|Publication number||US3787162 A|
|Publication date||Jan 22, 1974|
|Filing date||Apr 13, 1972|
|Priority date||Apr 13, 1972|
|Publication number||US 3787162 A, US 3787162A, US-A-3787162, US3787162 A, US3787162A|
|Original Assignee||Ici Ltd|
|Export Citation||BiBTeX, EndNote, RefMan|
|Patent Citations (13), Referenced by (34), Classifications (9)|
|External Links: USPTO, USPTO Assignment, Espacenet|
United States Patent 1191 Cheetham Jan. 22, 1974 CONJUGATE FILAMENTS APPARATUS  Inventor: John Laurence Cheetham,
Harrogate, England  Assignee: Imperial Chemical Industries Limited, London, England  Filed: Apr. 13, 1972  App]. No.: 243,878
3,559,237 2/1971 Biggelaar et a1. 425/198 3,613,170 10/1971 Soda et a1. 425/463 3,204,290 9/1965 Crompton 425/463 3,418,200 12/1968 Tanner 161/177 3,700,545 10/1972 Matsui et al. 161/175 FOREIGN PATENTS OR APPLICATIONS 43/11821 5/1968 Japan 264/171 44/22523 9/1969 Japan 425/463 Primary Examiner-Jay H. Woo Attorney, Agent, or FirmThomas J. Morgan et a1.
 ABSTRACT Process and apparatus for sheath/core conjugate fila- 156] References Cited ments in which a jet of a first fiber-forming polymer is UNITED STATES PATENTS forced into confined space, second fibre-forming poly- 2,815,532 12/1957 Braunlich 425/463 mer is forced around first P y from one Side and 3,017,686 H1962 Breen et a1. 264/171 p lymers a trud d t f rm filaments. Preferably 3,075,241 H1963 Dietzsch et a1. 425/463 the ducts for first and second polymers are formed in 3,439,382 4/1969 Sluijters 425/463 part by appropriate apertures in metal shims. 3,500,498 3/1970 Fukuma et a1.... 425/133 3,540,080 11/1970 Goossens 425/133 1 Claim, 9 Drawing Figures 8, 1.1 W 8 I 1 l I 10 5 5 10 73 74 9 5 5 9 PATENTEDJAN 22 I974 3 787 l 62 sum 1 nr 4 WWW m4 smart a or 4 b, .XM
W 5 m/ O CONJUGATE FILAMENTS APPARATUS The present invention relates to the manufacture of sheath/core conjugate filaments.
According to the present invention we provide a process for the manufacture of a sheath/core conjugate filament wherein a jet of a first fiber-forming polymer is forced into a confined space communicating with a spinning orifice, a second fiber-forming polymer is forced into said confined space from one side of said jet of said first fiber-forming polymer and said first and second polymers are allowed to flow in sheath/core relationship through said spinning orifice with formation of a sheath/core filament.
Preferably said confined space is elongated, with the entry points for the first and second polymers at one end and the communication with said spinning orifice at the other end. Conveniently said confined space is essentially cylindrical with length greater than its diameter.
Preferably the second fiber-forming polymer is forced into said confined space in the form of a thin sheet of flow, the width of the sheet being greater than the width of the confined space at the level of entry of the second fiber-forming polymer. Preferably the confined space is elongated in the direction at right angles to the plane of the thin sheet of flow of the second polymer.
Although the second fiber-forming polymer is forced into the confined space from one side, it should be free to surround the jet of the first fiber-forming polymer at an early stage in its transit through the confined space. This may be facilitated by the provision of a widening of the confined space at the point of entry of the second polymer. Such widening should preferably be at the upstream end of the confined space.
According to our invention we also provide an apparatus suitable for carrying out the process of our invention, comprising a confined space with exit to a spinneret aperture at one end, a first entry aperture substantiably at the end distant from the exit, and a second entry aperture to one side of the first entry aperture.
Preferably the confined space is elongated in the direction from entry aperture to spinneret aperture. Conveniently the confined space if essentially cylindrical with length greater than its diameter. Preferably the second entry aperture is in communication with the confined space by way of a radially enlarged portion of the confined space near the end of the confined space preferably where the first entry aperture is situated.
A plurality of confined spaces with apurtenances according to our invention may be combined in a single apparatus and this may be used to produce simultaneously a plurality of conjugate filaments.
The apparatus according to our invention may advantageously comprise a spinneret plate having a plurality of spinning orifices each with its own confined space, separated from an orifice plate bearing an orifice for each spinning orifice, by a first metal shim and the orifice plate being separated from a pack body by a second metal shim, said spinneret plate being urged towards said pack body so as to compress said shims and the orifice plate into good contact with each other and with said spinneret plate and said pack body, said shims and said orifice plate having appropriate apertures cut through their thickness in order to form when assembled the desired distributive ducts for each of the polymeric constituents of the conjugate filaments from a common source for each of the polymeric constituents to each of the confined spaces. The distributive ducts may be formed in the faces of the spinneret plate or in the face of the pack body or partly in each, and may be fed by feed passages entering the pack body from the side distance from the spinneret plate.
A specific embodiment of our invention will now be described with particular reference to FIGS. 1, 2, 3, 4, 5, 6, 7 and 8 wherein FIG. I shows a vertical section of a multiple spinneret,
FIG. 2 shows a plan of a distributor, shown at (8) in FIG. 1,
FIG. 3 shows a plan of a spinneret, shown as (l) in FIG. 1,
FIG. 4 shows a section of FIG. 3 through A A,
FIG. 5 shows a section of FIG. 3 through B B,
FIG. 6 shows a plan of a shim, shown as (12) in FIG.
FIG. 7 shows a plan of a shim, shown as (13) in FIG.
FIG. 8 shows a plan of an orifice plate, shown as (14) in FIG. 1,
FIG. 9 shows a detail of FIG. 1, not strictly to scale, showing direction of flow, and including the widening of the confined space at the point of entry of the second polymer, referred to hereinbefore.
Referring to FIG. 1, a spinneret plate 1 has spinneret apertures 2, communicating by way of a lead-in cone 3 with a confined space 4. A first entry aperture 5 communicates with the confined space 4 and, by way of a connecting passageway 6, with a central molten polymer feed duct 7, formed in a distributor 8 and fed by a feed pipe 18 of 0.125 inches diameter, to which the spinneret plate 1 is urged when the apparatus is assembled. A second feed aperture 9, situated to one side of the first aperture 5, communicates with the confined space 4 and, by way of a connecting passageway 10, with one of two outer molten polymer feed ducts 11, formed partly from the spinneret plate 1 and partly from the distributor 8. The connecting passageways 6 and 10 serve as metering passageways for the molten polymers.
In a particular embodiment of the apparatus according to FIG. I, the first and second entry apertures are formed by an orifice plate 14, of length 3.122 inches, width 1.62 inches and thickness 0.020 inches, of stainless steel, and shims 12 and 13 of aluminium, and each of thickness 0.005 inches. The apparatus is assembled as shown in FIG. 1 and the spinneret plate 1 urged (by means not shown) towards the pack body (not shown), which lies above the distributor 8 and in face contact with it, with formation of a liquid tight joint between the contacting faces of spinneret plate 1 and shim 13, between shim l3 and orifice plate 14, between orifice plate 14 and shim 12, between shim 12 and the distributor 8 and between the distributor 8 and the pack body (not shown).
In the orifice plate 14 (and also FIG. 8) the distance x between rows of orifices is 0.437 inches. The orifices 5 are each of 0.009 inches diameter. The alignment holes 16 are each of 0.125 inches diameter and with centres 2.25 inches apart. The molten polymer feed holes 17 are each of diameter 0.125 inches and with centres 0.808 inches apart.
In FIG. 1, taken together with FIG. 8, the first entry aperture 5 is shown as circular and centrally disposed with respect to the cross-section of the confined space 4. The first entry aperture 5 may, however, be of noncircular cross-section and may further be eccentrically disposed with respect to the cross-section of the confined space 4. By such variation of the disposition of the first entry aperture 5 in relation to the centre line of the confined space 4, the cross-section of the core of the filament produced by the apparatus and the relative disposition of the cross-section of the core with relation to the cross-section of the filament produced can be varied.
The apparatus depicted in FIG. 1, taken together with HO. 8 in general leads to the production of very eccentric sheath/core filaments.
Our invention is particularly applicable to the manufacture of sheath/core conjugate filaments of which each of the components is a polyester, a polyamide or a polyolefine.
The apparatus according to the particular embodiment was used for the melt-spinning of sheath/core filaments of poly(ethylene terephthalate), the central polymer feed duct 7 being fed with molten poly(ethylene terephthalate) of intrinsic viscosity 0.47 as measured on a l g. per lOO ml solution in orthochlorophenol at 25C and the second feed aperture 9 being fed with poly(ethylene terephthalate) of intrinsic viscosity 0.67. The resultant molten threadlines showed no significant tendency towards kneeing. The filaments were very eccentric sheath/core filaments which after drawing and heat relaxing showed marked crimp formation.
I. An apparatus for spinning a plurality of eccentric sheath/core conjugate filaments comprising a spinneret plate having a plurality of spinning orifices each with its own confined space, separated from an orifice plate bearing an orifice for each spinning orifice, by a first metal shim, and the orifice plate is separated from a pack body by a second metal shim, said spinneret plate being urged towards said pack body so as to compress said shims and the orifice plate into good contact with each other and with said spinneret plate and said pack body, said shims and said orifice plate having appropriate apertures cut through their thickness in order to form when assembled the desired distributive ducts for each of the polymeric constituents to each of the confined spaces.
|Cited Patent||Filing date||Publication date||Applicant||Title|
|US2815532 *||May 25, 1953||Dec 10, 1957||American Viscose Corp||Spinneret mixing element|
|US3017686 *||Aug 1, 1957||Jan 23, 1962||Du Pont||Two component convoluted filaments|
|US3075241 *||Mar 8, 1956||Jan 29, 1963||Schiesser Ag Trikotfabriken||Multiple hole spinning nozzle and process of manufacture|
|US3204290 *||Dec 27, 1962||Sep 7, 1965||Monsanto Co||Laminated spinneret|
|US3418200 *||Nov 27, 1964||Dec 24, 1968||Du Pont||Splittable composite filament|
|US3439382 *||Dec 23, 1966||Apr 22, 1969||American Enka Corp||Spinneret assembly for spinning highly viscous polymeric substances|
|US3500498 *||May 26, 1967||Mar 17, 1970||Asahi Chemical Ind||Apparatus for the manufacture of conjugated sheath-core type composite fibers|
|US3540080 *||Sep 21, 1967||Nov 17, 1970||Inventa Ag||Device for the spinning of multicomponent synthetic fibers|
|US3559237 *||Nov 22, 1967||Feb 2, 1971||American Enka Corp||Apparatus for producing synthetic yarns formed of bicomponent filaments|
|US3613170 *||Apr 28, 1970||Oct 19, 1971||American Cyanamid Co||Spinning apparatus for sheath-core bicomponent fibers|
|US3700545 *||Nov 12, 1969||Oct 24, 1972||Kanegafuchi Spinning Co Ltd||Novel synthetic multi-segmented fibers|
|JP43011821A *||Title not available|
|JP44022523A *||Title not available|
|Citing Patent||Filing date||Publication date||Applicant||Title|
|US4052146 *||Nov 26, 1976||Oct 4, 1977||Monsanto Company||Extrusion pack for sheath-core filaments|
|US4251200 *||Nov 23, 1979||Feb 17, 1981||Imperial Chemical Industries Limited||Apparatus for spinning bicomponent filaments|
|US5162074 *||Aug 7, 1989||Nov 10, 1992||Basf Corporation||Method of making plural component fibers|
|US5227109 *||Jan 8, 1992||Jul 13, 1993||Wellman, Inc.||Method for producing multicomponent polymer fibers|
|US5256050 *||Jun 5, 1992||Oct 26, 1993||Hoechst Celanese Corporation||Method and apparatus for spinning bicomponent filaments and products produced therefrom|
|US5344297 *||Jun 4, 1992||Sep 6, 1994||Basf Corporation||Apparatus for making profiled multi-component yarns|
|US5424115 *||Feb 25, 1994||Jun 13, 1995||Kimberly-Clark Corporation||Point bonded nonwoven fabrics|
|US5466410 *||May 11, 1994||Nov 14, 1995||Basf Corporation||Process of making multiple mono-component fiber|
|US5533883 *||Oct 18, 1993||Jul 9, 1996||Basf Corporation||Spin pack for spinning synthetic polymeric fibers|
|US5534339 *||Jan 27, 1995||Jul 9, 1996||Kimberly-Clark Corporation||Polyolefin-polyamide conjugate fiber web|
|US5551588 *||Jun 6, 1995||Sep 3, 1996||Basf Corporation||Profiled multi-component fiber flow plate method|
|US5562930 *||Jun 6, 1995||Oct 8, 1996||Hills; William H.||Distribution plate for spin pack assembly|
|US5575063 *||May 23, 1995||Nov 19, 1996||Basf Corporation||Melt-spinning synthetic polymeric fibers|
|US5578330 *||Mar 23, 1995||Nov 26, 1996||Conoco Inc.||Pitch carbon fiber spinning apparatus|
|US5605739 *||Dec 21, 1995||Feb 25, 1997||Kimberly-Clark Corporation||Nonwoven laminates with improved peel strength|
|US5620644 *||May 23, 1995||Apr 15, 1997||Basf Corporation||Melt-spinning synthetic polymeric fibers|
|US5750063 *||Jun 10, 1997||May 12, 1998||Basf Corporation||Plate-type sheath/core-switching device and method of use|
|US5989004 *||Oct 22, 1997||Nov 23, 1999||Kimberly-Clark Worldwide, Inc.||Fiber spin pack|
|US6361736||Aug 20, 1998||Mar 26, 2002||Fiber Innovation Technology||Synthetic fiber forming apparatus for spinning synthetic fibers|
|US6461133||May 18, 2000||Oct 8, 2002||Kimberly-Clark Worldwide, Inc.||Breaker plate assembly for producing bicomponent fibers in a meltblown apparatus|
|US6474967||May 18, 2000||Nov 5, 2002||Kimberly-Clark Worldwide, Inc.||Breaker plate assembly for producing bicomponent fibers in a meltblown apparatus|
|US6548166||Sep 28, 2001||Apr 15, 2003||E. I. Du Pont De Nemours And Company||Stretchable fibers of polymers, spinnerets useful to form the fibers, and articles produced therefrom|
|US6783853||Sep 27, 2002||Aug 31, 2004||Invista North America S.A.R.L.||Hetero-composite yarn, fabrics thereof and methods of making|
|US7919419||Nov 5, 2008||Apr 5, 2011||Buckeye Technologies Inc.||High strength and high elongation wipe|
|US8501647||Feb 4, 2011||Aug 6, 2013||Buckeye Technologies Inc.||High strength and high elongation wipes|
|US20050008855 *||Jul 26, 2004||Jan 13, 2005||Invista Sarl||Hetero-composite yarn, fabrics thereof and methods of making|
|US20080095875 *||Oct 10, 2006||Apr 24, 2008||Serge Rebouillat||Spinnerets for making cut-resistant yarns|
|US20090092809 *||Nov 5, 2008||Apr 9, 2009||Buckeye Technologies Inc.||High Strength And High Elongation Wipe|
|US20110159265 *||Feb 4, 2011||Jun 30, 2011||Buckeye Technologies Inc||High Strength and High Elongation Wipes|
|EP2463425A1||Dec 8, 2011||Jun 13, 2012||Buckeye Technologies Inc.||Dispersible nonwoven wipe material|
|EP3199682A1||Dec 8, 2011||Aug 2, 2017||Georgia-Pacific Nonwovens LLC||Dispersible nonwoven wipe material|
|WO2012078860A1||Dec 8, 2011||Jun 14, 2012||Buckeye Technologies Inc.||Dispersible nonwoven wipe material|
|WO2015073917A1||Nov 14, 2014||May 21, 2015||Buckeye Technologies Inc.||Dispersible nonwoven wipe material|
|WO2017123734A1||Jan 12, 2017||Jul 20, 2017||Georgia-Pacific Consumer Products Lp||Nonwoven cleaning substrate|
|U.S. Classification||425/463, 264/172.18, 425/133.1, 264/172.15, 425/131.5, 264/172.17|