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Publication numberUS3811437 A
Publication typeGrant
Publication dateMay 21, 1974
Filing dateOct 26, 1971
Priority dateOct 26, 1971
Also published asCA969481A1, CA1022470B, DE2251774A1, DE2251774B2, DE2251774C3, USRE29487
Publication numberUS 3811437 A, US 3811437A, US-A-3811437, US3811437 A, US3811437A
InventorsR Gardner
Original AssigneeCabot Corp
Export CitationBiBTeX, EndNote, RefMan
External Links: USPTO, USPTO Assignment, Espacenet
Earplugs
US 3811437 A
Abstract
There are disclosed earplugs composed of certain polymeric foam materials. The earplugs are of generally cylindrical shape and of somewhat larger diameter than the human ear canal. The earplugs are composed of a foamed plasticised polymeric material having a sufficiently high concentration of plasticizer to provide the earplug with a reduced rate of recovery from compression.
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Description  (OCR text may contain errors)

The present invention .relates generally to earplug constructions and more particularly to earplug constructions adapted for insertion into the ear canal.

Many devices are known which are adapted for insertion into the human ear canal in order to suppress or attenuate the transmission of dangerous noise and thus confer a measure of protection to the anatomical hearing apparatus. Such devices have taken many forms. For instance, perhaps the simplest earplug is formed of wadded cotton. While blessed with the benefit of simplicity, such earplugs are not normally greatly effective as acoustic barriers. In another embodiment of this simple earplug, a fibrous material, such as cotton wadding,

known which take the form of molded elastomeric structures, natural rubber being a common material of construction. Included within this class are earplugs having molded therein-check valves and other substructures designed to allow normal voice tones to be transmitted therethrough while cancelling or preventing transmission of injurious overpressures. Such molded elastomer earplugs suffer from the fact that their size and shape is preordained and fixed in the molding thereof. Thus, they must initially be carefully fittedto the wearer in order to provide security, comfort and effective sound attenuation properties. Unfortunately, the size and shape of the human ear canal is quite variable amongst persons; indeed, bilateral symmetry in a single individual is often lacking. Accordingly, it is not possible to manufacturemolded elastomeric earplugs of a universally useful size and shape.

In recent years there have come into extensive usage lightweightearphones or headphones comprising generally a miniature speaker having tubular member(s) extending therefrom the tips of which members are adapted for insertion in the external auditory meatus. Said tips are generally comprised of a foamed or unfoamed polymeric material such as neoprene or sponge rubber. In the case of the unfoamed polymeric tip .members major deficiencies usually reside in the facts that the tip members (1) tend to slip out of the ear canal, and (2) the relatively non-compliant character of the polymeric material does not lend itself to complete obturation of the ear canal. Thus, bothersome external ambient noise can often by-pass such unfoamed tip members. In the case of sponge rubber tip members the resiliency of the sponge materials is generally excessively rapid and mitigates against actual insertion of the tip member into the ear canal proper. Such tip members are usually worn, therefore, in a manner such as to urge the respective members inwardly against the external auditory meatus. This is often found uncomfortable and, in any case, is not ordinarily efficient in blocking the ear canal.

In accordance with the present invention, however, there are provided earplug structures which substantially ameliorate or overcome the aforedescribed problems.

careers or THE INVENTION- It is a principal object of the invention to provide novel earplug.

It is another object of the invention to provide earplugs adapted for insertion into the ear canals with substantially complete obturation thereof.

It is another object of the invention to provide earplugs having excellent sound barrier properties.

It is another object of the invention to provide earplugs adapted for insertion into the ear canals wherein GENERAL DESCRIPTION OF THE INVENTION In accordance with the present inventionthere are provided earplugs of generally cylindrical shape and of somewhat larger diameter thanfthat of the human ear canal. Said earplugs are composed of a foamed polymeric material having a rate of recoveryfrom 60 percent compression to 40 percent'compression thereof of from 1 to 60 seconds and an equilibrium pressure at 40 percent compression thereof of from 0.2 to 1.3 p.s.i.

THE DRAWINGS FIG. 1 is a perspective view of one embodiment of an earplug of the invention.

FIG. 2 is a perspective, partially sectioned view of an earpiece portion of an earphone bearing a modified foamed polymeric earplug of the invention as the external ear insertable tip member.

DETAILED DESCRIPTION OF THE INVENTION Referring to FIG. 1 it will be seen that the earplug of the invention is of generally cylindrical shape and has a diameter somewhat greater than that-of the average adult human ear canal. For instance, a diameter of between about inch and about 56 inch is generally acceptable. Optirn'ally, the diameter of the earplug will be between 9/16 inch and 11/ 16 inch. Further, it should be noted and understood that the term cylindrical as employed herein includes'within its scope structures having a relatively shallow truncated cone shape or a substantially spherical shape. Where the earplug takes the form of a truncated cone, the above diameter criteria may be employed taken at the midpoint of the cone. Where the earplug is spherical, the above criteria may be applied to the diameter of said'sphere.

The length of the earplug can generally be between about /fi inch to about 1 inch. At lengths substantially greater than about 1 inch, for instance, sufficient material can overhang the external ear so as to be bothersome to the wearer. Desirably, the length of the earplug will be between 7/ 16 and about inch.

Any flexible polymeric material which can be foamed so as to result in an ultimately formed earplug structure meeting the recovery rate and pressure criteria set forth hereinabove constitutes a satisfactory material of construction in the earplugs of the invention. Accordingly, polymers of ethylene, propylene, vinyl chloride,

vinyl acetate, diisocyanate, cellulose acetate or isobuarias-shamanism.

dichlorostxrene,

tylene can all be generally employed. in particular,

however, I much favor vinyl chloride homopolymers and copolymers comprising at least- 85 percent by weight of vinyl chloride and up to percent by weight of other monomers such as vinylidene chloride, vinyl esters of carboxylic acids, e.g., vinyl acetate, vinyl propionate, vinyl butyrate and vinyl benzoate. esters of unsaturated acids, e.g., alkyl acrylates such as methyl acryiate, ethyl acrylate, propyl acrylate, butyl acrylate, allyl acrylate, and the corresponding esters of methacrylic acid; vinyl aromatic compounds, e.g., styrene,

a -aara:sh!q 9trtsssaa 2,4-dichlorostyrene, paraethylstyrene, vinyl naphthalene and a-methyl tyrene, dienes such as butadiene and chl'orobutadiene, unsaturated amides such as acrylic'acid amide and acrylic acid anilide; unsaturated nitriles such 'as acrylic acid nitrile; and esters of a, B-unsaturated carboxylic acids, e.g., the methyl, ethyl, propyl, butyl, amyl, hexyl, heptyl, octyl, allyl, methallyl, and phenyl esters of maleic, crotonic and fumaric acids and the like. Such vinyl chloride based polymers, and particularly the vinyl chloride homopolymers, can normally be compounded into plastisol form with a blowing agent and a high concentration of a suitable organic plasticizer so asto result in stabilized foams having the rate of recovery and pressure characteristics necessary in the compositions from 'which the earplugs of the invention-are fabricated.

With respect to said characteristics, it is clear that the relatively slow recovery rate in returning from 60 percent compression to 40 percent compression of the foamed materials employed in the earplug construction of the invention confers to the user the ability to initially compressor otherwise deform the earplug and provide sufficient time for insertion thereof into the ear canal. Subsequent, to said insertion, the compressed or deformed earplug slowly recovers and attempts to regain its original shape. By so doing, the recovering polymeric material conforms to the structure of the ear canal and establishes substantially complete obturation thereof. In a preferred embodiment of the invention, the recovery rate of the foamed polymer composition will be between 2 and about seconds.

The manner in which the recovery rate of the foamed polymer composition is determined for the purposes of the present invention is as follows:

Plugs of the polymeric foam composition are cut with a hollow tube borer, the dimensions of the plugs being about 0630-0640 inch in diameter and having a length of between 0.495 and 0.615 inch. A parallel plate gauge is employed having a spacing of 0.375 inch between the opposing plate surfaces. Said 0.375 inch spacing between plates thus corresponds to about 40 percent compression of the original plug diameter. A plug specimen is twirled lengthwise between the fingers for 15 to 30 seconds with an ultimate compression of the plug to about 0.25 inch in diameter, corresponding to about 60 percent reduction in the original diameter thereof. The plug is then inserted lengthwise and released between the parallel plates, the time from said release to contact of percent of the linear surface of the plug with both plates being determined by stopwatch measurement. In order to maximize the relative precision of the test, a number of test specimens taken from the same sample foam are employed and the results averaged.

The 40 percent compression equilibrium pressure testing of the polymeric foam is accomplished employing the test plugs produced and employed in the above recovery rate testing procedure. In pressure testing, however, there is employed an Instron Universal Testing Instrument, Model TTC, having a parallel plate specimen holder in which the parallel plates are spaced 0.375 inch apart. The lnstron is further equipped with a 1 pound load cell. Test plugs of the foamed polymeric composition are finger twirled in the manner described previously for a 30 second period and are placed lengthwise between the plates of the parallel sepcimen holder. When the load cell reading attains a 40 to g total measured pressure no. of specimens X4 40 compression The pressure criteria established hereinbefore for the foamed polymeric compositions employed in the fabrication of the earplugs of the invention is also important in that the achievement of such pressure characteristics insures that the completed earplug will bear in obturating relationship against the ear canal but with insufficient pressure as to cause discomfort to the wearer. in a preferred embodiment, the foamed polymeric compositions employed in the fabrication of the earplugs of the invention will have a 40 percent compression equilibrium pressure of between 0.35 and 1.0 p.s.i.

Taken together, the pressure and recovery rate criteria of the foamed polymeric compositions also define a compositionhaving the further characteristic of relative deadness. Thus, while form stable in the sense that the earplug, when deformed, will tend to recover its original shape and size, the slow rate of recovery thereof and the very small overall pressure exerted by the plug surfaces on the constraining ear canal further insure the fact that little sound will be transmitted through the material and into the bony structure of the canal. This, too, is highly advantageous since substantial undesirable sound transmission by way of bone conduction through the mastoid process can occur with solid earplugs.

There follow a number of non-limiting illustrative Examples:

l LE MPE E- A vinyl chloride plastis ol formulation was compounded employing the following ingredients:

Admex 523, an aromatic polyester plasticlzer produced by Archer-Daniels-Midland Co., Minneapolis, Minnesota -Continued hc,24 Parts by Weight Estynox 203, an epoxidized soya bean oil 5 stabilizer/plasticizer produced by The Baker Castor Oil Co., Bayonne, New Jersey Kempore 200, an azodicarbonamide foaming agent 8 produced by National Polyehemicals, lnc, Wilmington, Massachusetts Antimony Trioxide flame retardant 8 Advastab T-l50, organometallic stabilizer produced I 2 by Advance Division, Carlisle Chemical Works, Inc.,

New Brunswick, New Jersey l-loudry FS-l00, a polymeric surfactant produced by 2 Air Products and Chemicals, Inc., Philadelphia, Pennsylvania Vanstay 80l4, stabilizer produced by R. T. 3

Vanderbilt Co., Inc., New York, New York The resulting plastisol was cast on release paper and doctor bladed to a thickness of about 77 mils. The cast plastisol was continuously-conducted through an oven heated to a nominal temperature of about 420 F at a nominal residence time of about 5 minutes. The resulting foamed sheet composition had a density of about 7 lbs/ft, a rate of recovery from 60 percent compression to 40 percent compression of about 4 seconds and a 40 percent compression equilibrium pressure of about- 0.78 p.-s.i. Whenexamined under 75x magnification, the foamed polymer appeared to be of predominantly closed-celled structure.

When out into cylindrical plugs of about inch diameter by about 56 inch length,.the resulting structures Continued Parts by Weight Houdry FS-lOO 2 Vanstay 80M j 3 The resulting plastisol composition was cast on release paper and doctor bladed to a thickness of. about 114 mils. The cast sheet was then-[continuously fed through an oven as in Example 1. The resulting foamed polyvinylchloride sheet had a density of about 13 lbs/ft, a

rate of recovery from 60 percent compression to 40 percent compression of about 1 second and a 40 percent compression equilibrium pressure of about 1.32.

When cut into cylindrical structures of about inch diameter and inch length, the resulting wares were l.....a a trtaa; Two polyvinylchloride formulations havingsubstantially similar ingredients as employed in Examples 1 could be finger compressed and inserted into the ear canals without difficulty. The compressed plugs thereafter recovered to substantially completely and comfortably obturate the ear canals and were found to be highly effective in attenuating the transmission of 4 15-15 ,000 Hz/sec frequencies therethrough.

Referring now to FIG. 2, several of the earplugs are coaxially bored throughout their lengths with a central corer having a diameter of abouti inch. The resulting structures are then employed as a covering 3 over tubular tip portion 5 of a lightweight headphone set (partially shown). Again, it is found that the foamed polymeric structures are compressible to below the dimensions of the ear canal and can be comfortably inserted therein with subsequent slow recovery thereof to substantially completely fill the cross-section of the ear caml. The headphone set is adjudged to be superior in wearer comfort and is highly effective in selectively conducting sound only through the tubular sound conductor 7 thereof.

EXAMPLE 2 A foamable polyvinylchloride plastisol composition was formulated employing the following ingredients:

Advastab T-l50 and 2 but different relative concentrations were produced. Upon testing, one of the resulting polyvinylchloride foams had a density of about 4 lbslft a recovery rate from percent compression to 40 percentcompression of about 106 seconds and an exerted equilibrium pressure at 40 percent compression of about 0.19 p.s.i. Earplugs formed of thismaterial were'found to be deficientin that the recovery rate was excessively slow and the exerted pressure upon the ear canal was slightly below that required to completely obturate the ear canal with the foamed polymeric shape. .The other foamed polyvinylchloride sheet composition was found to have an apparent density of about 6 lbs/ft'f, a recovery rate (60 to 40 percent compression) of about 1-3 seconds and an exerted equilibrium pressure at 40 per-' cent compression of about 0.37 p.s.i. Cylindricalv (ineluding truncated cone shapes) earplugs formed of this material were found to beof excellent quality in terms of facile insertion, wearer comfort and sound attenua-' tion properties.

While there are above described a number of specific embodiments of the present invention, it is obviously possible to produce other embodiments and various equivalent modifications thereof without departing from the spirit of the invention.

Having set forth the general'nature and several preferred embodiments of the present invention, the true scope thereof is now particularly pointed out in the appended claims.

What is claimed is:

1. An earplug of generally cylindrical shape having a diameter of between and inch, a-length tobet'ween 1e and 1 inch andcomposed of a resilient plasticised polymeric foam having a sufficiently high concentration of organic plasticizer therein as to provide said foam with a rate of recovery of 60 percent compression thereof to 40 percent compression of from 1 to 60 seconds and an equilibrium pressure of 40 percent compression thereof of from 0.2-to 1.3 p.s.i.

2. The earplug of claim 1 wherein said polymeric foam has a-rate of recovery of from 2 to 20 seconds.

3. The earplug of claim 1 wherein said polymeric foam has an equilibrium pressure at 40 percent compression of between'0.35 and 1.0 p.s.i.

4. The earplug of claim 1 wherein the polymeric constituent of said foam is a polymer of vinyl chloride.

5. The earplug of claim 1 wherein the polymeric constituent of said foam is a homopolymer' of vinyl chloride.

6. The earplug of claim 1 having a diameter of be-

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Referenced by
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US4461290 *Nov 29, 1982Jul 24, 1984Cabot CorporationHearing protectors
US4579112 *May 17, 1984Apr 1, 1986Scott Robert TFoam earplug
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US6408981Sep 27, 2000Jun 25, 2002Saint-Gobain Performance Plastics CorporationExtruded monolithic foam earplug
US6484726Jun 30, 2000Nov 26, 20023M Innovative Properties CompanyArticulating earplug
US7078443Oct 22, 2003Jul 18, 2006Intellectual Property Holdings, LlcCombining a diisocyanate or allophenates wtih a polyether polyol containing propylene oxide extended-monoethanolamine based polyether polyol, propylene oxide extended- triethanolaminetriol based polyether and propylene oxide extended-diethanolamine based polyol, a polyether, to form semi-rigid foam
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Classifications
U.S. Classification128/864, 181/256, 521/73
International ClassificationA61F11/08, A61F11/10, H04R1/10
Cooperative ClassificationA61F11/08, A61F11/10
European ClassificationA61F11/10, A61F11/08