ester, polyhydroxy anthraquinone, alkyl thioacid ester
US4179386 *May 30, 1978Dec 18, 1979Texaco Inc.Synthetic aircraft turbine oil
US4188298 *May 30, 1978Feb 12, 1980Texaco Inc.Synthetic aircraft turbine oil
US4189388 *Dec 27, 1977Feb 19, 1980Texaco Inc.Aliphatic ester oil with phenylnaphthylamine, dialkyldiphenylamine, polyhydroxyanthraquinone, organic phosphate and n,n'-dialkylthio-dipropionamide additives
US4216100 *Aug 3, 1978Aug 5, 1980Texaco Inc.Pentaerythritol-fatty acid ester lubricant composition
US4320018 *Oct 19, 1979Mar 16, 1982Texaco Inc.Synthetic aircraft turbine oil
US4917809 *Nov 2, 1987Apr 17, 1990Ciba-Geigy CorporationOil-soluble 5-membered ring heterocyclic compound, which may be benzo-fused, and phosphorus compound
Classifications
U.S. Classification508/271, 548/183, 252/402
International ClassificationC07D277/36, C10M169/00
Cooperative ClassificationC10M2223/042, C10M3/00, C10M2223/041, C10M2215/064, C10M2207/282, C07D277/36, C10M2209/109, C10M2207/283, C10M2207/286, C10M2207/025, C10M2207/281, C10M2223/04
European ClassificationC10M3/00, C07D277/36