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Publication numberUS3790484 A
Publication typeGrant
Publication dateFeb 5, 1974
Filing dateJan 18, 1972
Priority dateJan 18, 1972
Publication numberUS 3790484 A, US 3790484A, US-A-3790484, US3790484 A, US3790484A
InventorsR Blair
Original AssigneeBlalock E
Export CitationBiBTeX, EndNote, RefMan
External Links: USPTO, USPTO Assignment, Espacenet
Fragrance-imparting laundering composition
US 3790484 A
Abstract  available in
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Claims  available in
Description  (OCR text may contain errors)

3,790,484 FRAGRANCE-IMPARTING LAUNDERING COMPOSITION Rhio H. Blair, Santa Ana, Calif., assignor to Edwin O. Blalock, Los Angeles, Calif.

N Drawing. Filed Jan. 18, 1972, Ser. No. 218,827

Int. Cl. Clld 3/50 U.S. Cl. 252-89 2 Claims ABSTRACT OF THE DISCLOSURE BACKGROUND 'OF THE INVENTION According to U.S. Pat. 3,271,305 various silicone compounds capable of being hydrolyzed to fragrant essential alcohols are impregnated in textiles to provide a persistent essence therein. Those skilled in the art will recognize that the technique described in this patent is subject to several serious limitations. First, the procedure requires the use of relatively expensive silicone compounds. Secondly, the fragrances available to practice are limited to those which can be produced from a hydrolyzable silicone compound. Thus, many preferred fragrances are not available in this way. Still further, the release of the fragrance is dependent upon the amount of moisture in contact with the treated textile, and washing or laundering releases comparatively large amounts of the essential alcohol so that the source of the essential alcohol is quickly depleted. Finally, because of the tendency of the silicone compounds to hydrolyze, they cannot be incorporated in home laundering procedures to restore the fragrance once the initial treatment has been exhausted. Normally, the silicone compounds can be incorporated in the textile only under carefully controlled conditions which exist only in a textile treatment mill.

Accordingly, the present invention is directed to a composition for imparting fragrances to textiles which is uniquely adapted for administration in the home in the normal laundering operations.

BRIEF SUMMARY OF THE INVENTION According to this invention, there are provided aqueous compositions suitable for use in home laundering operations to impart lasting fragrance to articles comprised of cellulosic fabrics, e.g., cotton, linen, cottonpolyester blends, viscose rayon, etc. The compositions are principally comprised of a cationic agent such as a fatty quaternary ammonium halide, an amine sufficient in quantity to neutralize the composition to pH in the range from about 5 to 8, preferably 6 to 7, a minor proportion of fragrant oil, a non-ionic detergent suflicient in quantity to solubilize the fragrant oil in the composition and water, essentially all of which is deionized. Placed in a conventional home washing machine during or at the inception of the final rinse cycle, from about 1 to 2 ounces of the composition of the invention sufllciently endures normal automatic drying temperatures (e.g., up to about 180 F.) as to impart to laundered articles residual fragrances lasting up to a week or more after laundering.

United States Patent 0 "ice 3,790,484 Patented Feb. 5, 1974 DESCRIPTION OF THE PREFERRED EMBODIMENTS A preferred cationic agent for inclusion in the present composition is a dialkyldi(hydrogenated tallow) ammo nium halide such as the dimethyldi(hydrogenated tallow) ammonium chloride available from Armour Chemical Corporation under the name Arquad 2HT-75. The quaternary ammonium halides exhibit an innate aflinity for cellulosic fabrics and are believed to so condition the surface of the fabric as to transiently bind the fragrant oils thereto.

Preferably, from about 8 to about 12 parts by weight dialkyldi(hydrogenated tallow) ammonium chloride active) is employed for from about 2 to about 4 parts by weight fragrant oil in parts deionized water. Increased proportions of the fragrant oil, of course, call for additional increments of the cationic agent if fragrance retention through the drying cycle is to be maximized. In any case, the foregoing relative proportions have been found to serve admirably in imparting a useful, albeit not overpowering, degree of fragrance to laundered fabric when the preferred oils are empolyed, i.e. Alpine Aromatics, Inc. (of Metuchen, NJ.) Jasmine 24-711, Orange Blossom 44-931, LE. Type 42-431, Baby Powder 5606 and Ginger Spice 62-701. I also employed in the fragrance-imparting composition an organic amine base, preferably a tertiary amine base such as polyoxyethylene cocoamine available from Armour Chemical Corporation under the name Ethomeen C-25. The base is used in proportion suflicient to provide pH between about 5 and 8, preferably from about pH 6 to about pH 7. In the case of the composition proportioned above, about 2.5 parts by weight polyoxyethylene cocoamine is preferably employed. Finally, the composition desirably contains a substantial proportion of non-ionic detergent, e.g., alkylphenoxy polyethoxyethanol (Rohm & Haas Triton X-100), sufficient in amount as to solubilize the fragrant oil in the composition. Where the foregoing fragrances are employed in the proportions referred to above, about 25 to about 50 parts by weight non-ionic detergent may be employed, about 25 parts being the preferred proportion. Of course, coloring agents and non-ionic or anionic conventional laundry addends may optionally be added to the composition.

I claim:

1. As a fragrance-imparting composition, an aqueous liquid having as its water component essentially only deionized water, said liquid comprising from about 8 to 12 parts of a dimethyl di(hydrogenated tallow) quaternary ammonium chloride, from about 2 to 4 parts fragrant oil, polyoxyethylene cocoamine suflicient in proportion to provide said composition with pH in the range from about 5 to about 8, and at least an effective fragrant oil-solubilizing amount of an octyl phenoxypolyethoxyethanol, said parts being by weight based upon 100 parts by weight deionized water.

2. A liquid according to claim 1 having about 25 parts by weight of said non-ionic detergent, based upon 100 parts by weight deionized water.

References Cited McCutcheon: Detergents and Emulsifiers, 1970 edition, Allured Publ. Corp., p. 243.

WILLIAM E. SCHULZ, Primary Examiner U.S. Cl. X.R. 2528.6, 522

Referenced by
Citing PatentFiling datePublication dateApplicantTitle
US4134838 *Feb 15, 1978Jan 16, 1979Lever Brothers CompanySuppressing body odor
US4326967 *Jun 24, 1980Apr 27, 1982Lever Brothers CompanyLiquid formulations for depositing perfumes on fabrics
US4636330 *Jan 25, 1985Jan 13, 1987Lever Brothers CompanyPerfume depositing detergents containing perfume in a particulate matrix of a cationic compound
US5731282 *Nov 30, 1995Mar 24, 1998Jean-Pierre DuquesneNonionic detergent and cationic preservative
US6022845 *Oct 25, 1996Feb 8, 2000The Procter & Gamble Co.Comprising a liquid cationic fabric softener, hydrophobic perfume, a nonionic surfactant, a water-soluble ionizable inorganic salt and water; discrete hydrophobic perfume particles surrounded by softener and surfactants; uniformity
DE3911363A1 *Apr 7, 1989Oct 11, 1990Freytag Von Loringhoven AndreaVerfahren zum herstellen von mit duftstoff anzureichernder wasch- oder spuellauge und dazu dienendes duftstoffzugabemittel
DE3911363B4 *Apr 7, 1989Feb 3, 2005Freytag Von Loringhoven, AndreasVerfahren zur Herstellung von mit Duftstoffen anzureichernder Wasch- oder Spüllauge und Duftstoffzugabemittel zur Durchführung des Verfahrens
EP0011499A1 *Nov 16, 1979May 28, 1980Unilever PlcLiquid formulations for depositing perfumes on fabric surfaces
EP0034048A2 *Feb 5, 1981Aug 19, 1981Unilever PlcA method of cleaning and depositing perfume on a surface and compositions therefor
EP0041328A1 *May 14, 1981Dec 9, 1981Unilever PlcMethod of depositing perfume on fabrics and product for use therein
EP0391087A1 *Mar 8, 1990Oct 10, 1990Freytag von Loringhoven, AndreasMethod and means for adding scent to washing or rinsing solution
WO1980001075A1 *Nov 16, 1979May 29, 1980J MelvilleLiquid formulations
WO1997016516A1 *Oct 25, 1996May 9, 1997Avila Garcia Maria CristinaStable high perfume, low active fabric softener compositions
WO1997031086A1 *Feb 19, 1997Aug 28, 1997Procter & GambleFabric softener composition with improved environmental impact
WO2002004587A1 *Jul 5, 2001Jan 17, 2002Givaudan SaProcess for imparting conditioning and good fragrance perception to both damp and dry fabric
Classifications
U.S. Classification510/513, 510/101
International ClassificationD07B1/06, D06M23/00, C11D3/50, C11B9/00, D07B1/00
Cooperative ClassificationC11D3/50
European ClassificationC11D3/50
Legal Events
DateCodeEventDescription
Feb 23, 1983AS06Security interest
Owner name: BLALOCK, EDWIN O.
Effective date: 19810406
Owner name: BUILDER INVESTMENT PARTNERSHIP, A GENE
Owner name: GUINNESS FINANCIAL, INC., A CORP. OF GA.
Feb 23, 1983ASAssignment
Owner name: BUILDER INVESTMENT PARTNERSHIP, A GENERAL PARTNERS
Free format text: SECURITY INTEREST;ASSIGNOR:BLALOCK, EDWIN O.;REEL/FRAME:004097/0671
Effective date: 19810406
Owner name: GUINNESS FINANCIAL, INC., A CORP. OF GA.